Organic light-emitting diodes with improved hole–electron balance and tunable light emission with aromatic diamine/bathocuproine multiple hole-trapping-layer

Organic light-emitting diodes (OLEDs) with multiple hole-trapping-layer (HTL) structures, which consist of N,N′-bis-(1-naphthyl)-N, N′-diphenyl-1,1′-biphenyl 4,4′-diamine (NPB), bathocuproine (BCP) and tris(8-hydroxy-quinoline)aluminum (Alq₃) have been fabricated. The emitting zone of the device with the structure of ITO/[NPB/BCP]_n/Alq₃/LiF/Al can be changed by the number n of HTL. The effect of the multiple HTL structure upon the performance of OLEDs with tris(8-hydroxyquinoline) aluminum as the emitting material has been investigated. Compared with the brightness of the conventional green emitting diode without the multiple HTL structure, that of the diode with periodic number of five has been increased from 2512.8 cd/m² to 8661.0 cd/m². Such an improvement in the device performance was attributed to the improved hole–electron balance, which can be further attributed to the introduction of the multiple HTL structure.     

Highly efficient styrylamine-doped blue and white organic electroluminescent devices

We have developed highly efficient blue and white organic electroluminescent devices based on a blue fluorescent styrylamine dopant EBDP. The blue and white organic light emitting diodes (OLEDs) with the structures: Indium–tin oxide (ITO)/copper phthalocyanine(CuPc)/N,N′-bis-(1-naphenyl)-N,N′-biphenyl-1,1′-bipheny1-4-4′-diamine (NPB)/2-t-butyl-9,10-di-(2-naphthyl)anthracene (TBADN):EBDP/tris(8-hydroxyquinoline)aluminum(Alq₃)/LiF/Al and ITO/CuPc/NPB/TBADN:EBDP: 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB)/Alq₃/LiF/Al were studied by using EBDP as blue dopant. For the blue device, the maximum luminance and maximum efficiency were 26961 cd/m² and 8.29 cd/A, respectively, the luminance at a current density 20 mA/cm² was 1597 cd/m². For the white device, the maximum luminance of 32,291 cd/m², maximum efficiency 8.31 cd/A and the luminance of 1413 cd/m² at a current density 20 mA/cm² were obtained. The slow decrease of efficiency with the increase of current density indicates weak exciton–exciton annihilation, which is resulted from the large steric hindrance due to the non-planar structure of the fluorescence dye EBDP.     

Efficient enumeration of all minimal separators in a graph

This paper presents an efficient algorithm for enumerating all minimal a-b separators separating given non-adjacent vertices a and b in an undirected connected simple graph G = (V, E), Our algorithm requires O(n³R_ab) time, which improves the known result of O(n⁴R_ab) time for solving this problem, where ¦V¦= n and R_ab is the number of minimal a-b separators. The algorithm can be generalized for enumerating all minimal A-B separators that separate non-adjacent vertex sets A, B < V, and it requires O(n²(n − n_A − n_b)R_AB) time in this case, where n_a = ¦A¦, n_B = ¦B¦ and r_AB is the number of all minimal A−B separators. Using the algorithm above as a routine, an efficient algorithm for enumerating all minimal separators of G separating G into at least two connected components is constructed. The algorithm runs in time O(n³R⁺_Σ + n⁴R_Σ), which improves the known result of O(n⁶R_Σ) time, where R_σ is the number of all minimal separators of G and R_ΣR⁺_Σ = ∑_1i, v_j) ER_vivj n − 1)/2 − m)R_Σ. Efficient parallelization of these algorithms is also discussed. It is shown that the first algorithm requires at most O((n/log n)R_ab) time and the second one runs in time O((n/log n)R⁺_Σ+n log nR_Σ) on a CREW PRAM with O(n³) processors.     

Development of a screen-printed cholesterol biosensor: Comparing the performance of gold and platinum as the working electrode material and fabrication using a self-assembly approach

Gold (Au) and platinum (Pt) were used as the working electrode material to detect cholesterol in solution through enzymatically generated hydrogen peroxide (H₂O₂). Both gold and platinum were capable of detecting cholesterol through the electrochemical oxidation of H₂O₂, and could be used as the working electrode material. By comparison, however, Au was preferable over Pt in terms of higher response current and better sensitivity. Therefore, Au was chosen as the working electrode material for the fabrication of a thick-film screen-printed cholesterol biosensor consisting of three electrodes on an alumina substrate (working: Au, reference: Ag/AgCl, and counter: Au). The immobilization of the enzyme cholesterol oxidase (ChOx, E.C. 1.1.3.6) on the Au working electrode was achieved using a self-assembly approach. A thiol, 3-mercaptopropionic acid (MPA), was self-assembled onto the gold working electrode forming a thin organic layer that served as the anchor for the enzyme immobilization. 1-Ethyl-3(3-dimethylamino propyl)carbodiimide methiodide (EDC) was then used to immobilize the enzyme ChOx covalently on the gold working electrode through the carbodiimide coupling between the carboxyl (–COOH) groups of the self-assembled MPA layer and the amino (–NH₂) groups of the enzyme. Electrochemical measurements showed that this biosensor responded well to cholesterol, confirming that the self-assembly immobilization method was effective. The reproducibility, the interference, and the storage stability of the biosensor were studied and assessed.     

Fast evaluation of radial basis functions: I

This paper describes some new techniques for the rapid evaluation and fitting of radial basic functions. The techniques are based on the hierarchical and multipole expansions recently introduced by several authors for the calculation of many-body potentials. Consider in particular the N term thin-plate spline, s(x) = Σ_j=1^N d_jφ(x−x_j), where φ(u) = |u|²log|u|, in 2-dimensions. The direct evaluation of s at a single extra point requires an extra O(N) operations. This paper shows that, with judicious use of series expansions, the incremental cost of evaluating s(x) to within precision ε, can be cut to O(1+|log ε|) operations. In particular, if A is the interpolation matrix, a_i,j = φ(x_i−x_j, the technique allows computation of the matrix-vector product Ad in O(N), rather than the previously required O(N²) operations, and using only O(N) storage. Fast, storage-efficient, computation of this matrix-vector product makes pre-conditioned conjugate-gradient methods very attractive as solvers of the interpolation equations, Ad = y, when N is large.     

Heaps and heapsort on secondary storage

A heap structure designed for secondary storage is suggested that tries to make the best use of the available buffer space in primary memory. The heap is a complete multi-way tree, with multi-page blocks of records as nodes, satisfying a generalized heap property. A special feature of the tree is that the nodes may be partially filled, as in B-trees. The structure is complemented with priority-queue operations insert and delete-max. When handling a sequence of S operations, the number of page transfers performed is shown to be O(∑_{i = 1}^S(1/P) log_(M/P)(N_i/P)), where P denotes the number of records fitting into a page, M the capacity of the buffer space in records, and N_i, the number of records in the heap prior to the ith operation (assuming P 1 and S> M c · P, where c is a small positive constant). The number of comparisons required when handling the sequence is O(∑_{i = 1}^S log₂ N_i). Using the suggested data structure we obtain an optimal external heapsort that performs O((N/P) log_(M/P)(N/P)) page transfers and O(N log₂ N) comparisons in the worst case when sorting N records.     

Analytic-numerical solutions with a priori error bounds for time-dependent mixed partial differential problems

The aim of this paper is double. First, we point out that the hypothesis D(t₁)D(t₂) = D(t₂)D(t₁) imposed in [1] can be removed. Second, a constructive method for obtaining analytic-numerical solutions with a prefixed accuracy in a bounded domain Ω(t₀,t₁) = [0,p] × [t₀,t₁], for mixed problems of the type u_t(x,t) − D(t)u_xx(x,t) = 0, 0 < x < p, t> 0, subject to u(0,t) = u(p,t) = 0 and u(x,0) = F(x) is proposed. Here, u(x,t) and F(x) are r-component vectors, D(t) is a C^{r × r} valued analytic function and there exists a positive number δ such that every eigenvalue z of (1/2) (D(t) + D(t)^H) is bigger than δ. An illustrative example is included.     

BP神经网络和支持向量机相结合的电容器介损角辨识

针对电力电容器介质损耗的计算方法稳定性较差,频率波动对介损角的辨识有较大影响的问题,提出了BP神经网络和支持向量机（support vector machine, SVM）相结合（BP-SVM）的辨识方法,并且首次应用于电容器介损角的辨识。在辨识过程中,首先,对电容器工作一段时间的信号进行采样和预处理,预处理后的信号作为训练集训练BP-SVM模型;然后,使用训练好的BP-SVM模型对预处理后新的采样信号进行辨识,判断介损角的变化量。此外,给出了基于BP-SVM模型的介损角表示信号D_δ（t）的计算过程,同时分析了在讨论域内信号D_δ（t）的幅值即是介损角δ。仿真分析结果表明,提出的BP神经网络和SVM相结合的电容器介损角辨识方法比基于深度学习的辨识方法具有更高的辨识准确率,并且频率变化对BP-SVM方法的辨识性能无明显影响。     

Simulation and fabrication of piezoresistive membrane type MEMS strain sensors

Two piezoresistive (n-polysilicon) strain sensors on a thin Si₃N₄/SiO₂ membrane with improved sensitivity were successfully fabricated by using MEMS technology. The primary difference between the two designs was the number of strips of the polysilicon patterns. For each design, a doped n-polysilicon sensing element was patterned over a thin 3 μm Si₃N₄/SiO₂ membrane. A 1000×1000 μm² window in the silicon wafer was etched to free the thin membrane from the silicon wafer. The intent of this design was to fabricate a flexible MEMS strain sensor similar in function to a commercial metal foil strain gage. A finite element model of this geometry indicates that strains in the membrane will be higher than strains in the surrounding silicon. The values of nominal resistance of the single strip sensor and the multi-strip sensor were 4.6 and 8.6 kΩ, respectively. To evaluate thermal stability and sensing characteristics, the temperature coefficient of resistance [TCR=(ΔR/R₀)/ΔT] and the gage factor [GF=(ΔR/R₀)/] for each design were evaluated. The sensors were heated on a hot plate to measure the TCR. The sensors were embedded in a vinyl ester epoxy plate to determine the sensor sensitivity. The TCR was 7.5×10⁻⁴ and 9.5×10⁻⁴/°C for the single strip and the multi-strip pattern sensors. The gage factor was as high as 15 (bending) and 13 (tension) for the single strip sensor, and 4 (bending) and 21 (tension) for the multi-strip sensor. The sensitivity of these MEMS sensors is much higher than the sensitivity of commercial metal foil strain gages and strain gage alloys.     

A novel thick-film ceramic humidity sensor

The paper describes the results of studies on the fabrication and characterisation of a thick-film humidity sensor based on the semiconducting metal oxide MnWO₄. The sensor element possesses a novel ‘sandwich’-configuration with a 40 μm porous MnWO₄ ceramic layer sandwiched by two 10 μm polarity-reversed, interdigitated metal films. Instead of traditional glass frits, LiCl powders are used as adhesion promoters for sintering the sensor paste. With this method, MnWO₄ powders with an average particle size of 3.0 μm are sintered at the standard thick-film firing temperature of 850°C. The sintered ceramic layer exhibits a porous structure. The novel electrode arrangement combines the advantages of humidity sensors in the form of a parallel capacitor with those in the form of an interdigital capacitor, permitting a high sensitivity and a fast response. The influence of temperature on the sensor characteristics has been compensated for by integrating a thick-film NTC resistor. The humidity sensor shows no cross-sensitivity to organic vapour. The organic contamination on the sensor surface can be burned out by heating the sensor element at about 400°C with the refresh heater printed on the back side of the substrate.     

ITO lift‐off technique for TFT mask‐reduction process

Abstract— In recent years, reducing the number of TFT‐manufacturing steps has become an unavoidable technology development stream for all TFT‐LCD makers for the purpose of cost reduction. In this paper, an advanced photomask‐process‐reduction technique, a three‐mask TFT process, by chemical lift‐off which is inherent of the conventional four‐mask TFT fabrication process, is proposed. The major feature of this three‐mask technique is the combining of the passivation‐layer and pixel‐electrode formation within one photolithography process. A new halftone mask (HTM) design has been applied to the photolithography process. With this new HTM design, a small SiN_x island bridge was formed, located at the TFT source contact‐edge border. And it provided an ITO pixel electrical conducting path and avoided the undercut issue where ITO breaks from the gate insulator (GI). In order to enhance the chemical lift‐off efficiency, different process and structure designs were also implemented and introduced. Furthermore, a new laser lift‐off technology was adopted to improve the ability of ITO lift‐off. By using this new laser lift‐off technology, unnecessary ITO film could be easily lift‐off before photoresist stripping. Finally, the first HTM lift‐off panel was successfully demonstrated by using our new three‐mask TFT design scheme.     

On the overflow processes from the PH1 + PH2/M/S/K queue with two independent PH-renewal inputs

This paper presents an analysis of overflow processes from a PH₁ + PH₂/M/S/K queue having two independent phase type renewal input streams. Both the superposed overflow process and individual overflow processes for the PH₁- and PH₂-streams are analyzed using first passage time distributions for the number of customers in the system. Each overflow process is characterized as a Markov renewal process. The nth moment of the number of customers in an infinite server group to which these overflows have been offered is derived using a theory for the MR/M/∞ queue with a Markov renewal input. The numerical examples for means and variance-to-mean ratios (peakednesses) of the individual overflow streams are given for an H₂ + H₂/M/S/S queue with interrupted Poisson inputs, which is a vital model for telephone network planning. In addition, overflow traffic characteristics are discussed by using these examples.     

Trace detection of nitroaromatic compounds with layer-by-layer assembled {SBA/PSS}n/PDDA modified electrode

The {SBA/PSS}_n/PDDA films modified electrode was prepared by layer-by-layer (LBL) assembly with mesoporous SiO₂ (SBA), poly(sodium 4-styrene-sulfonate) (PSS) and poly(diallyldimethylammonium chloride) (PDDA) in this paper. SBA is a large pore-size mesoporous material with highly ordered hexagonally arranged mesochannels and high thermal stability etc. The electrochemical characteristics of the {SBA/PSS}_n/PDDA films have been studied by electrochemical impedance spectroscopy in 0.1 M KCl solution containing 5.0 mM Fe(CN)₆³⁻/Fe(CN)₆⁴⁻ at the formal potential of 0.230 V. The ultratrace nitroaromatic compounds (NACs) such as TNT, TNB, DNT and DNB were determined by differential pulse voltammetry (DPV) measurement. The sensitivities for NACs determination with {SBA/PSS}_n/PDDA modified electrode were dependent on the number of layers, pH and ionic strength of electrolyte, based on which a set of optimized conditions for film fabrication was inferred. The current responses were linear with NACs ranging from 10⁻⁹ to 10⁻⁷ mol/l. The results showed that the {SBA/PSS}_n/PDDA modified electrode established a new way for fast, simple and sensitive analysis of NACs.     

Electrochemical studies on the performance characteristics of alkaline solid embeddable sensor for concrete environments

In this study, alkaline solid embeddable MnO₂ is used as a reference sensor for concrete environments. The performance characteristics are evaluated in a saturated calcium hydroxide solution, a synthetic concrete pore solution and ordinary Portland cement (OPC) extracts which correspond to the concrete environments. The electrochemical stability of the MnO₂ electrode is studied in the said concrete environments. The uniformity of the MnO₂ sensor is tested in concrete environments. The reversibility of MnO₂ sensor in three alkaline solutions is within ±10 mV, which is very well within the limit as sensor for concrete. The polarization behaviour of MnO₂ electrode in concrete environments is carried out potentiodynamically and impedance behaviour showed the stability of sensor. All the studies revealed that MnO₂ as a suitable sensor electrode for concrete structures.     

Thermodynamics of the cao-si02 system

In order to maintain consistency, analytical expressions for the free energy of mixing of phases should reproduce not only the phase diagrams but also the experimentally determined activities. Information on the partial molar free energies and the phase boundaries, in turn, can be used to estimate the free energy of formation of compounds.

An examination of thermochemical data in the CaO-SiO₂ system showed that ΔGδf values for -Ca₂Si0₄, which are stable at temperatures above 1710°K, are limited a maximum of 1800°K. The free energy of formation in a temperature range from about 1700 to 2400°K was estimated from the phase boundary and the activity of silica to be as follows:

2Ca0(s) + Si0₂(cristo.) = Ca2Si0₄() ΔG°f = −86303.50 − 34.338 Tjoules

An analytical expression for the free energy of mixing of the liquid phase was obtained for the entire composition range in the CaO-Si0₂ system. Confidence in the estimated G‡f for -Ca₂Si0₄ was demonstrated by good agreement of the calculated phase diagram and the experimentally determined activity of silica.     

Biinfinite words with maximal recurrent unbordered factors

A finite non-empty word z is said to be a border of a finite non-empty word w if w=uz=zv for some non-empty words u and v. A finite non-empty word is said to be bordered if it admits a border, and it is said to be unbordered otherwise. In this paper, we give two characterizations of the biinfinite words of the form ^ωuvu^ω, where u and v are finite words, in terms of its unbordered factors.

The main result of the paper states that the words of the form ^ωuvu^ω are precisely the biinfinite words w=a₋₂a₋₁a₀a₁a₂ for which there exists a pair (l₀,r₀) of integers with l₀<r₀ such that, for every integers ll₀ and rr₀, the factor a_la_l0a_r0a_r is a bordered word.

The words of the form ^ωuvu^ω are also characterized as being those biinfinite words w that admit a left recurrent unbordered factor (i.e., an unbordered factor of w that has an infinite number of occurrences “to the left” in w) of maximal length that is also a right recurrent unbordered factor of maximal length. This last result is a biinfinite analogue of a result known for infinite words.     

Separating k-separated eNCE graph languages

An eNCE graph grammar is k-separated (k1) if the distance between any two nonterminal nodes in any of its sentential forms is at least k. Let SEP_k denote the class of graph languages generated by k-separated grammars. Then, SEP₁ (SEP₂) is the class of eNCE (boundary eNCE) graph languages, and so SEP₂SEP₁. Recently, Engelfriet (1991) showed that SEP₃SEP₂ and conjectured that, in fact, SEP_k+1SEP_k for each k 1. We prove this conjecture affirmatively.     

Behavior of the beta-splines with values of the parameters beta2 negative

In this paper we study the behavior of the beta-spline functions in the case the parameter β₂(i) is negative. We prove that a negative value exists so that if , the beta-spline functionsN_i(u) are positive. Moreover, if the control vertices are such that x₀ x_m−1, we have proved that the design curve keeps the properties already proved in the case β₂(i) 0.     

Robust H∞ control design for systems with structured parameter uncertainty

In a recent paper a unification of the H₂ (LQG) and H_∞ control-design problems was obtained in terms of modified algebraic Riccati equations. In the present paper these results are extended to guarantee robust H₂ and H_∞ performance in the presence of structured real-valued parameter variiations (ΔA, ΔB, ΔC) in the state space model. For design flexibility the paper considers two distinct types of uncertainty bounds for both full- and reduced-order dynamic compensation. An important special case of these results generates H₂/H_∞ controller designs with guaranteed gain margins.