共查询到20条相似文献,搜索用时 15 毫秒
1.
2 Hydroxydiphenylaceticacid (HD PHA) ,agoodplantgrowthregulator ,canformstableaqueousbinarycomplexeswithrareearths .TointroducePhen ( 1 ,1 0 Phenanthro line) ,theniceligandtorareearths ,intothesystem ,aternarycomplexEu(DPHA) 3·Phen·2H2 Owassynthesizedanditsphotophysic… 相似文献
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Synthesis and Crystal Structure of [Yb(NTO)_3(H_2O)_4]·6H_2O 总被引:3,自引:0,他引:3
SynthesisandCrystalStructureof[Yb(NTO)3(H2O)4]·6H2OSongJirong(宋纪蓉),DongWu(董武)(DepartmentofChemicalEnginering,NorthwestUniver... 相似文献
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Synthesis and Structural Characterization of a Novel Two-Dimensional Heterometallic Coordination Polymer Nd_2Zn_3(EDTA)_3(H_2O)_( 11)·12H_2O 总被引:1,自引:0,他引:1
Themagneticpropertiesofheteropolynu clearcomplexescontainingboth 4fand 3dionshaveattractedconsiderableinterestssince1 985 [1] .Carboxylicacidisakindofpotentialligandforthedesignandsynthesisofthiskindofmagneticmolecularmaterials .Somecar boxylatecompoundswerep… 相似文献
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Inthepastfewyears ,themagneticprop ertiesofcomplexescomprisinglanthanideandtransitionmetalionshaveattractedincreasinginterest[1~ 6 ] .Thesecomplexesareimportantinthestudiesofmagneticexchangeinteractionbetweenlanthanideandd transitionmetalions,andtheycanpro… 相似文献
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Crystalengineeringofcoordinationpoly merswithopenframeworksassembledfromor ganic metalcompoundshasbeenofgreatinter estsowingtotheirpotentialpropertiesasnovelmaterialssuchasgasadsorption[1,2 ] ,ion ex change[3] andcatalysis[4] .Theconstructionofcoordinationpolym… 相似文献
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Rareearthionspossessobviousfosteref fectonthegrowingofcrop[1] .Aminoacidsarethecomponentsofproteins ,andtherearemanyreportsaboutthestudyonthebinarycomplexesofrareearthwithaminoacids[2 ,3] .Imidazoleisaheteroclycliccompoundpossess ingbactericideandanti infecti… 相似文献
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Owingtothevariationofcoordinatedmodesforcarboxylateanions ,manydifferenttypesofcrystalstructuresfortherareearthcomplexeswitharomaticacidandnitrogen containingligandswereobtained[1~ 4 ] .Theirthermaldecompositionbehaviorhadbeenre portedinpreviouspapers[5~ 8] .… 相似文献
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Becauseoftheirpossiblerelevancetomodelcompoundsofcationtransportacrossmembranes,differenttypesofopenchain“crown”ethermoleculeshavebeensynthesizedinordertostudytheirinteractionwithsodium ,potassiumandrareearthions[1,2 ] .Panetal.[3 ] showedthatCe3 formsa 1∶1com… 相似文献
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Inrecentyears ,researchonnewmaterialswithimprovedspectralpropertiesfordiodepumpingisofincreasinginterest ,sincediode laserpumpedsolid statelasershavebeenfoundinawidevarietyofappli cationsinthefieldsofmilitary ,industry ,medicaltreatmentandscientificresear… 相似文献
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1 Phenyl 3 methyl 4 acylpyrazol 5 onederivativesarewellknownasβ diketonetypechelatingligandscoordinatingtoametalionwithoxygenatomsas“hard”Lewisbases .Dongetal .[1 ] andYangetal .[2 ] weresynthe sizedaspecialfamilyofbis( 4 acylpyrazol 5 one)derivatives ,inwhich ,two 1 … 相似文献
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SynthesisandCrystalStructureofanErbiumComplexwithValine[Er2(Val)4(H2O)8](ClO4)6·4H2OYangWeichun(杨维春),WangRuiyao(王瑞瑶),JinTian... 相似文献
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Thesynthesisof 3d 4fheteronuclearcom plexesisofinterestforseveralreasons[1~ 9] .Thesecomplexesareimportantinthestudiesofmagneticexchangeinteractionbetweenlan thanideandd transitionmetalions,andtheycanprobablybeusedasmagneticmateri als[2~ 8] .Thecoordinationands… 相似文献
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Synthesis and Structural Determination of Eight Coordinate NH_4[Yb(Ⅲ)(Cydta)(H_2O)_2]·5H_2O 总被引:1,自引:0,他引:1
ecausesomerareearthmetalcompoundshavethepromotiveactiontothegrowthofani malsandplants[1 ] ,andthefunctionofantiin flammation ,antibacterium ,anticoagulantionandanticaner[2 ] ,theinvestigationonthesyn thesesandstructuresoftheeverykindsofrareearthmetalcompounds… 相似文献
14.
MechanochemicalEfectsinLn2O3Ln(OH)3(H2O)(Ln=La,Nd)SystemDimitrTodorovsky,AtanasTerziev(FacultyofChemistry,UniversityofSofia... 相似文献
15.
SynthesisandFluorescenceofTb~(3+)andEu~(3+)ComplexeswithN,N',N"-1,3,5-triazine-2,4,6-triyltris-[N-(carboxymethyl)]-glycine¥Gon... 相似文献
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CrystalStructureandSpectraoftheComplexEu(p-ClC_6H_4COO)_3C_(12)H_8N_2JinLinpei(金林培)(DepartmentofChemistry,BeijingNormalUniversit... 相似文献
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Severalrareearthcomplexeswithcrownethersofstructureformula[RE(OH2)8]Cl3·mL·nH2Ohavebeenstructuralydetermined[1~4],whereL=12c... 相似文献
19.
Synthesis,Characterization,CrystalStructureandQuantumChemistryCalculationoftheMixedLigandComplexes[Ln(CF_3COO)_3·(Phen)_2·(H_2O... 相似文献
20.
Fe(Ⅲ)-Mn(Ⅱ)-As(Ⅴ)-H2O系相图的建立 总被引:1,自引:1,他引:0
依据实验数据利用DIASTAB计算机程序,建立了Fe(Ⅲ)-Mn(Ⅱ)-As(Ⅴ)-H20系的稳定性相图.所建立的相图表明,在pH=3.5~6.0范围内,体系内稳定存在的固体化合物为Fe(Ⅲ)-Mn(Ⅱ)-As(Ⅴ)化合物、MnHAsO4和Mn3(AsO4)2,用DIASTAB计算机程序对实验数据进行逼近计算,算得前者的生成自由能为-245.5kcalmol-1;相图还表明,依靠所研究的体系,水相除砷不可能达到WHO规定的砷最大污染值0.05mg/L的标准. 相似文献