Corrosion properties of plastically deformed AZ80 magnesium alloy

AZ80 magnesium alloys were deformed at 200,250,300,350 and 400℃ with different deformation degree of 50%,75%, 83%,87%and 90%,respectively.The corrosion properties of different deformed AZ80 samples were studied by galvanic test in 3.5%NaCl solution.The results show that plastic deformation could improve the corrosion resistance of AZ80 alloy;and the corrosion rate of AZ80 deformed at 250℃ with the deformation degree of 83%was the lowest,which was 33%of the as-cast AZ80 alloy.Further studies of the microstructure show that the refined grain size and continuously distribution ofβphase around the grain boundary did have a positive effect on the improvement of corrosion resistance of AZ80 alloys.For AZ80 alloys,the smaller the grain size is,the more homogeneous the structure is,and the better the corrosion resistance is.     

锻压态AZ61镁合金的变形行为

对模压态AZ61镁合金在室温～150℃条件下的的力学性能及变形机制进行研究.结果表明:在拉伸速度1 mm/min,随着拉伸温度的升高,拉伸后的显微组织中晶界逐渐软化,动态再结晶有减少趋势,并伴随有孪晶出现,抗拉强度及屈服强度显著下降,而其伸长率在低温拉伸中的变化幅度有限;同时在90 ～ 130℃发生了动态应变时效;对拉伸断口的观察分析表明,随着温度的逐渐升高(≤150℃),其断裂机制由韧脆混合断裂逐渐变为韧性断裂.     

固相再生AZ31B镁合金的组织与力学性能

在不同的挤压温度和挤压比下,将AZ31B镁合金机加屑冷压后热挤压固结而再生镁合金。与铸锭挤压合金对比,从动态再结晶组织与屑间结合情况两个主要方面分析了加工工艺对再生合金力学性能的影响。随着挤压温度升高,再生合金的极限抗拉强度和延伸率先增加而后降低。随挤压温度升高,晶粒长大与屑间结合增强的相反作用共同导致了再生合金力学性能的变化。当挤压比从4:1 增加到 44:1,晶粒细化且屑间结合增强,使再生合金的抗拉强度增加。而当挤压比高于25:1时,由于显著的形变强化作用导致延伸率下降。     

Microstructure development and thixoextrusion of magnesium alloy prepared by repetitive upsetting-extrusion

Thixoextrusion involves processing alloys with a spheroidal microstructure in the semi-solid state. Before thixoextrusion, repetitive upsetting-extrusion (RUE) is introduced into the strain induced metal activation (SIMA) process to predeform AZ80 magnesium alloy. Microstructure evolution of RUE formed AZ80 magnesium alloy during partial remelting is studied at temperatures for times. Tensile mechanical properties of thixoextruded components are determined and compared with those of AZ80 magnesium alloy thixoextruded from starting material produced by casting. The results show that with increasing number of RUE passes solid grain size decreases and the rate of liquation is improved. Prolonged holding time results in grain coarsening and the improvement of degree of spheroidization. The variation of the solid grains with holding time obeys the Lifshitz, Slyozov and Wagner law. Increasing the heating temperature is favorable for the formation of spheroidal solid grains. The tensile properties for AZ80 magnesium alloy thixoextruded from starting material produced by RUE are better than those of AZ80 magnesium alloy thixoextruded from starting material produced by casting.     

温变形对AZ31镁合金组织的影响

为了有效细化镁合金的晶粒 ,以提高其力学性能 ,通过对铸态AZ31进行等温压缩实验 ,并采用现代微观分析手段 ,研究变形参数对AZ31镁合金组织的影响。结果表明 :2 10℃变形可以显著地细化铸造AZ31合金的晶粒 ,其尺寸可由铸态的约 10 0 μm减少到 5 μm左右 ;同时证明温变形能明显提高镁合金的抗拉强度。     

累积叠轧温度对AZ31镁合金组织和性能的影响

通过光学显微镜、室温拉伸试验、显微硬度计、X射线衍射仪、扫描电镜等方法研究了累积叠轧温度对AZ31镁合金晶粒尺寸、基面织构、界面结合情况及力学性能的影响。结果表明:3道次累积叠轧后的AZ31镁合金晶粒细化效果明显,硬度增大,随着累积叠轧温度的升高,晶粒细化效果减弱,硬度增加趋势减弱。累积叠轧温度升高有弱化基面织构的作用。AZ31镁合板材在450 ℃累积叠轧3道次,综合力学性能最佳,为显微硬度70.64 HV0.05,抗拉强度288.64 MPa,屈服强度203.76 MPa,伸长率16.96%,界面结合强度21.53 MPa。     

挤压速度和电磁铸造锭坯对AZ31镁合金板材组织和性能影响

文章研究挤压条件下挤压速度和电磁铸造锭坯对挤压态AZ31镁合金板材组织和性能的影响。研究结果发现,挤压速度比较低时,板材晶粒尺寸小,板材的表面质量比较好;随着挤压速度的降低,抗拉强度、屈服强度和延伸率都有一定的提高。由于镁合金是HCP的晶体结构,同时对挤压速度非常敏感,对变形均匀性影响比较大,因此造成挤压板材的内外晶粒大小不均。在电磁场的作用下,溶质在晶内的固溶度增大,同时晶粒大小也比常规铸造的细小,因此电磁铸造的锭坯经挤压机挤压后,挤压板材的晶粒尺寸比较细小,且强度和塑性都有所提高。     

Al-Ti、Al-Ti-C中间合金对AZ91D镁合金组织和性能的影响

研究了Al-5Ti、Al-5Ti-0．25C和Al-8Ti-2C中间合金对AZ91D镁合金的组织、力学性能和耐腐蚀性能的影响。结果表明,添加Al-5Ti中间合金使晶粒粗化,而添加Al-5Ti-0．25C和Al-8Ti-2C中间合金使晶粒细化,Al-8Ti-2C中间舍金的细化效果明显且细化后组织细小均匀;添加Al-5Ti中间合金使合金的力学性能降低,而添加Al-5Ti-0．25C和Al-8Ti-2C中间合金均使合金的拉伸强度和伸长率得到了提高;添加Al-5Ti、Al-5Ti-0．25C和Al-8Ti-2C中间合金均使合金的耐腐蚀性能得到了改善。对于AZ91D合金而言,Al-8Ti-2C中间合金是一种良好的晶粒细化剂。     

AZ91D镁合金屑的固相再生(英文)

利用固相再生技术回收利用AZ91D镁合金屑,具体工艺为先冷压再热挤。结果表明:制备的AZ91D镁合金具有较好的力学性能且晶粒明显细化。在热挤出过程中发生了动态再结晶,且动态再结晶组织受到热挤温度和应变速率的影响,在300-350 °C下基面滑移和孪晶协调变形导致动态再结晶晶粒产生,形成"项链"组织;在 350-400 °C下位错的交滑移控制动态再结晶形核;高于400 °C时位错攀移控制了整个动态再结晶过程,形成均匀的再结晶组织。随着应变速率增加AZ91D镁合金力学性能增大,改善了材料的力学性能,但应变速率过大,制备试样表面出现裂纹,影响材料的力学性能。     

AZ31镁合金挤压棒退火组织和织构的演变

试验研究了退火温度对AZ31镁合金挤压棒组织和织构的影响.结果表明:铸态镁合金挤压后,初始强点织构向(80°,90°,0°)面聚集,主要织构组分强度提高.对热挤压后的AZ31镁合金进行退火,可以细化晶粒,使组织均匀,300℃退火时平均晶粒尺寸5μm为最小;随着退火温度的升高,形变织构(80°,90°,0°)逐渐减弱,再结晶织构(0°,90°,0°)和(90°,55°,0°)逐渐增强,300℃退火之后二者均被弱化,400℃退火之后取向分布漫散度增大.     

挤压比对热挤压AZ80镁合金管材组织和性能的影响

选用不同的挤压比对变形镁合金AZ80进行管材热挤压工艺试验研究,对挤压前后材料组织与力学性能的变化进行分析。结果表明,热挤压可以显著细化AZ80镁合金的晶粒,而且随着挤压比的增加,晶粒变得更加细小;增大挤压比也可以提高AZ80镁合金的抗拉强度和屈服强度。结果表明,挤压比为18.2,坯料温度为390℃,模具预热温度为360℃,凹模的半模角为60°～70°,可得到均匀的合金组织和良好的力学性能。     

Relationship between mechanical properties and grain size of AZ80 at 350℃ under different strain rates

The dynamic recrystallization refinement of magnesium alloy AZ80 by compression tests was studied,and its effect on the mechanical properties was investigated.It is observed that the microstructure of the as-cast billet with grain size of 240μm becomes refined to about 120,110,94 and 50μm after upsetting at 350℃ under strain rates of 0.01,0.1,1 and 10 s -1 respectively.The changes in the mechanical properties according to grain size show that yield strength significantly decreases with grain size increasing,while strain hardening exponent and micro hardness increase very sharply.Further,the grain size vs strain rate and change in Vickers micro hardness according to the various strain rates show that grain size and micro hardness decrease with strain rate increasing.     

Solid-state recycling of AZ91D magnesium alloy chips

A method for recycling AZ91D magnesium alloy chips by solid-state recycling was studied. The experiments were carried out adopting the cold-press pressure and hot extrusion. The results indicate that recycled specimens of AZ91D magnesium alloy present better mechanical properties and consist of fine grains due to dynamic recrystallization. The mechanisms of dynamic recrystallization depend on plastic deformation process and change with the deformation temperature. At 300-350 °C, the deformation mechanisms are associated with the operation of basal slip and twinning, and the “necklace” structures are formed. At 350-400 °C, the cross slip results in the formation of new grains and grain refinement. At above 400 °C, the dynamic recrystallization mechanisms are controlled by dislocation climb, and recrystallized grains are homogeneous. The tensile strength of recycled specimens increases with the increase of the strain rate. When the strain rate is overhigh, the cracks and fractures in the surface appear and affect the tensile strength of recycled specimens.     

Corrosion and mechanical properties of hot-extruded AZ31 magnesium alloys

AZ31 magnesium alloys were hot-extruded at 573 K and 623 K with extrusion ratio(λ) of 20,35 and 50.The corrosion and mechanical behavior of hot-extruded AZ31 were studied by galvanic tests and tensile tests.The microstructures of the studied AZ31 alloys were also investigated with optical microscope.The results show that,compared with the as-cast AZ31 alloy,the corrosion potentials of all hot-extruded AZ31 alloys are increased by 60 mV.Moreover,at the extrusion temperature of 623 K,the galvanic current o...     

热机械加工对EW75镁合金组织与性能的影响

采用金相显微镜、扫描电镜和拉伸试验机等手段,研究了恒温多向锻造工艺对EW75镁合金显微组织和力学性能的影响,并分析了动态再结晶机制。结果表明,500和470℃锻造态EW75镁合金薄板都发生了动态再结晶,而440和410℃锻造态EW75镁合金薄板中可见大量细小颗粒状析出相,未见明显动态再结晶组织,且在平行于锻压方向上,可见原始晶粒形貌以及颗粒状析出相,而在垂直于锻压方向上,可见明显加工变形流线。470℃锻造态EW75镁合金薄板发生了完全动态再结晶,平均晶粒尺寸约为15μm,且合金中动态再结晶晶粒大部分为大角度晶界。经过锻造处理后的EW75镁合金薄板的强塑性相较于固溶态均有明显提升,随着锻造温度的降低,EW75镁合金薄板的抗拉强度和规定塑性延伸强度都呈现逐渐上升的趋势,而断后伸长率则表现为先增加后减小的特征。在470℃锻造时,EW75镁合金薄板具有最好的塑性,这主要与完全再结晶协调塑性变形以及较大的晶粒间取向差有助于晶面滑移有关。     

Nd添加对AZ80镁合金显微组织及力学性能的影响(英文)

研究添加稀土元素Nd对AZ80镁合金显微组织及力学性能的影响。结果表明:添加1.0%Nd元素可以有效地改善AZ80合金的铸态组织,其晶粒尺寸由448μm细化至125μm,凝固组织中出现条状的Al11Nd3相和块状的Al2Nd相,且β-Mg17Al12相显著细化,由连续网状变为不连续分布。时效过程中Nd元素的添加抑制了晶界处不连续析出相的出现,并推迟合金时效峰值的出现。在AZ80合金中添加1.0%Nd时,合金的综合力学性能最佳,屈服强度、抗拉强度和伸长率分别为103.7MPa、224.0MPa和8.4%。该合金T6态的屈服强度和抗拉强度分别达到141.1和231.1MPa。     

MICROSTRUCTURE AND MECHANICAL PROPERTIES OF AZ91D EXTRUDED TUBE

The effect of extrusion ratio on microstruetures and mechanical properties of magnesium alloy AZ91D extruded tube at 430℃ has been studied. After the evolution of microstracture and mechanical properties of AZ91D during extrusion were studied, the following parameters were obtained： tensile strength reached the climax value of 306.9MPa and elongation peak value of 10.1% at an extrusion ratio of 7.125, and with the increase of the extrusion ratio to 7.45, yield strength reached a top value of 285.795MPa with decreased tensile strength and elongation. It was concluded that mechanical properties of magnesium alloys AZ91D could be enhanced by adjusting the extrusion ratio near recrystallization.     

时效态Mg-Gd-Y-Zr镁合金压缩性能和组织演变

采用Gleeble-3500热模拟机对时效态Mg-10Gd-3Y-0.5zr (GW103)和Mg-12Gd-3Y-0.5Zr(GW123)稀土镁合金在变形温度为25～350℃、应变速率为0.01 s~(-1)、最大变形程度为1的条件下进行压缩模拟试验,利用金相显微镜和扫描电镜观察组织变化.结果表明:GW103和GW123合金的室温抗压强度分别为419MPa和460MPa;150-200℃时GW123合金的抗压强度大干GW103合金;当温度高于250℃时,两种合金的抗压强度相近.分析表明250℃以下压缩时,孪生变形是影响压缩力学性能的主要因素;300～350℃压缩时,晶界和变形带处发生动态再结晶是影响压缩力学性能的主要因素.     

变形条件对AZ61镁合金力学行为的影响

用热模拟实验机对AZ61镁合金在变形温度为150℃～400℃,应变速率为0.01s-1～10s-1的条件下进行压缩变形,研究不同变形条件下AZ61镁合金的力学响应。结果表明,AZ61镁合金压缩变形时表现出动态再结晶特征,随温度上升,再结晶容易发生且应力峰降低;随变形速率增加,发生再结晶转变的临界应变增大。相比之下,变形温度对AZ61合金力学行为的影响要大于应变速率的影响。     

异步轧制AZ31镁合金板材在退火处理中的组织性能演变

研究了异步轧制AZ31镁合金板材经200～350 ℃退火30～120 min后的组织性能演化.在试验条件下,AZ31镁合金板材在200 ℃退火时,随保温时间的延长,组织的均匀程度和晶粒尺寸没有明显变化;在300 ℃退火30 min,基本完成再结晶过程,获得均匀细小的等轴晶,保温时间增加到60 min时,部分再结晶晶粒长大;在350 ℃退火30 min和60 min,均在完成再结晶的同时晶粒长大;300 ℃退火30 min后AZ31镁合金板材的综合性能较好,室温抗拉强度为315 MPa,伸长率为33.0%.