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小型金属陶瓷惰性阳极的低温铝电解实验 总被引:2,自引:1,他引:1
本实验采用自行研制的小型镍铁尖晶石基惰性阳极 (直径 43mm)与冰晶石 -氧化铝系低温电解质 ,在 85 0℃下进行电解实验 ,保持阳极电流密度lA/cm2 ,实验共进行 11小时 ,得到了少量的金属铝。实验结果表明 ,在此电解温度下 ,构成惰性阳极的金属陶瓷材料抗电解质腐蚀的能力较强 ;阳极在实验后出现的裂纹说明材料的抗热震性有待进一步提高 ,而且本实验中惰性阳极与金属导杆的连接方式也需更深入研究。 相似文献
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铝电解惰性阳极研究现状 总被引:12,自引:3,他引:9
惰性阳极是铝工业新技术的一个重要课题,本文对近年来铝电解阳极材料多已集中在金属、金属陶瓷、氧化物陶瓷和氧化铈涂层几个方面的现状及研究进展分别加以介绍。指出铝电解惰性阳极的研制一开始就遇到的问题,如氧化,腐蚀,产出铝受惰性阳极材料的污染,阳极寿命,导电性和成本问题仍未完全解决。 相似文献
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本文研究了两种惰性阴极材料,即TiB_2/Tic/C复合材料TiB_2/C涂层材料,在铝电角质较低熔点电解质中的电流效率,测量了不同阴极材料的过电压;此外,还考察了铝液对这两种阴极材料的化学侵蚀。 相似文献
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文中报道了中温铝电解质的研制结果。采用酸性冰晶石 氟化铝 氧化钙 氟化镁 氟化钡体系。在实验室的35A电解槽上;采用碳阳极以及碳阴极和惰性TiB_2阴极,进行电解,电解温度为920±5℃。 相似文献
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Argon is the process gas of choice for most magnetron sputtering applications due to its large atomic mass, inert chemistry, and relatively low cost. Other inert gases are available for use in sputtering deposition that have varying mass and hence different momentum behaviour during ion bombardment of solid surfaces — affecting sputter yield, particle implantation and incorporation of process gas into deposited films. The plasma discharges generated from these gases vary in terms of the nature and energy of species incident at both target and substrate. In particular, the contribution from energetic neutrals varies as a consequence of the atomic mass of the process gas in comparison to the target material to be sputtered.Magnetron plasma discharges were generated from neon, argon, krypton and xenon gases in DC and mid-frequency pulsed-DC modes with both silver and molybdenum cathodes. The electrical characteristics, such as potential and current at the target and substrate were measured and compared. Thin metallic films were then deposited and analysed in terms of structure; mechanical, optical and electrical properties; and process gas incorporation. The data generated is used to establish the relationship between process gas species, plasma discharge characteristics of those gases, and the subsequent growth and properties of deposited coatings. 相似文献
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陈冰 《特种铸造及有色合金》2005,25(8):476-478
惰性气体保护熔炼的基本原理是将低温液态惰性气体滴在熔池表面或直接将惰性气体覆盖在熔池上方,驱赶熔池上方的空气,降低熔池上方气体中的氧含量,从而避免合金液氧化和吸气。使用该技术后,熔炼过程无须熔剂覆盖和脱氧,不仅非金属夹杂物、气体夹渣等铸造缺陷大为减少,而且由于合金液纯净度提高,流动性也有所改善,浇不足、冷隔等缺陷随之减少: 相似文献
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A binary Cu-Al alloy (9.4 wt.% Al) has been investigated as a potential inert anode for aluminium electrowinning. Anodes have been tested in a laboratory electrolysis cell both with and without preformed oxides. Electrolysis was conducted in cryolitic electrolytes with anode current densities of 0.5 A cm−2. The anodes operated satisfactorily as measured by electrical parameters. However, substantial corrosion of the Cu-metal substrate was observed. The external oxide generated on pre-treated anodes was porous and allowed the electrolyte to penetrate through to the Cu-metal whereby corrosion was initiated. An untreated anode formed an in situ surface alumina film, but this did not prevent corrosion of the substrate. 相似文献
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(Cu-Ni)/(10NiO-9ONiFe2O4 ) cermet inert anodes containing metal Cu-Ni 0,5, 10, 15 and 20 wt pet were prepared and their corrosion resistance to Na3AlF6-Al2O3 melts was investigated. The results indicate that the content of metal Cu-Ni has little effect on the steady-state concentration of Ni in the electrolyte and the values could not be used to effectively differentiate their corrosion resistance. The steady-state concentration of Fe decreases from 304×10-8 to 168×10-6 and that of Cu increases from 21×10-6 to 71×10-6 with the content of metal Cu-Ni increasing from 0 to 20 wt pct. Post-examination shows that metallic phase Cu-Ni is corroded preferentially during electrolysis and many pores are left at the anode surface. Considering the corrosion resistance and electrical conductivity, the cermet containing metal Cu-Ni 5 wt pct should be selected and studied further. 相似文献
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Z.L. Tian Y.Q. Lai J. Li Y.X. Liu 《金属学报(英文版)》2008,21(1):72-78
(Cu-Ni)/(10NiO-90NiFe204) cermet inert anodes containing metal Cu-Ni0, 5, 10, 15 and 20 wt pct were prepared and their corrosion resistance to Na3AlF6-Al2O3 melts was investigated. The results indicate that the content of metal Cu-Ni has little effect on the steady-state concentration of Ni in the electrolyte and the values could not be used to effectively differentiate their corrosion resistance. The steady-state concentration of Fe decreases from 304×10^-6 to 168×10^-6 and that of Cu increases from 21×10^-6 to 71×10^-6 with the content of metal Cu-Ni increasing from 0 to 20 wt pct. Post-examination shows that metallic phase Cu-Ni is corroded preferentially during electrolysis and many pores are left at the anode surface. Considering the corrosion resistance and electrical conductivity, the cermet containing metal Cu-Ni 5 wt pct should be selected and studied further. 相似文献
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对于铝电解惰性阳极的选材与研究方向的思考 总被引:4,自引:0,他引:4
本文简要介绍了国际上铝电解惰性阳极方面较有影响的研究工作,以及国内在此领域的研究状况。对惰性阳极材料的选择问题进行较深入的探讨,分析了陶瓷、金属和金属陶瓷材料在隋性阳极研究应用中所出现的问题,并对惰性阳极未来的研究发展方向提出了一些建议。 相似文献
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ZhongLiang Tian YanQing Lai ZhiYou Li DengPeng Chai Jie Li YeXiang Liu 《JOM Journal of the Minerals, Metals and Materials Society》2014,66(11):2229-2234
The new aluminum electrolysis technology based on inert electrodes has received much interest for several decades because of the environment and energy advantages. The key to realize this technique is the inert anode. This article presents China’s recent developments of NiFe2O4-based cermet inert anodes, which include the optimization of material performance, the joint between the cermet inert anode and metallic bar, as well as the results of 20 kA pilot testing for a large-size inert anode group. The problems NiFe2O4-based cermet inert anodes face are also discussed. 相似文献
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1 INTRODUCTIONAluminumhasthelargest productivityamongthenonferrousmetals ,2 4Mtperyearintheworld .Whilegreatprogresshavebeenmadeintheprimaryaluminum production ,theindustrycontinuestopur sueresearchtosolvesomeformidablechallenges ,suchas quitealargeenergyintensity(14 0 0 0 15 0 0 0kW·hpertonaluminum) ,highcon sumptionofcarbonanode(5 0 0 6 0 0kgpertonalu minum) ,significantemissionsofgreenhousegas(1.71tpertonaluminum )andotherdetrimentalgases ,highcapitalinvestmentandcost[1] .Inertelectr… 相似文献