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1.
The present paper deals with the hydrogen liquefaction with absorption precooling cycle assisted by geothermal water is modeled and analyzed. Uses geothermal heat in an absorption refrigeration process to precool the hydrogen gas is liquefied in a liquefaction cycle. High-temperature geothermal water using the absorption refrigeration cycle is used to decrease electricity work consumption in the gas liquefaction cycle. The thermoeconomic optimization procedure is applied using the genetic algorithm method to the hydrogen liquefaction system. The objective is to minimize the unit cost of hydrogen liquefaction of the composed system. Based on optimization calculations, hydrogen gas can be cooled down to ?30 °C in the precooling cycle. This allows the exergetic cost of hydrogen gas to be reduced to be 20.16 $/GJ (2.42 $/kg LH2). The optimized exergetic cost of liquefied hydrogen is 4.905 $/GJ (1.349 $/kg LH2), respectively.  相似文献   

2.
Environmental degradation and global warming are presently two of the most pressing global concerns. According to the (IAE), around 80% of global energy demand has been met by fossil fuels in recent years, resulting in an increase in CO2 emissions as the primary greenhouse gas. Switching to renewable energy sources and using more energy-efficient energy systems are vital for mitigating environmental challenges and reducing our reliance on fossil fuels, among other things. Hydrogen fuels are primary renewable resources because of their reduced cost and ability to produce net-zero CO2 emissions. In the present study, a system is designed to generate power and liquid hydrogen from geothermal sources. The generated power by employing either the organic Rankin cycle (ORC) or absorption power cycle (APC) is compared to seek the best cycle performance from power generation standpoint. A comprehensive thermodynamic and economic modeling is carried out for the proposed system. In addition, a parametric study is applied to see which parameters affect the performance of the system. Multi-objective optimization is carried out to find the best operating point of the hydrogen liquefaction energy system. The system demonstrates better performance when APC is applied for power generation. The cost of generated liquid hydrogen by ORC and APC is 3.8 $/kg.LH2 and 3.6 $/kg.LH2, respectively. Furthermore, 0.014 $/kWh of electricity cost is reached by ORC compared to 0.012 $/kWh of APC. Parametric analysis shows that the higher the temperature and flow rate of the brine of geothermal fluid, the higher the efficiency and the lower cost. Finally, the multi-objective optimization pinpoints that the system's efficiency and unit product cost at the optimal ORC-based design is 33.85% and 0.0121 $/kWh. In comparison, the APC demonstrates better performance by 34.5% and 0.011 $/kWh.  相似文献   

3.
The study aims to optimize the geothermal and solar-assisted sustainable energy and hydrogen production system by considering the genetic algorithm. The study will be useful by integrating hydrogen as an energy storage unit to bring sustainability to smart grid systems. Using the Artificial Neural Network (ANN) based Genetic Algorithm (GA) optimization technique in the study will ensure that the system is constantly studied in the most suitable under different climatic and operating conditions, including unit product cost and the plant's power output. The water temperature of the Afyon Geothermal Power Plant varies between 70 and 130 °C, and its mass flow rate varies between 70 and 150 kg/s. In addition, the solar radiation varies between 300 and 1000 W/m2 for different periods. The net power generated from the region's geothermal and solar energy-supported system is calculated as 2900 kW. If all of this produced power is used for hydrogen production in the electrolysis unit, 0.0185 kg/s hydrogen can be produced. The results indicated that the overall energy and exergy efficiencies of the integrated system are 4.97% and 16.0%, respectively. The cost of electricity generated in the combined geothermal and solar power plant is 0.027 $/kWh if the electricity is directly supplied to the grid and used. The optimized cost of hydrogen produced using the electricity produced in geothermal and solar power plants in the electrolysis unit is calculated as 1.576 $/kg H2. The optimized unit cost of electricity produced due to hydrogen in the fuel cell is calculated as 0.091 $/kWh.  相似文献   

4.
Seven models are considered for the production and liquefaction of hydrogen by geothermal energy. In these models, we use electrolysis and high-temperature steam electrolysis processes for hydrogen production, a binary power plant for geothermal power production, and a pre-cooled Linde–Hampson cycle for hydrogen liquefaction. Also, an absorption cooling system is used for the pre-cooling of hydrogen before the liquefaction process. A methodology is developed for the economic analysis of the models. It is estimated that the cost of hydrogen production and liquefaction ranges between 0.979 $/kg H2 and 2.615 $/kg H2 depending on the model. The effect of geothermal water temperature on the cost of hydrogen production and liquefaction is investigated. The results show that the cost of hydrogen production and liquefaction decreases as the geothermal water temperature increases. Also, capital costs for the models involving hydrogen liquefaction are greater than those for the models involving hydrogen production only.  相似文献   

5.
In this study, the performance of the combined cooling cycle with the Organic Rankine power cycle, which provides cooling of the hydrogen at the compressor inlet which compresses the constant temperature in the Claude cycle used for hydrogen liquefaction, on the system is examined. The Organic Rankine combined cooling cycle was considered to be using a geothermal source with a flow rate of 120 kg/s at a temperature of 200 °C. The first and second law performance evaluations of the whole system were made depending on the heat energy at different levels taken from the geothermal source. The thermodynamic analysis of the equipment making up the system has been done in detail. The temperature values at which the hydrogen can be effectively cooled were determined in the presented combined system. The efficiency coefficient of the total system was calculated based on varying pre-cooling values. As a result of the study, it was determined that cold entry of hydrogen into the Claude cycle reduced the energy consumption required for liquefaction. Amount of hydrogen cooled to specified temperature increase by increase in mass flow of geothermal water and its temperature. Liquefaction cost is calculated to be 0.995 $/kg H2 and electricity produced by itself is calculated to be 0.025 $/kWh by the new model of liquefaction system. Cost of the liquefaction in the proposed system is about 39.7% lower than direct value of hydrogen liquefaction of 1.650 $/kg given in the literature.  相似文献   

6.
The investment in the hydrogen infrastructure for hydrogen mobility has lately seen a significant acceleration. The demand for energy and cost efficient hydrogen liquefaction processes has also increased steadily. A significant scale-up in liquid hydrogen (LH2) production capacity from today's typical 5–10 metric tons per day (tpd) LH2 is predicted for the next decade. For hydrogen liquefaction, the future target for the specific energy consumption is set to 6 kWh per kg LH2 and requires a reduction of up to 40% compared to conventional 5 tpd LH2 liquefiers. Efficiency improvements, however, are limited by the required plant capital costs, technological risks and process complexity. The aim of this paper is the reduction of the specific costs for hydrogen liquefaction, including plant capital and operating expenses, through process optimization. The paper outlines a novel approach to process development for large-scale hydrogen liquefaction. The presented liquefier simulation and cost estimation model is coupled to a process optimizer with specific energy consumption and specific liquefaction costs as objective functions. A design optimization is undertaken for newly developed hydrogen liquefaction concepts, for plant capacities between 25 tpd and 100 tpd LH2 with different precooling configurations and a sensitivity in the electricity costs. Compared to a 5 tpd LH2 plant, the optimized specific liquefaction costs for a 25 tpd LH2 liquefier are reduced by about 50%. The high-pressure hydrogen cycle with a mixed-refrigerant precooling cycle is selected as preferred liquefaction process for a cost-optimized 100 tpd LH2 plant design. A specific energy consumption below 6 kWh per kg LH2 can be achieved while reducing the specific liquefaction costs by 67% compared to 5 tpd LH2 plants. The cost targets for hydrogen refuelling and mobility can be reached with a liquid hydrogen distribution and the herewith presented cost-optimized large-scale liquefaction plant concepts.  相似文献   

7.
In this study, the thermodynamic and economic analysis of a geothermal energy assisted hydrogen production system was performed using real-time Artificial Neural Networks on Field Programmable Gate Array. During the modeling of the system in the computer environment, a liquid geothermal resource with a temperature of 200 °C and a flow rate of 100 kg/s was used for electricity generation, and this electricity was used as a work input in the electrolysis unit to split off water into the hydrogen and oxygen. In the designed system, the net work produced from the geothermal power cycle, the overall exergy efficiency of the system, the unit cost of the produced hydrogen and the simple payback period of the system were calculated as 7978 kW, 38.37%, 1.088 $/kg H2 and 4.074 years, respectively. In the second stage of the study, Feed-Forward Artificial Neural Networks model with a single hidden layer was used for modeling the system. The activation functions of the hidden layer and output layer were Tangent Sigmoid and Linear functions, respectively. The system was implemented on Field Programmable Gate Array using the Matlab-based model of the system as a reference. The maximum operating frequency and chip statistics of the designed unit of Field Programmable Gate Array based geothermal energy assisted hydrogen production system were presented. The result can be used to gain better knowledge and optimize hydrogen production systems.  相似文献   

8.
In this study, biogas power production and green hydrogen potential as an energy carrier are evaluated from biomass. Integrating an Organic Rankine Cycle (ORC) to benefit from the waste exhaust gases is considered. The power obtained from the ORC is used to produce hydrogen by water electrolysis, eliminate the H2S generated during the biogas production process and store the excess electricity. Thermodynamic and thermoeconomic analyses and optimization of the designed Combined Heat and Power (CHP) system for this purpose have been performed. The proposed study contains originality about the sustainability and efficiency of renewable energy resources. System design and analysis are performed with Engineering Equation Solver (EES) and Aspen Plus software. According to the results of thermodynamic analysis, the energy and exergy efficiency of the existing power plant is 28.69% and 25.15%. The new integrated system's energy, exergy efficiencies, and power capacity are calculated as 41.55%, 36.42%, and 5792 kW. The total hydrogen production from the system is 0.12412 kg/s. According to the results of the thermoeconomic analysis, the unit cost of the electricity produced in the existing power plant is 0.04323 $/kWh. The cost of electricity and hydrogen produced in the new proposed system is determined as 0.03922 $/kWh and 0.181 $/kg H2, respectively.  相似文献   

9.
Hydrogen is produced via steam methane reforming (SMR) for bitumen upgrading which results in significant greenhouse gas (GHG) emissions. Wind energy based hydrogen can reduce the GHG footprint of the bitumen upgrading industry. This paper is aimed at developing a detailed data-intensive techno-economic model for assessment of hydrogen production from wind energy via the electrolysis of water. The proposed wind/hydrogen plant is based on an expansion of an existing wind farm with unit wind turbine size of 1.8 MW and with a dual functionality of hydrogen production and electricity generation. An electrolyser size of 240 kW (50 Nm3 H2/h) and 360 kW (90 Nm3 H2/h) proved to be the optimal sizes for constant and variable flow rate electrolysers, respectively. The electrolyser sizes aforementioned yielded a minimum hydrogen production price at base case conditions of $10.15/kg H2 and $7.55/kg H2. The inclusion of a Feed-in-Tariff (FIT) of $0.13/kWh renders the production price of hydrogen equal to SMR i.e. $0.96/kg H2, with an internal rate of return (IRR) of 24%. The minimum hydrogen delivery cost was $4.96/kg H2 at base case conditions. The life cycle CO2 emissions is 6.35 kg CO2/kg H2 including hydrogen delivery to the upgrader via compressed gas trucks.  相似文献   

10.
Hydrogen as an energy carrier can play a significant role in reducing environmental emissions if it is produced from renewable energy resources. This research aims to assess hydrogen production from wind energy considering environmental, economic, and technical aspect for the East Azerbaijan province of Iran. The economic assessment is performed by calculation of payback period, levelized cost of hydrogen, and levelized cost of electricity. Since uncertainty in the power output of wind turbines may affect the payback period, all calculations are performed for four different turbine degradation rates. While it is common in the literature to choose the wind turbine based on a single criterion, this study implements Multi-Criteria Decision-Making (MCDM) techniques for this purpose. The results of Step-wise Weight Assessment Ratio Analysis illustrates that economic issue is the most important criterion for this research. The results of Weighted Aggregated Sum Product Assessment shows that Vestas V52 is the most suitable wind turbine for Ahar and Sarab cities, while Eovent EVA120 H-Darrieus is a better choice for other stations. The most suitable location for wind power generation is found to be Ahar, where it is estimated to annually generate 2914.8 kWh of electricity at the price of 0.045 $/kWh, and 47.2 tons of hydrogen at the price of 1.38 $/kg, which result in 583 tons of CO2 emission reduction.  相似文献   

11.
Parabolic dish solar collector system has capability to gain higher efficiency by converting solar radiations to thermal heat due to its higher concentration ratio. This paper examines the exergo-economic analysis, net work and hydrogen production rate by integrating the parabolic dish solar collector with two high temperature supercritical carbon dioxide (s-CO2) recompression Brayton cycles. Pressurized water (H2O) is used as a working fluid in the solar collector loop. The various input parameters (direct normal irradiance, ambient temperature, inlet temperature, turbine inlet temperature and minimum cycle temperature) are varied to analyze the effect on net power output, hydrogen production rate, integrated system energetic and exergetic efficiencies. The simulations has been carried out using engineering equation solver (EES). The outputs demonstrate that the net power output of the integrated reheat recompression s-CO2 Brayton system is 3177 kW, whereas, without reheat integrated system has almost 1800 kW net work output. The overall energetic and exergetic efficiencies of former system is 30.37% and 32.7%, respectively and almost 11.6% higher than the later system. The hydrogen production rate of the solarized reheat and without reheat integrated systems is 0.0125 g/sec and 0.007 g/sec, accordingly and it increases with rise in direct normal irradiance and ambient temperature. The receiver has the highest exergy destruction rate (nearly 44%) among the system components. The levelized electricity cost (LEC) of 0.2831 $/kWh with payback period of 9.5 years has proved the economic feasibility of the system design. The increase in plant life from 10 to 32 years with 8% interest rate will decrease the LEC from (0.434-0.266) $/kWh. Recuperators have more potential for improvement and their cost rate of exergy is higher as compared to the other components.  相似文献   

12.
The increasing threat to environmental sustainability as a result of greenhouse gas (GHG) emissions from fossil fuel base power plants has necessitated the need to find sustainable energy sources to meet the world's energy demands. This study focuses on assessing the potential of a hybrid power plant for the production of electricity, hydrogen for the production of fertilizer for agricultural activities, farmland irrigation, environmental impact as well as its employment potential in northern Ghana. The Shannon entropy weight and TOPSIS multi-criteria decision-making approach were adopted to rank and identify the optimal configuration out of five possible options for the study area. Results from the simulation show that the winning system, i.e., Hydro + Battery system would generate a total electricity of 1,095,679 kWh/year. A cost of electricity of 0.06 $/kWh with an operating cost (OC) of $18,318 was recorded for the winning system. The total produced hydrogen by the optimum configuration is 8816 kg/year at a levelized cost of hydrogen (LCOH) of 4.47 $/kg. The quantity of low-carbon fertilizer that can be produced from the produced hydrogen is also assessed. The optimum configuration also recorded an employment potential of 4 persons in 25 years. A total GHG equivalence of 383.49 metric tons of CO2 equivalent indicating the level of emissions that will be avoided should the optimum system be used to meet the demands specified in this study was obtained.  相似文献   

13.
In this paper, a parametric study of the triple effect absorption cooling system (TEACS) integrated with solar photo-voltaic/thermal (PV/T), geothermal, and Linde–Hampson cycle is conducted. The effect of different operating parameters on the COPs, ratio ‘n’, amount of hydrogen gas pre-cooled, amount of hydrogen liquefied, and utilization factor of the integrated system are studied. It is found that when mass flow rate of air increases the energetic and exergetic COPs decrease in an exponential form from 2.6 to 1.9, and 0.4 to 0.3, respectively. The amounts of hydrogen gas pre-cooled and hydrogen liquefied decrease from 0.39 kg/s to 0.32 kg/s and 0.082 kg/s and 0.066 kg/s, respectively with increase in mass flow rate of air. Moreover, the amounts of hydrogen gas pre-cooled and hydrogen liquefied decrease from 0.42 to 0.27, and 0.088 to 0.066, respectively with increase in mass flow rate of geothermal. In addition, energetic and exergetic utilization factors of integrated system decrease from 0.059 to 0.037, and 0.21 and 0.13, respectively with increase in mass flow rate of geothermal.  相似文献   

14.
A feasibility study exploring the use of geothermal energy in hydrogen production is presented. It is possible to use a thermal energy to supply heat for high temperature electrolysis and thereby substitute a part of the relatively expensive electricity needed. A newly developed HOT ELLY high temperature steam electrolysis process operates at 800 – 1000°C. Geothermal fluid is used to heat fresh water up to 200°C steam. The steam is further heated to 900°C by utilising heat produced within the electrolyser. The electrical power of this process is reduced from 4.6 kWh per normalised cubic meter of hydrogen (kWh/Nm3 H2) for conventional process to 3.2 kWh/Nm3 H2 for the HOT ELLY process implying electrical energy reduction of 29.5%. The geothermal energy needed in the process is 0.5 kWh/Nm3 H2. Price of geothermal energy is approximately 8–10% of electrical energy and therefore a substantial reduction of production cost of hydrogen can be achieved this way. It will be shown that using HOT ELLY process with geothermal steam at 200°C reduces the production cost by approximately 19%.  相似文献   

15.
This paper presents a thermoeconomic analysis aimed at the optimization of a novel zero-CO2 and other emissions and high-efficiency power and refrigeration cogeneration system, COOLCEP-S (Patent pending), which uses the liquefied natural gas (LNG) coldness during its revaporization. It was predicted that at the turbine inlet temperature (TIT) of 900 °C, the energy efficiency of the COOLCEP-S system reaches 59%. The thermoeconomic analysis determines the specific cost, the cost of electricity, the system payback period and the total net revenue. The optimization started by performing a thermodynamic sensitivity analysis, which has shown that for a fixed TIT and pressure ratio, the pinch point temperature difference in the recuperator, ΔTp1, and that in the condenser, ΔTp2 are the most significant unconstrained variables to have a significant effect on the thermal performance of novel cycle. The payback period of this novel cycle (with fixed net power output of 20 MW and plant life of 40 years) was 5.9 years at most, and would be reduced to 3.1 years at most when there is a market for the refrigeration byproduct. The capital investment cost of the economically optimized plant is estimated to be about 1000 $/kWe, and the cost of electricity is estimated to be 0.34–0.37 CNY/kWh (0.04 $/kWh). These values are much lower than those of conventional coal power plants being installed at this time in China, which, in contrast to COOLCEP-S, do produce CO2 emissions at that.  相似文献   

16.
For liquid hydrogen (LH2) to become an energy carrier in energy commodity markets at scales comparable to for instance LNG, liquefier capacities must be scaled up several orders of magnitude. While state-of-the-art liquefiers can provide specific power requirements down to 10 kWh/kg, a long-term target for scaled-up liquefier trains is 6 kWh/kg. High capacity will shift the cost weighting more towards operational expenditures, which motivates for measures to improve the efficiency. Detailed exergy analysis is the best means for gaining a clear understanding of all losses occurring in the liquefaction process. This work analyses in detail a hydrogen liquefier that is likely to be realisable without intermediate demonstration phases, and all irreversibilities are decomposed to the component level. The overall aim is to identify the most promising routes for improving the process. The overall power requirement is found to be 7.09 kWh/kg, with stand-alone exergy efficiencies of the mixed-refrigerant pre-cooling cycle and the cryogenic hydrogen Claude cycle of 42.5% and 38.4%, respectively. About 90% of the irreversibilities are attributed to the Claude cycle while the remainder is caused by pre-cooling to 114 K. For a component group subdivision, the main contributions to irreversibilities are hydrogen compression and intercooling (39%), cryogenic heat exchangers (21%), hydrogen turbine brakes (15%) and hydrogen turbines (13%). Efficiency improvement measures become increasingly attractive with scale in general, and several options exist. An effective modification is to recover shaft power from the cryogenic turbines. 80% shaft-to-shaft power recovery will reduce the power requirement to 6.57 kWh/kg. Another potent modification is to replace the single mixed refrigerant pre-cooling cycle with a more advanced mixed-refrigerant cascade cycle. For substantial scaling-up in the long term, promising solutions can be cryogenic refrigeration cycles with refrigerant mixtures of helium/neon/hydrogen, enabling the use of efficient and well scalable centrifugal compressors.  相似文献   

17.
In this paper, we propose a novel integrated geothermal absorption system for hydrogen liquefaction, power and cooling productions. The effect of geothermal, ambient temperature and concentration of ammonia-water vapor on the system outputs and efficiencies are studied through energy and exergy analyses. It is found that both energetic and exergetic coefficient of performances (COPs), and amounts of hydrogen gas pre-cooled and liquefied decrease with increase in the mass flow rate of geothermal water. Moreover, increasing the temperature of geothermal source degrades the performance of the quadruple effect absorption system (QEAS), but at the same time it affects the liquefaction production rate of hydrogen gas in a positive way. However, an increase in ambient temperature has a negative effect on the liquefaction rate of hydrogen gas produced as it decreases from 0.2 kg/s to 0.05 kg/s. Moreover, an increase in the concentration of the ammonia-water vapor results in an increase in the amount of hydrogen gas liquefied from 0.07 kg/s to 0.11 kg/s.  相似文献   

18.
The energy efficiency of the hydrogen liquefaction process is studied, and a general model of the hydrogen liquefaction process is built for analyzing the energy efficiency and the influence of multiple parameters. Energy and exergy analysis models of the typical single-pass cycle and multiple-pass cycle are developed. The specific relationships among the parameters and energy efficiency of the total liquefaction system are deduced. A hydrogen liquefaction process with precooling nitrogen and cryogenic helium cycles is studied. For the precooling and cryogenic cycles, the SEC and net power consumption of the cryogenic helium cycle have different variation trends along with the precooling temperature and hydrogen liquefaction ratio. Their optimal values are identified to be ?194 °C and 0.9453, and the corresponding SEC, exergy efficiency, total capital expense, and total annual cost are 3.619 kWh/kgLH2, 33.44%, 82.58%, 8.263 M$, and 531.62 M$/yr, respectively. The proposed model can be used in the design and operation stages to analyze the variation of energy efficiency along with multiple parameters of the hydrogen liquefaction process.  相似文献   

19.
Hydrogen has been a promising energy carrier to meet the world's energy needs as well as reduce pollutant emissions. Although many countries have policies and programs to expand hydrogen production, the potential for hydrogen production in different regions of Qatar has not yet been evaluated. Therefore, this paper, for the first time, evaluates the possibility of an average annual cogeneration of 14 kWh of electricity and 85 kg/day of hydrogen by a home-scale solar-wind system connected to the grid in Qatar. NASA's 20-year average of meteorological data, the electricity tariff and gasoline price in 2018, along with annual real interest rate, were used as inputs to HOMER software. The techno-econo-enviro analysis was done over a one-year period hour by hour. From the results, it was found that the lowest prices of hydrogen and electricity generated, with $ 2.092/kg and $ 11.495/kWh, were related to Grid and PV-Wind-Grid scenarios, respectively. Also, results indicated that Ar-Ruways station and PV-Wind-Grid scenario were the most environmentally suitable options that resulted in a CO2 emission rate of 1434 kg annually. To select just one station among five areas, a fuzzy method was deployed as a prioritization technique. Its results suggested that Doha Intl Airport site is the most suitable one for constructing solar-wind hybrid energy generation system.  相似文献   

20.
Most inhabitants of rural communities in Africa lack access to clean and reliable electricity. This has deprived the rural dwellers access to modern healthcare delivery. In this paper, an off-grid renewable energy system consisting of solar PV and wind turbine with hydrogen storage scheme has been explored to meet the electrical energy demands of a health clinic. The health clinic proposed is a group II with 10 beds located in a typical village in South Africa. First, the wind and solar energy resources of the village were analysed. Thereafter, the microgrid architecture that would meet the energy demand of the clinic (18.67 kWh/day) was determined. Some of the key results reveal that the average annual wind speed at 60 m anemometer height and solar irradiation of the village are 7.9 m/s and 4.779 kWh/m2/day, respectively. The required architecture for the clinic composes of 40 kW solar PV system, 3 numbers of 10 kW wind turbines, 8.6 kW fuel cell, 25 kW electrolyser and 40 kg hydrogen tank capacity. The capital cost of the microgrid was found to be $177,600 with a net present cost of $206,323. The levelised cost of energy of the system was determined to be 2.34 $/kWh. The project has a breakeven grid extension distance of 8.81 km. Since this distance is less than the nearest grid extension distance of 21.35 km, it is established that the proposed renewable energy microgrid with a hydrogen storage system is a viable option for the rural community health clinic.  相似文献   

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