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对硫化返原的动力学、抗硫化返原助剂的作用机理、不同抗硫化返原助剂在不同的配合体系中的用量及对硫化胶性能的影响进行评述。对于抗硫化返原助剂,在半有效硫化体系中Si69抗返原性最好。在传统硫化体系中HVA-2最好。实际应用时不同本的配方应采取相应的抗硫化还原剂。 相似文献
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研究了抗硫化返原剂Perkalink900(简称PK900)、AK-73对纯天然橡胶复合体系的抗硫化返原性能、物理机械性能及生热性能的影响,结果表明:无论是在普通硫化体系还是在半有效硫化体系中,加入一定量PK900、AK-73后,胶料的抗硫化返原性能均得到提高。就这2种抗硫化返原剂而言,在不同的硫化体系中,在不同的温度下,表现的结果有所不同:在半有效硫化体系中,高温过硫情况下,PK900的作用更加明显,同时,加入一定量的抗硫化返原剂后,胶料的定负荷压缩生热性能得到一定程度的改善。 相似文献
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提高工程机械轮胎抗硫化返原性的措施 总被引:2,自引:0,他引:2
分析橡胶的耐热性、胶料硫化返原的机理及影响因素,讨论提高工程机械轮胎抗硫化返原性的措施。指出选择合适的硫化体系、添加抗硫化返原剂、降低胶料生热、并用耐热胶种、调整轮胎不同部位胶料硫化速度的匹配性等,以及利用计算机数值模拟的方法确定合适硫化条件是提高工程机械轮胎抗硫化返原性的有效措施。 相似文献
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对3种不同取代基的秋兰姆类促进剂在天然橡胶中的硫化特性及物理性能进行了比较。结果发现,不论在有效、半有效或普通硫化体系中,含促进剂TE的天然橡胶胶料均具有最长的焦烧时间和较好的抗硫化返原性。对物理机械性能和抗热氧老化性能亦无不良影响,适合于在天然橡胶大型厚制品胶料中应用。 相似文献
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The dynamic vulcanization process, usually used for the preparation of thermoplastic elastomers, was used to prepare polypropylene (PP)/epoxy blends. The blends had crosslinked epoxy resin particles finely dispersed in the PP matrix, and they were called dynamically cured PP/epoxy blends. Maleic anhydride grafted polypropylene (MAH‐g‐PP) was used as a compatibilizer. The effects of the reactive compatibilization and dynamic cure were studied with rheometry, capillary rheometry, and scanning electron microscopy (SEM). The crystallization behavior and mechanical properties of PP/epoxy, PP/MAH‐g‐PP/epoxy, and dynamically cured PP/epoxy blends were also investigated. The increase in the torque at equilibrium for the PP/MAH‐g‐PP/epoxy blends indicated the reaction between maleic anhydride groups of MAH‐g‐PP and the epoxy resin. The torque at equilibrium of the dynamically cured PP/epoxy blends increased with increasing epoxy resin content. Capillary rheological measurements also showed that the addition of MAH‐g‐PP or an increasing epoxy resin content increased the viscosity of PP/epoxy blends. SEM micrographs indicated that the PP/epoxy blends compatibilized with PP/MAH‐g‐PP had finer domains and more obscure boundaries than the PP/epoxy blends. A shift of the crystallization peak to a higher temperature for all the PP/epoxy blends indicated that uncured and cured epoxy resin particles in the blends could act as effective nucleating agents. The spherulites of pure PP were larger than those of PP in the PP/epoxy, PP/MAH‐g‐PP/epoxy, and dynamically cured PP/epoxy blends, as measured by polarized optical microscopy. The dynamically cured PP/epoxy blends had better mechanical properties than the PP/epoxy and PP/MAH‐g‐PP/epoxy blends. With increasing epoxy resin content, the flexural modulus of all the blends increased significantly, and the impact strength and tensile strength increased slightly, whereas the elongation at break decreased dramatically. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 1437–1448, 2004 相似文献
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通过IR分析了用顺酐和反酸与聚酯合成不饱和聚酯树脂的反应机理,讨论了二种树脂体系固化放热曲线不同的原因。 相似文献
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In the present study, an epoxy resin was dynamically cured in a polypropylene (PP)/maleic anhydride–grafted PP (MAH‐g‐PP)/talc matrix to prepare dynamically cured PP/MAH‐g‐PP/talc/epoxy composites. An increase in the torque at equilibrium showed that epoxy resin in the PP/MAH‐g‐PP/talc composites had been cured by 2‐ethylene‐4‐methane‐imidazole. Scanning electron microscopy analysis showed that MAH‐g‐PP and an epoxy resin had effectively increased the interaction adhesion between PP and the talc in the PP/talc composites. Dynamic curing of the epoxy resin further increased the interaction adhesion. The dynamically cured PP/MAH‐g‐PP/talc/epoxy composites had higher crystallization peaks than did the PP/talc composites. Thermogravimetric analysis showed that the addition of MAH‐g‐PP and the epoxy resin into the PP/talc composites caused an obvious improvement in the thermal stability. The dynamically cured PP/MAH‐g‐PP/talc/epoxy composites had the best thermal stability of all the PP/talc composites. The PP/MAH‐g‐PP/talc/epoxy composites had better mechanical properties than did the PP/MAH‐g‐PP/talc composites, and the dynamically cured PP/MAH‐g‐PP/talc/epoxy composites had the best mechanical properties of all the PP/talc composites, which can be attributed to the better interaction adhesion between the PP and the talc. The suitable content of epoxy resin in the composites was about 5 wt %. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006 相似文献
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The present article describes a methodology for examining the evolution of the properties vs. cure of a complex thermosetting isocyanate/epoxy reactive mixture which reacts through two consecutive but separable reaction regimes. The methodology is based on the use of the torsional braid analysis (TBA) technique and the continuous heating (CHT) and isothermal time—temperature—transformation (TTT) cure diagrams. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 64: 15–25, 1997 相似文献
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Zhi‐Qi Cai Siva Movva Nan‐Rong Chiou Dante Guerra Yunior Hioe Jose M. Castro L. James Lee 《应用聚合物科学杂志》2010,118(4):2328-2335
Polyaniline (PANI) “nanograss” was grown on carbon nanofibers (CNFs). The cure behavior of an epoxy resin with and without unmodified CNFs or PANI modified CNFs was studied by means of non‐isothermal and isothermal differential scanning calorimetry (DSC). CNFs accelerated the reaction of epoxy and diamine. PANI surface modification further increased the reaction rate and the extent of reaction. An autocatalytic cure kinetic model was used to fit the reaction curves. It was found that activation energies of the epoxy reaction decreased in the presence of CNFs and PANI modified CNFs. The observed catalytic effect of CNF and PANI surface coating can be very useful for low temperature cure of large epoxy composite products. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
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有机硅树脂合成及其共混改性研究 总被引:4,自引:0,他引:4
通过实验筛选出合成有机硅树脂的配方,讨论了原料配比、水解温度,介质酸度和溶剂组成对有机硅树脂的影响。采用傅里叶变换红外光谱表征了聚甲基丙烯酸丁酯(PBMA)共混改性有机硅树脂前后的结构特征;采用扫描电子显微镜分析了有机硅树脂、PBMA和PBMA共混改性有机硅树脂的微观结构,进而探讨,改性有机硅树脂室温同化机理,即有机硅树脂分子和PBMA分子之间的互相介入、互相贯穿使之形成网络,具有了自由基协同效应。 相似文献
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We investigated improvement of workability (viscosity), storage stability, and curing ability of thiirane resin for adhesive applications. The viscosity of bisphenol‐F thiirane resin was lower than that of bisphenol‐A thiirane resin, especially at low temperatures, thus improving ease of handling. Addition of diphenyl decyl phosphite improved its storage stability to a level similar to that of bisphenol‐A epoxy resin. The curing of bisphenol‐F thiirane resin increased three times faster by adding 2,4,6‐tris(dimethylaminomethyl)phenol (DMP‐30) as a tertiary amine. In applications of this new thiirane resin as civil and architectural adhesives, a superior curing ability at low temperature was attained. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 2953–2957, 2001 相似文献