去应力退火对等离子喷涂ZrO2-NiCoCrAlY热障涂层热震性能的影响

研究了等离子喷涂ZrO2-NiCoCrA1Y不同结构热障涂层的硬度分布800℃和1000℃温度下的热震性能。并进一步研究了去应力退火对涂层热震性能的影响。结果表明,与非梯度涂层相比,梯度涂层具有较平缓的硬度分布,不存在金属与陶瓷层界面间的硬度突变。热循环温度增加,使抗热震性能降低,但梯度涂层在两种温度下均具有较高的抗热震性。去应力退火处理较显著地提高了涂层的抗震性。     

石墨高温粘接部件的抗热震性能研究

以酚醛树脂（Phenol-Formaldehyde Resin,PF)和B4C、SiO2为原料制备了高温粘结剂，并对石墨材料进行高温粘接，同时考察了粘接石墨制品经历ΔT=800℃和ΔT＝1000℃温度交变后的抗热震性能。结果表明，用该粘结剂粘接的石墨样品有着优良的抗热震性能，经历数次热震后其强度保持率仍然较高。此外，还对影响粘接样品抗热震性能的因素进行了理论探讨，指出优化原料性质、提高热处理温度、控制胶层厚度等对提高抗热震性能有重要的影响。     

常规和纳米ZrO_2-7%Y_2O_3等离子喷涂热障层及其激光重熔后的抗热震性能

为了探讨激光重熔对等离子喷涂常规和纳米热障涂层(TBCs)的影响,采用等离子喷涂工艺在γ-TiAl合金表面制备了常规和纳米ZrO2-7%Y2O3TBCs,并对其进行激光重熔处理,研究了等离子喷涂常规TBCs、激光重熔-等离子喷涂常规TBCs、等离子喷涂纳米TBCs及激光重熔-等离子喷涂纳米TBCs 4种涂层在850℃下的抗热震性能。结果表明:4种TBCs热震失效次数依次为73,118,146,163次,相应的热震破坏形式分别为整体剥落、局部剥落、边角剥落和局部剥落;纳米结构有利于提高涂层的抗热震性能;激光重熔在一定程度上改善了等离子喷涂层的抗热震性能。     

微波冶金用堇青石莫来石耐火材料制备及性能

为探索适合于微波冶金高温反应过程使用的耐高温、抗热震、低微波吸收率耐火材料,采用常压烧结法在不同温度合成了不同配比的堇青石-莫来石质耐火材料.采用XRD分析、三点弯曲法及Angilent阻抗分析等测试了烧结温度及配比对耐火材料物相组成、抗弯强度、抗热震性能及介电性能的影响规律.结果表明,随烧结温度由1400℃提高至14...     

不同粒度板状刚玉对矾土基喷涂料性能的影响

以铝矾土为主要原料,铝酸钙水泥、硅微粉为粘合剂,分别研究不同粒度板状刚玉对矾土基喷涂料性能的影响。试样自然干燥24 h脱模后,再经110℃烘干24 h,分别于1 000、1 300、1 500℃热处理3 h,检测各温度热处理后试样的线变化率、体积密度、抗折强度、抗压强度以及试样的热膨胀系数、耐磨性能和抗热震性能。结果表明:经过1 300、1 500℃热处理后,试样的线收缩率随着板状刚玉粒度的减小而增大。此时,含有粒度小于45μm板状刚玉试样的抗折强度和抗压强度最大;经过1 300℃热处理后,细粒度的板状刚玉有利于提高试样的耐磨性能;含有粗粒度板状刚玉试样的抗热震性能优于含有细粒度板状刚玉试样的抗热震性能。     

纳米Si3N4和喂料等离子处理对等离子喷涂Al2O3-YSZ涂层抗热震性能的影响

Si3N4可以提高Al2O3-ZrO2涂层的力学性能和抗氧化性能,但其对Al2O3-YSZ(Y2O3部分稳定的ZrO2)抗热震性能的影响未见报道.采用等离子喷涂的方法在304不锈钢表面制备了Al2O3-YSZ涂层.在喂料制备过程中加入纳米Si3N4,然后对添加和未添加纳米Si3N4的喂料进行等离子处理,研究纳米Si3N4和喂料等离子处理对涂层在800℃和1 000℃下抗热震性能的影响.采用扫描电子显微镜和X射线衍射仪分析了涂层热震试验前后的形貌及物相的变化.结果表明:喂料添加纳米Si3N4和等离子处理的综合作用显著地提高了涂层的抗热震性能;与喂料未添加纳米Si3N4且未经等离子处理的涂层相比,喂料添加纳米Si3N4且经等离子处理的涂层在800℃和1 000℃条件下的抗热震寿命分别提高了0.7倍和1.1倍;热震过程中涂层发生了α-Al2O3到γ-Al2O3的相变;在1 000℃下热震,涂层中形成了较宽的裂纹,涂层抗热震性能明显下降.     

抗热震陶瓷研究进展

简单介绍了陶瓷材料抗热震性的评价方法，分析了陶瓷材料改善陶瓷抗热震性途径，综述了各种抗热震陶瓷的性能以及主要用途。     

液相等离子喷涂制备纳米ZrO2/Y2O3涂层的研究

传统的喷涂技术制备的ZrO2/Y2O3涂层存在原料需团聚烧结致密,纳米晶粒不定和物理性能不佳等缺点.采用一种新型的液相等离子喷涂法制备了纳米氧化锆热障涂层,初步分析了液相前驱体液滴在等离子焰流中和基体表面的沉积变化过程,研究了雾化液滴尺寸对纳米氧化锆涂层的显微结构,特别是其相结构的影响;同时分析了纳米氧化锆涂层的抗热震循环性能.结果表明,纳米氧化锆涂层可以承受1 000多次的热循环试验,具有优良的抗热震性能.     

等离子喷涂ZrO2热障涂层的抗热震性能

为了进一步了解等离子喷涂ZrO2涂层的制备及失效控制措施,提高涂层的使用寿命,研究了涂层在水淬和火焰喷烧两种条件下的抗热震性能.结果表明:水淬条件下垂直裂纹主要分布在距涂层中心12mm范围内,随热震次数的增加,垂直裂纹最终进入次表层,靠近中心处裂纹扩展较快;火焰喷烧条件下垂直裂纹分布在距涂层中心10 mm范围内,随热震次数的增加,裂纹在表面层和次表层界面处发生偏转,中心处裂纹扩展较快;火焰喷烧条件下涂层的抗热震性能优于水淬下,涂层中孔隙的存在加速了两种条件下裂纹的扩展.     

Al2TiO5-ZrO2复相材料的制备与性能

以α-Al2O3,TiO2,ZrO2为主要原料,以MgO,SiO2,Fe2O3为稳定剂,经1500℃×2h烧结可制得低热膨胀系数的Al2TiO5-ZrO2复相材料.实验发现:随试样中ZrO2含量的提高或随ZrO2稳定程度的提高,Al2TiO5-ZrO2材料的RT～1000℃热膨胀系数逐步降低,这与材料复合体热膨胀系数的常规相悖.ATZ-5试样的抗弯强度为39.15MPa,吸水率为3.28%,热膨胀系数为4.46×10-6 /℃,其抗热震性能优良,可承受的热震温差是P-ZrO2试样的1.62倍.     

Investigation the effect of sintering temperature on Young’s modulus evaluation and thermal shock behavior of a cordierite–mullite based composite

A marked mismatch between CTE of cordierite and mullite in composition develops internal stress, which causes significant growth of cracks and subsequent damages which confer them a very good ability to thermal shock resistance. To investigate the effect of sintering temperature on the thermal shock resistance, the samples sintered at four different temperatures and evaluation of Young’s modulus monitored during 25 shock cycles. The results showed that densification behavior, thermomechanical properties and thermal shock resistance of this refractory was closely related to sintering temperature. Furthermore, during specific (5th to 10th) thermal-shock cycles a notable increase occurs in the Young’s modulus of the samples, this attributed to the formation of viscose bridges, which shield the tip of growing cracks.     

Fabrication and thermal shock resistance of HfB2-SiC composite with B4C additives

A HfB₂ based ceramic matrix composite containing 20 vol.% SiC particles with 2 vol.% B₄C as sintering additives was fabricated by hot-pressed sintering. The microstructure and properties, especially the thermal shock resistance of the composite were investigated. Results showed that the addition of B4C improved the powder sinterability and led to obtaining nearly full dense composite. The flexural strength and fracture toughness of the composite were 771 MPa and 7.06 MPam^1/2, respectively. The thermal shock resistance tests indicated that the residual strength decreased significantly when the thermal shock temperature difference was higher than 600 °C. The large number of microcracks on the sample surface was the main reason for the catastrophic failure.     

热处理温度对刚玉基耐火材料组织和微粒脱落的影响EI北大核心CSCD

为研究温度对刚玉基耐火材料组织和微粒脱落的影响,对粉末冶金高温合金粉末制备用刚玉基(Al_(2)O_(3))耐火材料进行950~1350℃不同温度保温60 min处理。采用XRD分析热处理前后耐火材料的结构,采用扫描电镜对各样品进行微观形貌观察和微区成分测定,并用黏附实验评价不同温度处理后耐火材料颗粒脱落性的改善情况,探索加热保温处理对减少颗粒脱落的机理。采用热冲击测试评价不同温度处理后耐火材料耐热冲击性,并测试耐火材料的显气孔率与体积密度。结果表明:随着加热温度升高,耐火材料中的铝酸钙黏结剂成分将逐步从CaAl_(2)O_(4)(CA)转化为CaAl_(4)O_(7)(CA_(2)),一方面耐火材料中细小的陶瓷颗粒逐步烧结在一起,直至形成相互连接的稳定网状结构;另一方面逐步在大颗粒骨料上润湿铺展并相互连接,最后形成对大颗粒的包覆,同时耐火材料微粒黏附力将随着加热温度的升高逐渐增强。采用预热处理对于耐火材料的显气孔率、体积密度以及整体的耐热冲击性影响不大,但是随着温度升高,对于耐火材料表面在热冲击测试中的局部脱落程度和质量损失率有较明显改善。在保温60 min的条件下,加热温度在1150~1350℃时微粒脱落明显减少,其中1250~1350℃为较优预热温度段。     

Sodium corrosion resistance of translucent alumina: effect of additives and sintering conditions

The resistance of Al₂O₃ against corrosion by sodium in the temperature range 800 to 1000° C was studied by holding samples in liquid sodium in molybdenum containers for several hundred hours. Thermodynamic calculations indicating that Al₂O₃ is unstable in contact with sodium were confirmed by testing sapphire samples. A remarkable aspect was the large anisotropy in the corrosion resistance of sapphire. The effect of the sintering atmosphere and the amount of MgO and CaO dopant in polycrystalline alumina on the corrosion resistance was considered. Vacuum sintering yielded more resistant materials than hydrogen sintering. Low firing temperatures as well as low dopant levels also proved beneficial. In particular, the absence of CaO improves the corrosion resistance considerably. Consequently, the use of this additive should be avoided.     

Thermal shock behavior of nano-sized SiC particulate reinforced AlON composites

Aluminum oxynitride (AlON) has been considered as a potential ceramic material for high-performance structural and advanced refractory applications. Thermal shock resistance is a major concern and an important performance index of high-temperature ceramics. While silicon carbide (SiC) particles have been proven to improve mechanical properties of AlON ceramic, the high-temperature thermal shock behavior was unknown. The aim of this investigation was to identify the thermal shock resistance and underlying mechanisms of AlON ceramic and 8 wt% SiC–AlON composites over a temperature range between 175 °C and 275 °C. The residual strength and Young's modulus after thermal shock decreased with increasing quenching temperature and thermal shock times due to large temperature gradients and thermal stresses caused by abrupt water-quenching. A linear relationship between the residual strength and thermal shock times was observed in both pure AlON and SiC–AlON composites. The addition of nano-sized SiC particles increased both residual strength and critical temperature from 200 °C in the monolithic AlON to 225 °C in the SiC–AlON composites due to the toughening effect, the lower coefficient of thermal expansion and higher thermal conductivity of SiC. The enhancement of the thermal shock resistance in the SiC–AlON composites was directly related to the change of fracture mode from intergranular cracking along with cleavage-type fracture in the AlON to a rougher fracture surface with ridge-like characteristics, crack deflection, and crack branching in the SiC–AlON composites.     

Preparation and characterization of cordierite-zirconia composites from co-precipitated powder

Composite materials with 85 to 65 wt% cordierite and 15 to 35 wt% ZrO₂ were prepared from co-precipitated cordierite powder, and their densification behaviour, microstructure, mechanical strength, fracture toughness, thermal expansion and thermal shock resistance were studied. Addition of ZrO₂ to pure cordierite lowered the sintering temperature needed to obtain a dense sintered body. The fracture strength could be increased from 110 to 260 MPa and the thermal shock resistance from 350 to 500 °C by dispersing 15 wt% ZrO₂ particles in the cordierite matrix.     

Cr_2O_3对氧化钙陶瓷烧结过程的影响

研究Cr2O3添加剂对氧化钙陶瓷烧结性能的影响。结果表明:Cr2O3能促进氧化钙陶瓷烧结密度和抗水化性能的提高,并且随着添加剂含量的增加,陶瓷抗水化性能不断提高;提高烧结温度,能提高陶瓷密度和抗水化性能;在烧结过程中,生成的CaCr2O4为液相,连结CaO晶粒,促进陶瓷烧结,增大了陶瓷的烧结密度,CaCr2O4包裹在CaO晶粒表面,能大幅度提高陶瓷抗水化性能。     

Sintering of Fused Mullite Based Particulate Composites Containing Zirconia

2r0₂ and its modified versions containing MgO and Y₂0₃ were selected as particulate reinforcement in order to achieve better mechanical properties in fused mullite. Particulate composites containing up to 25 vol% Zr0₂ and its modifications were pressed to 65% relative density at 350 MPa followed by sintering at 1650°C and 1700°C for one hour. Studies were conducted on fracture toughness, transverse rupture strength, dielectric constant, microstructure, fractography and thermal shock resistance. Composites sintered at 1700°C were found superior in properties than those sintered at 1650°C.     

硅源对莫来石结合刚玉耐火材料性能的影响

以板状刚玉为骨料,莫来石为结合相,并以高岭土和无定型SiO2微粉作为合成莫来石的硅源,采用反应烧结工艺制备莫来石结合刚玉耐火材料,旨在降低莫来石的烧结成本及获得理想的显微结构.研究表明：以高岭土为硅源,莫来石生成量低于理论量,但生成温度较低,1550℃前已完成莫来石化反应,显微结构较均匀,烧结程度较好,莫来石呈长柱状;...