交流磁场对亚共晶Al-Fe合金组织的影响

研究了不同冷速下交流磁场对亚共晶Al-0．90％Fe合金凝固组织的影响，试验结果表明，在交流磁场作用下，共晶组织中的Al3Fe相均向样品的中心处富集，且随着冷速降低这种趋势增大。并对交流磁场的作用机制做了探讨。     

交流磁场对过共晶Al-Fe合金初生相的影响

利用XRD和OM研究了交流磁场对过共晶Al-2.55%Fe合金初生相的影响。结果表明:交流磁场不会改变过共晶Al-2.55%Fe合金初生相的类型,有无交流磁场作用下,初生相均为Al3Fe相,但交流磁场能显著改变初生Al3Fe相的分布和形貌。无磁场条件下,初生Al3Fe相在重力的作用下均匀分布在样品的底部,呈细小颗粒状。而在交流磁场的作用下,除了少部分细小颗粒状的初生Al3Fe相在样品底部呈金字塔状分布外,大部分初生Al3Fe相出现在样品的顶端边沿处,沿径向呈三角形分布。同时,顶部初生Al3Fe的相形貌由原来的细小颗粒状变为大的块状和棒状。随着磁感应强度的增大,交流磁场对初生Al3Fe相分布和形貌的影响增大,顶部初生Al3Fe相的含量增多。交流磁场对过共晶Al-2.55%Fe合金初生相分布和形貌的影响,主要是由交流磁场产生的Lorentz力和磁力共同作用的结果。     

Variety of solidification structures in Al-2.89%Fe alloy solidified under high magnetic field

考察了冷却速率、磁场强度及高梯度磁场对Al-2.89%Fe(质量分数)过共晶合金中Al3Fe 相形貌及分布规律的影响. 结果表明, 在无磁场条件下, 初生Al3Fe相沉积在试样下部; 施加12 T强磁场后, 初生Al3Fe相所受磁力作用和重力作用相平衡, 在整个试样中均匀分布, 且沿着易磁化方向[121]发生定向排列, 其取向程度不受冷却速率的影响, 但随着磁场强度的增大而加强; 在高梯度磁场中, 初生Al3Fe相所受磁力作用大于重力作用而偏聚在试样的上部, 且多个针状初生Al3Fe相结合在一起, 形成近似星状聚合体. 此外, 对强磁场的作用机理进行了分析和探讨.     

强磁场对Al-2．89％Fe合金凝固组织的影响

考察了冷却速率、磁场强度及高梯度磁场对A1-2.89?(质量分数)过共晶合金中Al3Fe相形貌及分布规律的影响.结果表明,在无磁场条件下,初生Al3Fe相沉积在试样下部;施加12T强磁场后,初生Al3Fe相所受磁力作用和重力作用相平衡,在整个试样中均匀分布,且沿着易磁化方向[121]发生定向排列,其取向程度不受冷却速率的影响,但随着磁场强度的增大而加强;在高梯度磁场中,初生A13Fe相所受磁力作用大于重力作用而偏聚在试样的上部,且多个针状初生Al3Fe相结合在一起,形成近似星状聚合体.此外,对强磁场的作用机理进行了分析和探讨.     

Fe对NiAl金属间化合物光束堆焊层成形及组织结构的影响

采用X射线衍射、SEM、EDS等分析方法，研究了铁元素对光束堆焊合成NiAl金属间化合物层的成形和组织结构的影响规律。结果表明，光束堆焊镍铝混合粉制备NiAl金属间化合物层时，NiAl的高熔点导致堆焊层成形困难。在镍铝混合粉中加入适量铁粉（11at％～28at％）可以降低堆焊合金体系的熔点、改善堆焊层成形。随着铁粉加入量的增加，堆焊层的稀释率呈现先增加后降低的趋势，过多的铁粉加入量（43at％）将使熔池金属不能润湿母材。铁元素的引入使堆焊层中析出了Fe3Al相，随着堆焊层中含Fe量的增加，Fe3Al的析出量增加，堆焊层的微观组织为NiAl柱状晶和柱状晶间的Fe3Al条状相。     

旋转交变磁场和静磁场对Al-18%Si合金变质处理的影响

分别研究了旋转磁场和静磁场对过共晶Al-18％Si合金变质处理的影响。结果表明：变质处理后．不施加磁场的条件下，块状初晶Si偏聚在试样边缘处，试样中心处为共晶Si；施加旋转交变磁场的条件下，粗大的板条状初晶Si偏聚在试样边缘处，试样中心处为共晶Si；施加静磁场的条件下，在试样整个横断面上初晶Si都是细小的块状，且大小和分布均匀。     

1235铝合金在加工过程中析出相组织的演变

利用透射电镜对1235铝合金在加工过程中析出相显微组织进行观察。结果表明,1235铝合金在铸轧中液态铝经急冷形成了大小为10~30 nm的纳米晶区域,有的纳米晶区域被拉伸,铝有多种取向分布,并且有明显的滑移带,没有检测到Al与Fe、Si等晶粒细化剂形成的析出相,这说明它们极可能是以固溶体形式存在。在轧制过程中有Al3Fe Si相析出,析出相沿轧制方向被拉伸,分别呈线状、散点状或棒状分布。经630℃7h的均匀化退火后形成的析出相是Al4Si,经380℃7h中间退火后形成的析出相是(Al,Fe,Si),这些析出相都团聚成球状。     

强磁场处理固态铝基复合材料的组织和性能

在不同磁感应强度下对固态Al_2O_3增强7055铝基复合材料进行了脉冲磁场处理。经脉冲磁场处理后,铝基复合材料的位错密度随磁感应强度的增加呈上升趋势,分析原因在于位错应变能增加和位错钉扎中心自由基对状态的改变。随着磁感应强度的提高,晶内析出相的取向性减小,数量和尺寸增加;晶界析出相由连续状态转变为断开状态,析出相数量减少、尺寸增大,并出现了明显的无沉淀析出带。这些现象主要源于磁场作用增强了晶体内部溶质原子和空位的扩散;畸变能增加、内应力的释放为析出相析出、长大提供了驱动力。力学性能随磁感应强度的增加,呈现出先升高、后降低的趋势。在B=3 T时,抗拉强度、延伸率和显微硬度达到了548.04 MPa、17.235%和1224 MPa,较处理前试样分别提高了10.3%、16.2%和20.7%。力学性能的改善主要源于位错密度增加造成的位错强化和第二相强化。     

硅对45钢热浸镀铝层真空扩散处理显微组织的影响

利用扫描电镜和能谱分析手段研究了铝池中的硅对热浸镀铝层在真空高温扩散处理过程中的显微组织演变的影响。确定了扩散层的组成相,研究了镀层的生长动力学,讨论了扩散层空洞带的形成机理。研究表明,铝池中的硅能减少热浸镀铝层的厚度。在同样的扩散条件下硅的添加抑制了Fe2Al5的生长,促进了FeAl和富铝α-Fe层的生长。扩散处理时从含硅的Fe2Al5中容易析出τ1-（Al,Si）5Fe3相或FeAl相。硅的加入使得FeAl层和富铝α-Fe层间的空洞或晶间裂纹易于早期出现,但随着扩散时间的延长,又逐渐减小或消失。空洞的形成与消失与硅在FeAl层中的富聚有关。由于Fe2Al5相与其中析出的τ1-（Al,Si）5Fe3相发生包共晶反应,即：τ1＋Fe2Al5L＋FeAl,形成了不连续的外侧FeAl层。     

Al-22Si-3Fe-1.8Mn合金中的四元富铁相研究

利用X射线衍射仪、扫描电镜(带EDS)和金相显微镜对Al-22Si-3Fe-1.8Mn合金进行研究.结果表明:在铸态试样中存在晶体结构分别与Al8Fe2Si、Al9Fe2Si2和Al3FeSi2晶体结构相同的三种四元富铁相,并确定了其中两种相的化学式分别为Al12Si2Fe2Mn、AL42.5Si11Fe4.7Mn.通过萃取态试样确定了另一种富铁相的化学式为Al15.97Sil4.8.82Fe4.24Mn,并且该相为Al-22Si-3Fe-1.8Mn合金中最先析出的高温相.     

Morphology and distribution of Al3Fe phase in hypereutectic Al-Fe alloy solidified under magnetic field

In this study,the (low) DC and AC magnetic fields and the high magnetic field were applied separately during the solidification process of Al-2.89％Fe alloy.The influences of these magnetic fields on the morphology and distribution of Al3Fe phase in Al-2.89％Fe alloy were investigated.The microstructure and macrostructure of the samples were observed using an optical microscope.The results show that the majority of the primary Al3Fe phase particles in the hypereutectic Al-2.89％Fe alloy is gathered at the bottom of the sample under DC and AC magnetic fields or without magnetic field.The primary Al3Fe phase becomes coarse when the alloy solidifies under DC magnetic field,while it are refined and accumulated towards the center of the sample under the AC magnetic field.When the high magnetic field of 12 T is applied,the primary Al3Fe phase distributes throughout the sample homogeneously because the magnetic force acting on the primary Al3Fe phase balances with the gravity force; and the long axis of the Al3Fe phase aligns perpendicularly to the magnetic field direction.Also,the mechanism of the effect of magnetic fields is discussed.     

Effect of a direct magnetic field on the interfacial microstructure between molten aluminium and solid iron

Many processing techniques, such as hot dip aluminizing, bimetal formation, liquid metal corrosion, cementing, welding and diffusion bonding, are basically dependent on interfacial reactions [1-3]. It is therefore important to investigate the formation and growth of intermetallic layers at the interface. There have been several studies carried out to examine chemical compositions and growth kinetics of intermetallic layers in the Al-Fe system [4-9]. Most authors have come to an agreement that…     

强磁场对Bi-Mn和Al-Ni合金析出相形态的影响

采用逐层分析的方法研究了强磁场下MnBi和Al3Ni析出相的形态。发现Bi-6wt%Mn合金的铸态相中,MnBi析出相为薄片状,不呈树枝晶形貌。施加10 T磁场后,在平行磁场方向呈取向的棒状组织,在垂直磁场方向呈六方状。Al3Ni析出相在铸态组织中有初步聚合,施加10 T磁场后,沿磁场方向平行分布且层间距基本不变。     

Magnetically-triggered heating of Fe–Al powders

Powders of Fe and Al with a 3:2 atomic ratio were mechanically milled for either 1 or 2 h and subsequently subjected to an alternating magnetic field (AMF) to evaluate their heating. The microstructures of both the milled and heated powders were characterized using X-ray diffractometry, differential scanning calorimetry (DSC), scanning electron microscopy, and vibrating sample magnetometry. The results show that the milled powders consisted of fine intermixed Fe and Al layers. These were found to be susceptible to heating in an AMF, and underwent a significant heat output (21.3 kJ mol^?1) around 400 °C, corresponding to the reaction between the Fe and Al layers to form B2-structured FeAl. The temperature increase depended on the square of the field strength and the frequency of the AMF. By using a Kissinger analysis of the exothermic peaks obtained in a DSC at different heating rates, the activation energy for the formation of FeAl was found to be 67 ± 10 kJ mol^?1.     

STUDY OF AMORPHOUS Fe-Zr-B-(Cu) ALLOYS BY MECHANICAL ALLOYING

ＳＴＵＤＹＯＦＡＭＯＲＰＨＯＵＳＦｅ－Ｚｒ－Ｂ－（Ｃｕ）ＡＬＬＯＹＳＢＹＭＥＣＨＡＮＩＣＡＬＡＬＬＯＹＩＮＧ￥ＺＨＡＮＧＪｉａｎｑｉａｎｇ;ＷＵＢｉｎｇｙａｏＳｏｕｔｈｅａｓｔＵｎｉｖｅｒｓｉｔｙ,Ｎａｎｊｉｎｇ,ＣｈｉｎａＷＵＨｉａｏｈｕａ;ＷＡＮ...     

Al—Cu—Mg—Si系锻铝合金夹杂相的微观结构

利用Ｘ射线能谱分析和选区电子衍射技术对工业ＡｌＣｕＭｇＳｉ系锻铝合金中粗大夹杂物的成分和结构类型进行了研究     

Inductive heat property of Fe3O4 nanoparticles in AC magnetic field for local hyperthermia

Magnetite (Fe3O4) nanoparticles with different magnetic properties were prepared by coprecipitation of Fe3+ and Fe2+ with aqueous NaOH solution.The inductive heat properties of Fe3O4 nanoparticles in an alternating current (AC) magnetic field were investigated for local hyperthermia. The maximum saunder the optimum conditions of Fe3+:Fe2+ molar ratio at 1.8:1. The Ms of Fe3O4 nanoparticles decreased as the Fe3+ /Fe2+ molar ratio increased. But the coercivity Hc increases with the increasing of Fe3+ /Fe2+ molar ratio. Exposed in the AC magnetic field for 29 min, the temperatures of physiological saline suspension containing Fe3O4 nanoparticles were 42-97.5 ℃.The inductive heat property of Fe3O4 nanoparticles in AC magnetic field decreases as Hc increases, but increases with the increasing of Ms. The Fe3O4 nanoparticles would be useful as good thermoseeds for localized hyperthermia treatment of cancers.     

热处理工艺对22MnB5钢铝硅镀层氧化层厚度和组织演变的影响

目的探究奥氏体化工艺对铝硅镀层氧化层厚度和微观组织的影响规律及其演变机理。方法以热浸镀Al-10%Si的22MnB5为研究对象,采用扫描电子显微镜(SEM)、辉光放电光谱仪(GD-OES)和X射线衍射仪(XRD)等仪器,观察镀层在奥氏体化过程中氧化层厚度的变化和微观组织的演变规律。结果当试样以15℃/s的速率升温到900℃后立即水淬,镀层氧化层最薄,当试样升温到900℃保温5 min后水淬,镀层氧化层出现了不同程度的开裂,镀层表面出现孔洞和脱落的现象,氧化层厚度明显增加。结论奥氏体化保温时间比奥氏体化升温速率对镀层氧化层厚度的影响更大,保温时间越长,氧渗入镀层的深度越深,氧化层越厚,奥氏体化时间的延长不利于镀层氧化层保持完整性,影响镀层对钢基体的保护功能。镀层及其氧化层的微观组织演变规律为:镀层中首先形成Al2Fe3Si3(τ1)和Fe2Al5相,随后Fe2Al5相生长并伴随FeAl2相形成,而后FeAl2+Fe2Al5相生长且有FeAl析出,随后FeAl相生长,氧化层出现孔洞,最后氧化层破裂,镀层表面孔洞增加,最终组织为FeAl2+Fe2Al5+FeAl。     

Structures and superparamagnetic properties of overaged Fe–Al–Mn–C alloys

Microstructures and superparamagnetic properties in aged-hardened Fe–9%Al–30%Mn– (x)C,Si alloys, resulting from overaging at a temperature of 823 K for 48 h to 313 days, have been investigated by transmission electron microscopy (TEM), X-ray diffraction patterns, and vibrating sample magnetometry (VSM). The results reveal that the precipitate κ-phase [(Fe,Mn)₃AlC] decomposition in this alloy, overaged at 823 K for one week, resulted from two separate mechanisms: (1) wetting of the antiphase boundary segment (APBs) of D0₃ [(Fe/Mn)₃Al] domains by the B2 [(Fe/Mn)Al] phase; and (2) precipitation of the B2 [(Fe/Mn)Al] phase within the domain. A superparamagnetic behaviour was discovered when the alloy was overaged at 823 K for ≈120–313 days. The super-soft magnetic property was mainly attributable to the ferromagnetic spinel-ordered (B2 [(Fe/Mn)Al]+D0₃ [(Fe/Mn)₃Al]) phases and ordered B2 with monoclinic ′Mn structures.