共查询到18条相似文献,搜索用时 234 毫秒
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冠醚化学交换分离锂同位素的影响因素分析及进展 总被引:1,自引:0,他引:1
锂同位素6 Li和7 Li是核聚变所需的重要原料,故锂同位素分离是核能开发必须解决的关键技术。本文系统综述了以冠醚类化合物为化学交换体系分离锂同位素的研究进展,详细讨论了冠醚分子的结构如冠醚环大小、给体原子种类、侧链种类,以及锂盐配位阴离子种类,溶剂种类,化学交换温度等因素对冠醚锂同位素分离效应的影响规律。结果表明,冠醚类化合物具有高的锂同位素分离因子,是非常有前途的锂同位素分离方法,但是以小分子冠醚为萃取剂的液-液萃取体系冠醚易于流失,无法重复利用,因此其未来发展方向是制备冠醚固载聚合物,采用固载冠醚的液-固体系分离锂同位素,提高分离效率,以实现其工业化应用。 相似文献
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杯芳烃作为继冠醚和环糊精之后的第三代超分子主体化合物,其应用领域日益广泛。本文综述了杯芳烃及其衍生物在医药、分子离子识别、模拟酶、相转移催化剂等方面的研究进展。 相似文献
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《精细化工原料及中间体》2018,(10)
正一、项目简介超分子作用是一种具有分子识别能力的分子间相互作用,以分子识别为基础,设计、合成、组装具有新颖性能的超分子功能材料,将为分析科学提供理论指导和新的应用体系,为生命科学、材料科学、环境科学等共同发展做出巨大贡献。将超分子化学与纳米化学进行有机地结合,采用冠醚、环糊精、杯芳烃等超分子主体化合物与与多种纳米材料相结合, 相似文献
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杯芳烃是继环糊精,冠醚之后又一类新兴的大环化合物,以其出色的超分子化学性能日益引起化学,化工界的关注。本文综合近年来的文献报道,介绍了杯芳烃及其衍生物的合成以及目前杯芳烃在诸多工业领域中的应用与发展前景。 相似文献
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Jing Ji Yongsheng Chen Yulai Zhao Hongtao Zhang 《Polymer-Plastics Technology and Engineering》2013,52(14):1494-1505
Chitosan is considered as a promising material in the pharmaceutical and biomedical fields based on its unique biological properties. This review presents chemical modifications of chitosan via using photosensitizers, dendrimers, sugars, cyclodextrins and crown ethers as modifiers and places an emphasis on the applications of chitosan derivatives as carriers in drug delivery systems, as supporting materials for tissue engineering, as dye removing agents and as metal ion adsorbents. Recently, the progress on chemical modifications of chitosan is quite rapid and we are confident that a more extensive range of applications of chitosan derivatives could be expected in the near future. 相似文献
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ABSTRACT The extraction of alkali metal nitrate salts by solutions of crown ethers in each of the two diluents 1,2-dichlorethane and 1-octanol has been surveyed. The crown ethers include 18-crown-6, 21-crown-7, and 24-crown-8 ethers bearing cyclohexano, benzo, t-alkylbenzo, and/or furano substitutents. The extraction efficiencies of the different crown ethers are examined in terms of ring-size, substituent, and solvent effects. Partition ratios for the crown ethers between water and either 1,2-dichloroethane or 1-octanol are discussed. The extraction selectivities, expressed as the separation factor for cesium over sodium, are examined in relation to crown ether structure. 相似文献
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《Inorganic chemistry communications》2001,4(1):9-11
The complex formation between large crown ethers – e.g. dibenzo-30-crown-10 – and Ag+ in propylene carbonate has been studied using potentiometric and calorimetric titrations. The values of the reaction enthalpies with larger crown ethers than 18-crown-6 especially with dibenzo-30-crown-10 indicate that more than six donor atoms are taking part in the interaction with the complexed cation. The values of the reaction entropies of the largest crown ethers examined indicate the high sterical requirements of the complex formation. Obviously large crown ethers are able to encapsulate the complexed cation. The effectiveness of the encapsulation however depends upon the ring size and flexibility of the crown ethers. 相似文献
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介绍了冠醚化学的产生、发展及应用,详细介绍了:几种新型臂式冠醚及其超分子金属配合物的合成;取代冠醚及其金属配合物的合成及应用;新型氮杂冠醚及其金属配合物的合成及应用。并对冠醚化学的发展进行了展望。 相似文献
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《Dyes and Pigments》2009,80(3):270-272
The syntheses and fluorescence properties of a series of novel crown ethers containing coumarin group are presented. 2-(Benzocourmarin-3-acyloxymethyl) crown ethers were synthesized by reacting the acyl chloride of benzocourmarin-3-carboxylic acid with 2-hydroxymethyl crown ethers, while 4′-(benzocourmarin-3-carboxamido) benzo crown ethers were secured by reacting the acyl chloride of benzocourmarin-3-carboxylic acid with 4′-aminobenzo crown ethers. Only the ester-type crown ethers were fluorescent. As the polarity of the solvent increased, the emission maximum λem showed a slight red shift. DMSO was used as the fluorescence quenching solvent. Increased fluorescence was observed upon the addition of alkali and alkaline earth metal ions. 相似文献
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The effect of some new crown ethers on the cation efflux and phase transition parameters of dipalmitoyl phosphatidylcholine
liposomes was studied. The effects were correlated with the lipophilicity of the crown ethers. The results indicate that the
presence of two crown ring structures in one crown ether molecule is a prerequisite for the increase of ion permeability of
liposomes. The effective crown ethers decrease the temperature, enthalpy and cooperativity of the gel-to-liquid crystalline
phase transition. The crown ethers increase membrane permeability for potassium and, to a lesser extent, for rubidium and
sodium. The ratio of permeability increase for potassium/rubidium significantly correlates with the lipophilicity of the crown
ethers. 相似文献
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Four novel Schiff‐type chitosan (CTS)‐crown ethers were synthesized through a reaction between ? NH2 in CTS or crosslinked chitosan (CCTS) and ? CHO in 4′‐formylbenzo‐crown ethers, and four secondary‐amino‐type CTS‐crown ethers were prepared through the reduced reaction of NaBH4, respectively. Their structures were characterized by elemental analysis, Fourier transform infrared (FTIR) spectra analysis, solid‐state 13C‐NMR analysis, and X‐ray diffraction (XRD) analysis. The elemental analysis results showed that the percentage of nitrogen in all CTS‐crown ethers were lower than that of CTS or CCTS. From the FTIR data of CTS, CCTS, and CTS‐crown ethers I–VIII, we saw that the characteristic peaks of C?N, N? H, and Ar appeared and that the characteristic peaks of pyranoside in the chain of CTS or CCTS were not destroyed. The XRD spectra demonstrated that CTS‐crown ethers I–VIII gave lower crystallinities than CTS or CCTS, which indicated that these compounds were considerably more amorphous than CTS or CCTS. In the solid‐state 13C‐NMR spectra, all of these CTS‐crown ethers had a particular peak of aromatic at 128 or 129 ppm, and the greatest difference between Schiff‐type CTS‐crown ethers and secondary‐amino‐type CTS‐crown ethers was that the Schiff‐type CTS‐crown ethers had the particular peak of C?N, which disappeared in secondary‐type CTS‐crown ethers. All these facts confirmed that the structures of CTS‐crown ethers I–VIII were as expected. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 87: 2221–2225, 2003 相似文献
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介绍了冠醚化学的产生发展及应用,详细综述了:①新型冠醚的合成及其对阳离子的选择性识别作用;②新型双冠醚配体及其稀土过渡金属配合物的合成;③新型氮杂冠醚的合成及应用。并对冠醚化学的发展进行了展望。 相似文献