共查询到19条相似文献,搜索用时 171 毫秒
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砂生槐总碱水乳剂及微乳剂农药的研制 总被引:3,自引:0,他引:3
为了制备砂生槐生物碱乳剂和微乳剂农药,筛选了不同溶剂和助溶剂系统,考察了亲脂性总碱在不同溶剂系统下的增溶作用。在乳剂配置的基础上,通过绘制生物碱原油-混合表面活性剂-水的拟三元相图,筛选出助表面活性剂乙醇,当Km值(助乳化剂和乳化剂的质量比值)为1:1时有较大微乳区形成。所形成的微乳经过测定是O/W型微乳性质稳定,浊点在57℃。通过论文数据可以指导配置不同质量浓度的砂生槐生物碱乳剂和微乳剂农药。 相似文献
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聚醚型非离子表面活性剂的浊点及其影响因素 总被引:1,自引:0,他引:1
总结了非离子表面活性剂浓度、外加聚合物、离子表面活性剂、无机电解质、助表面活性剂等对聚醚型非离子表面活性剂水溶液浊点的影响规律 ,发现聚合物由于其结构和分子量不同对浊点的影响也不同 ,一般可使浊点降低 ;加入离子表面活性剂可以和非离子表面活性剂形成混合胶束 ,从而使浊点升高 ;无机盐由于存在盐析和盐溶两种不同效应而对浊点的影响比较复杂 ;醇和有机酸等助表面活性剂根据其碳链的长短不同而影响浊点。这些规律对非离子表面活性剂的研究和应用有一定的指导意义。 相似文献
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采用单因素试验法初选出10%辛硫磷微乳剂的适宜表面活性剂组份,再通过正交试验法以浊点为主要考察指标对复配表面活性剂的用量、配比、助表面活性剂用量进行了筛选和优化,确定了该微乳体系中最佳表面活性剂组分及其含量:农乳1602#+宁乳33#为9%,农乳500#为5%、乙醇5%及消泡剂0.2%。研究结果表明:应用正交试验法可快速筛选出适量的表面活性剂及助表面活性剂,获得性能优异的微乳剂配方,并可降低配方成本。 相似文献
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农药微乳剂及其浊点问题的探讨和初步研究 总被引:17,自引:9,他引:8
浊点是以非离子表面活性剂为主要组分的微孔剂剂型的特性与质量技术指标之一。其浊点高低主要解决于原药性质及所含表面活性剂的种类和用量,配制微乳剂通常应该选择浊点高的非离子表面活性剂,对一般微乳剂的浊点指标建议定为≥54℃。 相似文献
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Cloud point studies on aqueous solutions of a polyethylene oxide (PEO)-polypropylene oxide-PEO triblock copolymer (Pluronic® L64: EO13PO30EO13, total m.w.=2900, PEO=40%; EO=ethylene oxide; PO=propylene oxide) in the presence of different additives show some interesting features. The effect of various inorganic salts was an increase or decrease in cloud point based on their salting in and salting out action and followed the Hofmeister lyotropic series. Nonelectrolytes and hydrotropes increased the cloud point by influencing water structure. Hydrotropes altered the cloud point of the copolymer at much lower concentrations than inorganic salts. Ionic surfactants produced a marked increase in the cloud point of copolymer solutions. The effect was greater for surfactants with greater hydrophobicity. Alcohols and other organic liquid additives that are infinitely miscible with water increase the cloud point of the copolymer, whereas additives that are partially miscible in water decrease the cloud point. 相似文献
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Liangping Yu Inmok Lee Earl G. Hammond Lawrence A. Johnson Jon H. Van Gerpen 《Journal of the American Oil Chemists' Society》1998,75(12):1821-1824
The objective of this study was to determine the effect of various amounts of unsaponifiables and bound glycerol on the crystallization
temperatures of methyl soyate used as biodiesel. The preparation of methyl esters did not affect the amount of unsaponifiable
matter in biodiesel. A synthetic unsaponifiable mixture added to distilled methyl soyate and blends of methyl soyate and No.
1 diesel fuel (20:80, vol/vol) did not affect the crystallization onset temperature, cloud point, or pour point at concentrations
up to 3% by weight. The amounts of monoglycerides and diglycerides in methyl soyate decreased from 2.60 and 9.87%, respectively,
to 0% as the methanol/soybean oil ratio increased from 90 to 200% of the theoretical requirement. Transesterification reactions
conducted with less than 130% of the theoretical amount of methanol resulted in methyl soyate with a higher cloud point because
of the presence of saturated mono- and diglycerides. Pure mono- and diglycerides added to distilled methyl soyate at 0 to
1.0% did not change the pour point of the esters, but the cloud point of esters increased with increasing amount of saturated
mono- or diglyceride. Pure saturated mono- or diglyceride presented in concentrations as low as 0.1% increased the cloud point
of methyl soyate. Similar results were obtained with mono- and diglyceride mixtures present in incompletely converted methyl
soyate. 相似文献
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Hirokazu Okamura Tomomi Maruyama Seizo Masuda Keiji Minagawa Takeshi Mori Masami Tanaka 《Journal of Polymer Research》2002,9(1):17-21
The thermosensitive properties of aqueous poly(methyl 2-acetamidoacrylate) (PMAA) solutions were investigated in the absence or presence of sodium sulfate. Poly(methyl 2-acetamidoacrylate) with a molecular weight of 23,000 (PMAA-1) exhibited the cloud point. On heating the PMAA-1 solution, the transmittance began to decrease from near 34°C and increased again after the minimum value was shown at 36.0°C. The minimum transmittance increased linearly with an increasing concentration of the polymer although the minimum-transmittance temperature did not depend on polymer concentration. The minimum transmittance was affected by the pH and the 1-butanol added. This finding suggests that the cloudiness is controlled by a delicate balance of hydrophilicity and hydrophobicity and by intra- and/or inter-molecular hydrogen bonding. Poly(methyl 2-acetamidoacrylate) with a molecular weight of 15,000 (PMAA-2) did not exhibit cloudiness in distilled water. However, the addition of sodium sulfate caused cloudiness to appear. The cloud point of a PMAA-2 solution depended on concentrations of polymer and salt added. It decreased with an increase in polymer and salt concentrations. The salting-out constants were determined from the relationship between the cloud point and concentrations of polymer and salt. 相似文献
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Cloud and pour points in fuel blends 总被引:1,自引:0,他引:1
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Phase behavior data are presented for poly(methyl methacrylate) (PMMA: Mw= 15,000, 120,000) in supercritical solvent mixtures of carbon dioxide (CO2) and chlorodifluoromethane (HCFC-22). Experimental cloud point curves, which were the phase boundaries between single and
liquid-liquid phases, were measured by using a high-pressure equilibrium apparatus equipped with a variable-volume view cell
at various CO2 compositions up to about 63 wt% (on a polymer-free basis) and at temperatures up to about 100 °C. The cloud point curves
exhibited the characteristics of a lower critical solution temperature phase behavior. As the CO2 content in the solvent mixture increased, the cloud point pressure at a fixed temperature increased significantly. Addition
of CO2 to HCFC-22 caused a lowering of the dissolving power of the mixed solvent due to the decrease of the solvent polarity. The
cloud point pressure increased with increasing the molecular weight of PMMA. 相似文献
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Hans Schott 《Journal of the American Oil Chemists' Society》1988,65(10):1658-1663
The effect of electrolytes and other additives on the foaming of solutions of the nonionic surfactant octoxynol 9 (Triton
X-100) was investigated and correlated with their effect on the cloud point. Foams were generated by pouring solutions as
a thin stream into a vertical tube. The height of the generally fast-draining foam columns was measured as a function of time,
and their stability was rated according to the damage sustained within 13 min. The surfactant concentrations used, 0.050,
0.100 and 2.00%, were above the critical micelle concentration. Increasing concentrations increased foam height but not foam
stability.
The electrolytes NaCl and Na2SO4 salted the surfactant out. They reduced its cloud point in proportion to their concentration. They also reduced the foam
height, albeit to a lesser extent than the cloud point, but hardly reduced the foam stability below the cloud point. 相似文献
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Malik Abdul Rub Abdullah M. Asiri Dileep Kumar Anish Khan Aftab Aslam Parwaz Khan Naved Azum Kabir-ud-Din 《Journal of surfactants and detergents》2012,15(6):765-775
The effect of various organic additives, viz. sugars, ureas, alcohols, hydrotropes and bile salts on the clouding (phase separation) phenomenon of the amphiphilic antidepressant drug amitriptyline hydrochloride was investigated in the present study. All sugars lowered the cloud point (CP) due to their water structure-making property. Urea and alkylureas were found to lower the CP. In contrast, thioureas increased the CP slightly, but the presence of methyl group(s) had a similar effect in alkylureas. Short chain alcohols affected the CP insignificantly while higher ones decreased it, and medium chain alcohols showed peak behavior. Addition of hydrotropes and bile salts increased the CP at lower concentrations, while a decrease was observed at higher concentrations (like the medium chain alcohols). In addition, thermodynamic parameters were also evaluated but only for those additives which formed mixed micelles with the drug. 相似文献
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Nanocomposites of blends of PMMA and poly(styrene‐co‐acrylonitrile) (SAN) with natural (PM) or organically modified montmorillonite clays (Cloisite 30B, 25A, and 15A) were prepared by solution mixing and the effect of clay on the phase separation behavior along with morphologies of nanocomposites was investigated. Nanocomposites containing clay C30B prepared from methyl ethyl ketone showed the noticeable decrease in the cloud points. None of the other nanocomposites showed the increase in the cloud point. Location of clay particles in the phase separated matrix is observed to be different depending on the type of clays and solvents. The lowest cloud point of nanocomposites containing C30B may arise from the good dispersion of C30B where Clay C30B may act as the nucleating agent inducing phase separation. Dynamic mechanical and thermal analyses support above observations. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献