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西他沙星是一广谱喹诺酮类抗菌药,N-(2-溴乙基)-邻苯二甲酰亚胺是其重要的中间体,以自制N-(2-羟乙基)-邻苯二甲酰亚胺和氢溴酸为原料,硫酸为脱水剂合成研究,探讨了原料配比、反应温度、反应时间等反应条件,结果表明合成的最佳条件为原料N-(2-羟乙基)-邻苯二甲酰亚胺与HBr的投料比为2∶9,HBr与浓硫酸的用量比为27∶10,反应温度72℃,反应时间12 h,反应收率可达82%,产品经红外图谱和质谱分析,结果证明产品为目标产物。 相似文献
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在Higashi直接缩聚法的基础上,利用分步投料法,以N,N-己二撑-1,6-双苯偏三酸酰亚胺二胺(IA6)、对羟基苯甲酸(PHB)和对苯二酚二对羟基苯甲酸酯(PHQ)为主要原料,合成了一种新型三元共聚液晶聚酯酰亚胺(IA6PP)。采用FTIR、DSC、TGA、POM和WAXD等方法研究了单体种类对所合成的聚合物结构和性能的影响。结果表明:IA6PP呈现出典型的向列型液晶的特征,液晶温度区间为252~365℃,热稳定性明显高于由4,4-二羟基二苯甲酮(DHBP)、IA6和PHB合成的液晶聚酯酰亚胺(IA6PD)。 相似文献
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一种简便的松果腺素的合成方法 总被引:5,自引:0,他引:5
以邻苯二甲酰亚胺钾、1,3二溴丙烷、对甲氧基苯胺为主要原料,经5步化学反应合成了松果腺素:邻苯二甲酰亚胺钾和1,3-二溴丙烷在155~160℃下反应6h,得到N-(3-溴丙基),邻苯二甲酸亚胺(Ⅱ),产率77%;Ⅱ在乙醇钠存在下和乙酰乙酸乙酯作用得到2-乙酸基-5-邻苯二甲酰亚氨基戊酸乙酯(Ⅲ),产率72%;Ⅲ与对甲氧基苯胺重氮盐偶联后发生环化作用,生成T2-羧乙基-3-(2-邻苯二甲酰亚氨乙基)-5-甲氧基吲哚(Ⅳ),产率74%;Ⅳ经碱皂化、水解、脱羧反萃取纯化,得到5.甲氧基色胺(V),产率66%;V经乙酸化后得到松果腺素(Ⅵ),产率82%。 相似文献
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A new polyesterimide has been synthesized from trimellitic acid anhydride, diaminodiphenylsulfone, and bisphenol-A following three different routes. Solubility behavior in different solvents, solution viscosity, density, crystallinity, and thermal and electrical properties of the polyesterimide have been discussed. Results indicate that the polyesterimide thus prepared has medium thermal stability. 相似文献
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A new type of polyesterimide has been synthesized by polycondensation of a dicarboxylic acid containing an internal imide group with ethylene glycol. The dicarboxylic acid was synthesized by reacting aminobenzoic acid with trimellitic acid anhydride in N, N-dimethylformamide solution. Three isomeric (ortho, meta, and para) polyesterimides were prepared from the respective isomer of the dicarboxylic acid. The solubility characteristics, solubility parameters, solution viscosity behavior, density, crystallinity, and thermal properties of these three isomeric polyesterimides were discussed. Some generalizations about structure–property relationship in polyesterimides were also made. It was found that while the ortho and meta isomers of the polyesterimide are amorphous, the para isomer tends to be somewhat crystalline and consequently less soluble, even in polar solvents. The thermal behavior of the meta isomer resembles closely that of the para isomer. The thermal stability of these isomers follows the order para ≥ meta > ortho. 相似文献
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M. Nedjar 《应用聚合物科学杂志》2011,121(5):2886-2892
The purpose of this investigation is to evaluate thermal lifetime of polyesterimide using Weibull statistics. Thermal aging was performed on twisted pair specimens of copper wire insulated by a polyesterimide layer. The study shows that breakdown voltage varies versus aging time. Its increase is allotted to a crosslinking inducing a diminution of mean‐free path of charge carriers leading thereby to a mobility decrease, whereas its decrease is attributed to the viscosity diminution expressing a weakening of molecular bonds and a mobility increase of charge carriers. Shape parameter changes in function of aging time. Its increase is ascribed to an arrangement of the molecular structure, whereas its decrease is due to an augmentation in the size of defects. The thermal endurance graph is a straight line indicating that the degradation is governed by a first‐order chemical reaction. Activation energy and temperature index were determined. The degradation is governed by the dissolution of copper into the polymer and accelerates its degradation occurring at the polyesterimide–copper interface. Oxygen can diffuse into the insulation and attack copper resulting in the formation of copper oxide. The degradation is caused by the scission of imide and ester bonds. The process is followed by a change in color and a presence of cracks. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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The crystallization and melting behaviors of the polyesterimide, derived from N,N′-hexane-1,6-diylbis(trimellitimides), 4,4′-dihydroxybenzophenone and p-hydroxybenzoic acid, were investigated by using polarized light microscopy (PLM), differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD). The nematic texture of the polyesterimide was observed on raising temperature to 265 °C, and the nematic phase was found to convert to isotropic melt beginning from about 300 °C, the ordered nematic micro-domains still surviving after 320 °C. Isothermal crystallization of the samples was performed at 180 °C after heating samples at various temperatures in the range of 265-360 °C, and a completed crystallization peak can appear on DSC curves up to the heating temperature of 360 °C in the presence of the nematic phase and the ordered nematic micro-domains. Non-isothermal crystallization of the samples at different cooling rate was carried out, and the melting of the resulting crystals exhibits double endotherms. It is indicated that a fast crystallization in the nematic phase forms relatively more ordered crystals, which melt at higher temperature, and a slow crystallization in the isotropic phase or in the biphasic melt produces poor crystals, which melt at lower temperature. The crystallized polyesterimide was annealed, which has a minor effect on the high-melting peak but leads to a continual shifting of the low-melting peak to higher temperature with increasing annealing temperature or annealing time. WAXD patterns indicated that the structural transform was not found during annealing process. 相似文献
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N-(carboxymethyl) trimellitimide, the imidodicarboxylic acid, was prepared by the reaction between trimellitic anhydride and glycine. This was subsequently condensed in N-methyl-2-pyrrolidone with the alcoholysis products obtained from linseed oil and glycerine to get different oil length polyesterimide resins. The drying characteristics of the resins and the physicochemical properties of the clear and the iron oxide pigmented coatings were evaluated. The results indicate that these materials form a promising class of film—formers for coatings of good durability and protective properties. 相似文献
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Polyesterimide (PEI) and phenol formaldehyde (PF) samples were synthesized, and composites of the two polymers, as well as composites with carbon, were prepared. Using a pinon-disc machine, the friction and wear properties of the following samples were studied in the load range of two to eight bars:
- Phenolformaldehyde vs. steel
- Phenol formaldehyde cured with hexamethylenetetramine vs. steel
- Polyesterimide vs steel
- Polyesterimide and carbon composite vs steel
- Phenol formaldehyde vs polyesterimide
- Phenol formaldehyde and polyesterimide composite vs. phenol formaldehyde
- Phenol formaldehyde and polyesterimide composite vs. steel.
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This article is aimed at the investigation of electrical aging of polyesterimide under AC voltage using Weibull statistical analysis. It's shown that the time to breakdown characteristic (V–t) of polyesterimide includes two zones (segments of straight line). The first zone characterizes a statistical dispersion of the intrinsic defects of material. The second zone expresses the real aging of polymer. The variation of the slope of lifetime curve is attributed to the change in the degradation mechanism. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
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We investigated the thermal decomposition behavior of three groups of polyesterimides that had been synthesized from different compositions of monomers that were added in different. We characterized these polymers with thermogravimetric analysis (TGA) and calculated the apparent activation energy (Ea) associated with the thermal decomposition process by the Ozawa method. The results showed that the Ea of the polyesterimides was correlated with the length of the methylene spacer and the content of the 4,4′‐dihydroxybenzophenone monomer. The polyesterimide with four methylene spacers in the main chain had a higher Ea than that with six methylene spacers. The polyesterimide with a higher 4,4′‐dihydroxybenzophenone content provided better thermal stability. The Ea of the polyesterimides also depended on the sequence in which the monomers were added during the copolycondensation process. The Ea of these polyesterimides followed the order: p‐hydroxybenzoic acid added first > p‐hydroxybenzoic acid mixed 4,4′‐dihydroxybenzophenone adding > 4,4′‐dihydroxybenzophenone added first. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 2467–2472, 2005 相似文献
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