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分光光度-低压离子色谱法测定Cu2+、Ni2+、Zn2+、Pb2+、Fe2+和Mn2+ 总被引:1,自引:1,他引:0
建立了分光光度-低压离子色谱法测定Cu2+、Ni2+、Zn2+、Pb2+、Fe2+和Mn2+6种重金属离子的分析方法.选用柠檬酸-草酸混合液作为洗脱体系进行梯度洗脱,将6种金属离子完全分离,柱后采用1-(2-吡啶偶氮)-2-萘酚(PAN)进行衍生反应,于波长560 nm处进行检测.6种离子的检出限分别为0.006、0.012、0.005、0.125、0.070、0.020 mg/L.该方法用于环境水样测定,结果与原子吸收法所测值基本吻合,分析结果令人满意. 相似文献
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添加助剂的过氧化氢漂白 总被引:2,自引:0,他引:2
麦草NaOHO2/NaOH两段蒸煮纸浆具有良好的可漂性,采用简单的酸处理H2O2漂白(AP)程序,仅用15%的H2O2可使漂白浆的白度达到74%~753%(ISO)。为了进一步提高麦草NaOHO2/NaOH两段蒸煮纸浆无氯漂白的效果,又进行了添加助剂的H2O2漂白试验。1试验部分漂白用浆为麦草NaOH预处理O2/NaOH蒸煮的氧碱浆,其白度为594%(ISO),卡伯值109,粘度827ml/g。漂白采用酸处理H2O2漂白(AP)程序,浆样先用H2SO4进行预处理,再进行H2O2漂白。酸处理在烧杯中进行,H2… 相似文献
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氯化钙用于高得率浆H2O2漂前预处理 总被引:2,自引:1,他引:2
研究了CaCl2用于高得率桦木浆H2O2漂前预处理的效果,并与DTPA、EDTA、H2SO4等预处理剂的预处理效果进行了比较。结果表明,CaCl,是一种优良的预处理剂。CaCl2预处理的适宜条件为:用量0.5%,pH值7,温度40℃,时间25min。 相似文献
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Yu-Jing Zhu Han-Tao Zhou Yong-Hua Hu Jian-Yang Tang Ming-Xing Su Yun-Ji Guo Qing-Xi Chen Bo Liu 《Food chemistry》2011
The inhibition kinetics of 2-phenylethanol, 2-phenylacetaldehyde and 2-phenylacetic acid on the enzyme activity of mushroom tyrosinase have been investigated. The results showed that these aromatic compounds can lead to reversible inhibition of the enzyme; furthermore, 2-phenylacetaldehyde and 2-phenylacetic acid are uncompetitive inhibitors and 2-phenylethanol is a mixed-type inhibitor. The inhibition constants have been determined and the inhibiting ability was: 2-phenylacetaldehyde > 2-phenylacetic acid > 2-phenylethanol, indicating that the functional group on the benzene ring group played an important role in the inhibition of the enzyme. In addition, 2-phenylacetic acid and 2-phenylethanol were found to have effective antibacterial activities, and 2-phenylacetic acid was more effective against Escherichia coli and Ralstonia solanacearum than 2-phenylethanol, but 2-phenylacetaldehyde lacked of antibacterial activity. 相似文献
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蔗渣化机浆过氧化物漂白及返黄的研究 总被引:1,自引:1,他引:1
本文的研究表明,白度为31.1%的蔗渣CMP原浆在H_2O_2消耗约4%时经单段或两段H_2O_2漂白后,白度分别达54.8%和75%;瀑白前后分别用EDTA、草酸等处理能有效地提高白度;H_2O_2总量不变时,提高第二段H_2O_2用量有利于浆料白度的提高。增加漂白段数能有效地减少漂浆返黄。与未漂浆相比,漂白浆的打浆度、成纸紧度、撕裂度和裂断长均有提高,不透明度下降。FI-IR显示用H_2O_2漂白蔗渣CMP浆有一定脱木素作用。 相似文献
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通过实验室制备,合成了二溴海因/二氧化硅复合粒子,运用扫描电镜(SEM)与红外光谱(IR)进行了表征,SEM结果显示,在SiO2的表面覆合了二溴海因,红外光谱图表明,复合粒子中二溴海因和二氧化硅之间以物理作用方式结合,将单纯二溴海因与二溴海因/二氧化硅复合粒子溶解于水,测定其在水中的释放速度,结果表明:二溴海因/二氧化硅复合粒子中的二溴海因在水中释放的速度明显慢于纯二溴海因,且能维持较长的作用时间,比较纯二溴海因与含等量二溴海因的复合粒子对大肠杆菌、金黄色葡萄球菌、白葡萄球菌和枯草芽孢杆菌的抑制效果,发现在二溴海因含量高于有效抑茵浓度时,复合粒子对茵体的抑制效果高于纯二溴海因。 相似文献
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Cerrato JM Barrows CJ Blue LY Lezama-Pacheco JS Bargar JR Giammar DE 《Environmental science & technology》2012,46(5):2731-2737
The dissolution of UO(2) in a continuously stirred tank reactor (CSTR) in the presence of Ca(2+) and Zn(2+) was investigated under experimental conditions relevant to contaminated groundwater systems. Complementary experiments were performed to investigate the effect of adsorption and precipitation reactions on UO(2) dissolution. The experiments were performed under anoxic and oxic conditions. Zn(2+) had a much greater inhibitory effect on UO(2) dissolution than did Ca(2+). This inhibition was most substantial under oxic conditions, where the experimental rate of UO(2) dissolution was 7 times lower in the presence of Ca(2+) and 1450 times lower in the presence of Zn(2+) than in water free of divalent cations. EXAFS and solution chemistry analyses of UO(2) solids recovered from a Ca experiment suggest that a Ca-U(VI) phase precipitated. The Zn carbonate hydrozincite [Zn(5)(CO(3))(2)(OH)(6)] or a structurally similar phase precipitated on the UO(2) solids recovered from experiments performed in the presence of Zn. These precipitated Ca and Zn phases can coat the UO(2) surface, inhibiting the oxidative dissolution of UO(2). Interactions with divalent groundwater cations have implications for the longevity of UO(2) and the mobilization of U(VI) from these solids in remediated subsurface environments, waste disposal sites, and natural uranium ores. 相似文献
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高锰酸钾-乙二醛-多羟基酚化学发光体系的研究 总被引:1,自引:0,他引:1
酸性高锰酸钾可以氧化乙二醛产生强的化学发光,而在一定范围内,多羟基酚邻苯三酚的存在能阻抑这种发光.采用流动注射技术,建立了高锰酸钾-乙二醛-多羟基酚体系测定邻苯三酚的化学发光分析法.方法的检出限为1.4×1-0 7m o l.L-1,相对标准偏差为1.27%(1×1-0 5m o l.-L 1邻苯三酚,n=11),线性范围为1.0×1-0 6~2.0×1-0 4m o l.-L 1. 相似文献
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用Fe^3+/H2O2、Cu^2+/H2O2、Cu^2+/Fe^3+/H2O2三种催化氧化体系,对四种不同结构的有机染料废水进行氧化脱色;考察初始pH值、反应时间及Fe^3+/Cu^2+比等因素对处理效果的影响;探讨重复利用Fe^3+/Cu^2+/H2O2体系中Fe^3+和Cu^2+结果表明,四种染料被氧化脱色的难易程度为:酸性橙Ⅱ(偶氮染料)〉中性红(醌亚胺染料)〉碱性品红(三芳甲烷染料)〉茜素紫(蒽醌染料);采用Fe^3+/Cu^2+/H2O2复合体系代替单一的催化离子,能有效适应pH值的变化;Fe^3+和Cu^2+可重复利用4—5次。 相似文献
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生产21/2维异形编带的首要障碍是生产周期长、成本高,最佳工艺过程不易掌握,复合成的产品质量受限。Herzog与复合材料最终用户、初制品生产商以及设计、生产、模拟领域的专家合作,共同开发了一种先进的机器设备。 相似文献