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1.
The rheological properties of chestnut flour (CF) doughs incorporated with agar, hydroxypropylmethyl cellulose (HPMC) and xanthan at different concentrations (0.5, 1.0, 1.5, 2.0%, flour basis) were determined at 30 °C using a controlled stress rheometer. The mixing behavior at the same temperature was achieved by the Mixolab® apparatus. The tests conducted in the rheometer were shear (0.01–10 s−1), oscillatory (1–100 rad s−1 at 0.1% strain), creep-recovery (loading of 50 Pa for 60 s) and temperature sweep (30–100 °C) measurements. These rheological properties were significantly modified by the type and content of gelling agent added. The values of apparent viscosity in all tested shear rate range as well as the values of storage (G′) and loss (G″) moduli of CF doughs in the tested angular frequency decreased with increasing agar and HPMC concentration and increased with xanthan addition. Flow curves and storage and loss moduli of assayed doughs were satisfactorily fitted using Cross model and a potential model, respectively. The initial gelatinization temperature decreased with agar and increased with xanthan as well as the gelatinization temperatures range with HPMC addition was shorter. This pasting trend was also noticed using Mixolab®. Creep-recovery data, successfully fitted using Burgers model, showed that elasticity of doughs improved significantly with HPMC and xanthan addition.  相似文献   

2.
The influence of the addition of NaCl (0.6, 1.2, 1.8%, w/w), sucrose (0.6, 1.8, 3.4, 5.0%, w/w), chestnut starch (5.0, 10.0, 15.0%, w/w) and NaCl–sucrose mixtures (0.6–0.6, 1.8–1.8%, w/w) on the rheological properties of chestnut flour (CF) doughs were studied using a controlled-stress rheometer. Mixing and complete tests were achieved by the Mixolab® apparatus. Shear (0.01–10 s−1), oscillation (1–100 rad s−1), temperature sweep (30–100 °C) and creep-recovery (loading of 50 Pa) measurements were performed. Steady-flow curves exhibited a Newtonian plateau at <0.1 s−1 that was shifted to lower shear rates with the additives. Apparent viscosities were satisfactorily fitted using Cross model. Moduli values of storage and loss decreased, at constant angular frequency, with increasing additives. Gelatinization temperatures were slightly modified. Creep-recovery data, fitted using Burgers model, showed that the elasticity was low (23.0%) and doughs with chestnut starch presented the highest recoverable proportion (45.6%).  相似文献   

3.
Droplet characteristics, flow properties and stability of egg yolk-stabilized oil-in-water (O/W) emulsions as affected by the presence of xanthan gum (XG), carboxymethyl cellulose (CMC), guar gum (GG), locust bean gum (LBG) and gum Arabic (AG) were studied. The dispersed phase (40%) of the emulsions was based on soybean oil/palm kernel olein blend (70:30) that partially crystallized during extended storage at 5 °C. In freshly prepared emulsions, the presence of XG, CMC, GG and LBG had significantly decreased the droplet mean diameters. XG, LBG, GG and CMC emulsions exhibited a shear-thinning behavior but AG emulsion exhibited a Bingham plastic behavior and control (without gum) emulsion almost exhibited a Newtonian behavior. Both control and AG emulsions exhibited a severe phase separation after storage (30 days, 5 °C). The microstructure of stored XG emulsion showed the presence of partially coalesced droplets, explaining a large increase in its droplet mean diameters. Increases in droplet mean diameters and decreases in flow properties found for stored GG and LBG emulsions were attributed to droplet coalescence. Nevertheless, the occurrence of droplet coalescence in these emulsions was considered to be small as no free oil could be separated under centrifugation force. Increases in flow properties and excellent stability towards phase separation found for stored CMC emulsion suggested that CMC could retard partial coalescence. Thus, the results support the ability of CMC, GG and LBG in reducing partial coalescence either by providing a sufficiently thick continuous phase or by acting as a protective coating for oil droplets.  相似文献   

4.
Thermo-rheological behaviour of chestnut flour doughs supplemented with kappa/iota-hybrid carrageenan (HC) (up to 2.0%, flour basis (f.b.)) and sodium chloride (1.8%, f.b.) was determined at both target (C1) and final (C5) mixing peaks. For this purpose, small amplitude oscillatory shear (0.01 to 100 Hz), creep–recovery (loading of 50 Pa for 60 s, 30 °C), temperature sweeps (from 30 up to 180 °C) and heating/cooling cycles (between 30 and 60 °C) were conducted on a controlled stress rheometer. Previously, the thermal-mixing behaviour at proposed mixing temperature (50 °C) was conducted on Mixolab® apparatus. Results showed that the dough stability (from 2.2 to 5.8 min) in mixing stage and starch heat resistance to dough processing were significantly improved at proposed mixing temperature, even in the absence of HC. No statistical differences in rheological properties were observed for doughs evaluated in C1; however, those analysed in C5 were significantly modified in the presence of HC, mainly in terms of viscous behaviour (from 52.1 × 106 to 39.1 × 106 Pa s). Creep–recovery data sets, successfully fitted using Burgers model, revealed that the elasticity (J r/J max from 73.3 to 87.6%) of doughs analysed in C5 improved with HC addition. Thermal tests showed that the starch transitions were significantly promoted and stabilized with HC addition.  相似文献   

5.
BACKGROUND: The objective of this study was to develop a low‐fat (LF) mayonnaise containing polysaccharide gums as functional ingredients. Xanthan gum (XG, 15 g kg?1), citrus fiber (CF, 100 g kg?1) and variable concentration of guar gum (GG) were used to formulate the optimum ratios of polysaccharide gums as fat replacers. The fat content in LF mayonnaise was reduced to 50% if compared with full‐fat (FF) mayonnaise, and the products still maintained ideal rheological properties. RESULTS: The rheological parameters showed that there were no (P > 0.05) differences in yield stress, viscosity and flow behavior index between XG + 10 g kg?1 GG, CF + 5 g kg?1 GG and FF control. LF mayonnaises had lower caloric values and higher dietary fiber content than the FF counterpart. Scanning electron microscopy (SEM) micrographs illustrated that the network of aggregated droplets in LF treatments contained a large number of interspaced voids of varying dimensions. Furthermore, in a comparison of sensory evaluation of LF treatments with commercial and our FF mayonnaises, there were no (P > 0.05) differences in any sensory scores among XG + 10 g kg?1 GG control. CONCLUSION: This study shows that XG + 10 g kg?1 GG and CF + 5 g kg?1 GG could be used in LF mayonnaise formulations based on its multiple functions on processing properties. Copyright © 2010 Society of Chemical Industry  相似文献   

6.
Nowadays, the use of natural compounds is considered as an effective strategy for maintaining the quality and heath promoting capacity of fresh products. Changes in quality parameters, main phenolics and antioxidants of sweet cherries in response to coating with a novel bioactive edible coating were studied. Fruit were treated with different concentrations of galbanum gum (GG), cumin essential oil (CEO) and CaCl2 (CA) and stored at 2 ± 1°C with 90–95% RH for 30 days plus 1 day at ambient condition, and were subjected to quality analysis. All phenolic constituents and antioxidants of fruit juice were substantially decreased during storage in control fruit and a bioactive coating containing 1 or 2% GG + 100 or 200 µL L−1 CEO + 1% CA maintained main fruit phytochemicals including phenolics, phenolic acids, flavonols, anti-stress and antioxidant enzymes activities. The coating significantly (P ≤ 0.01) enhanced fruit total antioxidant activity, flavonoids and ferulic acid contents. The results showed that it is possible to enhance the sweet cherry fruit health-promoting phytochemicals and shelf life by the use of a natural edible coating containing GG and CEO.  相似文献   

7.
Pekmez, known also as grape molasses, was spray dried in the laboratory-type pilot drying unit to obtain pekmez powder. The flow characteristics of diluted pekmez powder (DPP), wheat starch (WS), and some hydrocolloids (locust bean gum, LBG; gum tragacanth, GT, and guar gum, GG) systems in double- or triple-mixed combinations were studied. The empirical power law model fitted the apparent viscosity-rotational speed data. DPP-gum and WS-gum mixed solutions exhibited a shear-thinning behaviour at 21°C with flow behaviour index (n) values of 0.88 ≤ n ≤ 0.94 and 0.17 ≤ n ≤ 0.32, respectively. WS-gum mixed solutions showed high shear-thinning behaviour with the highest consistency index (k = 49.93–214.24 Pa sn). However, DPP-WS and DPP-WS-gum mixed solutions at the same temperature exhibited the shear-thickening behaviour with flow behaviour index (n) values of 1.02 ≤ n ≤ 1.07.  相似文献   

8.
选取两种分子质量相近、黏度相差较大的天然高分子多糖阿拉伯胶(arabic gum,AG)和瓜尔胶(guar gum,GG)分别与肌原纤维蛋白(myofibrillarprotein,MP)进行复合,研究不同多糖添加量(0.1%~0.5%)对MP-多糖复合物乳液性质的影响规律。结果表明,AG和GG均可以显著改善MP的乳化性质,其中AG对乳化活性的改善效果较好,而GG更有利于乳液的稳定性。随着多糖质量分数增加,乳化活性指数和稳定性指数均呈先升高后降低趋势,AG和GG添加量分别为0.3%和0.2%时,乳化活性指数和稳定性指数达到最大值。界面蛋白含量测定结果显示,AG和GG均会导致界面蛋白含量下降,尤其是GG的作用更明显。随着AG和GG添加量增加,乳液粒径逐渐减小,且尺寸分布更加均一,添加量超过0.3%后,GG组乳液出现少量絮凝现象。同一添加量下,GG组乳液粒径明显小于AG组。流变学分析证实,所有乳液均为假塑性流体,表现出弱凝胶性质。AG添加量较少(≤0.3%)时会降低乳液黏度,并明显提高乳液的储能模量,而GG的添加使乳液表观黏度和储能模量均显著提高,与AG相比,高黏度GG制备的乳液拥有更高的...  相似文献   

9.
Dietary fiber incorporation into bread dough systems greatly interferes with protein association and behavior during heating and cooling. The objective of this study was to understand the individual and combined effects of dietary fibers on dough behavior during mixing, overmixing, pasting and gelling using the Mixolab® device. Impact of different commercial dietary fibers (inulin, sugar beet fiber, pea cell wall fiber and pea hull fiber) on wheat dough mixing, pasting and gelling profiles has been investigated. Mixolab® plots indicate that the incorporation of sugar beet fiber into the dough matrix induces the disruption of the viscoelastic system yielding weaker doughs, and it greatly competes for water with starch affecting pasting and gelling. Conversely, inulin in the range tested seems to integrate into the dough increasing its stability. Additionally, the responses acquired with this device were compared with those obtained with other available methodologies, such as the Brabender Farinograph and the Rapid Visco Analyser, to explore its use as a suitable technique for studying fiber-enriched bread dough physical properties. A broad range of correlation between Mixolab® and traditional devices were found.  相似文献   

10.
Dynamic rheological and mechanical properties of seven commercial (xanthan [XG], guar [GG], high methoxylated pectin [HMP], κ‐carrageenan [κ‐Car], agar [AG], alginate [ALG], and carboxymethylcellulose [CMC]) and four emerging hydrocolloids (basil seed gum [BSG], sage seed gum [SSG], Balangu‐Shirazi seed gum [BSSG], and cress seed gum [CSG]) were investigated and the classification of the hydrocolloids were carried out based on them. AG belonged to the first class with 0.81 membership function (MF), κ‐Car and HMP grouped in the second class with 0.68 and 0.71 MFs, respectively, XG, BSG, and SSG were depended to the third class with 0.61–0.70 MFs, finally, CMC, GG, BSSG, ALG, and CSG related to the fourth class, as the most populated class, with MF > 0.61. The first class contained the highest amount of hardness parameter (43.40 ± 2.76 g), the second class included the highest pseudoplasticity parameter (shear‐thinning ratio = ?0.54 ± 0.03) and relaxation time (66.25 ± 2.61 s) and the fourth cluster comprised the highest frequency dependency of viscous modulus (exponent of power‐law model for viscous modulus vs. frequency = 0.30 ± 0.05). In addition, the results of this study showed that there was a distinct relationship between nonlinear harmonics in the stress wave and fundamental characteristics of hydrogel networks. The investigation of the rheo‐mechanical properties of biopolymers in large deformation under shear and normal forces can have an important role in the prediction of the behavior of the material in real processes and application conditions, especially in the food industry. Due to the inconvenience of large deformation mechanical tests, such as Weissenberg effect, the complication of the results analyzing and sampling difficulty of semi‐dilute samples; herein, we determined the correlation between large deformation (LAOS and texture analysis) and small deformation (SAOS) tests properties. The studied rheo‐mechanical parameters showed high correlation with the four mentioned network parameters (more than 65% similarity index). Using these results, other scientists could rationally design the experiments and avoid experiments with similar parameters.  相似文献   

11.
BACKGROUND: Lallemantia royleana (Balangu) is a mucilaginous endemic plant which is grown in different regions of world. The flow behaviour of Balangu seed extract (BSE) and its mixture with xanthan, guar and locust bean gums at 1:3, 1:1 and 3:1 ratios, in addition to control samples (0% BSE), were evaluated. To describe the rheological properties of samples, the power law model was fitted on apparent viscosity–shear rate data. To evaluate the interaction between BSE and selected hydrocolloids in dilute solutions, the relative viscosity was also investigated. RESULTS: There was no significant difference between the consistency coefficient of guar and locust bean solutions and their blends substituted with 250 g kg?1 BSE. The BSE–xanthan mixture at 1:3 and 1:1 ratios had consistency index equal to xanthan solution. BSE–locust bean gum at all ratios, BSE–xanthan at 1:3 ratio and BSE–guar gum at 1:1 and 3:1 ratios indicated relative viscosity lower than values calculated assuming no interaction. The intrinsic viscosity value of BSE was determined 3.50 dL g?1. CONCLUSION: The apparent viscosities of BSE, selected hydrocolloids and their blends were the same at a shear rate of 293 s?1 and the commercial gums can be substituted by 250 g kg?1 and 500 g kg?1 BSE. Copyright © 2011 Society of Chemical Industry  相似文献   

12.
We report the optimization of oleogel formulation based on sodium caseinate (CN, 0–4 g/100 g), xanthan gum (XG, 0–1 g/100 g), guar gum (GG, 0–1 g/100 g), and drying method (freeze and oven drier) using response surface methodology to achieve the desired oil binding capacity, textural, and rheological attributes. All the selected responses were successfully fitted by a quadratic model with determination coefficient values higher than .95 with the exception of firmness values which was fitted by linear model. There were considerable increases in all the responses for the samples containing ternary mixtures of protein-gum (CN:XG:GG) as well as binary mixtures (CN:GG and CN:XG) compared to samples containing protein or gums alone due to the synergistic effect of CN and gums on formation of highly ordered and strong gel network. Regression modeling demonstrated that freeze drying method led to significantly greater structure recovery values than those of oven drying method. The best formulation was the freeze dried oleogel containing 4 g/100 g CN, 0.43 g/100 g XG, and 0.98 g/100 g GG. Results showed that fabrication of oleogels with at least 94.5 g/100 g sunflower oil and characteristics similar to industrial shortening is feasible.  相似文献   

13.
The rheological properties of chestnut flour (CF) doughs with different particle size were studied using a controlled stress rheometer. The mixing curves and heating–cooling cycle responses were previously obtained from the Mixolab® apparatus. Shear measurements (0.1–10 s−1), oscillation measurements (1–100 rad s−1 at 0.1% strain), temperature sweep (30–100 °C) to achieve the gelatinization temperatures and creep-recovery tests (loading of 50 Pa for 60 s) were conducted in the rheometer. Mixolab® showed that CF samples with smaller particle size needed more water absorption to reach a consistency of 1.1 Nm. Shear viscosities of CF doughs exhibited a Newtonian plateau at low shear rate and shear thinning behaviour at higher shear rate. Apparent viscosity increased with increasing average particle size and steady-flow curves were fitted using Cross model. Oscillatory measurements of CF dough showed that the storage modulus, G′, was greater than loss modulus, G″, for all samples in the tested angular frequency range. CF samples with smaller particle size presented lower G′ and G″ values. Creep-recovery tests of these flours showed that elasticity was limited and unrecoverable proportion was very high. Gelatinization temperatures measured using Mixolab® and rheometer were practically coincident.  相似文献   

14.
Gluten-free flours blends using chestnut flour (CF) and rice flour (RF) were assayed in order to determine mixing and rheological properties of doughs at 30 °C as well as the thermal behaviour employing heating–cooling temperature steps. CF with different mean particle size (commercial, CCF: 169 μm and low particle size, CF1: 77 μm samples) was employed and blended with RF (46 μm) at several ratios (%) (CCF/RF: 90/10, 80/20, 70/30, 60/40, 50/50; CF1/RF: 25/75, 15/85, 5/95). Doughs from CCF, CF1 and RF flours were employed as reference systems. The rheological characterization of doughs conducted on the rheometer was performed by shear, oscillatory and creep-recovery assays. Rheological properties were significantly modified by flour ratio and by CF particle size. Creep-recovery curves showed that CCF/RF (70/30) and CF1/RF (25/75) improved the doughs elasticity by 41.1 % and 87.5 % compared with CCF and CF1, respectively. Cross, power and Burgers models were used to describe the flow curves, mechanical spectra and creep-recovery behaviour, respectively, of doughs. A mixing rule successfully reproduced the experimental data and fitting parameters of applied models as function of each flour fraction in the blends, except for oscillatory data.  相似文献   

15.
In this study, rheological properties of several food hydrocolloids (carrageenan, pectin, gelatin, starch and xanthan) were evaluated using a rotational viscometer at three concentrations (1–6%, depending on the type of hydrocolloid) and four temperatures (20, 40, 60 and 80°C). Samples were subjected to a programmed shear rate increasing linearly from 0 to 300 s−1 in 3 min, followed by a steady shear at 300 s−1 for 10 min and finally a linearly decreasing shear rate from 300 s−1 to 0 in 3 min. Experiments were performed in duplicate. In general, the power law model fitted most of the experimental results. Xanthan gum and carrageenan (at 20oC) were exceptions, characterized by a yield stress and hence the rheograms were fitted with the Herschel-Bulkley model. Furthermore, gelatin showed a Newtonian behavior. Three models (power, exponential and polynomial) were used to evaluate the concentration effect on apparent viscosity. Arrhenius model was used to describe the temperature effect. Among the samples, carrageenan showed the most temperature dependency and xanthan gum, the least.  相似文献   

16.
Abstract: The performance of several hydrocolloids (3 gum acacias, 1 modified gum acacia, and 3 modified starches) in stabilizing beverage emulsions and corresponding model beverages was investigated employing different core materials, emulsifier usage levels, and storage temperatures. Concentrated emulsions were prepared using orange terpenes or Miglyol® 812 (comprising medium-chain triglycerides, MCT) weighted 1:1 with ester gum, stored at 25 or 35 °C, and analyzed on days 0, 1, and 3. On day 3, model beverages were made from each emulsion, stored at both temperatures, and analyzed weekly for 4 wk. Stability of concentrated emulsions was assessed by measuring mean particle size and by visual observations of ringing; beverage stability was judged similarly and also by loss of turbidity. Particle size measurements showed concentrated emulsions containing gum acacia or modified gum acacia with either core material were stable over 3 d storage at both temperatures whereas those made with modified starches were not, destabilization being faster at 35 °C. Beverages based on orange terpenes, in contrast to Miglyol, yielded smaller mean particle sizes, both on manufacture and during storage, regardless of hydrocolloid used. Visual observations of ringing generally supported this finding. Modified gum acacia was evaluated at both recommended and higher usage levels, stability increasing in the latter case. In general, all gum acacia and modified gum acacia emulsifiers were superior in stability to those based on modified starches, at either temperature, for orange terpene-based beverages. In Miglyol-based beverages, similar results were seen, except 1 modified starch performed as well as the gum acacia products.  相似文献   

17.
Incorporation in pasta of either of two soluble fibres, carboxymethylcellulose sodium salt (CMC) and guar gum (GG), was found to significantly reduce the rate of invitro starch digestion. The amount of reducing sugars produced over 300 min was reduced by 18% at 1.5% CMC incorporation and 24% at 20% GG incorporation. Negative effects on sensory and technological properties were seen at the high levels of GG needed to reduce the rate of in vitro digestion, and a ‘matty’ layer covering the surfaces of starch granules was observed by scanning electron microscopy and confocal scanning laser microscopy. By contrast, levels of CMC incorporation giving large reductions in in vitro digestion had no negative effects on pasta properties. No significant alteration in pasta structure on CMC incorporation was observed by microscopy. The large difference in the amounts of soluble fibre required to bring about equivalent reductions in digestion rate suggests that different mechanisms may be involved in the two cases.  相似文献   

18.
The viscosity of diluted guar gum solutions and the viscosity of xanthan and guar gum mixture solutions have been studied. Guar gum solutions showed pseudoplastic behaviour. Apparent viscosity increased with gum concentration and decreased with the temperature at which viscosity was measured. A maximum in the plot of viscosity versus increasing dissolution temperature was observed at 60 °C. This behaviour was related to differences in molecular structure of the polymers solved at different temperatures. Mixtures of xanthan and guar gum showed a higher combined viscosity than that occurring in each separate gum. This synergistic interaction was affected by the gum ratio in the mixture and dissolution temperature of both gums. The effect of polysaccharide concentration (1.0, 1.5 and 2.0 kg m−3), xanthan/guar gum ratio (1/5, 4/2, 3/3, 4/2 and 5/1) and dissolution temperature (25, 40, 60 and 80 °C for both gums) on the viscosity of solutions of mixtures were studied. The highest viscosities were observed when 2.0 kg m−3 gum concentration was used together with a ratio of xanthan/guar gum of 3/3 (w/w) and dissolution temperature of 40 and 80 °C for xanthan and guar gum, respectively. © 2000 Society of Chemical Industry  相似文献   

19.
The extractability of oat gum from oat bran and rolled oats was studied using 12 treatment combinations in a factorial design (2x3x4x2) i.e. 2 oat products; 3 pH (8.0–10.5); 4 temperatures (5O–70°C); 2 replications. The extraction procedure involved: (a) alkaline treatment of flour and removal of starch residue; (b) isoelectric precipitation of protein residue [namely, protein concentrates (PC)]; (c) and alcohol precipitation of oat gum/β-glucan and collection of gum by centrifu-gation. Extracted oat gum ranged from 2.99–6.28% for oat bran and 1.82–5.24% for rollcd oats whereas β-glucan (in gum) ranged from 70–89% and 50–68%, respectively. Protein contents of the PC from oat bran was 69–91% and rolled oats 66–89%. Correspondingly, starch content of residues ranged from 30–63% and 61–47%. Oat gum/β-glucan extracted at pH 9.2/50°C or pH 10.5/50/55°C showed little or no starch contamination.  相似文献   

20.
The flow properties of the fluid portion of fruit fillings were assessed to investigate the effects of gums. Results indicated that the shear rate–shear stress relations of the fluid portion of commercial fruit fillings and the model fillings made of waxy corn starch, fructose, citrate buffer, and a gum which could be guar gum, locust bean gum, CMC, xanthan gum or κ-carrageenan, fit well into the Herschel–Bulkley equation for pseudoplastic fluids. The fluid portion of the commercial fruit fillings was characterized with a yield stress between 39–51 Pa, a consistency index between 52–104 Pa·sn, and a flow index (n) around 0.4. In addition, the shear rate–shear stress relations could be fitted into a modified Herschel–Bulkley equation with a flow index fixed at 0.4. Addition of guar gum, locust bean gum and CMC increased while xanthan gum and κ-carrageenan decreased the consistency and flow indices in the modified Herschel–Bulkley equation. The effect of gum addition on the apparent viscosity of model fillings varies with the type of gum, amount of addition, and shear rate.  相似文献   

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