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直接胺化缩合制备葡萄糖胺为化合物 总被引:1,自引:0,他引:1
在催化剂存在条件下,通过对葡萄糖与一乙醇胺或乙二胺的直接胺化缩合反应的研究,制备了N-葡萄糖基-乙醇胺和N,N′-双葡萄糖基-乙二胺,考察了反应温度,时间及催化剂用量对该类反应产物产率的影响。 相似文献
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以溴代十二烷和乙二胺为原料,通过亲核取代反应制备了N,N-双十二烷基乙二胺(C26H56N2),通过实验考察了合成条件变化对N,N-双十二烷基乙二胺合成的影响。结果表明:在n(溴代十二烷)∶n(乙二胺)=2.4∶1、回流温度下反应8 h得到目标产物,收率为45.5%;利用FTIR、1H NMR、元素分析等手段对其结构进行了表征。探索了N,N-双十二烷基乙二胺作为润滑油添加剂的新应用。采用四球摩擦磨损试验考察了其在聚乙二醇400中的摩擦学性能。结果显示,当N,N-双十二烷基乙二胺添加量为2%时,聚乙二醇400的PB值可由696 N提高至862 N。 相似文献
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申桂英 《精细与专用化学品》2005,13(21):15-16,25
N,N-二烷基乙二胺可用于医药、表面活性剂和涂料领域,制备方法有胺氰甲基化法、胺用氮杂环丙烷处理法和乙二胺法等。在我国,淮安华东化工研究所和北京朝福化工实验厂生产N,N-二乙基乙二胺,丹东市精细化学品厂和溧阳市蒋店化工厂生产N,N-二甲基乙二胺。 相似文献
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2—丙烯酰胺基十六烷磺酸的合成与表征 总被引:1,自引:0,他引:1
以丙烯腈,1-十六烯与发烟硫酸反应,合成了2-丙烯酰胺基十六烷基磺酸单体,借助IR,H-NMR和元素分析确定了产物的结构。 相似文献
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一种多功能表面活性剂的合成 总被引:4,自引:0,他引:4
以长链烷基替代EDTA分子中的一个乙酸基,使其改性为既具表面活性又有络合金属离子能力的多功能表面活性剂。合成分两步,先以乙二胺、溴代烷为原料,合成了中间体N-长链烷基乙二胺(R-en),然后R-en和氯乙酸反应生成了N-长链烷基乙二胺三乙酸钠盐(RNa3edta)。用正交实验法探讨了R-en的合成条件为:n(乙二胺):n(溴代烷)=(2.5-3.0):1.0,反应温度为60℃,反应时间为8-10h,其收率均达98%。终产品合成条件为n(R-en):n(氯乙酸)=1.05:2,反应时间为10h,反应温度为80℃,收率达86%。并通过红外光谱、核磁共振氢谱对终产品结构进行了初步确认。 相似文献
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Detergent range linear alkylbenzene (LAB) currently is manufactured by two different processes, using either aluminum chloride
or hydrogen fluoride as the alkylation catalyst. The alkylates from the two processes are not exactly the same. Furthermore,
the properties of the linear alkylbenzene sulfonate (LAS) surfactants made by sulfonation of the LABs also differ. Because
LAS is used in most types of detergent products, it is important to known how the properties of each type of LAS differ. This
paper compares the formulating characteristics (such as viscosity, solubility and foaming) of high and low 2-phenyl LAS in
some typical household cleaning product formulations. It is concluded that the two types of LAS should not be used interchangeably
without first checking carefully all the physical properties required in a product.
Presented at the AOCS meeting in Honolulu, Hawaii in May 1986. 相似文献
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Yee Seng Lim Nur Bazlina Baharudin Yee Wei Ung 《Journal of surfactants and detergents》2019,22(3):549-558
The detergency performance of α-sulfo fatty-methyl ester sulfonate (α-MES) under different water hardness conditions was compared against the dominant workhorse in Home Care products, linear alkylbenzene sulfonate (LAS). Results demonstrate that α-MES has a higher soil removal index and its detergency performance is not drastically affected by water hardness, compared to that of LAS. The addition of α-MES to LAS also shows an improved cleaning performance and better water hardness resistance, due to the structural characteristics of α-MES, which allow the molecules to be relatively insensitive toward polyvalent ions such as Ca2+ and Mg2+. The washing performance of α-MES, α-MES/LAS, and LAS with different builders at various dosages was studied, and the results indicated that the dosage of builders in the detergent product could be reduced up to 33% with the application of α-MES, while the detergency is not sacrificed. 相似文献
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木质素两性表面活性剂的合成及表面物化性能 总被引:2,自引:1,他引:1
以十二烷基二甲基叔胺、环氧氯丙烷为原料,合成了中间体(2,3-环氧丙基)十二烷基二甲基氯化铵(DMAC),再与磺化木质素(SL)酚羟基反应,合成了木质素两性表面活性剂LAS。通过正交实验确定了最佳合成条件:以丙酮为溶剂,n(SL)∶n(DMAC)=1∶1.1,反应时间3h,pH=12,反应温度55℃,产物中氮质量分数达2.25%。通过元素分析、傅立叶变换红外光谱、UV,确证了目的产物结构。测定产物的临界胶束质量浓度CMC为3g/L,γCMC为21.11mN/m,HLB值为10。表明所合成的木质素两性表面活性剂具有较高的表面活性。 相似文献
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粉末活性炭应急处理模拟突发LAS污染源水试验研究 总被引:2,自引:1,他引:1
论文考察了粉末活性炭预吸附对模拟突发阴离子表面活性剂(LAS)污染源水的应急处理效果,利用烧杯实验研究了粉末活性炭的炭种、投加量、吸附时间、混凝剂种类以及投加量对粉末活性炭预吸附消除LAS的影响。进行了为期约一个月,处理规模为4m3/h的中试试验,考察了常规处理对含LAS源水的处理效果,优化了活性炭投加点,并且探寻了粉末活性炭预吸附对模拟突发LAS污染源水的处理能力。烧杯实验结果表明木质活性炭对LAS的去除效果优于煤质活性炭,优化的投加量为30mg/L,吸附时间30min以上。活性炭吸附后投加混凝剂(PAC)20mg/L可达最佳效果。中试结果表明常规处理对含LAS源水处理效果差,滤后去除率低于5%。活性炭投加点宜设在常规处理前端,接触时间45min。采用粉末活性炭预吸附应急处理突发LAS污染源水,在LAS超标6倍以下,滤前出水可达标。粉末活性炭预吸附应急技术可行性高,处理费用仅0.0255元/m3,为可能突发的水源LAS污染事故应急处理提供了技术支持。 相似文献
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采用氢氧化物共沉淀法,设计了表面活性剂十二烷基苯磺酸钠(LAS)辅助工艺,在pH=11条件下制备了LiNi1/3Co1/3Mn1/3O2的前驱体,经过空气气氛炉900 ℃下煅烧15 h后,对所得样品进行XRD、SEM表征、电性能测试,探讨了LAS添加量对产物的影响。结果表明,LAS不仅不会影响材料的层状结构,还改善了材料颗粒分布,使颗粒分布均匀,粒径均一。在2.5~4.6 V电压区间、0.1 C的倍率条件下,首次放电比容量高达181.9 mA·h/g,经过30次循环后,放电比容量为168.2 mA·h/g,容量保持率达到92.46%。 相似文献
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Darrell A Patterson Ian S Metcalfe Feng Xiong Andrew G Livingston 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2002,77(9):1039-1049
Shake flask experiments were conducted to determine the biodegradability of aqueous linear alkylbenzene sulfonate (LAS) and LAS (1600 mg dm?3) subjected to wet air oxidation (WAO), to assess the suitability of WAO as a pre‐treatment for biological degradation. The effects of WAO temperature (180–240 °C) and the concentration of the orthophosphoric acid catalyst (0–1.0 mol dm?3) were investigated. Results showed that a higher WAO temperature increased the biodegradability of the WAO effluent. This was due to a greater removal of both recalcitrant sulfonated organics and organic concentration (TOC and COD). Conversely, greater orthophosphoric acid concentrations decreased the biodegradability of the WAO effluents. This was because the higher acid concentration increased the ionic strength and changed the WAO intermediate and product distribution, inhibiting microbial action. Nevertheless, the effluents from both variations of WAO were still more biodegradable than LAS at equivalent concentrations. However, since higher WAO temperatures can substantially increase capital costs, future work should focus on developing a WAO catalyst that both desulfonates and mildly oxidises LAS at moderate temperatures (200 °C). © 2002 Society of Chemical Industry 相似文献
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The solution characteristics of the system linear alkylbenzene sulfonate (LAS)/Ca++/builder were studied using a dynamic surface tension technique. The results showed that the rate of CA++/LAS interaction is slower than the CA++ binding rate of zeolite A. Consequently, zeolite A is effective in preventing precipitation of LAS by calcium ions. The data
obtained from the study of Ca++ binding detergent builders on solubilization of Ca(LAS)2 showed that zeolite A was effective but the rate of solubilization was much slower than that for STPP. Incorporation of a
small amount of phosphate with zeolite A in a detergent significantly increases the rate of solubilizing of Ca(LAS)2. 相似文献
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用浊度法研究了聚合物对烷基苯磺酸钠与钙离子的相互作用的影响,不同聚合物,如聚乙烯亚胺(PEI)、聚乙烯吡咯烷酮(PVP)和聚乙二醇(PEG)在同一pH条件下的研究结果表明,PEI比后两能更好地抑制LAS钙盐的形成。同时一聚合物在不同pH条件下的研究发现,PEI只有在一个适当的pH范围内,即自身具有适当的电荷密度,才能很好地发挥其上述作用。在体系中存在一定量的AEO3条件下,也观察到了PEI在抑制 相似文献
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用离子对高效液相色谱法研究了直链烷基苯的碳数分布 ,从而建立了一个快速、准确直接测定烷基苯磺酸平均相对分子质量的新方法。所测得的烷基苯磺酸的平均相对分子质量与气相色谱法相比 ,相对偏差不大于 0 .1 %。一次测定的时间仅需半小时。 相似文献