稀土变质处理ZnAl4合金的研究

为改善和提高ZnAl4合金的力学性能,采用Ce基混合稀土对ZnAl4合金进行变质处理,研究了稀土对ZnAl4合金力学性能的影响规律.结果表明,稀土的加入能够显著细化ZnAl4合金的铸态组织,共晶组织区域增加.随着稀土含量的增加,合金的力学性能得到不同程度的改善,当稀土加入量为0.5％时,该合金的综合力学性能最好.     

稀土Ce对7A04铝合金组织和力学性能的影响

通过金相组织分析、扫描电子显微镜观察、能谱仪分析及力学性能测试等手段,研究了稀土Ce对7A04铝合金铸态组织和加工态力学性能的影响。结果表明:当稀土Ce加入量为0.39%时,7A04铝合金的晶粒最为细小,第二相与夹杂最少,合金基体组织得以改善。稀土Ce的加入使合金中生成了大量的CeAl_2和Al_4Cu_2Ce等稀土相。稀土Ce对7A04铝合金硬度影响不大,但是能提高其抗拉强度与伸长率。     

微量稀土Ce对Al-Cu5合金组织和力学性能的影响

制备了稀土Ce添加量分别为0、0.05%、0.10%、0.15%、0.20%的Al-Cu5合金.通过金相显微组织分析和力学性能测试,研究了微量稀土Ce对Al-Cu5合金铸态及相同热处理后的显微组织和力学性能的影响.结果表明:相同热处理条件下,稀土对铝铜合金组织性能的影响取决于它对铸态组织结构的影响,当稀土添加量为0.10%Ce时,稀土对Al-Cu5合金熔体的净化、细化和微合金化综合效应显著,铝合金铸态及热处理后的抗拉强度和伸长率同时达到最大值,分别为180.1 MPa、8.8%和387.4MPa、7.9%.此时,铸态组织中呈黑色点状分布的析出相较少,大小较均匀,树枝状的共晶组织变得分散,且短而薄.     

Ce含量和T6热处理对Al-0.3Fe-0.1Si合金组织与性能的影响北大核心

研究了稀土元素Ce和T6热处理工艺对Al-0.3Fe-0.1Si合金组织和性能的影响。结果表明，添加适量的稀土Ce和T6热处理均可抑制晶粒长大，并有效细化Al-0.3Fe-0.1Si合金的晶粒尺寸。当稀土Ce的加入量为0.2%时，铸态合金的抗拉强度为81.7 MPa，比加入量为0.1%时提高了10.7%。稀土Ce的加入量为0.3%时，T6态合金的电导率为58.13%IACS，比铸态合金提高了2.3%。热处理前后的Al-0.3Fe-0.1Si-0.1Ce合金与Al-0.3Fe-0.1Si-0.3Ce合金的电导率接近。当稀土Ce的加入量为0.1%～0.2%时Al-0.3Fe-0.1Si合金获得较好的综合性能。本研究的结果可为导电Al-0.3Fe-0.1Si合金制备提供理论和试验参考。     

稀土对AZ61镁合金变形过程中组织与性能的影响

研究了不同的稀土含量(富Ce和Mg-Nd中间合金)对AZ61镁合金在热挤压变形过程中显微组织和力学性能的影响。结果表明,在加入1%～4%的混合稀土后,铸态AZ61镁合金组织中的β相明显减少,铸态组织晶粒得到细化,大部分的Ce,Nd与Al结合生成高熔点、高稳定性的稀土相Al4Ce或者Al4Ce和Al3Nd稀土混合相,并呈针状、棒状或者不规则块状分布于晶界或晶粒内部,同时各试验合金中均不同程度分布有不规则的块状α-Al8Mn5相;在热挤压过程中,Al4Ce或者Al4Ce和Al3Nd稀土混合相阻碍晶粒或亚晶粒长大,使晶粒较铸态组织变细,合金力学性能随稀土含量的增加有所提升,但由于稀土相较粗大,割裂晶界及晶粒间的结合力,使其性能大幅度下降;铸态AZ61+xRE各试验合金均为脆性断裂机制,挤压态AZ61合金断裂方式属于以韧性为主的韧脆混合断裂,含稀土挤压态合金中分布有塑性特征的韧窝,但主要以解理断裂为主。     

稀土Ce对Al-10Mg合金组织及力学性能的影响

研究了添加稀土Ce及固溶处理对Al-10Mg合金显微组织及力学性能的影响。添加Ce能够细化Al-10Mg合金的铸态组织,并形成Al4Ce相,固溶处理可使Al3Mg2相溶解。随Ce添加量的增加,Al4Ce相由弥散分布的颗粒状、短杆状形态转变为粗大连续的枝状形态。综合考虑,添加0.4%的Ce对提高Al-10Mg合金的力学性能最为有效。     

Ce对Mg-Li-Al合金组织及力学性能的影响

研究了Ce对Mg-16Li-5Al合金铸态组织及力学性能的影响。结果表明,加入Ce后,晶粒细化,随稀土化合物Al2Ce的增加,Mg17Al12、AlLi两相减少;Ce的加入提高了合金的强度和耐热性能,大量Al2Ce的存在,易割裂基体,使强度降低;分布在晶界附近的稀土化合物改变了合金的断裂方式。     

微量元素Sc对ZA27合金组织与性能的影响

试验研究了微量元素Sc对ZA27合金铸态显微组织与力学性能的影响规律。试验结果表明:单独添加合金元素Sc,在Sc的加入量为0.5%时,ZA27合金铸态显微组织细化效果较好,粗大的树枝晶组织转变为均匀、细小的团絮状组织,晶界共晶体组织变得更为细小。合金的铸态抗拉强度和硬度分别达到了495MPa和HB120.2,伸长率达到7.6%。元素Sc在ZA27合金中与Al形成了与基体晶格类型和晶胞尺寸极为相近的Al3Sc粒子,起到了促进异质形核和细晶强化的作用,从而提高了合金的力学性能。     

稀土对AlZnMgCu合金铸态组织和力学性能影响

研究了单一稀土铈(Ce)、钇(Y)对航空用铝合金AlZnMeCu铸态枝晶组织和力学性能的影响规律。结果表明,稀土元素能有效细化合金的二次枝晶组织,减小最大共晶化合物尺寸。稀土的加入使合金的时效强度、硬度有所下降,但少量稀土可改善合金的冲击韧性。     

稀土加入量对A356合金力学性能的影响

研究了混合稀土对A356合金的铸态，固溶态、T6状态的组织和力学性能的影响，推出了合理的稀土加入量。     

Ce对Zn-Al合金组织性能的影响

研究了Ｃｅ对ＺｎＡｌ合金（ＺＡ２７、ＺＡ４３）的力学性能、淬火时效特性及耐磨性的影响。结果表明,Ｃｅ能明显细化合金的铸态组织,提高其强度和塑性。当ＺＡ２７和ＺＡ４３中含Ｃｅ量分别为０．１０％和０．１５％时,获得最佳的力学性能。提出了Ｃｅ细化ＺｎＡｌ合金的机理,加Ｃｅ后成分过冷效应所引起的枝晶熔断脱落对细化α相起主要作用。     

RE对ZA43合金组织、力学性能及抗磨性的影响

通过RE对ZA43合金进行变质处理,研究了该合金的显微组织、力学性能及抗磨性能。结果表明,在ZA43合金中加入适量RE,能有效地阻止树枝状晶长大,优化组织结构,细化晶粒,使合金的抗拉强度提高20%、硬度提高10%,抗磨性能也大幅度改善。这为进一步改善该合金的力学性能及抗磨性能提供了一条有效途径,从而使锌合金代替铜合金成为可能和现实。     

Effect of Mg-based spherical quasicrystal on microstructures and mechanical properties of ZA54 alloy

To improve the strength,toughness and heat-resistance of magnesium alloy,the microstructure and mechanical properties of ZA54 alloy reinforced by icosahedral quasicrystal phase(I-phase) particles were studied.Exceptα-Mg,φ-phase andτ-phase,MgZnYMn I-phase particles can be obtained in ZA54-based composites by the addition of icosahedral quasicrystal-contained Mg-Zn-Y-Mn master alloy.The introduction of MgZnYMn I-phase into ZA54 alloy has great contribution to the refinement of matrix microstructures and the improvement of mechanical properties.When the addition of Mg-based spherical quasicrystal master alloy is up to 3.5%(mass fraction) ,the macro-hardness of ZA54-based composites is increased to HB 68.The impact toughness of composites reaches the peak value of 18.3 J/cm2,which is about 29%higher than that of ZA54 mother alloy.The highest tensile properties at ambient and elevated temperatures with master alloy addition of 2.5%(473 K) are also obtained in ZA54-based composites with 3.5%(mass fraction) Mg-Zn-Y-Mn master alloy addition.The ultimate tensile strength of composites at ambient and elevated temperatures are 192.5 MPa and 174 MPa,which are 23.4%and 33.8%higher than that of ZA54 mother alloy,respectively. The improved mechanical properties are mainly attributed to the pinning effect of I-phase on grain boundaries.     

Ca对ZA63合金组织和力学性能的影响

通过合金制备、微观分析和力学性能测试等方法研究了Ca对ZA63合金微观组织和力学性能的影响.结果表明,当加入Ca元素后,舍金晶粒细化,半连续网状的τ相变为细小粒状或棒状,颗粒状τ相更为细小,并形成了细小高熔点Al_2Ca相.随着Ca含量的增加,固溶时效态合金在室温、150℃和175℃温度下的抗拉强度和延伸率基本上呈先升高后降低的趋势.当Ca含量为1.0%时,合金在各温度下的抗拉强度和延伸率都达到最大值.     

TiC颗粒对ZA43合金组织及力学性能的影响

采用 XD法与搅拌铸造法相结合的工艺制备了 Ti C/ZA43复合材料 (0 相似文献   

Microstructure and mechanical properties of ZA62 based magnesium alloys with calcium addition

As-cast microstructure and mechanical properties of Mg-6Zn-2Al-0.3Mn (ZA62) alloys with calcium addition were investigated.The as-cast microstructure of the base alloy ZA62 consists of the α-Mg matrix and eutectic phase Mg51Zn20.The Mg51Zn20 eutectic was gradually replaced by MgZn phase and Mg32(Al,Zn)49 phase when calcium is added into the base alloy.Further addition of calcium leads to the increase of grain boundary phases and formation of a new quaternary Mg-Zn-Al-Ca eutectic compound.In comparison with the base alloy,the increase of calcium addition to the base alloy results in the reduction of both strength and ductility at ambient temperature,but increase at elevated temperatures due to the thermal stability of Ca-containing phases.At elevated temperatures,the creep resistance of ZA62 based alloys containing calcium is significantly higher than that of AZ91 which is the most commonly used magnesium alloy.     

Effects of minor Sr,Sn and Sc addition on as-cast microstructure and mechanical properties of ZA84 magnesium alloy

The effects of minor Sr, Sn and Sc addition on the as-cast microstructure and mechanical properties of the ZA84 magnesium alloy were compared. The results indicate that addition of 0.1%Sr, 0.5%Sn or 0.3%Sc (mass fraction) to the ZA84 alloy can refine the grains of the alloy. Furthermore, addition of 0.1%Sr to the ZA84 alloy does not obviously change the morphology and distribution of Mg32(Al,Zn)49 phase. However, addition of 0.5%Sn or 0.3%Sc not only refines and modifies the Mg32(Al,Zn)49 phase but also suppresses the formation of Mg32(Al,Zn)49 phase, especially with the addition of 0.3%Sc. Furthermore, addition of 0.1%Sr, 0.5%Sn or 0.3%Sc to the ZA84 alloy improves the tensile properties at room temperature and 150℃, especially with the addition of 0.1%Sr and 0.3%Sc. However, addition of 0.1%Sr is not beneficial to the creep properties, and addition of 0.5%Sn has no obvious influence on the creep properties. Oppositely, addition of 0.3%Sc to the ZA84 alloy greatly improves the creep properties.     

热处理对挤压铸造ZA43—Mn合金组织和性能的影响

研究了热处理对冲头式挤压铸造ZA43-Mn合金显微组织和力学性能的影响。结果表明：挤压铸造ZA43-Mn合金的时效处理使α和β相分解,枝晶偏析减轻,富锰相碎化与钝化,可提高其塑性（δ5=18%）。固溶处理使富锰相和富铜相分解,基体内二次相弥散析出,晶间组织形态和分布改善,可获得较高强度的铸件（δb=510MPa)。     

Effects of spherical quasi-crystal on microstructure and mechanical properties of ZA155 high zinc magnesium alloy

Effects of spherical quasi-crystal contained in Mg-Zn-Y-Mn master alloy on the microstructure and as-cast mechanical properties of ZA155 high zinc magnesium alloy have been investigated by means of optical microscopy, XRD, SEM, EDS, tensile test, impact test and hardness test. Experimental results show that the addition of spherical quasi-crystal contained in the Mg-Zn-Y-Mn master alloy into the ZA155 high zinc magnesium alloy resulted in grain refinement of the matrix, changing the morphologies of φ-Al2Mg5Zn2 phase and τ-Mg32(Al,Zn)49 phase from continuous net-like structures to discontinuous strip-like structure and blocky one, respectively.In the present research, the best comprehensive mechanical properties of reinforced ZA155 high zinc magnesium alloy has been obtained when 5.0wt% spherical quasi-crystal was introduced from the Mg-Zn-Y-Mn master alloy into the target alloy system. In such case, the room-temperature tensile strength reached 207 MPa, about 23% higher than that of the base alloy; the impact toughness peaked at 5.5 J/cm2, about 40% higher than that of the base alloy; and the elevated-temperature tensile strength reached 203 MPa, indicating improved heat resistance.     

均匀化处理对ZA35-0.3Zr合金组织及性能的影响

为了探索均匀化处理对ZA35-0.3Zr合金组织和性能的影响规律,通过组织分析、力学性能、电化学性能测试,确定了ZA35-0.3Zr合金均匀化处理的适宜温度和时间。结果表明,ZA35-0.3Zr合金枝晶偏析明显,晶界上Cu富集严重,存在非平衡β相。随着均匀化处理时间增加,ZA35-0.3Zr合金中CuZn5相逐渐消除,β相共析分解程度加大。对合金进行370℃×12h均匀化处理后,晶界处CuZn5相消除,枝晶偏析大大减少,同时非平衡β相基本消除,抗拉强度为306MPa,伸长率为7.35%。在3.5%的NaCl溶液中,开路电位与未均匀化处理合金相比变正,腐蚀电流密度减小了33.1%,耐腐蚀性增强。ZA35-0.3Zr合金适宜的均匀化处理工艺为370℃×12h。