基于抗压强度比指标的锂渣粉活性对比试验分析

本文在水泥胶砂中掺一定比例的粉煤灰、矿渣进行矿物掺合料活性试验,并用不同磨细程度锂渣粉等质量替代矿渣作为水泥掺合料而得出试验结果,对比胶砂强度值、胶砂抗压强度比等指标分析水泥胶砂中矿物掺合料比例不同时,随着锂渣粉替代矿渣掺量的增加,锂渣粉对强度贡献程度的大小,量化不同磨细程度的锂渣粉与传统矿渣比较活性作用的大小。     

矿物掺合料对水泥胶砂力学性能的影响

本试验采用普通硅酸盐水泥和标准砂,通过单掺粉煤灰、花岗岩石粉、磨细砂和S95矿粉替代部分水泥制备水泥胶砂,在蒸压养护和常温养护条件下,系统研究矿物掺合料种类和掺量对水泥胶砂力学性能的影响。研究结果表明,采用矿物掺合料替代部分水泥制备水泥胶砂可以显著降低水泥的用量,其中在蒸压养护条件下使用掺量30%的粉煤灰制备的水泥胶砂力学性能最好,抗折强度为6.75 MPa,抗压强度为30.70MPa;在常温养护条件下S95矿粉的最优掺量为40%,28d抗折强度和抗压强度分别达到8.10 MPa和29.28 MPa。     

三种工业废渣作为活性矿物掺合料的对比研究

利用三种工业废弃物矿渣、磷渣、锰渣,部分取代水泥制备水泥胶砂,对比探讨了矿渣、磷渣、锰渣对水泥胶砂用水量、流动度、凝结时间和活性指数的影响。试验结果表明:添加三种S95级活性掺合料的水泥胶砂用水量与未添加掺合料的彼此都基本相同;添加S95级活性掺合料的水泥胶砂流动度比均≥95%,其中添加S95级锰渣的水泥胶砂流动度比为112%;添加S95级活性掺合料的水泥胶砂凝结时间比未添加掺合料的长,且磷渣矿渣锰渣,其中添加S95级磷渣的水泥胶砂初凝时间可以延长至425 min;添加三种S95级活性掺合料的水泥胶砂7、28 d活性指数:矿渣磷渣锰渣,其中添加S95级矿渣的水泥胶砂7 d活性指数可以达到77%,28 d活性指数为94%。     

掺复合型掺合料水泥胶砂强度的试验研究

运用均匀设计理论设计试验,得出了复合型掺合料中磨细钢渣粉、磨细矿渣粉和粉煤灰的最佳复合比例,采用优化配比考察了不同水胶比和取代量对水泥胶砂强度的影响,并从机理上分析了复合型掺合料的叠加效应。试验结果表明,复合型掺合料适量取代水泥,一方面改善了水泥胶砂的性能,另一方面达到利废、绿色环保、节约成本的效果。     

石灰石粉与活性矿物掺合料的协同效应

针对石灰石粉与不同活性矿物掺合料协同效应的问题,分析石灰石粉分别与粉煤灰、矿渣、硅灰复掺对水泥胶砂抗折、抗压强度的影响,并采用XRD微观测试方法分析其机理。试验结果表明:石灰石粉与活性掺合料协同作用有助于提高水泥胶砂强度,石灰石粉掺量为10%、活性掺合料掺量为20%时强度最大;微观测试分析发现粉煤灰、矿渣与硅灰能促进石粉的水化反应,其水化产物为碳铝酸钙(Ca_4Al_2O_6·CO_3·11H_2O);石粉可以更好地激发活性掺合料的活性,为水化产物提供成核基底。     

掺钢渣粉水泥胶砂早期收缩性能研究

混凝土保持体积稳定是防止混凝土早期开裂的关键措施,而磨细钢渣粉作为活性矿物掺合料对混凝土的干缩性能有着重要的影响。本文针对掺入不同种类、不同掺量钢渣粉的水泥胶砂早期干缩性能进行试验研究,探讨了钢渣粉对水泥胶砂干缩性能的影响规律。试验表明,磨细钢渣粉单掺或与矿渣粉复掺时,水泥胶砂的干缩率存在增大的趋势,在实际工程应用时不容忽视。     

磨细粉煤灰制备粉煤灰水泥的强度分析

试验通过对掺有不同细度及不同掺量粉煤灰的水泥胶砂进行力学性能试验及分析,研究磨细粉煤灰对水泥胶砂强度的影响规律。研究结果表明:粉煤灰的细度对水泥胶砂的抗压强度影响显著;细度不变时,掺10%粉煤灰能有效提升水泥胶砂强度,但掺超20%以上粉煤灰的水泥胶砂强度明显下降,且粉煤灰掺量越大其强度越小;另外随着龄期的增加,掺入磨细粉煤灰的水泥胶砂强度可超过纯水泥的胶砂强度。     

镍渣砂制备高性能灌浆料的试验研究

利用冶炼废弃物镍渣替代部分机制砂制备高性能灌浆料,研究了镍渣砂复掺对天然砂及机制砂胶砂流动性和强度的影响,并在此基础上设计正交试验,通过对样品总功效系数分析及各因素对灌浆料性能的平衡分析研究了镍渣砂、掺合料、减水剂及早强剂等对灌浆料各项性能的影响。结果表明,镍渣砂掺量占总集料10%～50%时能改善机制砂配制水泥胶砂的流动性、抗压强度、抗折强度以及压折比,各因素对灌浆料综合性能影响的程度大小依次为早强剂、减水剂、镍渣砂掺量和掺合料掺量。     

掺活性填料矿物掺合料对水泥胶砂强度的影响

以多种矿物掺合料等量替代水泥对水泥胶砂强度的影响进行了研究,得出用活性组分矿物掺合料等量替代水泥40%~70%水泥胶砂强度的发展规律,以解决矿物掺合料在混凝土中高掺量与早期强度的矛盾,对环境保护有积极意义。     

锂云母渣作为掺合料的可行性研究

针对宜春地区的锂长石矿粉、通过"锂云母固氟重构综合提取碳酸锂技术"提取碳酸锂之后产生的灰色锂云母渣和通过"变温碳化法"制备碳酸锂产生的白色锂云母渣进行研究。此3种粉末均作为掺合料以掺量10%、20%、30%和40%掺入水泥胶砂试件,且同条件下浇筑和养护掺有粉煤灰和硅灰的水泥胶砂试件作为对比组。标准养护至规定龄期后进行抗折和抗压试验;试验结果表明:锂长石矿粉的掺入极大的降低了胶砂试件的抗折强度和抗压强度;白色锂云母渣作为掺合料具有明显的优势,掺量在20%以内时,掺白色锂云母渣胶砂试件早期强度优于掺有其他掺合料的试件,后期强度亦与掺粉煤灰试件相当,且优于掺其他掺合料的试件。掺灰色锂云母渣试件虽早期强度具有优越性,但后期强度却不具优势。     

掺合料混凝土抗硫酸盐性能及评价方法

研究了硅灰、矿渣微粉和粉煤灰三种常用矿物掺合料对混凝土抗硫酸盐腐蚀能力的影响。试验结果表明:三种矿物掺合料均可改善混凝土的抗硫酸盐腐蚀能力,作用效率由高至低依次为:硅灰>矿渣>粉煤灰;掺合料混凝土中砂浆膨胀值发展与混凝土硫酸盐腐蚀程度有良好相关性,采用混凝土中砂浆的膨胀值和抗压强度比两项指标能较准确的评价混凝土抗硫酸盐腐蚀的能力。     

可再分散乳胶粉对钢渣砂砂浆性能的影响

通过试验,就可再分散乳胶粉(简称“乳胶粉”)掺量对钢渣砂砂浆的流动性、抗压强度、抗折强度、拉伸黏结强度和柔韧性的影响进行了研究.结果表明:随着乳胶粉掺量的增加,钢渣砂砂浆的流动性提高,抗压强度下降,早期抗折强度降低,28 d抗折强度提高,拉伸黏结强度大幅增加,柔韧性得到改善.由此可知,对于钢渣砂砂浆,可掺入一定量乳胶粉来提高其抗折强度,改善柔韧性,并大幅增加拉伸黏结强度.     

矿渣代砂水泥砂浆及混凝土物理力学性能研究

研究了高炉矿渣作为细骨料的本征特性及其不同代砂率水泥砂浆及混凝土的物理力学性能.结果表明:矿渣与天然砂作为细骨科时,其物理化学性能存在一定差异;与基准水泥砂浆相比,矿渣代砂水泥砂浆的需水性增大,早期抗折强度略有降低,但后期抗折强度不但不降低甚至还略有提高,抗压强度略有降低,干缩性减小;相对于普通混凝土,矿渣代砂混凝土的抗折强度和抗压强度均有所提高.     

矿渣颗粒对砂浆强度的影响

研究了矿渣颗粒（KZP）以不同比例替代河砂时,对砂浆流动度和强度的影响规律。结果表明,采用矿渣替代河砂,砂浆的3d．7d抗折强度和抗压强度降低;28d抗压强度降低,但有一个先降低、后平缓增加的变化;而28d抗折强度变化不大。用矿渣颗粒替代河砂能较大程度地提高7d和28d的强度增进率。     

Influence of activator on the strength and drying shrinkage of alkali-activated slag mortar

The development of new binders, as an alternative to traditional cement, by the alkaline activation of industrial by-products (i.e. ground granulated slag and fly ash) is an ongoing research topic in the scientific community [Puertas F, Amat T, Jimenez AF, Vazquez T. Mechanical and durable behaviour of alkaline cement mortars reinforced with polypropylene fibres. Cem Concr Res 2003;33(12): 2031–6]. The aim of this study was to investigate the feasibility of using and alkaline activated ground Turkish slag to produce a mortar without Portland cement (PC).Following the characterization of the slag, mortar specimens made with alkali-activated slag were prepared. Three different activators were used: liquid sodium silicate (LSS), sodium hydroxide (SH) and sodium carbonate (SC) at different sodium concentrations. Compressive and flexural tensile strength of alkali-activated slag mortar was measured at 7-days, 28-days and 3-months. Drying shrinkage of the mortar was measured up to 6-months. Setting times of the alkali-activated slag paste and PC paste were also measured.Setting times of LSS and SH activated slag pastes were found to be much slower than the setting time of PC paste. However, slag paste activated with SC showed similar setting properties to PC paste.LSS, SH and SC activated slag mortar developed 81, 29, and 36 MPa maximum compressive strengths, and 6.8, 3.8, and 5.3 MPa maximum flexural tensile strengths at 28-days. PC mortar developed 33 MPa compressive strength and 5.2 MPa flexural tensile strength. LSS and SH activated slag mortars were found to be more brittle than SC activated slag and PC mortars.Slag mortar made with LSS had a high drying shrinkage, up to six times that of PC mortar. Similarly, slag mortar made with SH had a shrinkage up to three times that of PC mortar. However, SC activated slag mortar had a lower or comparable shrinkage to PC mortar. Therefore, the use of SC as an activator for slag mortar is recommended, since it results in adequate strength, similar setting times to PC mortar and comparable or lower shrinkage.     

掺矿渣粉和减水剂的HEMC水泥砂浆力学性能

研究了掺矿渣粉和高效减水剂的羟乙基甲基纤维素改性水泥砂浆的力学性能（包括抗压强度、抗折强度、弹性模量、粘结抗拉强度）及其与新拌砂浆体积密度和硬化砂浆孔隙率的关系。掺加减水剂、矿渣粉和羟乙基甲基纤维素后,砂浆的抗压强度与新拌砂浆体积密度和硬化砂浆孔隙率密切相关,抗折强度与之部分相关,粘结抗拉强度则与之无关。减水剂和矿渣粉可增加砂浆的密实度,减小孔隙率,从而使砂浆的抗压强度、抗折强度、粘结抗拉强度和弹性模量得到提高;羟乙基甲基纤维素虽可保持砂浆的粘结抗拉强度稳定,但却使抗压强度和弹性模量降低,减小剂、矿渣 粉和羟乙基甲基纤维素的共同作用,即增加了砂浆的粘结抗拉强度,又使砂浆有足够的抗压强度、抗折强度和弹性模量,当羟乙基甲基纤维素掺量被抑制在一定范围内时,砂浆便可用作混凝土桥面材料及其修补材料。     

无机矿物掺合料在粘结砂浆中的应用研究

主要研究无机矿物掺合料膨润土、重钙、矿粉和粉煤灰对粘结砂浆性能的影响.实验表明,膨润土掺入会引起砂浆的稠度和含气量下降,抗折、抗压强度有一定的增长,掺量为5%时强度达到最大;掺入5%-15%重钙对砂浆稠度、含气量影响不大,抗折、抗压强度总体下降明显,压折比下降,粘结强度基本不变:掺入10%-50%矿粉对砂浆的稠度、含气量影响不大,后期抗折、抗压强度较未掺时有所增长,粘结强度有一定增大;掺入10%-50%粉煤灰使砂浆含气量、压折比和粘结强度下降.XRD分析显示,粘结砂浆28 d水化物主要为Ca(OH)2和C-S-H凝胶.     

Effect of copper slag as a fine aggregate on the properties of cement mortars and concrete

An experimental investigation was conducted to study the effect of using copper slag as a fine aggregate on the properties of cement mortars and concrete. Various mortar and concrete mixtures were prepared with different proportions of copper slag ranging from 0% (for the control mixture) to 100% as fine aggregates replacement. Cement mortar mixtures were evaluated for compressive strength, whereas concrete mixtures were evaluated for workability, density, compressive strength, tensile strength, flexural strength and durability. The results obtained for cement mortars revealed that all mixtures with different copper slag proportions yielded comparable or higher compressive strength than that of the control mixture. Also, there was more than 70% improvement in the compressive strength of mortars with 50% copper slag substitution in comparison with the control mixture. The results obtained for concrete indicated that there is a slight increase in density of nearly 5% as copper slag content increases, whereas the workability increased significantly as copper slag percentage increased compared with the control mixture. A substitution of up to 40–50% copper slag as a sand replacement yielded comparable strength to that of the control mixture. However, addition of more copper slag resulted in strength reduction due to the increase in the free water content in the mix. Also, the results demonstrated that surface water absorption decreased as copper slag content increases up to 50% replacement. Beyond that, the absorption rate increased rapidly and the percentage volume of the permeable voids was comparable to the control mixture. Therefore, it is recommended that up to 40–50% (by weight of sand) of copper slag can be used as a replacement for fine aggregates in order to obtain a concrete with good strength and durability requirements.     

利用碱性电解水激发砂浆中矿粉活性的研究

利用碱性电解水制备矿粉砂浆,研究了不同取代率矿粉对砂浆工作性和力学性能的影响,结合XRD分析,评价了利用碱性电解水激发矿粉的活性和改善矿粉砂浆性能的可行性。结果表明:碱性电解水矿粉砂浆的工作性和力学性能均优于自来水矿粉砂浆;当矿粉取代率为20%时,碱性电解水矿粉砂浆的28 d抗折强度和抗压强度较自来水矿粉砂浆分别提高了11.9%和23.5%;碱性电解水矿粉砂浆中存在多钙钾石膏和钾长石,且水化硅酸钙和铝酸钙矿物的衍射峰显著强于自来水矿粉砂浆。     

钢渣砂抗裂干混砂浆在工程中的应用研究

通过吸水量、压折比、粘结强度及凝结时间等技术指标的测定,对比分析了钢渣砂抗裂砂浆和市售抗裂砂浆的性能。分析表明:粒径小于0.6mm自然堆放钢渣砂和河砂混合配制出的抗裂干混砂浆性能符合工程使用要求,实际工程应用效果好。钢渣砂70%取代河砂配制的抗裂砂浆吸水量偏高,但依旧在国标要求的范围内。和参比样河砂配制的砂浆相比,钢渣砂抗裂砂浆压折比更小,表现出更好的抗裂性。同时,钢渣砂抗裂砂浆凝结时间延缓,具有更长的可操作时间,有利于工程施工。研究工作总体说明当钢渣砂粒径小于0.6mm时,可取代同粒径天然砂或石英砂配制抗裂干混砂浆,并可保证抗裂砂浆对力学性能和工作性能的要求。