白光有机电致发光器件的研究

白光有机电致发光器件在显示和照明领域有着极大的应用前景，受到人们广泛的关注。本文对白光有机电致发光器件的结构、工作原理、工艺流程、存在的问题等进行了简单的概述，力求总结出制备白光有机发光器件的新途径。     

有机白光LED

有机白光LED主要有电致发光与光致发光两类。电致发光的主要机理有:量子阱发光、激基复合物发光和能量转移。人们对有机电致发光白光LED研究较多,不久将有产品问世;而对光致发光研究较少。与电致发光相比,光致发光造价更小,其荧光量子效率或许比电致发光更高。有机白光LED制备工艺简单、成本低功耗小,具有巨大的应用价值及潜在的市场。对发光显示技术,有机白光LED代表了一条“便宜”经济的路径。综述了有机白光LED的机理及发展现状。     

电真空器件

0212615利用激基复合物发光的有机白光电致发光器件[刊]/冯晶//发光学报.—2002,23(1).—25～28(E)以 NPB 为空穴传输材料,(dPPY)BF 为发光层,Alq 为电子传输层和色度调节层,制备了有机白光电致发光器件。该器件的白光发射是来自于(dPPY)BF与 NPB 的固界表面形成的激基复合物发光,以及 NPB与(dppy)BF 发射的蓝光。该白光器件的色度稳定,在     

有机薄膜发光器件的研究进展

有机薄膜电致发光器件具有发光效率高、驱动电压低、功耗小、响应速度快等优点,已成为近年来显示技术领域的研究热点.基于有机发光器件的能级结构,分析了电极、有机薄膜以及界面三者对器件性能的影响及相应的改进措施.重点介绍了有机发光材料的研究进展,简要介绍了国内外在有机电致发光显示方面的最新进展.     

有机电致发光的研究及进展

介绍有机电致发光器件的优点、结构及发光机理，评价有机电致发光器件的一些主要参数。说明OLED是一种很有前途的显示技术。     

有机发光显示技术的进展

有机发光显示被认为是下一代最理想的显示技术,具有自主发光、功耗小、视角宽、成本低和响应速度快等优点。本文在简述有机电致发光器件的电极结构和发光材料的基础上,重点介绍了有机显示器件的驱动技术和面板的研发成果,并展望未来发展的前景。     

第二代有机电致发光显示：高功率、超长寿命、低成本OLED器件

第一代有机电致发光器件使用的是底部发光的结构,因而其效率较低,但工作电压却较高,目前,许多具有高效率且使用柔软低成本基板的有机电致发光结构已经制成功。在实现这些优越性能时,电子掺杂传输层起着重要的作用。首先讨论效率非常高的单色和白光Pin型有机电致发光结构,其次展示非常便于进行光学外耦合项部发光有机发光电致发光器件,最后证实Pin型OLED具有非常长的寿命。     

高效顶部发光的白光有机电致发光器件

通过改进阳极和阴极，研制成功了高效顶部发光有机电致发光显示器件，为减少不必要的微腔效应，并获得广谱白光，涂镀CFx于银阳极上，以调整反射率，并在Ca／Ag阴极上涂折射率匹配材料（SnO2），获得最大透过率80％。基于蓝光和黄光发射体的双层结构的顶部发光白光有机电致发光器件在20mA／cm^2的电流密度下，在7．3V驱动电压下，最高电致发光效率达到22．2cd／A（9．61m／W）。CIE色坐标为（x=0．31，y=0．47）。     

有机发光显示器件的研究及应用

有机发光显示器具有自主发光、功耗小、驱动电压低、视角宽、响应速度快等优点,已成为平板显示技术新的研究热点.在介绍有机电致发光器件结构和发光原理基础上,系统介绍了有机显示器件的三个核心部分-有机发光材料、显示面板和驱动技术的研究进展,分析了有机发光显示器的市场前景及可能的应用领域,最后指出有机发光显示器在产业化进程中所需要解决的问题.     

多层结构对有机电致发光器件性能的影响

将发光层进行多次堆叠,构造出有机电致发光器件.在堆叠过程中,改变各发光层厚度的相对比例,发现在总厚度相同、结构相同,而各发光层比例不同的条件下,器件呈现不同的发光特性.器件的电致发光光谱有着明显的变化,器件颜色由蓝光到近白光改变极其明显,器件的亮度和器件的效率也有不同程度的改变.     

High‐Color‐Rendering and High‐Efficiency White Organic Light‐Emitting Devices Based on Double‐Doped Organic Single Crystals

Organic single crystals with much higher carrier mobility and stability compared to the amorphous organic materials have shown great potential in electronic and optoelectronic devices. However, their applications in white organic light‐emitting devices (WOLEDs), especially the three‐color‐strategy WOLEDs, have been hindered by the difficulties in fabricating complicated device structures. Here, double‐doped white‐emission organic single crystals are used as the active layers for the first time in the three‐color‐strategy WOLEDs by co‐doping the red and green dopants into blue host crystals. Precise control of the dopant concentration in the double‐doped crystals results in moderately partial energy transfer from the blue donor to the green and red dopants, and thereafter, simultaneous RGB emissions with balanced emission intensity. The highest color‐rendering index (CRI) and efficiency, to the best of the authors' knowledge, are obtained for the crystal‐based WOLEDs. The CRI of the WOLEDs varies between 80 and 89 with the increase of the driving current, and the luminance and current efficiency reach up to 793 cd m^?2 and 0.89 cd A^?1, respectively. The demonstration of the present three‐color organic single‐crystal‐based WOLED promotes the development of the single crystals in optoelectronics.     

一种新型单偏振片反射式液晶显示器的设计

提出一种新型单偏振片反射式液晶显示器的设计方案。采用共面转换模式并在液晶和反射板之间加入四分之一光延迟膜。通过使用参数空间表示法优化选择器件参数,获得了高反射率、低色散和宽视角的常白、常黑反射式显示模式。     

Reduction of the switching time of polymer-dispersed liquid crystalusing field oriented addressing

Polymer dispersed liquid crystal (PDLC) is a promising liquid crystal for reflective displays in low power mobile applications. However, it is difficult to obtain full color PDLC displays. Color sequential PDLC is one solution but this requires short PDLC switching times. It is demonstrated that the PDLC switching times can be reduced to color sequential levels by changing the orientation of the electric field (field-oriented addressing). By choosing the right pixel geometry, this can be done at relatively low switching voltages compared to the classic addressing method which is based on changing the magnitude of the electric field     

The cholophor: A passive polarization-switched liquid crystal screen for multicolor laser displays

Cholophors are passive polarization-switched color display elements suitable for use with lasers or white light. Their hybrid structure, consisting of a thin layer of cholesteric liquid crystal over a layer of photoluminescent phosphor, provides properties of particular interest for large-screen optically scanned multicolor display applications. Cholophors permit more efficient use of available laser power while providing a solution to the problem of color registration for two-primary displays and a partial solution for three-primary displays. Two-primary or Land-color displays can be obtained with only one color of laser light and three-primary displays with only two colors. A three-primary cholophor display using a single argon ion laser would have over 7 times the efficiency of a typical state-of-the-art system using an argon-krypton mixed-gas laser. The liquid crystal layer provides polarization selectivity, and the phosphor layer produces the additional color not furnished by the laser. The liquid crystal transmits one sense of laser polarization while totally reflecting the other, thereby permitting polarization selective excitation of the underlying phosphor. The color selection information is coded into the polarization of the incident laser beam.     

Design Constraints on FSC LCD

Design constraints on field-sequential color liquid crystal displays (LCDs) are proposed and compared with those of conventional color filter LCDs. Application of these constraints to the design of LCD screens is demonstrated.     

Adaptive LC/BL Feedback Control in Field Sequential Color LCD Technique for Color Breakup Minimization

A full-color image on field sequential color (FSC) displays is composed of color fields in temporal sequence. With the FSC mechanism, color filters of liquid crystal displays (LCDs) can be removed to heighten the light efficiency and lower the material cost. Color breakup (CBU), however, has appeared intrinsically to degrade visual qualities. A novel gray level determination of liquid crystal and backlight (LC/BL) was proposed to suppress the CBU artifact on FSC-LCDs. Based on the image content in each frame, a dominated color-mixed field was found to minimize the color difference between the CBU and original image. Additionally, the feedback algorithm for the adaptive LC/BL signals was developed and implemented on a 32-inch optically compensated bend (OCB) mode LC panel. According to the evaluation of experiments and observations, the proposed method has been demonstrated to greatly suppress CBU in LCD applications.      

液晶盒边界效应对胆甾相液晶电控螺距的影响

研究了共面转换(IPS)液晶盒处于强锚定及弱锚定两种边界状态时横向电场与平面织构胆甾相液晶螺距的关系,探讨了液晶盒表面锚定对胆甾相液晶电控螺距的影响。理论结果表明,共面转换模式下电场可以调谐胆甾相液晶的反射光颜色,而边界锚定效应对电场调谐螺距有显著影响。这一结果为基于电控螺距原理的胆甾相液晶反射式彩色显示方案提供了理论上的依据。     

Manipulation of Charge and Exciton Distribution Based on Blue Aggregation‐Induced Emission Fluorophors: A Novel Concept to Achieve High‐Performance Hybrid White Organic Light‐Emitting Diodes

The aggregation‐induced emission (AIE) phenomenon is important in organic light‐emitting diodes (OLEDs), for it can potentially solve the aggregation‐caused quenching problem. However, the performance of AIE fluorophor‐based OLEDs (AIE OLEDs) is unsatisfactory, particularly for deep‐blue devices (CIEy < 0.15). Here, by enhancing the device engineering, a deep‐blue AIE OLED exhibits low voltage (i.e., 2.75 V at 1 cd m^?2), high luminance (17 721 cd m^?2), high efficiency (4.3 lm W^?1), and low efficiency roll‐off (3.6 lm W^?1 at 1000 cd m^?2), which is the best deep‐blue AIE OLED. Then, blue AIE fluorophors, for the first time, have been demonstrated to achieve high‐performance hybrid white OLEDs (WOLEDs). The two‐color WOLEDs exhibit i) stable colors and the highest efficiency among pure‐white hybrid WOLEDs (32.0 lm W^?1); ii) stable colors, high efficiency, and very low efficiency roll‐off; or iii) unprecedented efficiencies at high luminances (i.e., 70.2 cd A^?1, 43.4 lm W^?1 at 10 000 cd m^?2). Moreover, a three‐color WOLED exhibits wide correlated color temperatures (10 690–2328 K), which is the first hybrid WOLED showing sunlight‐style emission. These findings will open a novel concept that blue AIE fluorophors are promising candidates to develop high‐performance hybrid WOLEDs, which have a bright prospect for the future displays and lightings.     

A spectrum-adjusted white organic light-emitting diode for the optimization of luminous efficiency and color rendering index

High luminous efficiency and high color rendering index (CRI) are both the foremost factors for white organic light-emitting diodes (WOLEDs) to serve as next generation solid-state lighting sources. In this paper, we show that both luminous efficiency and CRI can be improved by adjusting the green/red spectra of WOLEDs. With green emission spectra matching with the human photopic curve, the WOLEDs exhibit higher luminous efficiency and higher CRI. Theoretical calculation shows that by tuning the white emission spectra to maximally match with the human photopic curve, the luminous efficiency can be improved by 41.8% without altering the color coordinates, the color correlated temperature (CCT) and the external quantum efficiency (EQE) of the WOLEDs.     

彩色滤光片用光阻剂研究

彩色滤光片为液晶显示中的重要零组件,而光阻剂是彩色滤光片的关键材料,其性能好坏直接影响了彩色滤光片的性能,如色饱和度、色纯度、透过率和耐候性能。因此,光阻剂的制取技术是必须掌握的关键技术,而光阻剂的配方为其主要研究对象。本论文研究了光阻剂中分别增加环氧树脂和润湿剂对其性能的影响。