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为提高Monte Carlo分子模拟的取样效率,加速模拟过程的收敛,本文提出了根据粒子能量进行取样的方法。通过对凝固点附近的L-J流体的模拟,将能量选择取样法与Metropolis取样法以及力偏倚取样法的收敛性和模拟结果作了比较,表明能量选择取样法的收敛速度显著高于Metropolis取样法,与力偏倚取样法相当,而计算量比力偏倚取样法小。 相似文献
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催化裂解过程分子尺度反应动力学模型研究 总被引:2,自引:0,他引:2
以工业数据为基础,运用结构导向集总方法来构造烃分子,对催化裂解原料油进行了分子尺度上的Monte Carlo模拟.在深入研究催化裂解反应机理的基础上,以原料油模拟产生的分子矩阵作为反应物分子,将结构导向集总方法与Monte Carlo方法相结合,建立了催化裂解过程分子尺度的反应动力学模型.结果表明:Monte Carlo方法可以在分子尺度上实现对催化裂解原料较好的模拟,产品产率和汽油组成与实际值能较好地拟合.且随着虚拟分子数的增加,对原料油性质和反应结果的模拟计算精度提高;模型具有较好的适应性和外推性. 相似文献
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通过对30种丁二酰亚胺类无灰分散剂在水和石墨表面作用的Monte Carlo Docking模拟,得到其在水和石墨表面的低能量吸附构象及结合能.QSAR分析和Monte Carlo Docking模拟的结果表明分散剂在水表面的吸附行为,与分散剂分子的极性基团的数量、分子正负电荷的分布、分子在水中的溶解自由能有关;而分散剂在石墨表面的吸附,与分散剂分子的链长度和支链数目有关.在此基础上合成了9个丁二酰亚胺无灰分散剂,对其分散烟炱(碳黑)的性能进行了模拟评定,通过对这些分散剂作用的计算机模拟,验证了模拟方法的可行性、可操作性. 相似文献
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基于MATLAB语设计编写了Monte Carlo法处理连续化学反应的动力学计算及其计算机模拟的应用程序,将所编程序用于模拟3-丁烯腈在盐酸催化剂溶液中的水解反应,模拟结果与按照常规化学反应动力学公式的计算结果相比较,表明Monte Carlo法模拟对于预测反应动力学过程具有较高准确性。 相似文献
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《Journal of the European Ceramic Society》2020,40(8):3158-3171
A two-dimensional Monte Carlo (MC) model is introduced for simulating the evolution of the pore on a bi-crystal grain boundary via grain boundary diffusion. Simulated pore shrinkage kinetics is found to be consistent with previously reported results over variable grain boundary diffusion rates and initial pore distances while the essential characteristics of the microstructural evolution are simultaneously realized. The influence on the pore densification kinetics of grain boundary motion, boundary energy ratio, simulation temperature and pore interactions in an array is found such that pore shrinkage rate increases as the grain boundary motion, the simulation temperature and the grain boundary energy increase. The interactions of the pores are found to hinder the pore densification. The body of results signify that the more elongated the pore shape and the shaper the pore tip region are favored for the faster pore shrinkage kinetics during the simulated densification process via grain boundary diffusion. 相似文献
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Hiroshi Itahara Toshihiko Tani Hiroshi Nomura Hideaki Matsubara 《Journal of the American Ceramic Society》2006,89(5):1557-1562
We have developed a computational model using Monte Carlo simulation in order to design grain-oriented microstructures of ceramics processed by templated grain growth for functional materials with anisotropic grain growth due to anisotropy in interfacial energies. The current model with plate-like template particles expressed the development of grain-oriented microstructures with the low interfacial energy planes well faceted. In addition, the proposed model gave a guiding principle for optimizing the initial parameters (i.e., ratio of templates to total solid particles, initial size and aspect ratio of template particles, and amount of liquid phase), leading to highly grain-oriented ceramics with improved performances. 相似文献
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Over the past few decades, a variety of models have been proposed in order to investigate the grain growth kinetics and the development of crystallographic textures in polycrystalline materials. In particular, a full understanding of the microstructure evolution is a key issue for ceramic systems, since their mechanical or thermal behaviour is intimately related to their microstructure. Moreover, the development of appropriate simulative tools is crucial to reproduce, control and finally optimize the solid-state sintering process of ceramics. Monte Carlo simulations are particularly attractive because of their ability to reproduce the statistical behaviour of atoms and grain boundaries with time. However, Monte Carlo simulations applied to two-phase materials, such as many ceramic systems, result complex because both grain growth and diffusion processes should be taken into account. Here the Monte Carlo Potts model, which is widely used to investigate the crystallization kinetics for monophasic systems, is modified and extended to biphasic ones. The proposed model maps the microstructure onto a discrete lattice. Each lattice element contains a number representing its phase and its crystallographic orientation. The grain formation and growth are simulated by appropriate switching and reorientation attempts involving the lattice elements. The effect of temperature is also discussed. 相似文献
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Monte Carlo method is applied to investigate the kinetics of ammonia oxidative decomposition over the commercial propylene ammoxidation catalyst(Mo-Bi). The simulation is quite in agreement with experimental results. Monte Carlo simulation proves that the process of ammonia oxidation decomposition is a two-step reaction. 相似文献
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A Monte Carlo simulation technique is developed to describe dispersed phase systems. The method is formulated for simultaneous coagulation, nucleation and surface growth, but can be extended to include other processes. These processes are considered in an initially constant simulation volume. The changes in the particle ensemble are determined by a random choice procedure, while the particle number in the simulation volume changes according to the chosen events. Every time, when the particle number in the simulation volume increases or decreases by a factor of two of its initial value, the simulation volume is halved or doubled, respectively. Therefore, this method is called a stepwise constant-volume Monte Carlo simulation. It allows to use only several thousands simulation particles, even if the particle number concentration experiences changes of several orders of magnitude. The simulations are validated through a comparison with the exact mathematical solutions for several simple cases. An example of simultaneous nucleation and coagulation in the free-molecular region demonstrates, that the stepwise constant-volume Monte Carlo simulations lead to more accurate results than the constant-number Monte Carlo simulations. 相似文献
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The current study utilises Monte Carlo simulation and Mie scattering theory to estimate the reflectance spectra of fabric coated with titanium dioxide nanopigments of various diameters and concentrations. Image processing was carried out and experimental data were gathered to evaluate the performance of Monte Carlo simulation. The distribution and location of the nanopigments on the surface of fabric were determined using the Monte Carlo method. Reflection of the fabric was calculated based on Monte Carlo simulation with the partitive mixing method and Mie theory. According to the experimental and simulation results, the reflectance of coated samples was increased by increasing the concentration and number of titanium dioxide nanoparticles. There was a good match between the results obtained by Monte Carlo simulation and the experimental results. For coated samples (dTiO2: 500 nm), the root mean square error between measured and predicted reflectance by the Monte Carlo and partitive mixing method and by Monte Carlo and Mie theory was 0.022 and 0.0078, respectively. The results indicate that the performance of the Monte Carlo and Mie method was better than that of the Monte Carlo and partitive mixing method. According to t-test analysis, there was no statistically significant difference between the experimental data and Monte Carlo simulation. 相似文献
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The Potts Monte Carlo simulation was used to simulate microstructural evolution in uranium dioxide fuel rods. During service, grain growth, pore migration, and thermal segregation of the pores and UO2 occur in the rods in a thermal gradient. In this investigation, we developed a model which simulates simultaneous grain growth, pore migration, and thermal segregation of the pores and UO2 in a temperature gradient. Grain growth in a thermal gradient was simulated using the Monte Carlo Potts model technique developed by Anderson, Srolovitz, and co-workers. Pore migration was simulated using conserved dynamics with minimum-energy exchanges at a finite temperature. A temperature gradient was introduced into the model via interfacial mobility gradient. Finally, thermal segregation of the pores and UO2 was achieved by introducing a heat of migration term, Δ E t , which biased the motion of porosity to the high-temperature region. The development of this model is described and the incorporation of the proper physics of pore migration and thermal segregation is discussed. 相似文献
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By suitably pressurizing iron substrates under different conditions, the resulting α-Fe(2)O(3) nanostructures, formed by its direct thermal oxidation, can gradually change in succession from nanowires to nanoleaves and to micropillars as the pressure is increased. The inter-relation between the pressure conditions and the resulting nanostructure is studied by density functional calculations using ultrasoft pseudopotentials with a plane-wave basis method and with the generalized gradient approximation (GGA). It is shown that the shape of the formed nanostructures is primarily determined by the anisotropic activation energy and, as the latter is lowered, there is a shape change from wire to pillar. A simulation model of diffusion using the Monte Carlo method is applied in the 3-D (dimensional) case to show how the anisotropic activation energy influences the growth process of the α-Fe(2)O(3) nanostructure. The present study provides a way to control the shape of the nanostructures grown by the thermal-oxidation method. 相似文献
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Sylvie Bordère 《Journal of the American Ceramic Society》2002,85(7):1845-1852
A Monte Carlo methodology different from others based on the Potts model has been developed to solve capillary-driven mass transport involved in the sintering process. The addition of a cohesive energy term to the energetic model enables quantification of the stress gradients within grains, as well as the induced mass fluxes. The study of two-particle sintering involving volume diffusion has been chosen as a first example. The morphological evolution of the two-particle system to a single particle is followed. Real-time-dependent neck growth and shrinkage rates are defined. The rheological behavior of the particles induced by the Monte Carlo procedure is discussed. 相似文献