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硬段含量对脂肪族阴离子水性聚氨酯性能的影响 总被引:1,自引:0,他引:1
以异佛尔酮二异氰酸酯和聚酯多元醇为主要原料,用预聚混合法合成了一系列硬段含量不同的脂肪族阴离子水性聚氨酯纳米乳液。通过FTIR、GPC、DSC等,研究了硬段含量对产品结构和性能的影响。结果表明,随着硬段含量增加,乳液平均粒径逐渐增大但仍小于100nm,粒径分布逐渐变宽;分子结构中成氢键的脲键增多;数均相对分子量略有增加;DSC分析表明软段玻璃化温度向低温漂移,而硬段玻璃化温度向高温漂移,说明两相微相分离程度增加。硬段含量为30%时胶膜拉伸强度最高达52MPa,而断裂伸长率随硬段含量增加从2250%急剧减小到863%。耐水性在硬段含量最高时最佳。 相似文献
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硬段含量对水性聚氨酯性能的影响 总被引:6,自引:0,他引:6
以聚酯多元醇和异佛尔酮二异氰酸酯(IPDI)为主要原料,引入亲水单体二羟甲基丙酸(DMPA),按不同配比合成了系列聚氨酯乳液。考察了硬段含量对乳液粒径、表观黏度、膜吸水性、硬度、力学性能的影响,并通过动态力学性能测试(DMA)研究了软段和硬段的玻璃化转变温度。结果表明:提高-NCP/-0H物质的量之比、DMPA用量均使聚氨酯中软段的玻璃化温度Tg(s)降低,硬段的玻璃化温度Tg(h)升高,△T值增加,软硬段相分离程度增加。随乙二胺用量的增加,会使软段玻璃化转变温度Tg(s)移向高温,软硬段相分离程度降低;硬段含量提高,胶膜硬度增加,拉伸强度增加,胶膜耐水性降低。 相似文献
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硬段含量对聚氨酯和聚氨酯脲氢键化程度的影响 总被引:1,自引:0,他引:1
以PPG600,PPG2000,甲苯二异氰酸酯(TDI)和1,4-丁二醇(1,4-BD)为原料合成了聚氨酯(PU),通过改变PPG600,PPG2000配比调节产品硬段含量;以PPG2000,TDI和异佛尔酮二胺(IPDA)为原料合成了聚氨酯脲(PUU),通过调节TDI与IPDA在体系中的比例调节产品硬段含量。利用FT-IR,DSC,旋转黏度计研究了硬段含量对聚醚型PU和PUU的微观结构及黏度的影响。结果表明,随硬段含量提高,PU和PUU的氢键化程度均提高,PU较多地形成不完善的氢键,而PUU倾向于形成完善有序的氢键结构。此外随硬段含量增大,PU和PUU的黏度增大,PU软段的玻璃化转变温度升高。 相似文献
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以PPG600和PPG2000混合聚醚、异佛尔酮二异氰酸酯(IPDI)和异佛尔酮二胺(IPDA)为原料合成溶剂型聚氨酯脲(Puu)树脂,通过改变PPG600和PPG2000配比调节树脂硬段含量。利用FTIR.DSC.TG等研究PPG600和PPG2000配比对聚氨酯脲微观结构、耐热性及力学性能的影响。结果表明,随着混合聚醚中PPG600含量增加,聚氨酯脲软段的玻璃化转变温度(Tg)升高,软硬段的相容性增强,脲羰基氢键化程度降低,树脂的定伸强度增大。 相似文献
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不同硬段含量聚天冬氨酸酯聚脲结构和性能研究 总被引:5,自引:0,他引:5
通过聚天冬氨酸酯、端氨基聚醚与脂肪族异氰酸酯六亚甲基二异氰酸酯三聚体/预聚物反应,合成了纯硬段聚脲和不同硬段含量的聚脲,并考察了硬段含量对聚脲的结构形态、动态力学性质和力学性质的影响。硬段含量为73%~50%的聚脲呈现微相分离的形态,随着硬段含量降低,软段和硬段相的混合程度提高,脲羰基的氢键化程度增加,NH基氢键键长增加,硬段玻璃化转变温度Tgh降低,软段玻璃化转变温度Tgs的变化幅度较小,微相分离程度降低。材料的拉伸强度、模量和硬度随着硬段增加而提高,弹性则随之降低。 相似文献
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红外光谱法研究聚氨酯脲氢键 总被引:1,自引:0,他引:1
采用间苯二胺为扩链剂制备聚氨酯脲,研究其力学性能。随着硬段含量的增加,产物的硬度和强度均增加,而断裂伸长率下降。并用红外光谱法对氢键化程度进行表征,结果表明:随着硬段含量的增加,其脲羰基区氢键化程度增加。 相似文献
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M. S. J. Simmonds W. M. Blaney F. Delle Monache M. Marquina Mac-Quhae G. B. Marini Bettolo 《Journal of chemical ecology》1985,11(12):1593-1599
Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria. 相似文献
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Cheng-Le Zhao Shane Porzio Alan Smith Haiyan Ge H. T. Davis L. E. Scriven 《Journal of Coatings Technology and Research》2006,3(2):109-115
Despite its industrial importance, the subject of freeze-thaw (F/T) stability of latex coatings has not been studied extensively.
There is also a lack of fundamental understanding about the process and the mechanisms through which a coating becomes destabilized.
High pressure (2100 bar) freezing fixes the state of water-suspended particles of polymer binder and inorganic pigments without
the growth of ice crystals during freezing that produce artifacts in direct imaging scanning electron microscopy (SEM) of
fracture surfaces of frozen coatings. We show that by incorporating copolymerizable functional monomers, it is possible to
achieve F/T stability in polymer latexes and in low-VOC paints, as judged by the microstructures revealed by the cryogenic
SEM technique. Particle coalescence as well as pigment segregation in F/T unstable systems are visualized. In order to achieve
F/T stability in paints, latex particles must not flocculate and should provide protection to inorganic pigment and extender
particles. Because of the unique capabilities of the cryogenic SEM, we are able to separate the effects of freezing and thawing,
and study the influence of the rate of freezing and thawing on F/T stability. Destabilization can be caused by either freezing
or thawing. A slow freezing process is more detrimental to F/T stability than a fast freezing process; the latter actually
preserves suspension stability during freezing.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004 in Chicago,
IL. Tied for first place in The John A. Gordon Best Paper Competition. 相似文献
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It is well established that a wide range of drugs of abuse acutely boost the signaling of the sympathetic nervous system and the hypothalamic–pituitary–adrenal (HPA) axis, where norepinephrine and epinephrine are major output molecules. This stimulatory effect is accompanied by such symptoms as elevated heart rate and blood pressure, more rapid breathing, increased body temperature and sweating, and pupillary dilation, as well as the intoxicating or euphoric subjective properties of the drug. While many drugs of abuse are thought to achieve their intoxicating effects by modulating the monoaminergic neurotransmitter systems (i.e., serotonin, norepinephrine, dopamine) by binding to these receptors or otherwise affecting their synaptic signaling, this paper puts forth the hypothesis that many of these drugs are actually acutely converted to catecholamines (dopamine, norepinephrine, epinephrine) in vivo, in addition to transformation to their known metabolites. In this manner, a range of stimulants, opioids, and psychedelics (as well as alcohol) may partially achieve their intoxicating properties, as well as side effects, due to this putative transformation to catecholamines. If this hypothesis is correct, it would alter our understanding of the basic biosynthetic pathways for generating these important signaling molecules, while also modifying our view of the neural substrates underlying substance abuse and dependence, including psychological stress-induced relapse. Importantly, there is a direct way to test the overarching hypothesis: administer (either centrally or peripherally) stable isotope versions of these drugs to model organisms such as rodents (or even to humans) and then use liquid chromatography-mass spectrometry to determine if the labeled drug is converted to labeled catecholamines in brain, blood plasma, or urine samples. 相似文献
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Ethanol and (−)-α-Pinene: Attractant Kairomones for Bark and Ambrosia Beetles in the Southeastern US
In 2002–2004, we examined the flight responses of 49 species of native and exotic bark and ambrosia beetles (Coleoptera: Scolytidae
and Platypodidae) to traps baited with ethanol and/or (−)-α-pinene in the southeastern US. Eight field trials were conducted
in mature pine stands in Alabama, Florida, Georgia, North Carolina, and South Carolina. Funnel traps baited with ethanol lures
(release rate, about 0.6 g/day at 25–28°C) were attractive to ten species of ambrosia beetles (Ambrosiodmus tachygraphus, Anisandrus sayi, Dryoxylon onoharaensum, Monarthrum mali, Xyleborinus saxesenii, Xyleborus affinis, Xyleborus ferrugineus, Xylosandrus compactus, Xylosandrus crassiusculus, and Xylosandrus germanus) and two species of bark beetles (Cryptocarenus heveae and Hypothenemus sp.). Traps baited with (−)-α-pinene lures (release rate, 2–6 g/day at 25–28°C) were attractive to five bark beetle species
(Dendroctonus terebrans, Hylastes porculus, Hylastes salebrosus, Hylastes tenuis, and Ips grandicollis) and one platypodid ambrosia beetle species (Myoplatypus flavicornis). Ethanol enhanced responses of some species (Xyleborus pubescens, H. porculus, H. salebrosus, H. tenuis, and Pityophthorus cariniceps) to traps baited with (−)-α-pinene in some locations. (−)-α-Pinene interrupted the response of some ambrosia beetle species
to traps baited with ethanol, but only the response of D. onoharaensum was interrupted consistently at most locations. Of 23 species of ambrosia beetles captured in our field trials, nine were
exotic and accounted for 70–97% of total catches of ambrosia beetles. Our results provide support for the continued use of
separate traps baited with ethanol alone and ethanol with (−)-α-pinene to detect and monitor common bark and ambrosia beetles
from the southeastern region of the US. 相似文献
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Peter A. Edwards Grant Striemer Dean C. Webster 《Journal of Coatings Technology and Research》2005,2(7):517-527
Glycidyl carbamate chemistry combines the excellent properties of polyurethanes with the crosslinking chemistry of epoxy resins.
Glycidyl carbamate functional oligomers were synthesized by the reaction of polyfunctional isocyanate oligomers and glycidol.
The oligomers were formulated into coatings with several amine functional crosslinkers at varying stoichiometric ratios and
cured at different temperatures. Properties such as solvent resistance, hardness, and impact resistance were dependent on
the composition and cure conditions. Most coatings had an excellent combination of properties. Studies were carried out to
determine the kinetics of the curing reaction of the glycidyl carbamate functional oligomers with multifunctional and model
amines. Detailed kinetic analysis of the curing reactions was also undertaken. The results indicated that the glycidyl carbamate
functional group is more reactive than a glycidyl ether group.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, on October 27–29, 2004, in Chicago,
IL. 相似文献