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二甲苯和苯乙烯的混合物,在稀土固体超强酸SO2-4 /TiO2/Sm3+的催化下发生傅-克烷基化反应,合成二芳基乙烷.研究了催化剂的催化性能,同时考察了影响合成反应的因素.结果表明,稀土固体超强酸SO2- 4/TiO2/Sm3+具有催化性能高,性能稳定和连续催化活性基本保持不变的优点,而且生产过程简单,无腐蚀,无废水污染. 相似文献
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二甲苯和苯乙烯的混合物,在稀土固体超强酸SO2 -4/TiO2 /Sm3 + 的催化下发生傅-克烷基化反应,合成二芳基乙烷。研究了催化剂的催化性能,同时考察了影响合成反应的因素。结果表明,稀土固体超强酸SO2 -4/TiO2 /Sm3 + 具有催化性能高,性能稳定和连续催化活性基本保持不变的优点,而且生产过程简单,无腐蚀,无废水污染。 相似文献
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稀土固体超强酸SO4^2-/TiO2/Sm^3+催化合成己二酸二异辛酯的研究 总被引:3,自引:0,他引:3
以稀土固体超强酸SO4^2-/TiO2/Sm^3 为催化剂合成了己二酸二异辛酯,考察了影响酯化反应的因素。实验结果表明,稀土固体超强酸SO4^2-/TiO2/Sm^3 催化活性高、性能稳定,是一种优良的醇化催化剂。 相似文献
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以稀土固体超强酸SO42-/TiO2/La3+为催化剂,邻苯二甲酸酐和2 乙基己醇为原料,合成邻苯二甲酸二(2 乙基)己酯,考察了影响反应的因素。结果表明,醇∶苯酐(质量比)=2.5∶1,催化剂用量为苯酐的5%,反应时间2 5h时,酯化率可达92.7%。 相似文献
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合成己酸异戊酯的催化剂研究 总被引:3,自引:1,他引:3
综述了氯化铁等Lewis酸 ,硫酸氢钠 ,硫酸钛 ,对甲苯磺酸 ,固体超强酸TiO2 /SO42 -,稀土固体超强酸SO42 -/TiO2 /La3 + ,磷钨杂多酸 ,TABP等几种不同催化剂催化合成了己酸异戊酯的实验结果。结果表明 :硫酸氢钠 ,磷钨杂多酸 ,TABP等 3种催化剂对合成己酸异戊酯的酯收率较高 ,具有实际应用价值。 相似文献
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固体超强酸催化合成乙酸正丁酯的研究 总被引:2,自引:1,他引:1
文章采用TiO2/SO42-固体超强酸为催化剂来合成乙酸正丁酯,考察了催化剂用量、酸醇物质的量之比、反应时间等因素对酯化率的影响,结果表明,TiO2/SO42-固体超强酸催化剂活性高,易分离,对设备不腐蚀,排放无污染等优点;在最佳反应条件下,酯化率可达99.3%。 相似文献
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以SO42-/TiO2-Al2O3固体超强酸为催化剂,进行新戊二醇和椰子油酸的酯化反应,合成了新戊二醇椰子油酸酯,考察了酸醇摩尔比、催化剂用量、反应温度、反应时间等条件对酯化反应的影响。结果表明,较优的合成条件为:n(椰子油酸)∶n(新戊二醇)=1.95∶1,催化剂用量为总反应物质量的0.040%,200℃下回流反应7 h。在此条件下,SO42-/TiO2-Al2O3固体超强酸有较高的催化活性,酯化率达97.0%,且催化剂重复使用5次仍保持较高活性。 相似文献
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固体超强酸SO2-4/TiO2/La3+催化合成氯乙酸乙酯 总被引:1,自引:0,他引:1
以稀土固体超强酸SO2-4/TiO2/La3+为催化剂,氯乙酸与乙醇为原料合成氯乙酸乙酯.研究了氯乙酸与乙醇的摩尔比、催化剂用量、环己烷的用量、反应时间诸因素对产品收率的影响.结果表明SO2-4/TiO2/La3+是合成氯乙酸乙酯的良好催化剂,适宜的反应条件如下氯乙酸与乙醇的摩尔比为1∶3.0,催化剂的用量0.8 g,环己烷用量15 mL,反应2.0 h,氯乙酸乙酯的收率可达92.7%. 相似文献
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Low-temperature combustion of various organic compounds on Pt/SO
4
–2
/ZrO2 and Pd/SO
4
–2
/ZrO2 was studied. For these organic compounds, especially saturated hydrocarbons, the combustion activities of Pt/SO
4
–2
/ZrO2 are higher than those of Pt/ Al2O3. Pt/SO
4
–2
/ZrO2 combustion catalysts can be used in a wide range of space velocity and oxygen content. The catalytic activity is enhanced with an increase of Pt loading from 0.1 to 1.0 wt%. The superacidity of the support material is responsible for the improvement in activity rather than an increase in catalyst surface area or metal dispersion. Pd/SO
4
–2
/ZrO2 are less active than Pt/SO
4
–2
/ZrO2. 相似文献
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We report results on the adsorption and desorption of H2S on polycrystalline UO2 at 100 and 300 K, using ultrahigh vacuum X-ray photoelectron spectroscopy (XPS), low energy ion scattering (LEIS), and temperature programmed desorption (TPD). Our work is motivated by the potential for using the large stockpiles of depleted uranium in industrial applications, e.g., in catalytic processes, such as hydrodesulfurization (HDS) of petroleum. H2S is found to adsorb molecularly at 100 K on the polycrystalline surface, and desorption of molecular H2S occurs at a peak temperature of 140 K in TPD. Adsorption rates of sulfur as a function of H2S exposure are measured using XPS at 100 K; the S 2p intensity and lineshapes demonstrate that the saturation coverage of S-containing species is 1 monolayer (ML) at 100 K, and is 0.3–0.4 ML of dissociation fragments at 300 K. LEIS measurements of adsorption rates agree with XPS measurements. Atomic S is found to be stable to >500 K on the oxide surface, and desorbs at 580 K. Evidence for a recombination reaction of dissociative S species is also observed. We suggest that O-vacancies, defects, and surface termination atoms in the oxide surface are of importance in the adsorption and decomposition of S-containing molecules. 相似文献
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Different catalysts based on platinum and a silica, titania or mixed titania/silica support were studied in NO reduction reactions by CO and H2 in the temperature range of 25–400C. The mixed oxide catalysts showed considerably lower onset temperatures in NO/CO reactions but this coincided with a maximum in N2O formation. In NO/H2 reactions all titania containing catalysts produced more N2O than silica supported platinum at low temperatures but were more selective to N2 at high temperatures. 相似文献
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The purpose of this study is to investigate the characteristics of soot particles in C2H4/CO2/O2/N2 combustion at equivalence ratio of 3.0-5.0. As the oxidant is switched from conventional air to CO2/O2/N2 mixture, the key species C2H2, C3H3 responsible for formation of first aromatic ring, the typical aromatics and 4-ring aromatics total production rate all decrease greatly. In addition, with CO2 mole fraction from 0.2 to 0.5 in the mixture, the soot particle number density, volume fraction, surface area density, which are three most important parameters to soot particle property, are suppressed obviously. Furthermore, the increasing content of CO2 in the oxidizer influences mostly H, OH radical concentrations by two reactions: CO+OH=CO2 H and H+O2=O+OH, and the production rate of H, OH from the two reactions declined, which revealed that CO2 in mixture has an inhibiting effect on soot particle generation. 相似文献
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Bifunctional catalysts (Ag-MnO2)/SWNT were prepared by using a simple chemical reduction route on single-walled carbon nanotubes (SWNT). Five weight percentage of Ag-MnO2 on SWNT was found to be the best loading in terms of current density. The (Ag-MnO2)/SWNT catalyst was characterized and the kinetics towards oxygen reduction reaction (ORR) was determined and compared with that of Ag-MnO2 on acetylene black (AB) catalyst. The number of exchanged electrons for the ORR was found to be close to four on both (Ag-MnO2)/SWNT and (Ag-MnO2)/AB. The kinetic rate constant of catalytic reaction for the two catalysts was of the same order. The zinc-air batteries with both catalysts were fabricated and examined. A stable discharge potential plateau appeared at approximately 1.2 and 1.1 V with discharge capacities 261 and 190 mAh/g, respectively. 相似文献
18.
K. V. R. Chary H. Ramakrishna K. S. Rama Rao G. Murali Dhar P. Kanta Rao 《Catalysis Letters》1991,10(1-2):27-33
A series of Mo/MgO catalysts with loadings ranging from 2–12 wt% Mo were studied by oxygen chemisorption, X-ray diffraction and activity for thiophene hydrodesulfurization (HDS) reaction. The results obtained from the above measurements are compared with those on Mo/--Al2O3. These results indicated that molybdenum is better dispersed on MgO. Hydrodesulfurization activity per g. Mo is found to be higher in the case of Mo/MgO. The higher activities are attributed to the increase in dispersion of Mo on MgO. A linear correlation is obtained between oxygen chemisorption and HDS activity. The parallelism between HDS and oxygen chemisorption is explained. 相似文献
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The crystallization kinetics of a glass based on one type of mica, NaMg3 AlSi3 O10 F2 , with the addition of a nucleating agent, TiO2 , has been studied using differential thermal analysis (DTA) under both isothermal and nonisothermal conditions. Two distinct crystallization exotherms in the DTA curve are observed and resolved that correspond to the initial formation of magnesium titanate (MgTi2 O5 ) and the later formation of mica. The activation energy for precipitation of each crystalline phase has been evaluated, and the crystallization mechanism has been studied. The results indicate that the growth of mica is a two-dimensional process, controlled by the crystal-glass interface reaction. The average calculated values of activation energies are 256 ± 11 kJ/mol and 275 ± 6 kJ/mol for the precipitation of MgTi2 O5 and mica from the glass matrix, respectively. 相似文献