复合材料层合板静压痕试验及全过程数值分析

复合材料层合板在静压痕力作用下主要发生层间分层、基体开裂、基体压缩破坏、纤维断裂和纤维压坏这几种损伤模式。本文利用ABAQUS有限元程序,对在静压痕力作用下的复合材料层合板建立一个基于Hashin强度准则的全过程模型,并对各层各单元进行损伤演判。利用有限元模型对碳纤维NCF材料层合板在静压痕力作用下的荷载-位移曲线进行预测,并模拟层合板的损伤全过程,以及预测凹坑深度与静压痕力的关系曲线。对层合板进行静压痕试验,测试复合材料层合板在静压痕力作用下的荷载-位移曲线,并在试验过程中用凹坑深度仪测量层合板的凹坑深度。将数值模拟与试验结果比较,两者结果较为吻合。     

准静态压痕作用下复合材料层合板损伤阻抗与损伤容限实验研究

参照标准实验方法,开展了复合材料层合板对准静态压痕力的损伤阻抗和损伤容限实验研究,获取了接触力、压痕深度、压头位移等实验数据,并对含静压痕损伤层合板进行了剩余压缩强度试验。研究了压痕深度-接触力与剩余压缩强度-压痕深度的变化关系,并讨论了准静态压痕过程中的损伤演变过程和层合板的压缩破坏模式。结果表明:当层合板表面出现目视勉强可见压痕时,初始损伤发生,压痕深度随接触力增大而明显增大,同时剩余压缩强度随压痕深度增加而明显降低;当达到最大接触力时,层合板失去承载能力,背面可看到大量纤维断裂。对于含静压痕损伤的层合板,压缩破坏模式为贯穿损伤区域的层合板断裂。     

复合材料层合板损伤区域扩展全过程分析

对碳纤维NCF层合板进行了2组准静态压痕试验。第1组采用不同的压头尺寸探究不同压头直径对层合板损伤区域和面积的影响;第2组进行固定压头尺寸的重复试验,使用非接触空气耦合超声波扫描试样损伤情况,研究静压痕力、凹坑深度、损伤面积三者之间的联系。利用Abaqus有限元软件,根据Hashin准则和内聚力单元的结合,对第2组层合板准静态压痕试验进行全过程的损伤扩展分析。分析结果表明,基体拉伸的破坏是层合板最容易出现的破坏,而且其损伤区域涵盖了其他4种损伤区域。凹坑深度与损伤面积存在一定联系,试验开始阶段凹坑增加速度缓慢,损伤面积增加速度较快;接近极限载荷时,凹坑深度增加速度加快,损伤面积增加速度减缓。     

纤维复合材料层合板在四点弯曲载荷下的损伤分析

实验测试了T300/7901碳纤维复合材料[0/90]_(8s)层合板在四点弯曲静载下的载荷-位移响应及破坏载荷。基于桥联模型,在商用软件Abaqus/CAE中实现对该层合板在四点弯曲静载条件下的层内以及层间损伤破坏进行模拟分析。分析方法分为四个部分:仅利用组分材料数据,基于桥联模型对单向复合材料层的本构关系建模;利用考虑三维应力的Hashin判据预报复合材料层的纤维拉伸、压缩损伤及基体拉伸、压缩损伤;出现组分材料损伤后对相应材料点采用Camando方法进行刚度退化;在复合材料单层中间插入薄的纯树脂层,通过树脂层的损伤破坏分析层间分层。在Abaqus/Explicit模块中,利用子程序VUMAT完成以上材料建模分析;将模拟结果与实验数据进行对比。结果表明,模拟得到的载荷-位移曲线及破坏载荷与实验结果吻合很好,所提出的材料模型能有效预报纤维复合材料层合板的层内及层间损伤破坏情况。     

复合材料层合板低速冲击后的力学性能试验研究

对特定铺层的5224/CF3052平纹织物复合材料层合板进行了低速冲击和冲击后拉伸、压缩及弯曲试验。探讨了层合板在冲击试验过程中的损伤过程、特征和机理;分析了凹坑深度对层合板冲击后拉伸、压缩和弯曲强度的影响规律。结果表明:冲击后拉伸、压缩及弯曲强度降幅分别为60.9%、50.4%及28.4%,冲击后拉伸强度降幅最大,应引起注意。与冲击后压缩试验结果类似,凹坑深度与冲击后拉伸、弯曲剩余强度关系曲线存在拐点现象。     

基于拉伸载荷的碳纤维/环氧树脂层合板疲劳断裂机理

为研究拉伸载荷下碳纤维/环氧树脂层合板的疲劳性能，开展了4种应力水平下的T300/6511碳纤维平纹织物层合板的拉-拉疲劳实验，得到了不同应力水平下层合板的疲劳寿命。采用超声波C扫和扫描电子显微镜（SEM）观察断口形貌及内部损伤，讨论复合材料疲劳损伤发展积累过程和断裂机理。通过复合材料疲劳有限元分析模型，模拟了复合材料织物层合板疲劳损伤积累和失效过程，绘制了S-lg N曲线，分析发现模型预测的疲劳寿命及失效模式与实验结果吻合良好。疲劳加载时，层合板两侧自由边的表面首先出现基体开裂和分层损伤，随后诱发基体与纤维间界面破坏，损伤加剧，并迅速向内侧扩展；最后大量纤维和基体断裂，损伤贯穿整个截面，导致疲劳断裂。     

基于Zinoviev理论的含孔复合材料层合板三维有限元渐进失效分析

建立了含孔复合材料层合板的三维有限元模型,以二维Zinovie理论为基础,结合改进的三维Hashin准则,对二维Zinoviev理论进行了简化和拓展,提出了适用于三维模型的刚度退化方案,完成了对层合板的渐进失效分析。从纤维失效、基体失效、分层失效三个方面讨论了层合板在拉伸载荷作用下的失效过程,并预测了层合板的拉伸极限强度及破坏模式。数值模拟结果与试验基本吻合,验证了所提出退化模型的正确性。     

复合材料层合板冲击损伤剩余强度分析

民用飞机复合材料结构设计时必须考虑复合材料层合板的冲击损伤。通过试验测量和数值模拟两种方法分析碳纤维增强复合材料层合板低速冲击损伤后的剩余压缩强度,试验采用标准试验规范进行测量,数值模拟分析采用层内渐进损伤模型和层间Cohesive模型模拟分析层合板冲击损伤以及剩余压缩强度。数值模拟与试验结果对比表明,该数值模拟分析方法的有效性,为民用飞机复合材料结构设计时预测和计算复合材料层合板的剩余强度提供方法。     

胶接碳纤维复合材料层合板拉伸性能及有限元模拟

使用自动铺带工艺制得胶接的碳纤维复合材料层压板试验件,通过轴向拉伸测试,测得了整个试验件的载荷-位移曲线和检测点附近的应变-载荷曲线。试验结果表明,在拉伸载荷作用下试件发生层间剪切破坏,由于胶层的剪切强度高于层合板的层间剪切强度,破坏并没有发生在胶接面内,而是发生在胶层以外的层合板的层间。建立了相应的有限元模型,模拟结果和试验结果的一致说明了有限元模型的合理性。     

盐雾环境对玻璃纤维-铝合金层合板力学性能的影响

通过研究玻璃纤维-铝合金层合板在盐雾环境下不同老化周期后的力学性能及复合材料层红外光谱,分析了层合板在盐雾老化条件下的性能变化。在加速盐雾老化条件下,树脂基体发生了降解,树脂-纤维界面及表面铝合金发生腐蚀破坏,随老化时间的延长,0°及90°层合板的拉伸、压缩及面内剪切强度均呈现出明显的下降趋势,90°层合板内部受到的损伤更为严重,盐雾环境会降低层合板内热固性树脂基体的交联程度,并破坏树脂-纤维及树脂-铝合金的界面,影响应力在玻璃纤维-铝合金层合板层间的传递,使材料力学性能发生衰减。     

Many Drugs of Abuse May Be Acutely Transformed to Dopamine,Norepinephrine and Epinephrine In Vivo

It is well established that a wide range of drugs of abuse acutely boost the signaling of the sympathetic nervous system and the hypothalamic–pituitary–adrenal (HPA) axis, where norepinephrine and epinephrine are major output molecules. This stimulatory effect is accompanied by such symptoms as elevated heart rate and blood pressure, more rapid breathing, increased body temperature and sweating, and pupillary dilation, as well as the intoxicating or euphoric subjective properties of the drug. While many drugs of abuse are thought to achieve their intoxicating effects by modulating the monoaminergic neurotransmitter systems (i.e., serotonin, norepinephrine, dopamine) by binding to these receptors or otherwise affecting their synaptic signaling, this paper puts forth the hypothesis that many of these drugs are actually acutely converted to catecholamines (dopamine, norepinephrine, epinephrine) in vivo, in addition to transformation to their known metabolites. In this manner, a range of stimulants, opioids, and psychedelics (as well as alcohol) may partially achieve their intoxicating properties, as well as side effects, due to this putative transformation to catecholamines. If this hypothesis is correct, it would alter our understanding of the basic biosynthetic pathways for generating these important signaling molecules, while also modifying our view of the neural substrates underlying substance abuse and dependence, including psychological stress-induced relapse. Importantly, there is a direct way to test the overarching hypothesis: administer (either centrally or peripherally) stable isotope versions of these drugs to model organisms such as rodents (or even to humans) and then use liquid chromatography-mass spectrometry to determine if the labeled drug is converted to labeled catecholamines in brain, blood plasma, or urine samples.     

Sapindaceae,cyanolipids, and bugs

Scentless plant bugs (Heteroptera: Rhopalidae) are so named because adults of the Serinethinae have vestigial metathoracic scent glands. Serinethines are seed predators of Sapindales, especially Sapindaceae that produce toxic cyanolipids. In two serinethine species whose ranges extend into the southern United States,Jadera haematoloma andJ. sanguinolenta, sequestration of host cyanolipids as glucosides renders these gregarious, aposematic insects unpalatable to a variety of predators. The blood glucoside profile and cyanogenesis ofJadera varies depending on the cyanolipid chemistry of hosts, and adults and larvae fed golden rain tree seeds (Koelreuteria paniculata) excrete the volatile lactone, 4-methyl-2(5H)-furanone, to which they are attracted.Jadera fed balloon vine seeds (Cardiospermum spp.) do not excrete the attractive lactone. Loss of the usual heteropteran defensive glands in serinethines may have coevolved with host specificity on toxic plants, and the orientation ofJadera to a volatile excretory product could be an adaptive response to save time.Mention of a commercial product does not consititute an endorsement by the USDA.     

Insect antifeedant properties of anthranoids from the genusVismia

Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria.     

Direct observation of freeze-thaw instability of latex coatings via high pressure freezing and cryogenic SEM

Despite its industrial importance, the subject of freeze-thaw (F/T) stability of latex coatings has not been studied extensively. There is also a lack of fundamental understanding about the process and the mechanisms through which a coating becomes destabilized. High pressure (2100 bar) freezing fixes the state of water-suspended particles of polymer binder and inorganic pigments without the growth of ice crystals during freezing that produce artifacts in direct imaging scanning electron microscopy (SEM) of fracture surfaces of frozen coatings. We show that by incorporating copolymerizable functional monomers, it is possible to achieve F/T stability in polymer latexes and in low-VOC paints, as judged by the microstructures revealed by the cryogenic SEM technique. Particle coalescence as well as pigment segregation in F/T unstable systems are visualized. In order to achieve F/T stability in paints, latex particles must not flocculate and should provide protection to inorganic pigment and extender particles. Because of the unique capabilities of the cryogenic SEM, we are able to separate the effects of freezing and thawing, and study the influence of the rate of freezing and thawing on F/T stability. Destabilization can be caused by either freezing or thawing. A slow freezing process is more detrimental to F/T stability than a fast freezing process; the latter actually preserves suspension stability during freezing. Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004 in Chicago, IL. Tied for first place in The John A. Gordon Best Paper Competition.     

Ethanol and (−)-α-Pinene: Attractant Kairomones for Bark and Ambrosia Beetles in the Southeastern US

In 2002–2004, we examined the flight responses of 49 species of native and exotic bark and ambrosia beetles (Coleoptera: Scolytidae and Platypodidae) to traps baited with ethanol and/or (−)-α-pinene in the southeastern US. Eight field trials were conducted in mature pine stands in Alabama, Florida, Georgia, North Carolina, and South Carolina. Funnel traps baited with ethanol lures (release rate, about 0.6 g/day at 25–28°C) were attractive to ten species of ambrosia beetles (Ambrosiodmus tachygraphus, Anisandrus sayi, Dryoxylon onoharaensum, Monarthrum mali, Xyleborinus saxesenii, Xyleborus affinis, Xyleborus ferrugineus, Xylosandrus compactus, Xylosandrus crassiusculus, and Xylosandrus germanus) and two species of bark beetles (Cryptocarenus heveae and Hypothenemus sp.). Traps baited with (−)-α-pinene lures (release rate, 2–6 g/day at 25–28°C) were attractive to five bark beetle species (Dendroctonus terebrans, Hylastes porculus, Hylastes salebrosus, Hylastes tenuis, and Ips grandicollis) and one platypodid ambrosia beetle species (Myoplatypus flavicornis). Ethanol enhanced responses of some species (Xyleborus pubescens, H. porculus, H. salebrosus, H. tenuis, and Pityophthorus cariniceps) to traps baited with (−)-α-pinene in some locations. (−)-α-Pinene interrupted the response of some ambrosia beetle species to traps baited with ethanol, but only the response of D. onoharaensum was interrupted consistently at most locations. Of 23 species of ambrosia beetles captured in our field trials, nine were exotic and accounted for 70–97% of total catches of ambrosia beetles. Our results provide support for the continued use of separate traps baited with ethanol alone and ethanol with (−)-α-pinene to detect and monitor common bark and ambrosia beetles from the southeastern region of the US.     

2008～2009年世界塑料工业进展

收集了2008年7月～2009年6月世界塑料工业的相关资料,介绍了2008～2009年国外塑料工业的发展情况,提供了世界塑料产量、消费量及全球各类树脂的需求量及产能情况。按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(尼龙、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、特种工程塑料(聚苯硫醚、液晶聚合物、聚醚醚酮)、通用热固性树脂(酚醛、聚氨酯、环氧树脂、不饱和聚酯树脂)不同品种的顺序,对树脂的产量、消费量、供需状况及合成工艺、产品应用开发、树脂品种的延伸及应用的进一步扩展等技术作了详细介绍。     

ICP-MS法测定地球化学样品中As、Cr、Ge、V等18种微量痕量元素的研究

建立了测定地球化学样品中包括As、Cr、Ge、V等18种微量、痕量元素的ICP-MS方法。地化试样用HF-HNO3混酸分解后,以1 1 HNO3溶解干渣。由于制样不使用盐酸,避免了Cl对As、Cr、Ge、V的质谱干扰。用国家一级地球化学标准物质GBW 07309制备溶液优化仪器工作参数,并用于校准。方法测定限(6s)为:0.007~6.4μg/g,精密度(RSD%,n=12)为:29%~9.4%,经过国家一级地球化学标准物质的分析验证,结果与标准值吻合。方法已应用于国土资源调查的试样分析。