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目的 研究高体分铝基复合材料无压浸渗近净形制备的可行性,分析近净形复合材料的微观组织和力学性能。方法 分别采用74 μm的碳化硅颗粒和5%(质量分数)的聚乙烯醇溶液作为增强相和黏结剂,通过模具冷压获得立方体陶瓷生坯,经干燥后加工成异形预制体,再经高温烧结脱胶处理,采用无压浸渗法制备高体分铝基复合材料近净形样品,并采用颗粒自然堆积方案制备复合材料对比样品。采用扫描电子显微镜、三点弯曲测试等手段对比分析复合材料的微观组织、力学性能和断口形貌。结果 基于无压浸渗法成功制备出具有特定外形结构的铝基复合材料,复合材料密度为2.93 g/cm3,弯曲强度为327 MPa,弹性模量为205 GPa,可达到自然堆积型复合材料弯曲强度的86.7%。碳化硅颗粒均为脆性解理断裂,说明颗粒和基体合金结合良好。结论 采用模压和烧结通用方法制备的异形陶瓷预制体可以实现特定外形结构铝基复合材料的无压浸渗近净形制备,近净形复合材料的弯曲强度可满足电子元器件的性能要求。 相似文献
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研究了SiC颗粒在1000~1200℃的氧化行为, 其氧化增重率与保温时间符合抛物线规律, 氧化增重受扩散过程控制, 氧化激活能为219 kJ/mol. 采用预氧化处理的SiC颗粒为增强体, 含Si、Mg的铝合金为基体, 通过无压浸渗方法制备了SiCp/Al复合材料, 分析了复合材料的微观组织与界面形貌, 探讨了无压浸渗机理. 复合材料中颗粒分布均匀, 无偏聚现象. 材料制备过程中存在界面反应, SiC颗粒表面的氧化层与铝合金中的Mg、Al反应形成了一定数量的MgAl2O4. 界面反应的存在提高了润湿性, 促进了无压自发浸渗. 相似文献
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熔融自发浸渗制备多孔陶瓷复合相变储能材料 总被引:1,自引:0,他引:1
研究了融盐Na2SO4与石英质多孔陶瓷预制体的自发熔融浸渗制备工艺,成功地制备出无机盐/陶瓷基(Na2SO4/SiO2)复合相变储能材料,观察和分析了该材料的物相组成与显微结构特征,对该材料的各项热物理性能和机械性能进行了测量.结果表明:自发熔融浸渗工艺比混合烧结工艺更适合于制备无机盐陶瓷基复合相变储能材料. 相似文献
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以3Y-TZP陶瓷为基体, 采用还原Fe粉包埋、高温浸渗的表面改性方法, 制备防静电性能与力学性能兼备的ZrO2陶瓷。研究了浸渗时间、浸渗温度对ZrO2陶瓷表面电阻率及硬度的影响, 结果表明:随着浸渗时间延长, 浸渗温度升高, 表面电阻率降低, 硬度下降。在1000℃浸渗4 h, ZrO2防静电陶瓷表面电阻率由1014 ?/□以上降低至8.3×107 ?/□, 硬度由12.7 GPa降低至11.23 GPa。采用XRD、SEM、XPS等方法对防静电ZrO2陶瓷的显微结构、化学组成及防静电机理进行了分析。结果表明, 浸渗过程中, 发生由t-ZrO2转变为m-ZrO2相变; Fe元素以Fe3O4、FeO、单质Fe的形式存在晶界处, 从而使ZrO2陶瓷具备了防静电性能。 相似文献
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Young -Wook Kim Jin -Soo Song Sang -Whan Park June -Gunn Lee 《Journal of Materials Science》1993,28(14):3866-3868
A new, faster process was developed for the fabrication of Nicalon-fibre-reinforced SiC composites by combining polymer solution infiltration (PSI) and chemical vapour infiltration (CVI). The process led to the near-net-shape fabrication of fibre-reinforced ceramic-matrix composites and reduced infiltration time. Typical flexural strength and fracture toughness of these composites were 296 MPa and 10.9 MPa m1/2 at room temperature (RT) and 252 MPa and 9.6 MPa m1/2 at 1000 °C, respectively. The composites exhibited load-carrying capability after crack initiation. 相似文献
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Honglei Wang Xingui Zhou Jinshan Yu Yingbin Cao Rongjun Liu 《Materials Letters》2010,64(15):1691-1693
Three-dimensional (3D) silicon carbide fiber reinforced silicon carbide matrix (SiCf/SiC) composites, employing KD-1 SiC fibers (from National University of Defense Technology, China) as reinforcements, were fabricated by a combining chemical vapor infiltration (CVI) and vapor silicon infiltration (VSI) process. The microstructure and properties of the as prepared SiCf/SiC composites were studied. The results show that the density and open porosity of the as prepared SiCf/SiC composites are 2.1 g/cm3 and 7.7%, respectively. The SiC fibers are not severely damaged during the VSI process. And the SiC fibers adhere to the matrix with a weak interface, therefore the SiCf/SiC composites exhibit non-catastrophic failure behavior with the flexural strength of 270 MPa, fracture toughness of 11.4 MPa·m1/2 and shear strength of 25.7 MPa at ambient conditions. Moreover, the flexural strength decreases sharply at the temperature higher than 1200 °C. In addition, the thermal conductivity is 10.6 W/mk at room temperature. 相似文献
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采用天然气为前躯体在不同压力下使用化学气相渗积法制备炭/炭复合材料。利用甲烷分解热力学与沉积动力学研究了渗积压力对渗积速率和热解炭组织结构的影响。采用偏光显微镜观察热解炭的组织结构。结果表明:随着渗积压力的增加,初始渗积速率增大;但在渗积后期,渗积速率随着渗积压力的增大而降低,导致在高渗积压力下相同时间制备样品的最终密度降低。热解炭组织结构对渗积压力具有很强的依赖性。在低压(1 kPa)下渗积得到的热解炭基体全部为粗糙层结构。在适中的压力(3kPa,5 kPa,10 kPa)下,以炭纤维为圆心由内到外依次得到各向同性和粗糙层热解炭,整个基体以粗糙层为主。在15 kPa下,得到的热解炭组织结构为各向同性和光滑层组织。 相似文献
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YingHu Dong RuiQing Zhang XinBo He ZhiGuo Ye XuanHui Qu 《Materials Science and Engineering: B》2012,177(17):1524-1530
The Ti-coated diamond/copper composites with near-net-shape are manufactured by pressurelessly infiltrating liquid copper into porous Ti-coated diamond preforms. The contact angle between diamond and copper, relative density, thermal conductivity (TC), coefficient of thermal expansion (CTE), leak rate and microstructure are evaluated and characterized. In addition, the numerical analysis of the pressureless infiltration kinetics is also discussed. The results indicate that the relative density, TC and CTE of composites are 99.3%, 385 Wm−1 k−1 and 3–8 × 10−6 K−1, respectively. It can meet heat-sink package requirement of high-power electronic devices as LED, insulated gate bipolar transistor (IGBT), etc. The liquid copper exhibits a turbulent flow with the Reynolds number in the range of 27.83–49.7. The porosity ? and the pressure drop Δp are the main influence factors controlling the velocity of liquid copper. Moreover, under vacuum condition of 8.7 × 10−3 Pa, the maximum theoretical infiltration length Lmax of Ti-coated diamond/copper composites is found to be 552 mm. 相似文献
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Partial infiltration of molten Al into three different open cell ceramic foams has been effected using pressure-assisted vacuum investment casting equipment. For the maximum pressure difference (only 0.25 MPa) up to 90% of the open porosity could be filled, but since the ceramic foams were found to contain closed pores, the resulting composite densities were low. A simple modelling approach accurately predicts the infiltration behaviour and enables the processing conditions and architecture of the preforms to be optimised in respect of the maximum infiltration pressure available from the processing equipment. 相似文献
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C/SiC-based composites were produced by infiltration of a woven carbon fabric preform with a polycarbosilane (PCS) solution. Progress of the infiltration process up to eight infiltrations was followed by density measurements, microscopy and mechanical testing. After six infiltration cycles, the density increase tended to a plateau. Dense deposition of the matrix on the outer surface sealed off the core of the composite, which hindered successive infiltrations. With further re-infiltration cycles, the development of the matrix and the degree of bonding between the fibre and matrix increased. There was also a transition in the failure mode of the composite, when tested in 3-point bending, from shear to plain brittle tensile failure, as the number of infiltrations increased. 相似文献
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Deuk Yong Lee 《Journal of Materials Science》2004,39(9):3141-3145
Spinel/zirconia-glass dental composites were prepared by melt infiltration to investigate the effect of zirconia addition on mechanical, optical properties and infiltration rate of the composites. The glass infiltration rate decreased with raising the zirconia content having a parabolic dependence of infiltration distance on time described by the Washburn equation due to the reduction in pore size. Although the optimum strength (308 MPa) of the spinel/zirconia-glass dental composite was observed when 20 wt% of zirconia was added, transmittance decreased with further increase in the zirconia content. 相似文献