W6Mo5Cr4V2钢形变诱发析出碳化物及规律

对Ｗ６Ｍｏ５Ｃｒ４Ｖ２钢经１２４０℃奥氏体化后于１７０－１１５０℃形变０－６５％直接淬火过程中诱发析出的碳化物进行了研究。结果表明，在７５０－１１５０℃热形变淬火迁程中均诱发析出直径约１－２μｍ，具有立方ＮａＣｌ晶型的ＭＣ型碳化物；碳化物的分在民形变温度有关，高温形变呈随机分布，而低温下则趋于沿Ｆ１１１Ｇγ滑移面析出呈方向性分布；碳化物的析出量主要由形变温度和该表变温度下热变形奥氏体的组织状态...     

W6Mo5Cr4V2钢形变等温淬火的组织和性能

对Ｗ６ＭＯ５ｃｒ４Ｖ２钢１２４０℃奥氏体化后、在１１５０℃以１．５×１０￣－２／ｓ的形变速率筹温形变０％～６５％，并在２７０℃等温淬火，５６０℃３次回火后的组织和性能进行了研究。结果表明：该钢在１０５０℃或更高温度形变会发生动态再结晶，且形变诱发析出了ＭＣ型碳化物，而使贝氏体中具有大量的碳化物颗粒；形变使等温淬火、回火组织的强度、硬度及韧度均有所提高，在１０５０℃形变１５％～２０％具有最佳的强韧性配合。     

热变形对高速钢组织的影响

此文研究了Ｗ６Ｍｏ５Ｃｒ４Ｖ２高速钢奥氏体化后在７５０－１１５０℃等温热压变形对该钢组织的影响。结果表明：该钢有１０５０℃或更高温度形变才会发生动态再结晶，而９５０℃或更低温度形变仅发生动态回复；同时热表变诱发析出了ＮａＣｌ晶型的ＭＣ型碳化物；由于形变及碳化物的析了，使得该钢等浊形变后直接淬火组织中的位错马氏体量增多。     

微量Mg在M2高速钢中的作用

研究了Ｍｇ对Ｍ２高速钢凝固组织和共晶碳化物高温球化的影响，试验表明：加入适量的Ｍｇ可以使Ｍ２高速钢通常的片状Ｍ２Ｃ型共晶碳化物转变成鱼骨状的Ｍ６Ｃ和块状的ＭＣ型碳化物，Ｍｇ还阻碍鱼骨状共晶碳化物的高温球化。     

EFFECTS OF CARBON AND YTTRIUM ON 500℃ AGING EMBRITTLEMENT OF ALLOY Fe-15Cr-4Al

测定了Ｆｅ－１５Ｃｒ－４Ａｌ合金在５００℃的时效脆化动力学，利用内耗，ＴＥＭ，ＥＰＭＡ和ＳＥＭ等手段研究了合金在时效后的组织变化和断裂行为。结果表明，时效脆化第一阶段（０－１００ｈ）主要是碳化物在α相晶界析出的作用，它损害界面结合，降低断裂应力，使塑性在时效０．２５ｈ后消失；第二阶段（１００－１０００ｈ）主要是富Ｃｒ－α＇相均匀析出的作用，它通过强化基体引起二次脆化。含０．２和０．４％的Ｆｅ－１５     

高速钢形变等温淬火的力学性能及其强韧化机理

对Ｗ６Ｍｏ５Ｃｒ４Ｖ２钢奥氏体化后,在１１５０℃～７５０℃以１．５×１０－２／ｓ的形变速率等温形变０％～６５％,并对２７０℃等温淬火、５６０℃回火后组织与性能进行了研究。结果表明：形变使等温淬火、回火组织的硬度、强度和冲击韧度均有所提高,１０５０℃形变１５％～２０％具有最佳强韧性配合。并根据力学性能与组织变化的关系,提出了组织细化强韧化、位错强化、碳化物沉淀强化和锯齿状晶界韧化的强韧化机理,其中锯齿状晶界韧化对最佳强韧性配合起着关键作用。     

碳和钇对Fe－Cr－Al合金500℃时效脆化的影响

测定了Ｆｅ－１５Ｃｒ－４Ａｌ合金在５００℃的时效脆化动力学，利用内耗，ＴＥＭ，ＥＰＭＡ和ＳＥＭ等手段研究了合金在时效后的组织变化和断裂行为．结果表明，时效脆化第一阶段（０－１００ｈ）主要是碳化物在α相晶界析出的作用，它损害界面结合，降低断裂应力，使塑性在时效０．２５ｈ后消失；第二阶段（１００－１０００ｈ）主要是富Ｃｒ－α＇相均匀析出的作用，它通过强化基体引起二次脆化．含０．２和０．４％Ｙ的Ｆｅ－１５Ｃｒ－４Ａｌ－Ｙ合金在固溶态下无Ｓｎｏｅｋ内耗峰，碳在α相中的浓度低于０．０００７％，这是碳原子被Ｙ_２Ｆｅ_（１７）相俘获的结果．因此，含钇合金在５００℃时效时不发生晶界碳化物析出，时效１０００ｈ后塑性无明显变化．     

高合金奥氏体铸造不锈钢析出相及腐蚀行为的研究

高合金奥氏体不锈钢铸态组织中有σ相存在，经８５０～１１２０℃热处理所形成的σ相包括：（Ｆｅ－Ｃｒ）σ相、（Ｆｅ－Ｍｏ）σ相、以及（ＣｒＮｉＳｉ）σ相。８５０℃左右有Ｍ６Ｃ型碳化物和ＮｂＣ析出。该钢经１１５０℃×２ｈ水冷固溶处理后，具有优良的抗均匀腐蚀、晶间腐蚀、点蚀和化学腐蚀性能。     

W6Mo5Cr4V2高速钢超塑性能的研究

对Ｗ６Ｍｏ５Ｃｒ４Ｖ２高速钢进行了组织超塑性研究。结果表明：经１０４０℃二次循环淬火处理后的Ｗ６Ｍｏ５Ｃｒ４２高速钢，在变形温度为７８０℃－８１５℃，     

变质M2高速钢中共晶碳化物加热团球化的动力学研究

采用高温淬火、退火等方法研究了变质Ｍ２高速负名共晶碳化物在加热时的团球化过程。随加热温度的提高和保温时间的延长,碳化物的团球化是通过碳化物层片的聚集与粗化、共晶碳化物网的熔断和球化、晶内二次碳化物的弥散析出与长大实现的;在此基础上建立了共晶碳化物的粗化、聚集和二次碳化物长大的动力学模型,推导了碳化物长大的瞬时速度公式;计算表明,碳化物的团球化受合金元素的扩散速度、碳化物的形貌、加热温度等动力学因素     

Effects of Post-weld Heat Treatment on Microstructure,Mechanical Properties and the Role of Weld Reinforcement in 2219 Aluminum Alloy TIG-Welded Joints

In as-welded state, each region of 2219 aluminum alloy TIG-welded joint shows diff erent microstructure and microhardness due to the diff erent welding heat cycles and the resulting evolution of second phases. After the post-weld heat treatment, both the amount and the size of the eutectic structure or θ phases decreased. Correspondingly, both the Cu content in α-Al matrix and the microhardness increased to a similar level in each region of the joint, and the tensile strength of the entire joint was greatly improved. Post-weld heat treatment played the role of solid solution strengthening and aging strengthening. After the post-weld heat treatment, the weld performance became similar to other regions, but weld reinforcements lost their reinforcing eff ect on the weld and their existence was more of an adverse eff ect. The joint without weld reinforcements after the post-weld heat treatment had the optimal tensile properties, and the specimens randomly crack in the weld zone.     

The First Phase of the SRIF Industrialized Base in ＂West Area＂ Has Been Put into Operation

After nearly two years＇ tense construction, the first phase of industrialized base of Shenyang Research Institute of Foundry （SRIF）, located at the Tiexi Casting and Forging Industrial Park in the west of Tiexi District, has now been completed and formally put into operation.     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

THERMODYNAMICS STUDY ON THE DECOMPOSITION OF CHROMITE WITH KOH

Institute of Process Engineering, Chinese Academy of Sciences, China, has proposed a method for oxidative leaching of chromite with potassium hydroxide. Understanding the mechanism of chromite decomposition, especially in the potassium hydroxide fusion, is important for the optimization of the operating parameters of the oxidative leaching process. A traditional thermodynamic method is proposed and the thermal decomposition and the reaction decomposition during the oxidative leaching of chromite with KOH and oxygen is discussed, which suggests that chromite is mainly destroyed by reactions with KOH and oxygen. Meanwhile, equilibrium of the main reactions of the above process was calculated at different temperatures and oxygen partial pressures. The stable zones of productions, namely, K2CrO4 and Fe2O3, increase with the decrease of temperature, which indicates that higher temperature is not beneficial to thermodynamic reactions. In addition, a comparison of the general alkali methods is carried out, and it is concluded that the KOH leaching process is thermodynamically superior to the conventional chromate production process.     

INFLUENCE OF HEAT TREATMENT ON DAMPING BEHAVIOUR OF THE MAGNESIUM WROUGHT ALLOY AZ61

The effect of isochronal heat treatments for 1h on variation of damping, hardness and microstructural change of the magnesium wrought alloy AZ61 was investigated. Damping and hardness behaviour could be attributed to the evolution of precipitation process. The influence of precipitation on damping behaviour was explained in the framework of the dislocation string model of Granato and Lücke.     

Theoretical Analysis for the Motion and Temperature of Melt Droplets in Spray Degassing Process

The motion of melt droplets in spray degassing process was analyzed theoretically. The height of the treatment tank in spray degassing process could be determined by the results of theoretical calculation of motion of melt droplets. To know whether the melt droplets would solidify during spraying process, the balance temperature of melt droplets was also theoretically analyzed. Then proof experiments for theoretical results about temperature of melt droplets were carried. In comparison, the experimental results were nearly similar to the calculation results.     

Growth Kinetics of Single Inclusion Particle in Molten Melts

On the basis of the single-particle framework, a new theory on inclusion growth in metallurgical melts is developed to study the kinetics of inclusion growth on account of reaction and collision. The studies show that the early growth of inclusion depends on reaction growth and Brawnian motion collision, and where the former is decisive, the late growth depends on turbulence collision and Stokes＇ collision, and where the former is dominant; collision growth is very quick during the smelting process, lessened in the refining process, but nearly negligible in the continuous casting process.     

Three-Dimensional Growth of Coherent Ferrite in Austenite: A Molecular Dynamics Study

Coherent second phase often exhibits anisotropic morphology with specifi c orientations with respect to both the second and the matrix phases. As a key feature of microstructure, the morphology of the coherent particles is essential for understanding the second-phase strengthening eff ect in various industrial alloys. This letter reports anisotropic growth of coherent ferrite from austenite matrix in pure iron based on molecular dynamics simulation. We found that the ferrite grain tends to grow into an elongated plate-like shape, independent of its initial confi guration. The fi nal shape of the ferrite is closely related to the misfi t between the two phases, with the longest direction and the broad facet of the plate being, respectively, consistent with the best matching direction and the best matching plane calculated via the Burgers vector content(BVC) method. The strain energy calculation in the framework of Eshelby's inclusion theory verifi es that the simulated orientation of the coherent ferrite is energetically favorable. It is anticipated that the BVC method will be applicable in analysis of anisotropic growth and morphology of coherent second phase in other phase transformation systems.     

An Easy Way to Quantify the Adhesion Energy of Nanostructured Cu/X(X=Cr,Ta,Mo,Nb,Zr) Multilayer Films Adherent to Polyimide Substrates

An approach based on film buckling under simple uniaxial tensile testing was utilized in this paper to quantitatively estimate the interfacial energy of the nanostructured multilayer films(NMFs) adherent to flexible substrates. The interfacial energies of polyimide-supported NMFs are determined to be *5.0 J/m2 for Cu/Cr, *4.1 J/m2 for Cu/Ta,*2.8 J/m2 for Cu/Mo, *1.1 J/m2 for Cu/Nb, and *1.2 J/m2 for Cu/Zr NMFs. Furthermore, a linear relationship between the adhesion energy and the interfacial shear strength is clearly demonstrated for the Cu-based NMFs, which is highly indicative of the applicability and reliability of the modified models.     

High-Speed Friction Stir Welding of SiC_p/Al–Mg–Si–Cu Composite

A 17 vol% SiCp/Al–Mg–Si–Cu composite plate with a thickness of 3 mm was successfully friction stir welded(FSWed) at a very high welding speed of 2000 mm/min for the first time. Microstructural observation indicated that the coarsening of the precipitates was greatly inhibited in the heat-affected zone of the FSW joint at high welding speed, due to the significantly reduced peak temperature and duration at high temperature. Therefore, prominent enhancement of the hardness was achieved at the lowest hardness zone of the FSW joint at this high welding speed, which was similar to that of the nugget zone. Furthermore, the ultimate tensile strength of the joint was as high as 369 MPa, which was much higher than that obtained at low welding speed of 100 mm/min(298 MPa). This study provides an effective method to weld aluminum matrix composite with superior quality and high welding efficiency.