共查询到20条相似文献,搜索用时 156 毫秒
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《现代化工》2020,(4)
为改善能源短缺,对新型光催化水解制氢材料进行了研究。通过改进Hummer法制备氧化石墨,溶胶-凝胶法制备锐钛矿型二氧化钛,采用浓碱法制得石墨烯-二氧化钛纳米管催化剂,考察了不同石墨烯的掺杂量对催化活性的影响。经过光解水制氢实验发现,掺杂不同质量分数石墨烯的催化剂催化活性得到了进一步提高,其中掺杂量为1%的产氢活性最好,产氢速率是纯二氧化钛纳米管的2. 5倍。通过BET、XRD、UV以及FT-IR等方法对催化剂进行了表征。结果表明,石墨烯与二氧化钛纳米管成功复合,并且石墨烯的掺杂在一定程度上提高了催化剂的BET比表面积;催化剂对可见光的响应范围得到进一步扩大,这为催化剂光解水制氢性能的提高提供了有力的条件。 相似文献
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采用阳极氧化法在纯钛表面生成结构高度有序的二氧化钛纳米管阵列,并通过室温固相反应制备了钯纳米颗粒。采用自组装方法将钯纳米颗粒修饰到Ti/TiO2表面制备了Ti/TiO2/Pd纳米电极。利用电子扫描显微镜、X-射线衍射分析二氧化钛纳米管、钯纳米颗粒和纳米电极的微观结构和表面形貌,并研究了Ti/TiO2/Pd纳米电极对甲醇的电催化性能。结果表明,TiO2纳米管排列整齐有序,Ti/TiO2/Pd电极中Pd纳米颗粒均匀分散在TiO2纳米管表面。电化学测试结果表明,Ti/TiO2/Pd纳米电极对甲醇的电催化氧化过程具有很好的电催化活性。 相似文献
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以钛丝网为基底制备三维二氧化钛纳米管阵列电极(3D-TNAs),之后通过晶种滴加法将NH2-MIL-125与三维二氧化钛纳米管阵列复合,制备3D-TNAs@NH2-MIL-125复合电极材料。通过调节晶种时间,研究不同制备时间对复合电极表面形貌、物理化学性质及光电化学性能的影响。结果表明,通过晶种滴加法合成的3D-TNAs@NH2-MIL-125复合电极具有优异的光电化学性能,其中晶种时间为6 h的复合电极综合性能最好,在模拟太阳光及0.7 V外加偏压的条件下,反应时间为150 min时对亚甲基蓝的降解率可达97.8%。 相似文献
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Li-Huei Lin Hsin-Jiant Liu Chung-Kung Lee Yu-Ching Lai 《Polymer-Plastics Technology and Engineering》2015,54(1):14-20
This study uses a series of hydrophilic PEG-silicone polyester and titanium dioxide nanotubes to prepare high-performance titanium dioxide nanotube (TNT) composites. The decomposition of these titanium dioxide nanotube composites for the methylene blue is investigated by using UV-Vis spectroscopy. These changes in structure have been observed by FTIR and Raman analysis at 365 nm UV irradiation. The surface microstructures of composites were characterized with scanning electron microscopy (SEM). It was found that titanium dioxide nanotube composites possessed excellent solubility and dispersion effects. This makes fixation of photocatalysts possible and retards oxidation of organic materials in the PEG-silicone polyesters. 相似文献
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Jongyun Moon Marianna Kemell Byungki Park Arho Suominen Ermei Mäkilä Risto Punkkinen Hannu‐Pekka Hedman Hong Kim Lippo V Lassila Aulis Tuominen 《Coloration Technology》2014,130(1):1-7
Titanium dioxide nanotube arrays were anodised from titanium foils in an aqueous electrolyte solution of hydrofluoric acid. The formed oxide showed visually different colours owing to light interference in the titanium dioxide layer. The behaviour of interference colour in anodic titanium dioxide film was investigated by varying anodisation parameters such as the applied voltage and the anodisation time. The morphologies and the crystalline phases of anodised samples were studied on a field emission scanning electron microscope and X‐ray diffractometer. The correlation between the interference colour and growth procedure of anodic titanium dioxide nanotube arrays was studied. The anodic films prepared under different conditions consisted of a compact oxide film with a nanoporous/tubular structure upon/beneath it. The crystalline phase of the anodic oxide layer was amorphous. The optical properties of the oxide film were investigated on a spectrophotometer. Optical interference could be detected in compact oxide layers when the thickness of the titanium dioxide was as small as 70 nm. In general, the interferences of the nanoporous/tubular structures were lower than those for compact structures. The empirical colour properties were estimated by the L*a*b* system. The relationships between the interference colour of anodic titanium dioxide film and its thickness and morphology are discussed. 相似文献
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《分离科学与技术》2012,47(9):1394-1402
Graphene-titanium nanotube composites with different ratios of graphite oxide were prepared via the hydrothermal method using ascorbic acid as a reducing agent. Properties of materials were characterized by X-ray diffraction, Fourier Transform Infrared Spectroscopy, high resolution transmission electron microscopy and UV–vis diffuse reflectance spectroscopy. The average diameter of the titanium dioxide nanotubes was about 8 nm. The photoresponse of nanocomposites have been extended to visible-light regions. In addition, graphene-titanium nanotube composites showed higher photocatalytic degradation efficiency for reactive black 5 (RBK5) than pure titanium dioxide and the 15%graphene-titanium nanotube composites catalysts possessed the best photocatalytic activity. The degradation efficiency for RBK5 dyes increased with increased dosage of graphite oxide from 3%-15% and decreased with increasing initial RBK5 concentration. This paper not only reports the fabrication of highly active photocatalysts but also provides insight into the photocatalytic mechanism of graphene-titanium nanotube composites. 相似文献
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半导体光催化剂被广泛地应用于光催化领域,但其常因自身的禁带宽度较大、量子效率较低、催化效率较低、与反应物接触几率较低等因素在实际应用中受到诸多限制。而碳基材料作为一类结构稳定的新材料,具有稳定性强、导电能力强、比表面积大、包含大量的吸附位点等特性,与光催化剂复合之后,能够有效减小其禁带宽度、降低其载流子的复合率并为其提供更多的吸附位点,很大程度上提高了光催化剂的光催化性能。该文章以石墨烯、碳纳米管、富勒烯以及碳纤维等碳材料与各类半导体光催化剂复合为例,综述了碳基材料与光催化剂复合的工艺、提高其光催化性能的机理、影响碳基材料改性程度的因素及其在产氢、杀菌等方面的应用,并且对其进行了展望。 相似文献
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Nanostructured titanium dioxide is one of the classic materials for photoelectrochemical water splitting. In the present work we dope TiO(2) nanotube anodes. For this, various low concentration bulk-Nb-doped TiO(2) nanotube layers were grown by self-organizing anodization of Ti-Nb alloys. At Nb-contents around 0.1 at%, and after an adequate heat-treatment, a strongly increased and stable photoelectrochemical water-splitting rate is obtained. 相似文献
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采用异丙醇钛[(C4H9O)4Ti]为先驱体配制二氧化钛溶胶,以阳极氧化铝模板(AAO,孔径尺寸200 nm,厚度约60 mm)直接浸渍和负压辅助浸渍的方法制备二氧化钛纳米管或管棒混杂的阵列结构,所得产物在450℃下进行热处理后,化学刻蚀去除模板. 利用FE-SEM, HR-TEM以及XRD对其微观形貌、结构等进行了观测和分析. 结果表明,产物450℃热处理后为多晶锐钛矿相. 模板法简单易行,制备出的管棒外径取决于模板孔道的尺寸,在负压辅助下可有效提高产物的连续性. 相似文献
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采用阳极氧化法在钛板表面制备出TiO2纳米管阵列,并以其为加热表面。以含不同浓度丁醇的自润湿溶液为实验工质,考察了自润湿溶液浓度变化对系统临界热流密度和传热系数的影响,并从气泡行为的不同分析了两者耦合强化传热的机理。结果表明:相比于光滑表面和蒸馏水的常规组合,TiO2纳米管表面和自润湿溶液耦合传热使得系统的临界热流密度大幅度提高,随自润湿溶液浓度的升高,传热系数依次降低。具有超亲水性和较大粗糙度的纳米管表面与1%(质量分数,下同)自润湿性溶液相耦合时,其最大传热系数和临界热流密度分别为11.963 kW·m-2·℃-1与623.706 kW·m-2,比常规组合传热分别提高了84.1%和143.8%。由气泡可视化可知,耦合传热在沸腾过程中产生的气泡细小,脱离速度快,不易团聚,合并后的气泡易破碎,易形成微气泡,从而使系统进入剧烈的微气泡沸腾状态。气泡的高脱离频率和特殊有效的液体补充路径,是提高系统传热系数和临界热流密度的主要原因。 相似文献
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Carbide nanofibres were synthesized by reaction of various transition metals with carbon nanotubes using a molten LiCl-KCl-KF salt system as a reaction medium. Metal sources included titanium, zirconium, hafnium, vanadium, niobium and tantalum powders. Multi-walled carbon nanotubes were used both as a carbon source and also as a template for the preparation of titanium carbide, zirconium carbide, hafnium carbide, vanadium carbide, niobium carbide and tantalum carbide nanofibres. Generally, the carbide products were characterized by scanning electron microscopy, transmission electron microscopy, selected-area electron diffraction and electron energy loss spectroscopy. The polycrystalline carbide nanofibres produced in these reactions have a similar morphology to that of their multi-walled carbon nanotube precursors. However, when using titanium mixed with titanium dioxide as a titanium source, both polycrystalline and straight, single crystal titanium carbide nanofibres are formed. 相似文献
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介绍了当前硫酸法钛白粉生产现状以及中钛科技研发的新型酸溶性富钛料产品、特性、生产工艺及在硫酸法钛白粉生产中的应用。通过工业试验对比可知,采用新型酸溶性富钛料为原料生产的钛白粉,根据添加比例不同,可以不同程度降低矿(渣)耗、酸耗和能源消耗。 相似文献