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研究了一种微波消解-原子荧光光谱法四通道同时测定中草药中砷、锑、铋和汞元素含量的方法。实验对仪器条件进行了优化,对方法进行了验证,并对中草药样品进行了砷、锑、铋和汞元素含量的测定。实验结果表明:相关系数R2均在0.9988以上,相对标准偏差均小于1.54%,砷、锑、铋和汞检出限分别为0.019ng/mL、0.015ng/mL、0.008ng/mL和0.005ng/mL;测定柑橘叶标准物质和黄芪标准物质的结果与标称值相符;样品加标回收率为90.8%~114.1%。采用该方法可以准确地测定中草药中砷、锑、铋和汞元素含量,四通道同时测定4种元素,减少了试剂消耗,提高了分析效率,该方法值得推广。 相似文献
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介绍了一种快速测定粮食中总汞的分析方法,本方法基于"燃烧-催化燃烧-冷原子吸收(C-CAAS)"原理,可准确测定汞含量较低粮食样品如大米、小麦、玉米等。将本方法与国标GB/T 5009.17—2014中"化学蒸汽发生-原子荧光法(HG-AFS)"进行对比,结果表明:本方法准确度、重复性均优于国标推荐方法,是一种高效、环保的汞分析技术。以进样量0.20g计算,方法检出限为0.02μg/kg,定量限为0.08μg/kg,相对标准偏差1.2%(@1ng Hg),样品加标回收率为90.2%~102.7%。这种快速、准确的汞分析方法,是粮食质量安全监管的利器,可指导超标粮食收购与储存,严防不符合食品安全标准的粮食流入口粮市场。 相似文献
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蒸气发生—原子荧光法测定中药材中的砷、汞、铅 总被引:2,自引:0,他引:2
研究了测定五种中药材中痕量的砷、汞、铅,建立了一种聚四氟乙烯消化罐梯度升温消解样品的方法,采用蒸气发生与原子荧光法联用技术进行测定。测得砷、汞、铅的回收率分别为94.5%、106.6%、106.0%。该方法完全可以用于中药材中砷、汞、铅的含量测定。 相似文献
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建立了微波消解样品,原子荧光法测定水产品中汞的方法。对样品的消解条件、仪器条件、酸度、还原剂等影响进行了实验并测定了水产品中汞含量。结果表明:汞含量在0~1.0ng/mL的范围内线性良好,线性方程Y =24.12+217.01 X ,r=0.9999。方法检出限为0.031 ng/mL。样品加标浓度为0.1~0.4 ng/mL时,方法回收率为96.4%~98.7%。方法操作简便、定量准确可靠,重现性好,可以满足水产品中汞检测的要求。 相似文献
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同位素稀释-电感耦合等离子体质谱法测定沉积物中铬和汞 总被引:1,自引:0,他引:1
采用同位素稀释-电感耦合等离子体质谱法(ID-ICP-MS)测定沉积物中铬和汞,分别以铬、汞单元素溶液标准物质标定53Cr和202Hg浓缩同位素,将稀释剂与样品混合均匀后,加酸进行消解。对质谱测定过程的数据采集参数进行优化,探究基体效应以及H2和He两种模式对铬测定的影响。为防止汞的记忆效应干扰比值的测定,采用5 mg/L EDTA、2.5 mg/L Au溶液和3%硝酸交替冲洗管路系统,分别测定了200Hg/202Hg和199Hg/202Hg两组比值,并比较测定结果。结果显示:积分时间为0.5 s时,同位素比值的测定精密度较好,对测定样品进行稀释能够消除质谱及基体效应干扰。H2和He模式均适用于该类样品中铬的测定,200Hg/202Hg和199Hg/202Hg两组比值对汞的测定结果无显著性差异,沉积物中铬和汞含量分别为81.7 mg/kg和0.471 mg/kg,相对标准偏差分别为0.35%和0.99%。采用美国NIST2709a标准物质进行方法验证,验证结果与标准值一致。该方法准确度高、精密度良好,适用于沉积物、土壤等基体样品中铬和汞的高准确度测定。 相似文献
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The method for determination of mercury speciation analysis in seafood by HPLC-ICP-MS has been established. Using hydrochloric acid extract, C18 Chromatography column (4.6 mm×150 mm), mobile phase is 5% methanol-0.06 mol·L-1 ammonium acetate-0.1% cysteine , the linear range for three mercury species are all between 0 and 100 μg·L-1, the linear coefficient(r) are all more than 0.999 0, detection limits are between 0.5—0.8 ·L-1; the relative standard deviations (RSD) for the determination of three mercury species are all less than 5%; the recoveries of different concentrations of mercury compounds: inorganic mercury is 72.5%—89.8%, methylmercury is 99.2%—117.6%, ethylmercury is 93.1%—111.2%; determination of mercury speciation analysis in fish reference material (GBW10029) and human hair reference material (GBW09101B) are all in the scope of standard values. The International Comparison in FAPAS of methylmercury, the result of Z score is 1.0. The experiments show that: this method had simple pre-treatment method, broad line-arrange, good accuracy and precision, it has been applied for determination of mercury speciation in aquatic product. 相似文献
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以矿渣和水泥作为研究对象,采用汞分析器对其中的汞进行检测。水泥是一种建筑过程中广泛使用的高凝结材料。由于汞具有较大的毒性,因此必须严格检测建筑材料中汞的含量以降低其对人体的损害。作为水泥的替代物,矿渣具有许多的优点,例如价格低廉、毒性较小等。 相似文献
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Abstract An accurate and rapid calibration procedure for mercury vapour indicators used for occupational exposure measurements is described, using a dynamic mercury vapour generator traceable to the standard bell-jar calibration apparatus. The method provides greater flexibility, accuracy, and trace ability than the usual methods for the calibration of mercury vapour indicators used for occupational exposure measurements. The calibration procedure allows a correction to be applied to the mass concentration value displayed by the mercury vapour indicator. Measurement results from the mercury vapour indicator at the occupational exposure limit of 25 µg ·m?3, following calibration, have been estimated to have an expanded uncertainty of 8%. 相似文献
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Abstract A new method of mercury detection at ng/mL concentrations in seawater, by total reflection x‐ray fluorescence (TXRF), is presented. Membranes that have complexation affinity to the mercury ions were produced on quartz reflectors. They were immersed in various seawater solutions containing mercury at low concentration (1–50 ng/mL) and they were left to equilibrate for 24 hours; membranes were well fixed on the reflectors. After the equilibration stage, they were taken out of the solution and they were analysed by TXRF; the minimum detection limit was determined to be equal to 0.4 ng/mL. The main ingredient of the membranes was the complexing reagent dithizone. The existence of high salt concentration in seawater did not prevent mercury's complexation from the membrane. 相似文献
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Abstract An alternative method for the determination of mercury (Hg) in solid samples is presented in this article. Gaseous Hg is evolved when a solid sample is heated above 500°C in the presence of oxygen. The evolved Hg is collected on silver wool and is analyzed using cold vapor methods. We have found greater than 95% Hg recovery with various sediment and ash standards. 相似文献
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ABSTRACT The mercury vapor monitor, MDC-1-01, described in this paper is the first prototype in the MDC series. It was designed and developed in our laboratory to measure airborne mercury vapor on a “continuous” basis in the range of 400 ng to 20 mg mercury per cubic meter of air. In comparison with other instruments, commercially available, it uses much improved principles as regards electronics, optics, and chemistry [l]. The double beam assembly, in combination with a selective filter, permits the measurement of mercury vapor in the presence of the most commonly encountered organic vapors and dusts. Practical applications are discussed. 相似文献
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原子荧光形态分析仪SA-10是基于高效液相色谱和氢化物发生原子荧光联用技术的一台元素形态检测仪,该仪器对汞和锑形态的分析性能是:Hg(Ⅱ)、MetHg、EtHg、Sb(Ⅲ)和Sb(Ⅴ)的检出限分别为0.5.0.3,0.4、1和5μg/L,线性范围分别是0.5~1000、0.3~1000、0.4~1000、1~1000和5~1000μg/L,该区间内的线性相关系数均大于0.9990,标准偏差均小于3.0%。本文主要介绍了该仪器在海产品、环境水样、土壤中的汞形态分析和化妆品中的锑形态的应用。 相似文献
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The fish tissue certified reference material is designed and prepared mainly for evaluating the determining accuracy of methyl mercury in sea fish or other seafood, as well as for a quality control standard. The property value was certified by three different methods, including high performance liquid chromatographic -cold vapor atomic fluorescence spectrometry(HPLC-CVAFS)method and species specific isotope dilution mass spectrometric analysis (IDMS) using an inductively coupled plasma mass spectrometer as detector after liquid chromatography (LC-ICP-MS) or gas chromatography (GC-ICP-MS). The experiment included spiking, extraction, derivatization, separation and detection procedures. The ERM 464 tuna fish reference material was used as the analytical quality control standard. The results obtained from three different methods were in good agreement. And the statistic average values were used as certified values of methylmercury in the fish tissue CRM. 相似文献