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系统研究了油页岩渣合成沸石过程中NaOH浓度、熔融温度、晶化时间、晶化温度对沸石生成及其Cr6+吸附性能的影响. 结果表明,NaOH浓度和晶化时间主要影响沸石的种类;沸石对Cr6+的吸附率随其制备的熔融温度、晶化时间、晶化温度的增加有增大的趋势,但随NaOH浓度降低而增加;沸石对1 mg/L含铬模拟废水中Cr6+的最大吸附量为1.120 mg/g,吸附率达到89.6%. 考虑到成本,最佳合成条件为:NaOH浓度4.6 mol/L,熔融温度400℃,晶化时间72 h,晶化温度140℃. 相似文献
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主要研究了载银树脂的制备工艺及静态吸附过程中银的行为。本文通过静态吸附实验,对载银树脂制备过程中引入添加剂锌或铜条件下的工艺条件,吸附性能,反应动力学、热力学进行了探讨。分阶段进行吸附工艺:选用001×7树脂作为载体,温度为25℃,溶液浓度为0.020 mol/L,吸附至平衡;选用锌或铜为添加剂,换取吸附溶液,通过对时间、温度及添加剂浓度的影响,分析银吸附及解吸行为,并为选择较佳的工艺条件和参数做理论基础。 相似文献
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以稻壳为原料,ZnCl2-CuCl2为复合活化剂,制备稻壳活性炭,并以BET比表面积和吸附性能为指标,通过正交试验对制备的工艺条件进行优化,并对制得的稻壳活性炭采用氮气吸附等温线、X射线衍射仪(XRD)表征。结果表明,稻壳可以被制得大比表面积活性炭。影响活性炭比表面积和吸附性能最重要的因素是氯化锌浓度和活化温度,最佳制备工艺条件是氯化锌浓度5 mol/L,氯化铜浓度 0.4 mol/L,活化温度500 ℃,活化时间2 h。该条件下制得的稻壳活性炭比表面积为1 924 m2/g,碘吸附值为1 041 mg/g,亚甲基蓝吸附值为 188 mg/g。 相似文献
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树脂吸附法回收焦化废水中的酚 总被引:7,自引:0,他引:7
通过静态吸附实验确定处理焦化废水中酚的最佳吸附树脂是NDA-99超高交联吸附树脂,并通过动态实验确定了树脂吸附法处理焦化废水中酚的最佳工艺条件是:pH为4.0,吸附流量为40mL/h,单柱废水处理量为300mL/批;在50℃下用10mL质量分数为8%的NaOH 10mL质量分数为4%的NaOH 20mL水脱附,流量为10mL/h;处理后废水中挥发酚质量浓度从1380mg/L降到12mg/L,COD从15500mg/L降到650mg/L。低浓度脱附液套用,高浓度脱附液用异丙醚萃取—蒸馏法回收杂酚,实现了焦化废水中酚的资源化。 相似文献
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M. S. J. Simmonds W. M. Blaney F. Delle Monache M. Marquina Mac-Quhae G. B. Marini Bettolo 《Journal of chemical ecology》1985,11(12):1593-1599
Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria. 相似文献
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Cheng-Le Zhao Shane Porzio Alan Smith Haiyan Ge H. T. Davis L. E. Scriven 《Journal of Coatings Technology and Research》2006,3(2):109-115
Despite its industrial importance, the subject of freeze-thaw (F/T) stability of latex coatings has not been studied extensively.
There is also a lack of fundamental understanding about the process and the mechanisms through which a coating becomes destabilized.
High pressure (2100 bar) freezing fixes the state of water-suspended particles of polymer binder and inorganic pigments without
the growth of ice crystals during freezing that produce artifacts in direct imaging scanning electron microscopy (SEM) of
fracture surfaces of frozen coatings. We show that by incorporating copolymerizable functional monomers, it is possible to
achieve F/T stability in polymer latexes and in low-VOC paints, as judged by the microstructures revealed by the cryogenic
SEM technique. Particle coalescence as well as pigment segregation in F/T unstable systems are visualized. In order to achieve
F/T stability in paints, latex particles must not flocculate and should provide protection to inorganic pigment and extender
particles. Because of the unique capabilities of the cryogenic SEM, we are able to separate the effects of freezing and thawing,
and study the influence of the rate of freezing and thawing on F/T stability. Destabilization can be caused by either freezing
or thawing. A slow freezing process is more detrimental to F/T stability than a fast freezing process; the latter actually
preserves suspension stability during freezing.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004 in Chicago,
IL. Tied for first place in The John A. Gordon Best Paper Competition. 相似文献
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Ethanol and (−)-α-Pinene: Attractant Kairomones for Bark and Ambrosia Beetles in the Southeastern US
In 2002–2004, we examined the flight responses of 49 species of native and exotic bark and ambrosia beetles (Coleoptera: Scolytidae
and Platypodidae) to traps baited with ethanol and/or (−)-α-pinene in the southeastern US. Eight field trials were conducted
in mature pine stands in Alabama, Florida, Georgia, North Carolina, and South Carolina. Funnel traps baited with ethanol lures
(release rate, about 0.6 g/day at 25–28°C) were attractive to ten species of ambrosia beetles (Ambrosiodmus tachygraphus, Anisandrus sayi, Dryoxylon onoharaensum, Monarthrum mali, Xyleborinus saxesenii, Xyleborus affinis, Xyleborus ferrugineus, Xylosandrus compactus, Xylosandrus crassiusculus, and Xylosandrus germanus) and two species of bark beetles (Cryptocarenus heveae and Hypothenemus sp.). Traps baited with (−)-α-pinene lures (release rate, 2–6 g/day at 25–28°C) were attractive to five bark beetle species
(Dendroctonus terebrans, Hylastes porculus, Hylastes salebrosus, Hylastes tenuis, and Ips grandicollis) and one platypodid ambrosia beetle species (Myoplatypus flavicornis). Ethanol enhanced responses of some species (Xyleborus pubescens, H. porculus, H. salebrosus, H. tenuis, and Pityophthorus cariniceps) to traps baited with (−)-α-pinene in some locations. (−)-α-Pinene interrupted the response of some ambrosia beetle species
to traps baited with ethanol, but only the response of D. onoharaensum was interrupted consistently at most locations. Of 23 species of ambrosia beetles captured in our field trials, nine were
exotic and accounted for 70–97% of total catches of ambrosia beetles. Our results provide support for the continued use of
separate traps baited with ethanol alone and ethanol with (−)-α-pinene to detect and monitor common bark and ambrosia beetles
from the southeastern region of the US. 相似文献
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It is well established that a wide range of drugs of abuse acutely boost the signaling of the sympathetic nervous system and the hypothalamic–pituitary–adrenal (HPA) axis, where norepinephrine and epinephrine are major output molecules. This stimulatory effect is accompanied by such symptoms as elevated heart rate and blood pressure, more rapid breathing, increased body temperature and sweating, and pupillary dilation, as well as the intoxicating or euphoric subjective properties of the drug. While many drugs of abuse are thought to achieve their intoxicating effects by modulating the monoaminergic neurotransmitter systems (i.e., serotonin, norepinephrine, dopamine) by binding to these receptors or otherwise affecting their synaptic signaling, this paper puts forth the hypothesis that many of these drugs are actually acutely converted to catecholamines (dopamine, norepinephrine, epinephrine) in vivo, in addition to transformation to their known metabolites. In this manner, a range of stimulants, opioids, and psychedelics (as well as alcohol) may partially achieve their intoxicating properties, as well as side effects, due to this putative transformation to catecholamines. If this hypothesis is correct, it would alter our understanding of the basic biosynthetic pathways for generating these important signaling molecules, while also modifying our view of the neural substrates underlying substance abuse and dependence, including psychological stress-induced relapse. Importantly, there is a direct way to test the overarching hypothesis: administer (either centrally or peripherally) stable isotope versions of these drugs to model organisms such as rodents (or even to humans) and then use liquid chromatography-mass spectrometry to determine if the labeled drug is converted to labeled catecholamines in brain, blood plasma, or urine samples. 相似文献
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Peter A. Edwards Grant Striemer Dean C. Webster 《Journal of Coatings Technology and Research》2005,2(7):517-527
Glycidyl carbamate chemistry combines the excellent properties of polyurethanes with the crosslinking chemistry of epoxy resins.
Glycidyl carbamate functional oligomers were synthesized by the reaction of polyfunctional isocyanate oligomers and glycidol.
The oligomers were formulated into coatings with several amine functional crosslinkers at varying stoichiometric ratios and
cured at different temperatures. Properties such as solvent resistance, hardness, and impact resistance were dependent on
the composition and cure conditions. Most coatings had an excellent combination of properties. Studies were carried out to
determine the kinetics of the curing reaction of the glycidyl carbamate functional oligomers with multifunctional and model
amines. Detailed kinetic analysis of the curing reactions was also undertaken. The results indicated that the glycidyl carbamate
functional group is more reactive than a glycidyl ether group.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, on October 27–29, 2004, in Chicago,
IL. 相似文献