双组分制冷工质R11-R113气泡动力学特性的可视化研究

A digital photographic study of pool boiling with binary mixture Rll（CC13）-Rll3（CCl3CF3） was performed on a horizontal transparent heater at pressure of 0.1MPa. A high speed digital camera was applied to record the bubble behaviors in boiling process. Strong effects of composition on bubble departure diameter, deparatre time, nucleation density were observed, which was attributed to the nature of the activation of the boiling surface and mass diffusion effects. The bubble departure diameter, departure period and nucleation density as functions of composition for binary mixtures R 11-R 113 were presented respectively. From the video images, it can be concluded that evaporation of microlayer is very important to the growth of bubble. It is also observed that there is not any liquid recruited into the microlayer below the bubble.     

THEORETICAL AND EXPERIMENTAL STUDIES ON BUBBLE DIAMETER AND GAS HOLDUP IN AERATED STIRRED TANKS

1 INTRODUCTIONBubble diameter distribution and gas holdup are very important parameters indicatingthe characteristics of gas-liquid dispersion,works done are mostly experimentalobservation.Theoretical analysis of bubble diameter has been mostly focused on thebreak-up of bubbles in the impeller region,and only the theoretical relationship be-tween bubble diameter and operating variables in the impeller region has been reported     

BOILNG HEAT TRANSFER ON SURFACES WITH ARTIFICIAL NUCLEATION SITES (Ⅱ) MECHANISM OF NUCLEATE BOILING AND EFFECT OF CAVITY SIZE, CAVITY DENSITY ON BOILING HEAT TRANSFER

A new comprehensive physical model for nucleate boiling heat transfer on surfaces with artificial nucleation sites has been proposed. Good agreement with experimental results has shown the applicability of the model.     

支流电场中的单气泡行为

The investigation on bubble behavior in electric field helps to analyze the mechanism of electric enhancement of boiling heat transfer. Experiments were performed to investigate the bubble deformation in direct current （DC） electric field with bubbles attached to the orifice. The air bubbles were slowly generated in the transformer oil pool at different orifices, so that the effect of flow on bubble shape was eliminated. The results showed that the bubbles were elongated and the departure volume decreased when the electric field was intensified. The major and minor axes, aspect ratio and departure volume increased with increasing the orifice diameter. Both the electric field and orifice size have great influence on bubble behavior. The bubble deformation was also simulated to compare with the experimental results. The numerical and experimental data qualitatively agree with each other.     

气液错流条件下孔口气泡直径的模型预测(英文)

The size of initial bubbles is an important factor to the developed bubble size distribution in a gas-liquid contactor. A liquid cross-flow over a sparger can produce smaller bubbles, and hereby enhance the performance of contactor. A one stage model by balancing the forces acting on a growing bubble was developed to describe the formation of the bubble from an orifice exposed to liquid cross-flow. The prediction with this model agrees with the experimental data available in the literatures, and show that orifice size strongly affects the bubble size. It is showed that the shear-lift force, inertia force, surface tension force and buoyancy force are major forces, and a simplified mathematical model was developed, and the detachment bubble diameter can be predicted with accuracy of ±21%.     

垂直管内通气空泡掺气过程仿真分析简

A semi-empirical gas entrainment model was proposed for the ventilated cavity in vertical pipe, based on which, a complete numerical scheme was established by coupling with the Eulerian-Eulerian two-fluid model to predict the multiscale flow field created by ventilated cavity. Model predictions were validated against experimental measurements on void fraction and bubble size distributions. Simulations were carried out to explore the effect of ventilation rate and inlet turbulence intensity on the macroscale cavity shape and the bubbly flow downstream of the ventilated cavity. As the ventilation rate increasing, a reverse trend was observed for the void fraction and bub- ble size distributions. It is concluded that the average void fraction in the pipe flow region is determined by the volumetric ratio between liquid and gas. However, the bubble size evolution is dominated by the breakage effect induced by turbulence in the vortex region. Furthermore, simulations were conducted to analyze geometric scale effect based upon Froude similitude. The results imply that the velocity distributions were properly scaled. Slight scale effect was seen for the void fraction caused by faster dispersion of bubbles in the larger size model. The com- paratively greater bubble size was predicted in the smaller model, implying significant scale effects in terms of tur- bulence and surface tension effect. It reveals that empirical correlations valid in wide range are required for the ex- trapolation from small-size laboratory models.     

Graphite Surface Modification by Heterogeneous Nucleation Process

1IntroductionIn recent years,surface modification on the inor-ganic particles has been a very hot research subject inthe field of material science and surface and interfacescience.The heterogeneous nucleation method is avery applicable technical process[1…     

水平管气液两相弹状流液弹频率的水动力学新模型

The prediction of slug frequency has important significance on gas-liquid two-phase flow. A hydrodynamic model was put forward to evaluate slug frequency for horizontal two-phase flow, based on the dependence of slug frequency on the frequency of unstable interfacial wave. Using air and water, experimental verification of the model was carried out in a large range of flow parameters. Six electrical probes were installed at different positions of a horizontal plexiglass pipe to detect slug frequency development. The pipe is 30 m long and its inner diameter is 24 ram. It is observed experimentally that the interracial wave frequency at the inlet is about i to 3 times the frequency of stable slug. The slug frequencies predicted by the model fit well with Tronconi (1990) model and the experimental data. The combination of the hydrodynamic model and the experimental data results in a conclusion that the frequency of equilibrium liquid slug is approximately half the minimum frequency of interfacial wave.     

HYDRODYNAMICS AND AXIAL MIXING OF LIQUIDSOLID SYSTEM IN OPEN TURBINE ROTATING DISC CONTACTOR

The open turbine rotating disc contactor (OTRDC) has been installed simply by adding three narrow strips to the lower surface of each rotating disc in the rotating disc contactor (RDC), so it can be used for the system with high solid particle content. Hydrodynamics and axial mixing have been investigated in a 0.152m diameter OTRDC of different compartment height for the system of tap water and quartz particles. A model has been developed to describe the flow of liquid and solid phases. The solid phase holdup can be calculated satisfactorily according to the model equations. Axial mixing data have been treated by the backflow model and the correlations for predicting backflow ratios of liquid and solid phases in OTRDC have been presented.     

Detachment Size Measurement of Two Interacting Bubble Plumes Formed at Neighboring Needles Using an Acoustic Method

Detachment size determination with an acoustic method has been carried out fur two interacting bubble plumes formed at neighboring needles in quiescent water. Two sets mv needle pairs, one with 1.5mm and 0.8mm inner diameters and the other with the equal 1.5mm diameters, were separately used as the bubble pair injectors in the experiments. Consequently, four typical patterns of bubble plumes interaction could be observed in the two cases mv need lepair matches. Through measuring the pressure pulses radiated by the bubble pairs immediately after their ‘pinching-off‘ and by making use of a sophisticated relation between obcilintion frequeacy of volume mode and radius of gas bubbler the detachment size mv the bubble plumes have been determined from the amplltude/frequency spectrum mVthe sound pressure pulses. The experimental results demonstrate that the scoustical method is valid in both of the interacting and non-interacting circumstances in bubble field and the bubble size measurements by thls acoustical method agree well with the measurements from photographic analysis. Finally, a comparison has been made on the strong and weak pointe of the acoustical method with the other size determination methods.     

Hydrodynamics of air–kerosene bubble column under elevated pressure in homogeneous flow regime

A multiphase computational fluid dynamics(CFD) model coupled with the population balance equation(PBE) was developed in a homogeneous air–kerosene bubble column under elevated pressure(P). The specific pressure drop(DP/L), gas holdup(a_G), and Sauter mean diameter(d_(32)) were experimentally measured in the bubble column with 1.8 m height and 0.1 m inner diameter, which was operated at a superficial gas velocity of 12.3 mm·s~(-1), and P = 1–35 bar(1 bar = 10~5 Pa). A modified drag coefficient model was proposed to consider the effect of bubble swarm and pressure on hydrodynamics of the bubble column.The Luo breakage model was modified to account for liquid density, viscosity, surface tension and gas density. The DP/L, a_G, and d_(32) obtained from the CFD model were compared with experimental data,and the gas density-dependent parameters of the CFD model were identified. With increasing P from 1 to 35 bar, the aGvaried from 5.4% to 7.2% and the d_(32) decreased from 2.3 to 1.5 mm. The CFD-PBE model is applicable to predict hydrodynamics of pressurized bubble columns for gas–organic liquid in the homogeneous regime.     

Eulerian–Lagrangian simulation of bubble coalescence in bubbly flow using the spring-dashpot model

The Eulerian–Lagrangian simulation of bubbly flow has the advantage of tracking the motion of bubbles in continuous fluid, and hence the position and velocity of each bubble could be accurately acquired. Previous simulation usually used the hard-sphere model for bubble–bubble interactions, assuming that bubbles are rigid spheres and the collisions between bubbles are instantaneous. The bubble contact time during collision processes is not directly taken into account in the collision model. However, the contact time is physically a prerequisite for bubbles to coalesce, and should be long enough for liquid film drainage. In this work we applied the spring-dashpot model to model the bubble collisions and the bubble contact time, and then integrated the spring-dashpot model with the film drainage model for coalescence and a bubble breakage model. The bubble contact time is therefore accurately recorded during the collisions. We investigated the performance of the spring-dashpot model and the effect of the normal stiffness coefficient on bubble coalescence in the simulation.The results indicate that the spring-dashpot model together with the bubble coalescence and breakage model could reasonably reproduce the two-phase flow field, bubble coalescence and bubble size distribution. The influence of normal stiffness coefficient on simulation is also discussed.     

Seeded Induction Period and Secondary Nucleation of Lithium Carbonate

Seeded nucleation of lithium carbonate in aqueous solution during reactive crystallization was monitored by FBRM (focused beam reflectance measurement) and PVM (particle video microscope). The impacts of operating variables, such as seed size and loading, stirring speed, on induction period and secondary nucleation were investigated and explained by an adsorption model. The results show that seed surface area plays an important role in secondary nucleation, for more surface area has higher adsorption capacity and consumes more supersaturation on seed growth, thus restrains nucleation better. A method through comparison between pure breakage/attrition and nucleation process was put forward to distinguish attrition-induced and surface-induced nucleations quantitatively, which can reveal the contributions of different nucleation mechanisms. The nucleation processes in different conditions were studied, the principles and valuable experimental data were obtained for seeding approach primarily. FBRM and PVM are useful on-line apparatuses to facilitate seed selection and seeding optimization.     

表面活性剂-油-水体系界面张力的分子热力学模型

An interracial equation of state based on perturbation theory for surfactant-oil-water system has been developed. By comblninE the interracial equation of state with Boudh-Hir and IViansoori‘s model, a molecular thermodynamic model has been proposed. The interracial tension of surfactant-oil-water systems can be calculated from the surface tensions of pure oil and water by this model. The interfacial tension data for sodium dodecyl sulphate-heptane-water system, polyoxyethylene n-octylphenol-heptane-water system and hexadecyl trimethyl ammonium bromide-heptane-water system have been correlated. By using the adjustable parameters obtained, the interfacial tensions of these systems at other temperatures have been predicted. Both the correlated and the predicted values are sstisfactorv.     

柴油液滴内空化气泡的破碎研究(英文)

A modified mathematical model is used to study the effects of various forces on the stability of cavitation bubbles within a diesel droplet. The principal finding of the work is that viscous forces of fluids stabilize the cavitation bubble, while inertial force destabilizes the cavitation bubble. The droplet viscosity plays a dominant role on the stability of cavitation bubbles compared with that of air and bubble. Bubble–droplet radius ratio is a key factor to control the bubble stability, especially in the high radius ratio range. Internal hydrodynamic and surface tension forces are found to stabilize the cavitation bubble, while bubble stability has little relationship with the external hydrodynamic force. Inertia makes bubble breakup easily, however, the breakup time is only slightly changed when bubble growth speed reaches a certain value (50 m·s?1). In contrast, viscous force makes bubble hard to break. With the increasing initial bubble–droplet radius ratio, the bubble growth rate increases, the bubble breakup radius decreases, and the bubble breakup time becomes shorter.     

Mixed convection in the heated semi-circular lid-driven cavity for nonNewtonian power-law fluids: Effect of presence and shape of the block

The present work delineates the hydrodynamics and thermal characteristics due to mixed convection in the liddriven semi-circular cavity affected by the presence of the adiabatic block at its geometric center for twodimensional, steady-state, laminar and for non-Newtonian power-law fluids. The semi-circular cavity has a diameter of D. The horizontal wall/lid is sliding with a uniform horizontal velocity(u = U) and is subjugated to the ambient thermal condition; while the curved surface is subjugated to a higher isothermal temperature.The convective characteristics inside the system is explored for the broad range of Richardson number(0.1 ≤Ri ≤ 10), Prandtl number(1 ≤ Pr ≤ 100) and non-Newtonian power-law index(0.5 ≤ n ≤ 1.5) at a constant Grashof number of 10~4. Apart from this, the effect of shape(cross-section) of the inserted block, i.e., circular, square and triangular on heat transfer characteristics has also been explored. It is observed that the shear thickening fluids display better cooling characteristics. Besides, the cavity with immersed triangular block shows better heat transfer results than the circular and square blocks. The deviations observed in the flow and heat transfer characteristics in the cavity by inserting an adiabatic block as compared with cavity without block have been ascertained by calculating normalized Nusselt number(Nu~N). The presence of the block was found to have a diminishing effect on the heat transfer due to convection in the cavity. In the end, the results of the study are summarized in the form of a predictive correlation exhibiting the functional dependence of average Nusselt number with Prandtl number, power-law index, and Richardson number.     

三甘醇水溶液池沸腾传热

Boiling of water/triethyleneglycol (TEG) binary solution has a wide-ranging application in the gas processing engineering. Design, operation and optimization of the involved boilers require accurate prediction of boiling heat transfer coefficient between surface and solution. In this investigation, nucleate pool boiling heat transfer coef-ficient has been experimentally measured on a horizontal rod heater in water/TEG binary solutions in a wide range of concentrations and heat fluxes under ambient condition. The present experimental data are correlated using major existing correlations. In addition a correlation is presented for prediction of pool boiling heat transfer for the system in which the vapour pressure of one component is negligible. This model is based on the mass transfer rate equation for prediction of the concentration at the bubble vapor/liquid interface. Based on this prediction, the temperature of the interface and accordingly, the boiling heat transfer coefficient could be straightforwardly calculated from the known concentration at the interface. It is shown that this simple model has sufficient accuracy and is acceptable below the medium concentrations of TEG when the vapor equilibrium concentration of TEG is almost zero. The presented model excludes any tuning parameter and requires very few physical properties to apply.     

Estimation of Pool Boiling Heat Transfer Coefficients of Ethanol-Water Mixtures

Based on the analysis of the principles of heat and mass transfer from the liquid bulk to bubble surface during nucleation, a new estimation method to predict the heat transfer of the nucleate pool boiling in binary mixtures is proposed in this paper by using t he heat and mass transfer analogy (Colburn analogy) at the bubble surface transfer layers. With the use of Thome‘s eaacept of boiling range, an approximate method is derived to vealise the calculation. The peedictbd results by this method are in good agreement with the experimental data from different sources.     

CONVECTIVE HEAT TRANSFER CHARACTERISTICS OF GAS IMPINGEMENT ON SMALL HEATED DEVICE IN LIQUID COOLANT BATH

Heat transfer characteristics of a small heated device have been investigated in a liquid bath with gas jetimpingement as function of gas flow rate,coolant temperature,liquid phsicochemical properties,heat flux,heat source size,ambient pressure and the distance between jet and heated wall.The experimental results show that the agitation of liquid caused by gas jet bubbles increases greatly therate of heat transfer,and the evaporation of coolant near the wall,which was due to the concentration differencebetween gas-liquid interface and bulk gas phase,gives additional enhancement of heat transfer.The rate ofevaporation related to the bubble growth was mathematically formulated.By using the simultaneous heat and mass transfer model,the convective heat transfer coefficient and masstransfer coefficient can be deduced from the experimental results.In addition,the local heat transfer coefficient and the distribution of evaporation heat flux on the smallheated surface are investigated mathematically and experimentally.     

Experimental Determination and Modeling of Bubble Size Distributions in Bubble Columns

Using a five point conductivity technique local values of bubble size,bubble velocity and gas fractionhave been experimentally determined in a 288 mmID and 4.3 m high bubble column as a function of axial andradial position for the air/water and CO_2/N_2/aqueous MDEA systems.The experimental results are comparedwith predictions from a fundamental two-fluid model.The implementation of a non-steady lateral drag term inthe two-fluid model has been shown.In addition to improving the physical realism of the model,it is found togive slight improvements in the predictions of the distributions of local bubble size.Predictions of bubble size arefound in reasonable agreement with experimental values in the heterogeous flow regime,whereas they are stil1found to be unreliable at low gas velocities.Local void predictions are found in reasonable agreement with experi-mental values,but deviations occur in the homogeneous flow regime towards the wall.This is attributed to defi-ciencies in the simplified bubble size mode