脉动压力诱导注射成型充模过程熔体表观黏度的实时测量

以脉动压力诱导注射成型充模过程浇口流道中熔体壁面表观剪切黏度的数学模型为基础,通过实时测量记录螺杆位置变化以及浇口流道两端熔体压力变化,表征脉动压力诱导注射成型充模过程熔体实时表现剪切黏度的方法,通过实验研究发现,脉动压力的引入使充模过程、熔体的剪切应力和表观剪切黏度降低,同时加剧了熔体的剪切速率变化,在强烈的振动条件下会引起动态充模过程中某些时刻出现断流现象.     

中心浇口圆盘模腔正弦脉动充模分析

聚合物动态注射成型通过螺杆的轴向振动实现熔体脉动充模。利用Tanner本构模型建立了中心浇口圆盘模腔正弦脉动充模过程的数学模型,分析了振动参数对注射压力及熔体输送功率的影响。当充模过程的平均注射速率不变时,在一定频率与振幅范围内,模腔入口处的压力随振动源振幅(频率)的增大而增大,但其平均值降低;充模过程中输送熔体所需要的功率降低。     

振动力场影响模腔压力的实验研究

介绍了立式液压振动注射机的工作原理。在立式液压振动注射机上进行振动参数不同的注射成型实验，制取线性低密度聚乙烯(LLDPE)圆盘试样。利用自制的压力传感器及数据采集系统对脉动压力注射过程中的充模压力进行实时采集。实验结果表明，充模压力的波动频率与柱塞杆的振动频率相同；随着柱塞杆振动频率、振幅的增大，充模压力的波动幅度增大，平均充模压力也增大，模腔最大压力也增大。     

螺杆轴向振动对熔体注射过程能耗的影响

研究了螺杆轴向振动对熔体注射过程中各个阶段能耗的影响,建立了振动力场作用下熔体流经圆锥形浇口流道和圆盘充模的物理模型和数学模型,并求得上述两个过程中功耗的解析式;通过实验验证了振动力场的引入使得注射过程能耗减小,在振动强度系数达到0．45以后,注射过程功耗减小的趋势更明显。     

振动力场下螺旋芯棒式管材机头内熔体流动的数值模拟

为了研究振动力场作用下螺旋芯棒式管材机头内熔体的流动特性,考虑非定常流动,使用Polyflow软件首次对熔体的流场进行了全三维非牛顿等温数值模拟。研究表明,随着振动力场的引入,流道内熔体的剪切速率、黏度、剪切应力、压力和速度等呈周期性规律变化。另一方面,随着振动频率或振幅的增加,流场的剪切速率平均值增加,而流场的黏度平均值、剪切应力平均值和压力平均值下降。     

脉动注射对螺线槽模腔熔体流动性能的影响

采用阿基米德螺线槽模具对脉动注射充模过程中聚合物熔体的流变行为进行了实验研究,分析了振动力场对聚合物熔体充模流动性及模腔不同位置聚合物熔体充模压力的影响。结果表明,振动力场的引入有利于降低聚合物熔体的表观粘度,改善熔体的流动性,减小熔体在充模过程的压力损失。这种效果尤其对表观粘度高的聚合物熔体更为明显。     

动态注射成型流道系统的压力脉动分析

研究了聚合物电磁动态注射成型过程中熔体在轴向振动力场作用下在圆柱形流道中的流动情况。从理论上分析了动态熔体流动过程,为研究聚合物熔体的动态充模过程提供流道系统压力降。得出在施加了轴向振动的情况下,熔体的压力梯度有明显的降低,并且随着振动强度的增强,降低的幅度加大。     

注射成型中模腔内振动剪切流动的理论模型

采用Ｌｅｏｎｏｖ本构模型,首次研究了在注射成型中模腔内聚合物熔体的振动剪切流动时所产生的振动剪切应力。结果表明,振动剪切应力的振幅随着聚合物熔体的粘度,振动频率和应变振幅的增加而增加,随着熔体温度的增加而减小。     

聚合物动态注射过程表观粘度的实时表征与分析

建立了模具锥形流道中熔体的动态表观粘度模型,通过实验的方法测得流道两端压力降,表征出动态充模过程流道中熔体的实际表观粘度。依靠实验及数据计算,检验此模型能够灵敏地定量反映外部加工条件对熔体表观粘度的影响。结果表明,在频率4Hz、振幅40μm时聚丙烯的注射充模表观粘度为最小,此模型的提出也为寻求其他聚合物动态注射时的最优振动加工参数组合提供了依据。     

微注塑充模过程中壁面滑移对熔体流动影响的研究*

针对微型塑料件注塑充模过程中,壁面滑移对流动的影响不可忽略的情况,运用流体分析软件Fluent,以微阶梯圆形截面通道为模型,在考虑和不考虑壁面滑移的情况下,对微注塑充模流动过程中壁面滑移的影响进行了数值模拟。分析了细通道近壁面处熔体的剪切速率和黏度,发现考虑壁面滑移时近壁面处的剪切速率略大,黏度略低。研究了熔体在粗通道和细通道中沿径向的流动速度和温度分布,以及沿微通道流动方向上的压力分布。结果表明,考虑壁面滑移时熔体流动速度较大,与壁面接触的熔体流动速度不再为零,且微通道截面尺寸越小,这种现象越明显;考虑壁面滑移时近壁面处熔体温度略高,并且粗通道中的这种现象更明显一些;壁面滑移对微通道中的压力分布几乎没有影响。总体而言,壁面滑移有利于微注塑充模。     

PP注射成型中的压力及熔体流动过程

讨论了聚丙烯在注射成型中充模、增密、保压、冷却各个阶段的压力变化情况和熔体流动过程，以及二者对制品成功质量的影响。认为在聚丙烯注射成型过程中，要保证制品成型质量，不应以升温的办法来降低熔体的粘度，而应以提高注塑压力和剪切速率为主。     

低频振动场中聚合物熔体的流变行为

介绍了自行研制的振动注射成型装置的结构及其用研究聚合物熔体流变行为的方法。通过对HDPE和PS的实验研究：发现熔体表观粘度与振动频率之间的关系表现为非线形关系,存在一最佳的振动频率使得处于振动场中的聚合物熔体在此频率下粘度最小;“频率－温度”等效原理可以用来加工热敏性聚合物,两者的综合作用在降低粘度、增加流动性方面会达到事半功倍的效果。     

Wall Slip of Linear Polymer Melts During Ultrasonic‐assisted Micro‐injection Molding

The wall slip of linear polymer melts under ultrasonic vibration is investigated by correcting the slip mechanism, and melt flow behaviors in ultrasonic‐assisted micro‐injection molding (UμIM) method are discussed. Based on the effect mechanism of ultrasonic vibration on the melt, theoretical models of the critical shear stresses for the onset of weak and strong wall slip during UμIM are established, and the change in rheological properties due to the onset of wall slip under ultrasonic vibration is experimental investigated by a built measurement system. The results show that the onset of weak and strong wall slip of the melt in micro cavity are promoted by ultrasonic vibration, which agree with the built theoretical models, and the melt filling capability in micro cavity is enhanced by reducing apparent viscosity and releasing shear stress of the polymer melt, which improves the molding quality of micro polymer parts via UμIM method. POLYM. ENG. SCI., 59:E7–E13, 2019. © 2018 Society of Plastics Engineers     

黏弹特性对模内微装配成型热流固耦合变形的影响

建立了综合考虑二次成型黏弹性熔体充填流动约束环境影响的模内微装配成型过程黏弹性热流固耦合变形机理的理论模型,并通过有限元数值模拟,研究了二次成型熔体黏度对模内微装配成型过程黏弹性热流固耦合变形的影响规律。结果表明,黏弹性热流固耦合作用诱导的预成型微型轴变形的驱动力来源于微装配界面形成的热流固耦合压力和黏性拖曳剪应力,而二次成型熔体流动的弹性正应力对耦合变形具有抑制作用,微装配界面的热流固耦合载荷和微型轴的变形均随着二次充填熔体的黏度增大而增大,减小二次成型熔体黏度有利于提高其微装配加工精度。     

注射成型过程中非牛顿塑料熔体的粘度模型

本文在探讨塑料熔体粘度模型基础上,重点讨论了一种适用范围更广的Cross粘度模型,并根据塑料熔体在注射成型过程的流动特点,采用Arrhenius方程建立了适用于注射充填过程的五参数Cross粘度模型和利用WLF方程建立起适用于注射保压过程的七参数Cross粘度模型。具体讨论模型的特征和适用范围,为注射模设计和成型模拟提供了理论依据。     

Application of the rheology of monodisperse and polydisperse polystyrenes to the analysis of injection molding behavior

Monodisperse and polydisperse polystyrenes of equal weight average molecular weight (M _w) are evaluated for melt flow behavior in an Instron capillary rheometer and for injection molding behavior in a 12 ounce in-line reciprocationg screw injection molding machine. The influence of molecular weight distribution on the shape of the flow curves is deconstrated over a wide range of shear rate and temperature. The influence is also reflected in injection molding behavior as defined by pressure to fill or flash the mold at a given melt temperature. Studies of capillary rheometer data for correlation with injection moling beghavior indicate poor agreement when low shear rate viscosity data are used. Good agrement is foun using high shear rate viscosity data in the range 10³ to 10⁴ sec^?1 Striking crossover points on melt rheology and injection colding area diagram curvs are found with the monodisperse and polydisperse polystyrenes of the same M These crossovers shift with melt temperature and make possible the determination of a “controlling shear rate” for the injection molding process. This is found to be 3500 sec^?1 for short shot and 6200 sec^?1 for flash with the ASTM test specimen mold used in this study.     

In situ flow state characterization of molten resin at the inner mold in injection molding

Online viscosity information on processing lines can reflect the material flow resistance and offer valuable guidance for manufacturing across various industries. Considering the accuracy, devices, and processes involved in injection molding, characterizing the melt's flow state during material processing poses a significant challenge. To reduce investment in viscometers, avoid influencing the components' surface aesthetics due to the installation of sensors, and make the flow state detect online in mold, this study designs a rheometric mold with cylindrical runners for identifying the in situ viscosity of molten resin during injection molding. The detection conditions of injection speed and cavity pressure variations, the entrance effect, and the viscous dissipation for Polycarbonate are analyzed under various conditions. The in situ viscosity is identified and compared with the standard cross-WLF model. The result shows that the melt velocity and cavity pressure variations during the filling process create a stable environment for in situ rheological characterization and the detected viscosity is related to the shear rate, melt temperature, and channel dimension in injection molding. The designed mold with cylindrical runners for determining the in situ thermal-rheological behavior of polymer is distinguished successfully and exhibits prospects for the development of low-cost, nondestructive, and inner-mold measurement in manufacturing applications.