Hydrochemistry of the hyporheic zone in salmon spawning gravels: a preliminary assessment in a degraded agricultural stream

Hydrochemical changes were monitored in a simulated, sea run salmon redd in a small agricultural stream in northeast Scotland following the 1998–1999 spawning season. Immediately after redd construction, the hydrochemical characteristics of hyporheic water, at depths of 0.1 m and 0.3 m, were very similar to stream water. These apparently well‐mixed waters were alkaline, well‐oxygenated and enriched in nutrients. In the weeks and months following redd construction, clear and statistically significant differences in the chemistry of stream and hyporheic waters were observed. Typically, hyporheic water had lower concentrations of dissolved oxygen (mean 7.35 mg L^?1 at 0.3 m depth) than stream waters (mean=11.26 mg L^?1). Alkalinity, calcium, sulphate and conductivity levels tended to be higher in hyporheic waters, with concentrations increasing with depth. These data implied an increasing influence of groundwater with depth in the hyporheic zone following redd construction; an inference supported by subsequent hydraulic head measurements, which revealed an upwards groundwater flux in the stream bed. However, groundwater–surface water interactions were dynamic and complex: road salts eluted into the stream during periods of snowmelt simulated tracer experiments that implied that a reversed hydraulic gradient may occur at high flows with deeper streamwater penetration and mixing in the hyporheic zone. High flows also result in the mobilization of fine sediments from the stream bed which subsequently infiltrated into spawning gravels. These appear to cause ‘capping’ of redds and probably reduce the hydraulic conductivity of the redd matrix. Infiltrating sediments also contain a small, but probably important organic component, the decomposition of which may contribute to oxygen consumption and nutrient mineralization in the hyporheic zone. Copyright © 2001 John Wiley & Sons, Ltd.     

Anaerobic microbial metabolism in hyporheic sediment of a gravel bar in a small lowland stream

Distribution of dissolved oxygen, nitrate, sulphate, carbon dioxide and dissolved organic carbon (DOC), acetate and lactate was studied in the stream and interstitial water along the subsurface flowpath in the hyporheic zone of a small lowland stream. Sediments were found to act as a source of nitrous oxide and methane. Interstitial methane concentrations were significantly much higher in comparison to those from surface water, and were significantly lower in the relatively well oxygenated downwelling zone than in the rather anoxic upwelling zone. The interstitial concentrations of O₂, NO₃^?1 and SO₄^?2 showed significant decline along the subsurface flowpath, while concentrations of CO₂, N₂O, DOC, acetate and lactate remained unchanged. In addition to field measurements, ex situ incubation of sediments was carried out in the laboratory. Maximal methane production was found in the incubation assay using acetate (mean value 380 µg CH₄ kg DW^?1 d^?1). Mean value of the denitrification potential was 1.1 mg N₂O kg DW^?1 d^?1. Nitrous oxide production potential reached 71–100% of denitrification potential. Our results demonstrate that respiration of oxygen, nitrate, sulphate and methanogenesis may coexist within the hyporheic zone and that anaerobic metabolism is an important pathway in organic carbon cycling in the Sitka stream sediments. Copyright © 2005 John Wiley & Sons, Ltd.     

Survival of salmonid eggs in a degraded gravel‐bed stream: effects of groundwater–surface water interactions

The effect of hyporheic water quality on developing salmonids was assessed between spawning and hatch. Results from a low‐lying degraded agricultural catchment (Newmills Burn) were compared with those from a near‐pristine upland spawning stream (Girnock Burn), providing a set of comparisons beyond the range of hyporheic conditions present in the Newmills Burn. It was demonstrated that hyporheic water quality in the Newmills Burn varied temporally and spatially as a consequence of variable fluxes of chemically reduced groundwater through heterogeneous drift deposits. Mortality rates from samplers located within artificial redds ranged from 0 to 100% and showed a clear negative relationship with mean dissolved oxygen (DO) concentrations (r² = 0.85, P < 0.01). Where embryo mortality was less than 100%, low DO appeared to affect rates of embryo development. Embryos exposed to lower DO concentrations were observed to have a higher percentage mass of yolk sac than those developing in more favourable conditions. The chemical characteristics of hyporheic water in the stream were indicative of the mixing of longer residence regional groundwater with local surface water at shallow depths. The hyporheic water of the Girnock Burn approximated closely to that of surface water suggesting a local origin. Hyporheic water quality affects egg survival and may limit recruitment when egg deposition is marginal or inadequate. A consideration of hyporheic dynamics and groundwater–stream interactions should form part of channel modification or restoration works in salmonid spawning streams. Copyright © 2003 John Wiley & Sons, Ltd.     

Winter application of manure on an agricultural watershed and its impact on downstream nutrient fluxes

Whole Farm Planning was instituted and monitored over a 5-year period within the Graywood Gully sub-watershed of Conesus Lake, NY (USA). An array of agricultural Best Management Practices (BMPs) (strip cropping, fertilizer reduction, tiling, manure disposal practices, etc.) were simultaneously introduced to determine the impact of a concentrated management effort on nutrient and soil loss from one watershed within the Conesus Lake catchment. During the study period, significant decreases in winter concentrations of dissolved and particulate fractions, including total phosphorus (TP), soluble reactive phosphorus (SRP), total Kjeldahl nitrogen (TKN), and nitrate (NO₃) but not total suspended solids (TSS), were observed. These decreases may or may not be attributed to cessation of manuring practices. Three years into the study, an opportunity existed to test the responsiveness of the watershed to the curtailment of a single BMP — winter manure application to fields. We field-tested the hypothesis that a change in winter manure applications would impact dissolved and particulate fractions in stream water draining this watershed. We found that the water quality of Graywood Gully is very responsive to winter manure application on environmentally sensitive portions of the sub-watershed. With the short-term resumption of manure application, TP, SRP, TKN, and NO₃ concentrations rose dramatically in stream water; elevated phosphorus concentrations persisted over a 5-week period. Total suspended solids, however, were not elevated after short-term manure application. Factors that affected these results were slope of the land, application of manure over snow and during a snowfall, warm air and soil temperatures, and possibly tile drainage of snowmelt water. Managers of agricultural systems must recognize that phosphorus losses from the watershed during the nongrowing season may detrimentally affect nuisance population of algae in lakes during the summer.     

Contribution of bunker silo effluent discharged via a riparian zone to watershed phosphorus loads

Nutrient losses from agricultural operations are a major contributor to the eutrophication of freshwaters. Although many studies have quantified diffuse nutrient losses, less is known about agricultural point-source contributions, such as bunker silos, to watershed phosphorus (P) loads. This study examined the contributions of a dairy farm bunker silo effluent to watershed soluble reactive P (SRP) and total P (TP) losses. The bunker silo effluent discharged to an adjacent stream via a riparian soakaway for ca. 15 years. Prior to the annual refilling of the bunker silo, flow weighted mean concentrations of SRP (TP) were similar between stream locations up and downstream of the farm. After the bunker silo was refilled, flow-weighted SRP (TP) concentrations in the stream increased by factors of 1.5(2.2) during events and 3.1(2.3) during baseflow. Higher P concentrations occurred in the riparian soils receiving bunker silo effluent (525–3125 mg/kg TP, and 0.1–9.9 mg/kg water extractable P (WEP), compared with 525–939 mg/kg TP, and 0.11–1.43 mg/kg WEP on the opposite side of the stream with no bunker silo effluent. Riparian soils impacted by the bunker silo were near P-saturation, and the riparian zone did little to reduce P transfer in shallow groundwater. The net contributions of bunker silo effluent to annual watershed P losses were 32% (SRP) and 22% (TP). This study highlights the importance of agricultural point sources, and the need to quantify their contributions to watershed P budgets to target P remediation effectively.     

Seasonal and inter‐annual variability in hyporheic water quality revealed by continuous monitoring in a salmon spawning stream

Over a 3.5 year period, levels of dissolved oxygen (DO) saturation were continuously monitored in surface waters and at depths of 150 and 300 mm in the hyporheic zone of a riffle in a montane stream where Atlantic salmon spawn. Throughout this period, DO in surface waters remained close to 100% saturation, but exhibited daily variations related to CO₂ cycling driven by diurnal patterns of respiration and photosynthesis. However, in the hyporheic zone, variations were much more dynamic over storm event, seasonal and inter‐annual timescales. At 300 mm, DO saturation was generally close to 100% during summer low flows, though levels occasionally fell during warm periods which appeared to be related to diffusion gradients caused by benthic respiration. Such DO decreases at low flows were much more common and marked at 150 mm. During wetter conditions, DO saturation at 300 mm fell to zero for prolonged periods; this is consistent with increased fluxes of groundwater discharging through the hyporheic zone. During the wettest periods this also affects DO saturation at 150 mm. However, during hydrological events, hyporheic water quality is ‘re‐set’ as head reversals cause streamwater ingress which results in transient periods of re‐oxygenation, which end during the hydrograph recession. This is consistent with stream‐ward hydraulic gradients being re‐established in riparian ground water as the stream stage falls. The connectivity between groundwater and streamwater through the hyporheic zone is driven by climatic conditions and is reflected in marked inter‐annual variability in water quality characteristics. In some cases, this variability may have implications for the ecology of the hyporheic environment—including the survival of salmon eggs—particularly if oxygen levels are affected. Copyright © 2009 John Wiley & Sons, Ltd.     

Catchment‐scale controls on groundwater–surface water interactions in the hyporheic zone: implications for salmon embryo survival

The spatial and temporal variability of groundwater–surface water (GW–SW) interactions in the hyporheic zone were investigated in a semi‐pristine upland salmon spawning catchment (Girnock Burn) in the Cairngorm Mountains, northeast Scotland. Stream and hyporheic water quality (200–300 mm depth) were monitored fortnightly at 16 spawning locations distributed throughout the catchment. Hydrochemical tracers were used to assess local GW–SW interactions. Stratified streambed incubators (50–300 mm) provided information on salmon embryo mortality at a sub‐set of ten locations. Hyporheic water quality varied both temporally and spatially according to local GW–SW interactions. It was possible to categorize sites into three broad typologies reflecting local stream–aquifer interactions: (1) groundwater‐dominated; (2) surface water‐dominated; and (3) sites exhibiting transient water table features. Groundwater upwelling occurred in areas where low permeability glacial moraine features caused substantive valley constriction. These locations were also conducive to accumulation of spawning grade gravels and consequently were utilized heavily by spawning salmon. Long residence groundwater was typically characterized by low dissolved oxygen (DO), of sufficiently low quality to be detrimental to salmon embryo survival. At sites dominated by surface water, hyporheic DO remained high throughout and rates of embryo survival were correspondingly high. Survival rates were also high at sites where hydrochemical characteristics indicated a transient water table. This is probably attributable to the hydrological conditions which resulted in increasing DO concentrations towards hatch time when embryo oxygen demand is at its maximum. The degree to which the findings of this study are directly applicable to other catchments is currently unknown. However, similar effects have been observed elsewhere, and based on the information presented here, there are clear implications for fisheries managers who may wish to consider the use of surface incubation facilities to negate the effects of low DO groundwater upwelling where it dominates available spawning habitat. It is suggested that future research should aim to integrate across spatial scales and disciplines to obtain a better understanding of the ways in which hillslope and riparian zone hydrology affect GW–SW interactions, hyporheic zone processes and stream ecology. © Crown copyright 2005. Reproduced with the permission of Her Majesty's Stationery Office. Published by John Wiley & Sons, Ltd.     

三河口水库消落带植物水解氮磷释放特征研究

以三河口水库5种消落带优势植物青蒿、艾、醴肠、菵草、酸模叶蓼的地上茎叶部分为样本,库水为实验原水,进行室内水解模拟实验。通过测定上覆水的基本水质指标及氮磷养分浓度,探明消落带植物经过水解后,对水体水环境的影响及不同形态氮磷养分的释放特征和负荷。结果表明：5种植物水淹后均引起上覆水颜色加深且产生异味,pH值下降,浊度增大,电解率增大,溶解氧降低;氮、磷养分得到释放,总氮和总磷的平均释放量分别为4.06和0.78 mg/g,其中颗粒态氮、磷相应占总氮和总磷的43.2%和36.2%;在水库的蓄水初期（30 d）,消落带植被向水体释放的氮、磷负荷可达40.4和7.6 kg/hm²,这些将对三河口水库的水环境安全造成影响。     

Comparative Limnology of Inner Long Point Bay,Lake Erie,and Adjacent Waters of the Outer Bay

Environmental characteristics of Inner Long Point Bay and adjacent waters of the Outer Bay were observed from April to November 1978–79, to determine differences in water quality between the two areas and to evaluate long term changes in water quality since the last Inner Bay study in 1962. The Inner Bay is shallow, receives diffuse-source nutrient loadings and supports dense stands of aquatic vegetation. Means of all fourteen parameters measured except nitrate nitrogen, total alkalinity, and dissolved oxygen were significantly different in the two bays. Moreover, seasonal distributions of concentrations of nitrate nitrogen and total alkalinity differed in the two basins due to photosynthetic activity of the macrophytes. Only phosphorus and dissolved oxygen showed similar seasonal patterns in mean concentrations in both bays. The Inner Bay warms more rapidly in the spring, attains higher summer temperatures, and cools more quickly in the autumn. On the basis of total phosphorus concentrations and chlorophyll a standing crops the Inner Bay is eutrophic and the Outer Bay mesotrophic. Apparent changes in the Inner Bay environment since 1962 include increases in nitrate and nitrite nitrogen and total alkalinity. Differences in nitrate concentrations between the two studies are probably due to changes in agricultural practices in the drainage basin. Changes in the seasonal cycle of total alkalinity indicate greater photosynthesis by macrophytes during the recent study. The data suggest continuation of a gradual enrichment process in the Inner Bay.     

An experimental assessment of the effectiveness of gravel cleaning operations in improving hyporheic water quality in potential salmonid spawning areas

Dissolved oxygen (DO) conditions within the hyporheic zone were investigated in a gravel stream (River Sieg) in North Rhine Westphalia, Germany, populated in the spawning season by recurring migratory fish species, like Atlantic salmon (Salmo salar L.) and sea trout (Salmo trutta trutta L.). The gravel bed was cleaned at three sites in an area of approximately 150 m² to a depth of 50 cm, reducing the quantity of grains <2 mm to below 0.2%. DO concentrations in cleaned and uncleaned sediments were monitored in situ at 10, 20 and 30 cm sediment depth from the end of November 2001 to the end of April 2002. DO showed only minor fluctuations at the cleaned sites and steadily decreased at all uncleaned sites over time. Fine sediment accumulation over 5 months in the cleaned sites was comparable to the proportion of material within the bed prior to the experimental cleaning and probably influenced the DO concentrations of the hyporheic water. Decreasing DO concentrations at all sites coincided with increasing water temperatures towards the end of the study period. The cleaning operation significantly improved the conditions of DO in the hyporheic zone of the three study sites. Copyright © 2008 John Wiley & Sons, Ltd.     

Phosphorus and nitrogen loading to Lake Huron from septic systems at Grand Bend,ON

Groundwater nutrient loading to L. Huron was assessed along a 1.7 km section of beach at Grand Bend, ON, Canada, where septic systems are used for wastewater disposal. The artificial sweetener acesulfame (ACE) was detected in all groundwater samples (7–842 ng/L, n = 78), revealing that the entire surficial aquifer was impacted by septic system wastewater. Nitrate concentrations (3.5 ± 1.4 mg/L, n = 78) were correlated with ACE (r² = 0.54), indicating that septic systems contribute to nitrate loading in the aquifer. Chloride was also elevated (37 ± 11 mg/L, n = 78), but was not correlated with ACE (r² = 0.008), indicating a non wastewater source was dominant, likely road salt. Soluble reactive phosphorus (SRP) values were low (5.3 ± 9.3 μg/L, n = 77) and were not correlated with ACE (r² = 0.006). Sediment profiling below two of the septic system drain-fields, showed that the sand grains had distinct secondary coatings containing P, indicating that mineral precipitation reactions played a role in limiting P concentrations present in the aquifer. Groundwater nutrient loading to the lake was estimated at 13,000 kg N/year from NO₃^? and 1.9 kg P/year from SRP. These amounts are insignificant compared to nutrient loading from a stream that drains an agricultural catchment and discharges to the lake at the north end of the study site (Parkhill Creek). This calls into question, in some cases, the rationale of decommissioning properly functioning septic systems as a mitigation measure for reducing nutrient loading to nearby water courses.     

Nitrate removal in the hyporheic zone of a salmon river in Alaska

Pacific boreal streams and riparian zones are believed to receive significant N loads that are derived from the ocean in the form of decaying sockeye salmon (Oncorhynchus nerka). Using a small stream in south‐central Alaska we examined whether the associated riparian forest could take up the pulse of marine‐derived nitrogen (MDN) entering the hyporheic zone from spawning and dying sockeye salmon. We evaluate the relative importance of riparian uptake and denitrification in nitrate‐N removal in hyporheic sediment. We found that maximum biological removal of nitrate peaked within 1 h of water entering the hyporheic zone, decreasing exponentially with subsurface flow duration. Plant and microbial uptake reached 14 µg NO‐N L^?1 min^?1 and denitrification reached 4 µg NO‐N L^?1 min^?1 during the initial 2 h of transit time. Our results reinforce the hypothesis that MDN from Pacific salmon can be transferred to riparian zone via hyporheic flow. Most nitrate‐N removal along hyporheic flow paths is by plant and microbial uptake (the respective contributions could not be determined). Denitrifying bacteria are present and active in the hyporheic zones of this well‐oxygenated Alaskan stream but their contribution to the nitrate‐N removal is small compared to plant and microbial uptake in such nitrate‐N poor environment. Copyright © 2008 John Wiley & Sons, Ltd.     

Assessment of the bacteriological quality and nitrate pollution risk of Quaternary groundwater in the southern part of Abidjan District (Côte d’Ivoire)

In this study, total coliforms, thermotolerant coliforms, Escherichia coli and groundwater nitrate concentration were monitored at 127 groundwater sampling points (only 62 water points for bacteriological parameters) located in the southern part of Abidjan District. Each water sampling location was sampled in March and July 2007, representing respectively the long dry season and the long wet season. Geostatistical methods were used to analyze the spatial variability of nitrates and the groundwater nitrate pollution risk. The maximum seasonal content of total coliforms and thermotolerant coliforms ranged from 400 to 1000 CFU/100 mL and from 200 to 500 CFU/100 mL respectively. Moreover, 94% of these locations presented traces of bacteriological contamination. This contamination was mainly recorded during the rainy period. The degree of correlation between bacterial abundance and chemical parameters is variable. Nitrites, ammonium and potassium favoured coliform abundance. In the 127 water points, groundwater nitrate concentrations ranged from 4 to 198 mg L^?1 and were log-normally distributed in the study area. The groundwater contamination risk map indicated that the strongly urbanized west side of the site presented a high probability of exceeding the WHO drinking water standard (50 mg L^?1NO₃^?).     

Effects of fluctuating river flow on groundwater/surface water mixing in the hyporheic zone of a regulated,large cobble bed river

Physicochemical relationships in the boundary zone between groundwater and surface water (i.e. the hyporheic zone) are controlled by surface water hydrology and the hydrogeologic properties of the riverbed. We studied how sediment permeability and river discharge altered the vertical hydraulic gradient (VHG) and water quality of the hyporheic zone within the Hanford Reach of the Columbia River. The Columbia River at Hanford is a large, cobble‐bed river where water level fluctuates up to 2 m daily because of hydropower generation. Concomitant with river stage recordings, continuous readings were made of water temperature, specific conductance, dissolved oxygen and water level of the hyporheic zone. The water level data were used to calculate VHG between the river and hyporheic zone. Sediment permeability was estimated using slug tests conducted in piezometers installed into the river bed. The response of water quality measurements and VHG to surface water fluctuations varied widely among study sites, ranging from no apparent response to covariance with river discharge. At some sites, a hysteretic relationship between river discharge and VHG was indicated by a time lag in the response of VHG to changes in river stage. The magnitude, rate of change and hysteresis of the VHG response varied the most at the least permeable location (hydraulic conductivity (K) = 2.9 × 10^?4 cms^?1) and the least at the most permeable location (K = 8.0 × 10^?3 cms^?1). Our study provides empirical evidence that sediment properties and river discharge both control the water quality of the hyporheic zone. Regulated rivers, like the Columbia River at Hanford, that undergo large, frequent discharge fluctuations represent an ideal environment in which to study hydrogeologic processes over relatively short time periods (i.e. days to weeks) that would require much longer periods (i.e. months to years) to evaluate in unregulated systems. Copyright © 2006 John Wiley & Sons Ltd.     

In situ experimental studies of Eurasian Watermilfoil (Myriophyllum spicatum) downstream from agricultural watersheds: Nutrient loading,foliar uptake,and growth

Recent studies in Conesus Lake, New York, documented significant decreases in the biomass of Eurasian watermilfoil (Myriophyllum spicatum) near the mouths of streams draining sub-watersheds where reductions in nutrient loading occurred as a result of the implementation of agricultural Best Management Practices (BMPs). In situ experiments were conducted to further investigate the relationship between stream loading, foliar uptake, and growth of Eurasian watermilfoil. In two of three experiments, plants cropped to a height of approximately 50 cm had the lowest growth (g/m²) downstream from a sub-watershed where major BMPs had been implemented (80% and 0%). In sub-watersheds where minimal or no BMPs were introduced, plants showed significantly higher growth as biomass increased (216% and 22%). In a second set of experiments, shoots of Eurasian watermilfoil plants were incubated for 24 h in ambient lake water and in lake water with enriched concentrations of nitrate and soluble reactive phosphorus comparable to rain event stream effluent concentrations and then allowed to grow in situ for a 2-week experimental period. For all experiments combined, the shoot biomass increased significantly in the enhanced nutrient treatments when compared to the ambient treatment at the Sand Point macrophyte bed (reduced loading) but not at the Eagle Point macrophyte bed (high loading). Overall, the results indicate that foliar uptake of nutrients in stream effluent can contribute to the growth of Eurasian watermilfoil and reinforce the hypothesis that reductions in stream loading through agricultural BMPs can help reduce macrophyte growth in the lake littoral.     

The effect of a flood pulse on the water column of western Lake Superior,USA

On June 19 and 20, 2012, western Lake Superior was impacted by a “mega-rain event” that raised lake levels by 8 to 10 cm. Within the flood plume on June 21, 2012, total suspended solids, total phosphorus, and soluble reactive phosphorus concentrations were elevated, with measurements of 87 mg/L, > 100 μg/L, and 5.8 μg/L, respectively. Despite the initially high phosphorus loadings, little impact was seen on water column particulate chlorophyll content, which remained in the range 0.7–1.9 μg/L, in the weeks to months following the flood. Both total phosphorus and soluble reactive phosphorus levels tracked those of total suspended solids, returning to background levels within two weeks. However, the availability of photosynthetically available radiation (PAR) was impacted for a month after the flood event, due mainly to colored dissolved organic matter that remained in the surface layer of the stratified lake water column. It appears that the mismatch in timing of nutrient and light availability acted as a check on phytoplankton biomass production in the flood-impacted portion of the lake.     

Synthesis review on groundwater discharge to surface water in the Great Lakes Basin

Groundwater in the Great Lakes Basin (GLB) serves as a reservoir of approximately 4000 to 5500 km³ of water and is a significant source of water to the Great Lakes. Indirect groundwater inflow from tributaries of the Great Lakes may account for 5–25% of the total water inflow to the Great Lakes and in Lake Michigan it is estimated that groundwater directly contributes 2–2.5% of the total water inflow. Despite these estimates, there is great uncertainty with respect to the impact of groundwater on surface water in the GLB. In terms of water quantity, groundwater discharge is spatially and temporally variable from the reach to the basin scale. Reach scale preferential flow pathways in the sub-surface play an important role in delivering groundwater to surface water bodies, however their identification is difficult a priori with existing data and their impact at watershed to basin scale is unknown. This variability also results in difficulty determining the location and contribution of groundwater to both point and non-point source surface water contamination. With increasing human population in the GLB and the hydrological changes brought on by continued human development and climate change, sound management of water resources will require a better understanding of groundwater surface–water interactions as heterogeneous phenomena both spatially and temporally. This review provides a summary of the scientific knowledge and gaps on groundwater–surface water interactions in the GLB, along with a discussion on future research directions.     

Water quality changes in hyporheic flow paths between a large gravel bed river and off‐channel alcoves in Oregon,USA

Changes in water quality that occur as water flows along hyporheic flow paths may have important effects on surface water quality and aquatic habitat, yet very few studies have examined these hyporheic processes along large gravel bed rivers. To determine water quality changes associated with hyporheic flow along the Willamette River, Oregon, we studied hyporheic flow at six‐bar deposit sites positioned between the main river channel and connected lentic alcoves. We installed piezometers and wells at each site and measured water levels and water quality in river, hyporheic and alcove water. Piezometric surfaces along with substrate characteristics were used to determine hyporheic flow path direction and hyporheic flow rate. At all sites, hyporheic flow moved from the river through bar deposits into alcove surface water. Stable isotope analysis showed little influence of upwelling groundwater. At a majority of sites, hyporheic dissolved oxygen and ammonium decreased relative to river water, and hyporheic specific conductance, nitrate and soluble reactive phosphorous increased relative to river water. At three sites, hyporheic temperature decreased 3–7°C relative to river water; there was less temperature change at the other three sites. At the two sites with the highest hyporheic flow rates, hyporheic cooling was propagated into the alcove surface water. Hyporheic changes had the greatest effect on alcove water quality at sites with highly permeable substrates and high‐hyporheic flow rates. The best approach to enhancing hyporheic flows and associated water quality functions is through restoring fluviogeomorphic channel processes that create and maintain high‐permeability gravel deposits conducive to hyporheic flow. Copyright © 2006 John Wiley & Sons, Ltd.     

天津海河磷的分布特征

采集海河干流重要断面、相应排污渠以及部分支流(北运河、子牙河、南运河)共29个监测断面的水样,对样品中的溶解性活性磷(SRP)、总溶解态磷(TDP)与总磷(TP)进行测定,并分析其分布特征。结果显示:海河干流各断面的TP质量浓度为0.4~3.5mg/L,已超出GB3838—2002《地表水环境质量标准》Ⅴ类水质标准,SRP质量浓度0.09~0.75 mg/L,TDP质量浓度0.24~1.42 mg/L;各排污渠(支流)TP质量浓度0.2~5.0 mg/L,SRP质量浓度0.01~3.63 mg/L,TDP质量浓度0.12~4.16 mg/L。排污渠(支流)多数断面的含磷量比相应干流的高。天津海河总磷以总溶解态磷为主要形态,这和海河悬浮颗粒物浓度较低有关。     

The impact of agricultural management practices on nutrient losses to water: data on the effects of soil drainage characteristics.

Against the background of increasing nutrient concentrations in Irish water bodies, this study set out to gain information on the potential of agricultural grassland to lose nutrients to water. Overland flow, flow from artificial subsurface drains and stream flow were gauged and sampled during heavy rainfall events. Dissolved reactive phosphorus (DRP), potassium (K), total ammonia (TA), and total oxidised nitrogen (TON) were measured in water samples. When the nutrient concentrations in water were examined in relation to the grassland management practices of the study catchments it emerged that soil P levels, the application of organic and inorganic fertilisers before heavy rainfall and the presence of grazing animals could all influence nutrient concentrations in surface and subsurface drainage water. Overall, the drainage characteristics of soil were found to have a considerable influence on the potential of land to lose nutrients to water.