SiCp/AI 复合材料的显微组织与常规力学性能研究

本文研究了流变铸造法制备的 SiCp/LY12和 SiCp/5083Al 复合材料中SiC 颗粒的分布情况,发现在特定的工艺条件下,只有当 SiC 颗粒的体积分数处在一定的范围内。复合材料才能获得良好的 SiC 颗粒分布均匀性:另外,加工工艺对SiC 颗粒的分布也将产生影响.研究结果表明,不同体积分数的 SiC 颗粒均使复合材料的屈服强度得到提高,除时效态 SiCp/LY12复合材料外,其余复合材料的抗拉强度也得到提高,但复合材科的冲击韧性却大大下降。     

SiCp/Al复合材料的ELID精密加工工艺

针对高体积分数SiCp/Al复合材料的加工难题,采用在线电解修整精密磨削加工工艺对其进行精密磨削实验研究.首先,通过建立单颗粒磨削模型,得到磨粒的最大变形磨屑厚度,进而利用Matlab软件,得到SiCp/Al复合材料塑性域磨削的试验参数范围.然后,通过单因素试验探究磨削深度、砂轮转速以及工件移动速度对加工表面粗糙度的影响,利用正交试验最优参数与理论分析得到的塑性域磨削的试验参数范围进行对比,确定了最优工艺参数.最后,以最优试验参数对体积分数40%的SiCp/Al复合材料进行精密磨削加工,获得表面粗糙度Ra 0.030μm的加工表面.研究表明:应用ELID精密磨削加工工艺,采用W5铸铁基金刚石砂轮,当砂轮转速为1 500 r/min,磨削深度在0.1μm,工件移动速度为2 m/min时,磨削效果最佳.     

冷却速度对SiCp/2024Al热残余应力影响的数值模拟

针对冷却速度对SiCp／2024Al复合材料热残余应力的影响，通过复合材料显微组织观察，根据复合材料的形貌特征，建立了平面应力状态的复合材料组织模型，利用有限元方法对SiCp／2024Al复合材料淬火和退火过程的热应力进行了数值模拟．结果表明，由于SiC增强颗粒与铝基体之间的热膨胀系数差异较大，热处理后颗粒和基体的界面附近产生很大的热残余应力场，同时基体发生塑性应变；冷却速度对复合材料热残余应力没有明显影响．     

磨削高体积分数SiCp/Al复合材料表面形成机制

针对高体积分数SiCp/Al复合材料精密加工问题,研究了磨削加工高体积分数SiCp/Al复合材料表面形貌的形成机制.使用金刚石砂轮在干式和湿式两种磨削条件下对高体积分数SiCp/Al复合材料进行磨削实验研究,通过表面粗糙度仪对表面粗糙度进行测量,运用扫描电镜对磨削加工的表面形貌进行观测研究.结果表明：该材料磨削表面的主要缺陷为SiC颗粒拔出、破碎、压入和Al基体的涂敷等,SiC颗粒的破碎和脱落是磨削加工该材料表面形成的主要机制.两种磨削条件下工件进给速度对表面粗糙度的影响比磨削深度更显著,湿式磨削无论是在工件已加工表面形貌和微观结构还是表面粗糙度上都好于干式磨削.     

纤维体积分数对 Al_2O_(3f)/ZA22 复合材料拉伸强度的影响

采用日本产ＡＧ １０ＴＡ型电子万能试验机对不同纤维体积分数的挤压铸造Ａｌ２Ｏ３ｆ／ＺＡ２２复合材料的拉伸强度进行了测定。采用Ｆｒｉｅｎｄ修正的混合律模型对纤维体积分数较小时该类复合材料拉伸强度低于基体合金强度这一现象进行了深入分析。理论分析与试验结果吻合较好。在本试验条件下,求得纤维强化临界体积分数Ｖｃｒｉｔ为２３６％,超过该值,复合材料强度高于基体强度。     

Modeling effects of constituents and dispersoids on tensile ductility of aluminum alloy

The modeling effects of constituents and dispersoids on the tensile ductility of aluminum alloy were studied.The results show that the tensile ductility decreases with the increase of the volume fraction and size of constituents.Thus,purification can improve the tensile ductility by decreasing the volume fraction of constituents(normally compositions of Fe and Si)and the first-class microcracks.The model also indicates that the tensile ductility decreases with the increase in the volume fraction of dispersoids.Decreasing the volume fraction of dispersoids along the grain boundaries by proper heat-treatment and improving the cohesion strength between dispersoids and matrix can also improve the tensile ductility by decreasing the volume fraction of the second-class microcracks.     

Effect of pressure on the solidification behavior and mechanical properties of SiCp/Al-Mg composites

SiCp/Al-Mg metal matrix composites were manufactured by semi-solid stirring technique. The composites were remelted and then solidified under different pressures to study the solidification behavior of composites by differential thermal analysis, scanning electron microscopy, and transmission electron microscopy. The experimental results show that SiCp reinforcements can not act as heterogeneous nucleation sites for α(Al), and an interfacial layer composed of MgAl2O4 spinel and Si-rich phase existed at Al/SiCp interface. The undercooling of the matrix alloy was improved by the pressure applied, resulting in the grain of matrix alloy refining. The X-ray diffraction pattern of composites testified that the matrix alloy exhibited a certain preferred orientation during solidification. In addition, with increasing the pressure for solidification, the pored defects in the composites decreased, while the relative density, hardness and compressive strength increased. Therefore, the microstructure and mechanical properties of the composites were improved by pressure placed during the solidification of SiCp/Al-Mg composites.     

Spark Effect on the Densification of SiCp/Al Composites by SPS

1 IntroductionSiCp/Al composites have aroused considerable inter-ests in manyfields of industry due to their tailorable me-chanical and thermophysical properties .SiCp/Al compos-ites have been developed mainly as structural materials inapplicationfor automobile industries and aerospace indus-tries . However ,thermal management applicationsin elec-tronic packaging,such as substrates ,heat slugs and heatspreads have been focused on. Electronic componentsused in thermal management applications …     

基于单颗磨粒划切试验的SiCp/Al复合材料表面去除机理研究

碳化硅颗粒增强铝基（SiCp/Al）复合材料中含有不规则碳化硅颗粒使得材料内部形成大量非理想截面,为材料表面的有效去除带来困难. 为了揭示材料去除机理,进行SiCp/Al 复合材料单颗磨粒变切深划切的表面去除仿真分析和试验验证. 研究结果表明,界面破坏对表面创成有重要影响,存在铝合金基体撕裂、界面分离,碳化硅颗粒裸露、裂纹扩展、破碎脱落、压入铝合金基体、碎片滑擦材料表面等去除过程,碳化硅颗粒中部大面积破碎脱落形成凹坑,并在刀具推挤作用下对材料进行二次切削,使铝合金基体表面形成非连续裂纹. SiCp/Al复合材料中由于铝合金基体的存在,实际划切深度小于名义切削深度. 研究可以为SiCp/Al复合材料去除机理与加工研究提供一定借鉴.     

Diffusion welding of SiCp/2014Al composites using Ni as interlayer

SiCp/2014Al composites were bonded with the vacuum diffusion welding technique using Ni as the interlayer metal. Ni and Al were interdiffused and there were intermetallic compounds formed in the inter transition layer, which was composed of Ni3Al//NiAl//NiAl3. The relation between the diffusion distance and the element concentration was calculated according to Fick＇s second law. The relations of the diffusion concentration and the diffusion welding technique parameters were calculated.     

Interface Stability of the SiC Particles/Fe Matrix Composite System

The interface reaction between the SiC particles （ SiCp ） and Fe was stndicd during sintering the SiCp reinforced Fe matrix composites at 1423 K for 1 h. In the composite having 3wt% （weight ratio） SiCp （the 3SiCp/ Fe composite）, the interface reaction products of Fe3 Si, the carbon precipitates, and Fe3 C or pearlite were generated. Fe3 Si coustructs the bright matrix of the reaction zone in the original situation of the SiCp. The carbon precipitates are randondy embedded in the reaction zone. Fe3 C or pearlite exists at the grain boundaries of the Fe matrix. As increasing the SiCp concentration in the SiCp/ Fe composite, the inteusity of the interface reaction between SiCp and Fe iacreases. After the 10SiCp/ Fe composite （ having 10wt .% SiCp ） sintered at 1423 K for 1 h, all of SiCp are decomposed, and replaced by the reaction zone composed of Fe3 Si and the carbon precipitates. No Fe3 C or pearlite was genertaed during the reaction. The effects of the techniques of oxidizing of SiCp , coating SiCp by interaction with the Cr powder, and alloying the Fe matrix by adding the Cr element on the interface stability of the SiCp/ Fe composite system were also investigated, respectitely. The oxide membrane and the coating layer on SiCp can inhibit the interface reaction between SiCp and Fe by isolating SiCp from the Fe matrix during sintering. The interface reaction does not occur in the 3 SiCp/ Fe- 10 Cr composite but in the 3 SiCp/ Fe-5 Cr composite. In the SiCp/ Fe-Cr alloy composites, the interface reaction between SiCp and the Fe- Cr alloys is weaker than that between SiCp and Fe . The Cr element behaves as a diluent, it causes a redaction in the interface reaction, which is proportional to the amount of the element added.     

Effect of Fiber Volume Fraction on Longitudinal Tensile Properties of SiC_f/Ti-6Al-4V Composites

The longitudinal tensile properties of SiC_f/Ti-6Al-4V composites with different fiber volume fractions were simulated by the Monte Carlo 2-D finite element model. The random distribution of fiber strength was expressed by the two-parameter Weibull function. Meanwhile, contact elements and birth-death elements were used to describe the interfacial sliding process after debonding and fiber breakage(or matrix cracking) respectively, which was realized by subroutine complied in ANSYS-APDL(ANSYS Parametric Design Language). The experimental results show that the yield stress and ultimate tensile strength of SiC_f/Ti-6Al-4V composites increase with increasing fiber volume fraction, while the corresponding strain of them is just on the contrary. In addition, almost the same failure mode is obtained in SiC_f/Ti-6Al-4V composites with various fiber volume fractions when the interfacial shear strength is fixed. Finally, the tensile strength predicted by finite element analysis is compared with that predicted by Global load-sharing model, Local load-sharing model and conventional rule of mixtures, thus drawing the conclusion that Local load-sharing model is very perfect for the prediction of the ultimate tensile strength.     

Microstructure and thermal properties of SiCp/Cu composites with Mo coating on SiC particles

SiCp/Cu composites with a compact microstructure were successfully fabricated by vacuum hot-pressing method. In order to suppress the detrimental interfacial reactions and ameliorate the interfacial bonding between copper and silicon carbide, molybdenum coating was deposited on the surface of silicon carbide by magnetron sputtering method and crystallized heat-treatment. The effects of the interfacial design on the thermo-physical properties of Si Cp/Cu composites were studied in detail. Thermal conductivity and expansion test results showed that silicon carbide particles coated with uniform and compact molybdenum coating have improved the comprehensive thermal properties of the Si Cp/Cu composites. Furthermore, the adhesion of the interface between silicon carbide and copper was significantly strengthened after molybdenum coating. Si Cp/Cu composites with a maximum thermal conductivity of 274.056 W/(m·K) and a coefficient of thermal expansion of 9 ppm/K were successfully prepared when the volume of silicon carbide was about 50%, and these Si Cp/Cu composites have potential applications for the electronic packageing of the high integration electronic devices.     

SiCp／Al复合材料无压自浸透工艺

研究了用Ｋ２ＺｒＦ６作为助浸剂与ＳｉＣｐ进行混合的工艺，实现用无压自浸透的工艺制造ＳｉＣｐ／Ａｌ复合材料。结果表明，直接混合工艺比Ｋ２ＺｒＦ６水处理工艺简便，并易于控制Ｋ２ＺｒＦ６的用量，Ｋ２ＺｒＦ６与ＳｉＣ混合后，能明显提高ＳｉＣ颗粒和Ａｌ液的湿润性。     

Effect of fiber volume fraction on longitudinal tensile properties of SiC<Subscript>f</Subscript>/Ti-6Al-4V composites

The longitudinal tensile properties of SiC_f/Ti-6Al-4V composites with different fiber volume fractions were simulated by the Monte Carlo 2-D finite element model. The random distribution of fiber strength was expressed by the two-parameter Weibull function. Meanwhile, contact elements and birth-death elements were used to describe the interfacial sliding process after debonding and fiber breakage (or matrix cracking) respectively, which was realized by subroutine complied in ANSYS-APDL (ANSYS Parametric Design Language). The experimental results show that the yield stress and ultimate tensile strength of SiC_f/Ti-6Al-4V composites increase with increasing fiber volume fraction, while the corresponding strain of them is just on the contrary. In addition, almost the same failure mode is obtained in SiC_f/Ti-6Al-4V composites with various fiber volume fractions when the interfacial shear strength is fixed. Finally, the tensile strength predicted by finite element analysis is compared with that predicted by Global load-sharing model, Local load-sharing model and conventional rule of mixtures, thus drawing the conclusion that Local load-sharing model is very perfect for the prediction of the ultimate tensile strength.     

凝固偏析对氧化铝/铝-铜合金复合材料性能的影响

利用挤压铸造技术制备氧化铝／铝-铜合金复合材料，研究了凝固偏析对复合材料机械性能的影响．结果表明：复合材料在凝固过程中由于选择结晶，基体中的溶质元素偏聚在纤维／基体界面或晶界上；纤维加速了复合材料的时效强化过程，随着纤维体积分数的增加，复合材料的硬度、强度、弹性模量增大，而塑性下降；随着预制件预热温度的升高，冷却速度减慢，凝固偏析加剧，复合材料的机械性能下降．     

Effects of Matrix on Tensile Strength of SiCw/Al Composites

ＥｆｆｅｃｔｓｏｆＭａｔｒｉｘｏｎＴｅｎｓｉｌｅＳｔｒｅｎｇｔｈｏｆＳｉＣｗ／ＡｌＣｏｍｐｏｓｉｔｅｓ￥（耿林）（王德尊）（姚忠凯）ＧＥＮＧＬｉｎ；ＷＡＮＧＤｅｚｕｎ；ＹＡＯＺｈｏｎｇｋａｉ（Ｄｅｔｐ．ｏｆＭａｔｅｒｉａｌＳｃｉｅｎｃｅａｎｄＥｎｇｉ...     

纳米颗粒弥散强化铜基复合材料的显微组织与性能

采用粉末冶金的方法,以Al2O3,SiO2,SiC和MgO等纳米颗粒为增强相,制备出4种不同颗粒的纳米复合材料,研究了各增强相对复合材料显微组织与性能的影响.结果表明:在相同的质量分数(ω)和制备工艺下,不同弥散相颗粒的弥散强化铜合金显微组织不同,铜基体上大体均匀地分布着细小的弥散相颗粒,但部分区域仍存在偏聚现象.4种复合材料的电导率相近,抗拉强度方面Cu/Al2O3与Cu/SiO2的性能要略好于Cu/SiC与Cu/MgO.     

Mechanical Properties of Phenolic-Resin Composites Reinforced with CF/BF Interlayer Hybrid Fibers

Phenolic-resin composites reinforced with carbon fiber (CF) and basalt fiber (BF) interlayer hybrid fibers plain fabric were fabricated. The tensile strength, compressive strength and interlaminar shear strength of the prepared composites were studied. The results indicated that hybrid fibers reinforced composites possessed the advantages of both CF and BF. When resin content was 35% by volume fraction, the comprehensive mechanical performance of BF/CF reinforced phenolic resin composites reached the optimal values with the warp and weft direction tensile strength, compressive strength and interlayer shear strength being 252 MPa and 487 MPa, 105 MPa and 129 MPa, 21 MPa and 20 MPa, respectively. The scanning electron microscope (SEM) observations showed that the BF/CF hybrid fibers reinforced composites had better interfacial adhesion.     

多尺度方法预测复合材料层板裂纹扩展

为了研究复合材料层板在细观和宏观尺度上的损伤分布,文中基于高精度通用单胞细观力学模型,发展了一种多尺度分析方法．该方法只需纤维和基体的材料属性、强度参数及纤维体积含量,而无需复合材料层合板的弹性参数和强度参数．文中使用该方法分析了复合材料结构的宏细观上的应力应变场;结合多尺度损伤模型,研究了复合材料的细观损伤以及宏观的裂纹扩展;通过二次开发ANSYS／LS-DYNA软件,文中将高精度通用单胞细观力学模型编译到用户自定义材料子程序中;使用这种方法分析了开孔层板轴向拉伸条件下的各个分层的应力分布、组分失效模式和裂纹扩展．并将计算结果与实验结果对比,结果表明: 数值模拟随时间变化的应力曲线与实验所得的曲线能较好的吻合; 预测的裂纹扩展与实验结果比较吻合．