DEWATERING OF WASTE ACTIVATED SLUDGE VIA CENTRIFUGAL FIELD

While conducting centrifugal dewatering tests on waste activated sludge, this work considered how the rotational speed and the application of cationic polyelectrolyte flocculation affected the sludge. Increased rotational speed and/or conditioning the sludge to a charge neutralization point could enhance dewatering efficiency. A model was proposed to estimate the disruption energy exerted on the sludge body using centrifugation. Experimental results indicate that the disruption energy level provided by the centrifuge increases with rotational speed and decreasing water content in the filter cake. Moreover, polyelectrolyte flocculation may significantly reduce the disruption energy level of the water from sludge particles and the residual water contents at the end of the test.     

Consolidation dewatering and centrifugal sedimentation of flocculated activated sludge

This study investigated experimentally the consolidation dewatering and centrifugal-settling processes for activated sludge subjected to cationic polyelectrolyte flocculation. The results were reported for the dynamic response of sediment cake thickness (an index for cake compaction) under various doses of polyelectrolyte conditioning, compression-permeability cell configuration and mode of operation (batch and continuous) in a centrifugal-settling cell. The reduction in sediment thickness of sludge by consolidation and centrifugation was found to correspond mostly well with the optimal dose of polyelectrolyte based on the capillary suction time. The relaxation/rebound of cake thickness was observed in both consolidation dewatering and centrifugal dewatering with comparable compaction/relaxation time scale ratios. The equilibrium sediment consolidation ratio increases with the effective solid pressure characterized by P_m and P_s, for the consolidation dewatering and centrifugal sedimentation, respectively. The experimentally determined time scales of the cake consolidation dewatering/centrifugal sedimentation processes agree reasonably well with the theory by Landman and Russel (Phys. Fluids A 5 (1993) 550).     

Sludge Dewatering and Aggregate Formation Effects through Taylor Vortex Assisted Flocculation

Abstract

For polymer induced flocculation processes, the effects of flow patterns in a gap of a conical stirrer on aggregate formation and subsequent sludge dewatering efficiency were analysed. Different flow regimes were identified by lab scale investigations with model substances and summarized in a Ta and Re number plane. An enhancement of sludge dewaterability for polymer induced flocculation processes was identified through post‐treatment of flocculated sludge aggregates by the specific flow pattern of stable and wavy Taylor vortices. Photo‐optical image analysis of flocculated aggregates shows a clear change of aggregate size distribution with less small particles during aggregate forming by Taylor vortices compared to classical flocculation procedure by stirrer. Results from technical scale dewatering analyses confirmed enhancement of sludge dewatering efficiency for six different dewatering machines using the identified wavy and stable Taylor vortex flow pattern regime.     

Flockung und Entwässerung von Klärschlamm mit Hilfe von Polyelektrolyten

An investigation was performed with the aim of ascertaining how a digested sewage sludge could be converted into mechanically stable flocs through the addition of a flocculating agent, while achieving the best possible dewatering efficiency with the lowest possible dosage of flocculation agent. In order to obtain conclusive results which can be transferred to large-scale plants, the effectiveness of the flocculating agents and the various flocculation procedures were tested in a patented, mobile, computer-assisted flocculation and dewatering apparatus. The sewage sludge was conditioned with flocculating agents which had previously been thoroughly characterized in terms of their chemical structure, charge density and molar mass. The cationic flocculating agents had charge densities ranging from 25–55 mol-% and molar masses from 1.5 · 10⁶–12.9 · 10⁶ g mol^?, whereas the anionic flocculating agent had a charge density of 36 mol-% and a molar mass of 7.6 · lo6 g mol^?. In contrast to other suspensions already investigated, for sewage sludge it was found that no improvement can be achieved in the already very high dewatering level when cationic monoflocculation is used (laboratory trial: 95% filtrate yield by mass after 4 s). Nor was it possible to reduce the optimum dosage by using the dual procedure. In addition, it was possible to show that the chemical structure, i.e. the nature of the polyelectrolyte, and the molar mass of the cationic polyelectrolytes investigated exert a by far larger influence on the dewatering efficiency than the charge density in a range between 25 and 55 mol-%. Furthermore, it has also been observed that the conditioning efficiency of the polyelectrolytes increases as the molar mass rises and the chemical structure influences the dewatering result primarily through the position of the charge-bearing group.     

Structural Analysis and Dewatering Characteristics of Waste Sludge from WWTP MBR

Abstract

A pilot‐scale UF membrane bioreactor (MBR) of 1 m³/day capacity was set up in an industrial wastewater treatment plant to evaluate its performance. This study mainly focused on testing the dewaterability and structural analysis of MBR sludge. MBR had 14% reduction of excess sludge production in relative to the conventional activated sludge process (CAS sludge). For dewatering, MBR sludge had comparable dewaterability with the CAS sludge but required nearly 20% less flocculant to reach the highest filterability χ and lowest specific filtration resistance (SRF). This could reduce the cost for running the dewatering facilities and final disposal. Meanwhile the chemical and morphological analyses on MBR sludge exhibited lower EPS (exocellular polymeric substances) content, slightly smaller flocs and more compact morphology. Additionally, to estimate the appropriate polyelectrolyte dose prior to dewatering, we measured the hysteresis loop area of the sludge rheogram (shear stress vs. shear rate) using a co‐axial cylinder viscometer. For both sludges, the area dramatically increased at some critical flocculant dosage and then plateaued off. The critical dosage, though not optimal, still led to an acceptable dewatering performance for the sludge.     

Anwendung von Polyelektrolyten bei der mechanischen Fest/Flüssig-Trennung

Use of Polyelectrolytes in Mechanical Solids/Liquid Separation. This article shows how optimisation tasks for the dewatering of sludge can be solved by starting from studies of chemical structure and steric properties of polyelectrolytes and laboratory experiments based thereon with a trans-portable computer-aided flocculation and dewatering apparatus. The optimum polyelectrolyte dosage lies in the range of the critical concentration c* (viscosimetric measurements) of the dissolved polyelectrolytes. On optimisation of the flocculant regime for mechanical solids/liquid separation by combined addition of anionic and cationic polyelectrolytes (dual process), it is necessary to consider the overall system of sedimentation and filtration. In an industrial scale plant, the consumption of flocculant could be reduced by up to 10% compared to laboratory studies. At the same time, the dewatering behaviour could be improved by up to 60%, a shearing strength of the sludge in excess of 20 kN/m² reliably established, and plant operating reliability achieved for changing sedimentation properties.     

PRACTICAL ASPECTS OF DEWATERING ENHANCED BY ELECTRO-OSMOSIS

ABSTRACT

Dewatering mechanism due to electro-osmosis is fairly different from that of mechanical dewataine which has been used conventionally. and electro-osmotic dewatering has Several advantages compared with the mechanical dewatering and it can be remarkably effective for hardly dewaterable sludges such as very fine Particles and gelatinous materials. In electro-osmotically enhanced dewatering, however, it would be a great problem that the achievement of complete water removal within the sludge could not be possible in principle. Because. when a liauid state in the sludge becomes to be not continuous gradually with proceeding of dewatering, the sludge does not lead electricity and and then electro-osmosis is no longer caused.

Applying electro-osmosis to sludge dewatering practically, methods for improvement of the electro-osmotic dewatering must be investigated taking account ofapos;such a situation for the performance of high dewatering efficiency. Some practical applications of the dewatering which can be considered to be available are described in this paper.     

Effects of polyacrylamide on microbial density levels and biodegradability in waste‐activated sludge

This study addressed the possible role of polyelectrolyte flocculation on microbial density levels in a waste‐activated sludge. Such an effect is commonly ignored. Applying polyelectrolyte reduced the density level of coliform bacteria in the flocculated sludge. Polyelectrolyte also reduced the 5‐day biochemical oxygen demand of sludge, possibly retarding the subsequent biodegradation processes. © 2001 Society of Chemical Industry     

Involvement of Gypsum (CaSO4 · 2H2O) in Water Treatment Sludge Dewatering: A Potential Benefit in Disposal and Reuse

Abstract

This research assessed the use of gypsum (CaSO₄ · 2H₂O) as a skeleton builder for sludge dewatering since polymer conditioning of sludge affected only the rate of water release, not the extent of dewatering. The use of gypsum as a physical conditioner, in association with a polymer, could improve sludge filterability. More significantly, gypsum serves as a skeleton builder, forming a permeable and rigid lattice structure that can remain porous under high positive pressure during the compression step after the cake growth of the filtration, thereby maintaining the size of the micro‐passages through which water is expressed. Experiments using a high pressure cell apparatus showed that a further decrease of two to seven percent of the equilibrium moisture content of the sludge cake was achieved, for sludge thicknesses for dewatering of 1 to 10 cm, by the addition of gypsum with 60% of the original sludge solids when compared to the single polymer conditioning. The importance of the addition of gypsum in alum sludge dewatering is not only the improvement in the extent of dewatering, but also the potential application of transforming dewatered alum sludge from “waste” for landfill to useful “fertilizer” or to be used as a filter medium/adsorbent for wastewater treatment engineering.     

Comparison of initiation methods in the structure of CPAM and sludge flocs properties

Cationic polyacrylamides (CPAMs) synthesized by thermal, ultrasonic, microwave, and UV initiation were characterized through magnetic resonance hydrogen spectroscopy (¹H NMR), Fourier transform infrared spectra, scanning electron microscopy, and thermal gravimetric analysis. The CPAMs for flocculation and dewatering of alum sludge produced through drinking water treatment were evaluated based on the residual turbidity of the supernatant, dry solid content, mean volume diameter and floc size distribution, fractal dimension of the flocs, and zeta potential as a function of flocculant dosage. Comparisons of the characteristics and performance of CPAMs synthesized through different initiation methods were systematically conducted. Flocculation and dewatering test results demonstrated that CPAMs synthesized through microwave and UV initiation had better flocculation performance and dewatering capability than those synthesized through thermal and ultrasonic initiation. All four CPAMs exhibited a similar final floc size distribution but different mean volume diameters and floc structures. The fractal dimension of the flocs and the zeta potential were in the following order: CPAM3 (microwave initiation) > CPAM4 (UV initiation) > CPAM1 (thermal initiation) > CPAM2 (ultrasonic initiation). Discussions on fractal dimension and zeta potential indicated that the electrostatic patches model and adsorption/bridging effect mechanisms played the main role in the formation of sludge flocs. Lastly, microwave and UV initiation were found to be alternative and recommendable initiation methods for the synthesis of CPAMs with improved flocculation performance and sludge dewatering capability. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44071.     

基于介观尺度模拟的污泥絮凝形态及机理

用介观动力学的方法对胶体颗粒与高分子链的絮凝过程进行了模型研究,并根据模型结果对污泥和阳离子聚丙烯酰胺的絮凝过程和污泥脱水机理进行有针对性的探讨。通过建立粗粒化模型和经验势函数力场有效模拟了负电性的胶体颗粒与阳离子型高分子链的絮凝过程;模拟得出了絮凝的外观形态,证明了高分子链对胶体颗粒的桥接作用以及表面电荷的中和作用对絮凝的影响;并对絮凝反应过程的体系势能变化进行了研究。对实际污泥胶体颗粒和阳离子聚丙烯酰胺溶液拍摄了电镜图片并观察了其吸附过程;最后研究了高分子链离子度对溶液体系絮凝的影响,验证了离子度的增加有利于絮凝体的形成,但同时也由于絮凝体结构的复杂而对污泥脱水造成了一定的不利影响。     

高分子絮凝剂特性对污泥调理和脱水效果的影响及在线絮凝检测技术应用研究

高分子絮凝剂品种及特性对污泥调理及脱水效果有很大影响,试验结果表明絮凝剂的相对分子质量是决定性因素,电荷特性影响较小。利用一种在线絮凝检测技术可连续检测污泥调理工艺中污泥颗粒絮凝过程,从而形成了一种全新的污泥絮凝检测方法,为污泥调理和脱水工艺的过程控制提供了可能性。     

Recycling of excess sludge using titanium tetrachloride (TiCl4) as a flocculant aid with alkaline-thermal hydrolysis

The highly strengthened treatment and disposal of excess sludge based on economic and environmental regulation factors is one of the important issues to be dealt with in the activated sludge process. In this study, the reduction and recycling technology of excess sludge were investigated for the aim of achieving a zero emission of excess sludge produced from the activated sludge process using titanium tetrachloride (TiCl₄) as a flocculant aid with alkaline-thermal hydrolysis. Alkaline-thermal hydrolysis of excess sludge was obtained 73% and 40% reduction rate at pH 13 (60 8 °C) and pH 11 (60 8 °C), respectively. Flocculation was carried out using a Ti-salt flocculant and the collected sludge was dewatered and incinerated at 600 °C to produce TiO₂ nanoparticles. The amount of total suspended solids and volatile suspended solids was significantly decreased with pH increase. The optimal dose of Ti-salt flocculation aid to improve dewatering ability of sludge breakage was 23.95 Ti-mg l^?1. Also, in the batch culture, the supernatant after flocculation and the organic matter released from the lysed sludge were found to be useful as a source of energy for the growth of microorganisms during the aerobic operations period. TiO₂ produced from Ti-salt flocculation of excess sludge (TES) was characterized by X-ray diffraction, scanning electron microscopy/energy dispersive X-ray and photocatalytic activity.     

A Study for Development of Real-Scale Thermal Filter Press Dewatering (TFPD)

Real-scale thermal filter press dewatering equipment (plate size: 630 mm × 630 mm) was installed and operated at a waterworks for one year in an attempt to achieve sludge reduction. During the period, the dewaterability was evaluated according to the seasonal sludge properties in order to compare the dewaterability of thermal dewatering and mechanical dewatering, as well as to determine the economics of thermal dewatering. According to the results, the winter season sludge showed a 36% decrease in water content and a two-thirds reduction in dewatering velocity compared to the summertime sludge. In addition, the dewatered cakes of the thermal filter press dewatering equipment showed a lower specific cake resistance and water content in the dewatered cakes than the mechanical filter press dewatering equipment, indicating superior dewaterability. This was attributed to the easier removal of the filtrate remaining in the capillary tubes due to thermal dewatering. The energy consumption for thermal dewatering was 300 kJ/dry solids (DS) kg. A comparison of the sludge dryers indicated that it is possible to produce dewatered cakes that consume less energy and can be recycled. According to the performance evaluation results, the real-scale thermal filter press dewatering equipment had high adaptability to the changes in seasonal sludge, showing excellent dewaterability compared to the mechanical filter press dewatering equipment, and was economical due to the lower energy consumption.     

WATER REMOVAL FROM SLUDGE IN A HORIZONTAL ELECTRIC FIELD

A new method for sludge dewatering was proposed, in which a horizontal electric field was applied in order to facilitate the dissipation of gases produced at electrodes and to keep the anode soaked in water during the dewatering process. The effects of operation conditions such as the magnitude of electric field strength, pH of aqueous phase, the pretreatment procedures including flocculation, freezing and heating on the water removal were examined, respectively. The morphological difference between the concentrated sludge produced by electrodewatering and by vacuum filtration was revealed with scanning electron microscopy, which shown that electrodewatering was effective in removing the capillary water in the sludge floc. At electric field strength of 1200 V/m, the sludge concentration could be increased from 3 to 8%(w/w), indicating that over 60% of water was removed from the sludge. Compared to those operated in a vertical electric field, the method described in the present study has the advantages in terms of high eficiency, simple structure and ease of operation.     

WATER REMOVAL FROM SLUDGE IN A HORIZONTAL ELECTRIC FIELD

A new method for sludge dewatering was proposed, in which a horizontal electric field was applied in order to facilitate the dissipation of gases produced at electrodes and to keep the anode soaked in water during the dewatering process. The effects of operation conditions such as the magnitude of electric field strength, pH of aqueous phase, the pretreatment procedures including flocculation, freezing and heating on the water removal were examined, respectively. The morphological difference between the concentrated sludge produced by electrodewatering and by vacuum filtration was revealed with scanning electron microscopy, which shown that electrodewatering was effective in removing the capillary water in the sludge floc. At electric field strength of 1200 V/m, the sludge concentration could be increased from 3 to 8%(w/w), indicating that over 60% of water was removed from the sludge. Compared to those operated in a vertical electric field, the method described in the present study has the advantages in terms of high eficiency, simple structure and ease of operation.     

阴极滤布对活性污泥电渗透脱水的影响(英文)

The mechanical dewatering of activated sludge is troublesome due to its high compressibility of solids. The dewatering can be enhanced dramatically by the use of electroosmosis,in which an electric field is applied to the sludge cake.In this study,the influence of filter cloth on the cathode on the dewatering of activated sludge was investigated.It was found that thicker filter cloth led to lower water removal from the sludge cake,so a stainless steel cathode net with small pore size instead of filter cloth was applied,which improves the dewatering efficiency and reduces the electric power consumption.Moreover,water absorbent materials were helpful to remove the water from the sludge cake.For the electroosmotic dewatering at 7 kPa and 24 V·cm-1,the water content in the sludge cake decreased to 60%(by mass) with the average 0.075 kW·h·kg-1of water removed by using the cathode net.     

叠螺脱水机与离心脱水机在污泥处理中的应用比较

阐述了炼油厂污泥的来源及特性,从工作原理、工艺流程和运行成本3方面对叠螺脱水机与离心脱水机进行了比较分析。2种污泥脱水机均适用于含油污泥(主要成分是浮渣)、剩余活性污泥的脱水处理;离心脱水机主要是依靠转鼓高转速产生的离心力使具有一定密度差的泥水分离,而叠螺脱水机主要是依靠螺杆的挤压来实现污泥脱水;离心脱水机必须配套污泥输送泵、比重剂加药设备;叠螺脱水机在运行成本上占有明显优势,还可以显著改善运行中对工作环境的污染。基于叠螺脱水机运用螺杆挤压原理实现污泥脱水,该设备不适用于含较大硬度颗粒的污泥脱水。     

Comparison of horizontal and vertical electric field in the treatment of river sediment by electro-dewatering

The aim of this study was to evaluate and compare the effectiveness of horizontal (H-EDW) and vertical (V-EDW) electro-dewatering fields, in terms of dewatering and energy consumption, for the treatment of river sediment. The influence of the sludge thickness (3, 4, 5, 6, 7?cm) and the applied voltage (10?30?V) were examined. V-EDW was found to significantly improve dewatering and reduce process time, while H-EDW has the potential to save energy but results in sludge containing greater moisture. As the applied voltage was increased from 10?V to 30?V, the final dry solids content and energy consumption increased for both modes. Increased sludge thickness from 3?cm to 7?cm was found to have a negative influence on the final dry solid content of the sludge for V-EDW, but is not a significant influence with H-EDW. The results demonstrate that H-EDW is an effective dewatering method and has potential for continuous operation and energy efficiency for industrial-scale applications.     

超声能量密度对污泥脱水性能的影响

<正>引言近年来,生物法在城市污水处理中得到广泛的应用,然而在处理过程中产生了大量的污泥,污泥中含有50%～70%的有机物和较多的氮、磷等营养成分以及致病菌、寄生虫卵等有害物质。其化学