共查询到20条相似文献,搜索用时 140 毫秒
1.
NPC太阳电池的TiO2薄膜结构的研究 总被引:3,自引:0,他引:3
采用溶胶凝胶法、粉末涂敷法和磁控溅射法在导电玻璃上制得纳米TiO2薄膜。电子衍射和X射线衍射实验表明该薄膜主要是锐钛矿相结构,透射电子显微镜实验证明了薄膜晶粒为纳米尺度,扫描电子显微镜实验观察了薄膜的表面形貌。分析并讨论了利用以上各种方法制得的纳米TiO2薄膜的结构及其所组成的染料敏化太阳电池的性能。发现由致密TiO2层和多孔TiO2层组成的多层TiO2薄膜组装的太阳电池的性能优于任一种单层TiO2薄膜。 相似文献
2.
3.
4.
非平衡磁控溅射法Ti/TiO2薄膜的制备及分析 总被引:1,自引:1,他引:1
在光学玻璃衬底上利用新型非平衡磁控溅射技术沉积了Ti/TiO2薄膜。原子力显微镜分析表明,薄膜表面光滑、致密、均匀,表面粗糙度(Ra)小于10nm,组成薄膜的颗粒尺寸小于100nm。膜厚测量分析表明,TiO2薄膜的沉积速率达110nm/min。在拉曼光谱中,没有出现晶态TiO2薄膜的散射峰,表明所得TiO2薄膜为非晶结构。利用紫外-可见光全反射谱分析了薄膜的光学性能,结果发现,单纯TiO2薄膜存在微弱吸收,在波长约550nm时出现最大反射率,其后波长越大,吸收率越高;在Ti/TiO2薄膜体系中,随着沉积的Ti膜的厚度增大,Ti薄膜界面的反射率增大,薄膜吸收率提高;在玻璃衬底的正反面均沉积适当厚度的Ti/TiO2薄膜时,能够获得不同的色彩效果;根据薄膜干涉特征,计算所得TiO2薄膜的折射系数约为3.0。另外,所得TiO2薄膜不存在明显光电效应。 相似文献
5.
利用微等离子体氧化方法,在纯Ti金属表面制备TiO2、TiO2(W)薄膜,并用X射线衍射(XRD)、扫描电镜(SEM)初步研究了薄膜的组织结构和表面形貌.在不同的条件下,得到3种不同类型结构组成的薄膜单一TiO2的锐钛型结构、单一TiO2金红石结构及TiO2(W)薄膜;同时对薄膜的催化特性进行了初步的研究. 相似文献
6.
阐述了对应用在染料敏化太阳能电池中作为电极的TiO2薄膜的要求,对如何能制备出具有较好电池性能的TiO2薄膜电极的方法进行了综述,分析了各种方法的优劣,对未来染料敏化太阳能电池中TiO2薄膜的制备方法提出了建议。 相似文献
7.
8.
9.
10.
11.
Ehrenfried Zschech Eckhard Langer Hans‐Jürgen Engelmann Kornelia Dittmar Werner Blum 《真空研究与实践》2001,13(1):29-36
Characterization of thin films and interfaces are necessary in semiconductor industry to ensure high yields and the required reliability of the products. Requirements to thin film and interface analysis are reviewed, and typical applications in semiconductor industry are shown. Thin film characteristics which have to be determined using physical analysis techniques are film geometry, surface and interface roughness, chemical composition, and microstructure. Advances in physical failure analysis are essential to the reduction of feature size and introduction of advanced materials and processes for future technology generations. Future trends are discussed. To reduce the time for problem solving in the manufacturing process, out of‐fab characterization tools will partly move to“at‐line” labs which are located next to or sometimes inside the cleanroom. 相似文献
12.
13.
Good knowledge of the mechanical properties of thin film materials is important for reliable design of advanced electronic packages such as multi-chip modules (MCMs). Strain at fracture is one of the important properties which has not been well characterized for some of the candidate thin film materials for MCMs. In part, this is due to the lack of simplw and accurate techniques to measure strain at fracture of thin film materials. Two new techniques have been developed to alleviate this problem. The first is an acoustic technique in which an accelerometer is attached to the film. The film is then gradually strained and when the film fractures, an acoustic wave propagates through the film thereby creating a transient signal from the accelerometer. This signal is used to trigger an oscilloscope. The second technique is similar except that it utilizes a laser probe to detect the acoustic wave. In this photo-acoustic method, the laser is reflected from the film onto a bisectional photodetector while the film is gradually strained. Upon film fracture, the acoustic wave modulates the laser beam and a transient voltage pulse is produced by the photodetector. Both techniques are capable of detecting the formation of extremely small cracks. The two techniques are compared with a previously reported electrochemical technique. All three techniques are accurate, simple to implement, and inexpensive but have relative advantages and disadvantages. 相似文献
14.
15.
《Thin solid films》1991,196(1):L5-L10
In the present work we discuss some methods for obtaining thin films with quasi-crystalline structures. Methods which produce decagonal and dodecagonal structures are presented in detail. Such techniques involve a post-deposition treatment heating treatment. We show that the analysis of thin film structures can play an important role in understanding the quasi-crystalline structures and the related crystalline phases. 相似文献
16.
SiC薄膜制备工艺进展 总被引:2,自引:0,他引:2
本文综述了SiC薄膜的制备工艺及进展,介绍了物理气相沉积、化学气相沉积、等离子化学气相沉积及光化学气相沉积等各种SiC薄膜的制备方法,简单阐述了各种工艺对薄膜性能的影响,评述了各种制备工艺的优缺点。 相似文献
17.
V. Rupertus 《Materialwissenschaft und Werkstofftechnik》2002,33(11):651-656
Surface and thin film analysis – indispensable tool for coating development and ‐production Development and production of thin films for functional coating on special materials is unalterable combined with a permanent quality control and therefore use of sophisticated analysis and measurement techniques. The field of interest is belonging to all steps of the production chain, starting with the characterization of the substrate surface (e. g. glass, plastics), followed by polishing and cleaning processes up to depth profiling of complex multilayers. The typical analyses are focused onto topographical and chemical features and their influence onto the product functionality. The use of surface and thin film analytics for problem oriented characterization is demonstrated by a few examples, which deal with surface roughness, contamination, impurities and dopand profiles as well as composition variations in the surface near region. 相似文献
18.
J.M. Morabito 《Thin solid films》1973,19(1):21-41
Auger electron spectroscopy (AES) has rapidly developed from a purely research oriented technique into an extremely versatile analytical method with unique features for qualitative and quantitative materials characterization. The low escape depth (5–10 Å) of the emitted Auger electrons makes it ideal for surface analysis and for depth profile impurity distribution analysis when combined with in situ ion sputtering.Both surface and depth profile analysis can be accomplished on a selected area by the use of optical or primary electron beam scanning techniques. Results are presented which illustrate the significance of the analytical capabilities of AES in the qualitative and quantitative analysis of thin film electronic materials used in the fabrication of precision thin film resistors, capacitors and conductors. 相似文献
19.
概括阐述了薄膜太阳电池用绒面结构ZnO透明导电薄膜(ZnO-TCO)方面的最新研究进展.绒面结构ZnO-TCO薄膜可以提高薄膜太阳电池效率和稳定性并降低生产成本.磁控溅射技术和MOCVD(Lp-MOCVD/LPCVD)技术是制备绒面结构ZnO-TCO薄膜(例如"弹坑"状和"类金字塔"状表面)的主流生长技术,而喷雾热分解技术则是正在开发的非真空法低成本工艺路线.论述了2种主流技术生长ZnO-TCO薄膜的发展历程,并重点讨论了近期关于绒面ZnO-TCO薄膜微观结构、电学以及光学等特性与工艺关系的研究结果.进一步降低成本和实现大面积产业化是绒面ZnO-TCD薄膜拓展应用的发展趋势. 相似文献