机制砂粉煤灰混凝土中钢筋锚固性能试验研究

通过拉拔试验研究了机制砂粉煤灰混凝土中热轧带肋钢筋和高强预应力钢绞线的粘结锚固性能,结果表明:水胶比、粉煤灰替代水泥率和超量系数等因素对钢筋和钢绞线在机制砂粉煤灰混凝土中的粘结锚固强度的影响规律,与机制砂粉煤灰混凝土轴心抗拉强度的影响规律是一致的,其粘结锚固强度取决于机制砂粉煤灰混凝土轴心抗拉强度的高低。通过分析粘结锚固强度与轴心抗拉强度之间的关系,提出了机制砂粉煤灰混凝土中热轧带肋钢筋和高强预应力钢绞线的锚固长度计算建议。     

人工砂粉煤灰混凝土试验研究和配合比设计

选择不同的水灰比、粉煤灰取代水泥率和超量系数,对人工砂粉煤灰混凝土进行了配合比试验研究。基于试验结果分析,提出一种易行的人工砂粉煤灰混凝土的配合比设计方法。     

高强轻集料混凝土力学性能试验研究

本文采用页岩陶粒，掺入粉煤灰和高效减水剂配制高强轻集科混凝土，试验研究水胶比、砂率和粉煤灰取代率对轻集科混凝土力学性能和表观密度的影响，并得出了一个合理的轻集料混凝土配合比。结果表明：轻集料混凝土强度与水胶比成反比；而对于砂率和粉煤灰取代率，存在一个最优的砂率和粉煤灰取代率。     

无砂大孔粉煤灰陶粒混凝土

通过对无砂大孔粉煤灰陶粒混凝土的试验研究 ,阐明用粉煤灰陶粒、水泥和外加剂 ,可以配制出轻质高强新型轻骨料混凝土。其技术性能符合结构保温轻骨料混凝土指标要求     

新旧标准砂粉煤灰需水量比对比试验

参照GB/T18736—2002《高强高性能混凝土用矿物外加剂》中关于磨细粉煤灰胶砂需水量比的试验方法,组织有代表性的粉煤灰样品,进行了新旧标准砂粉煤灰需水量比对比试验。结果表明,用IS0砂法代替旧标准砂法是可行的。     

矿物掺合料对高强混凝土配制的影响

本文总结了分别使用磨细沸石粉，硅灰和粉煤灰作为矿物掺合料配制高强混凝土的试验结果，分析了这些矿物掺合料对高强混凝土的强度和流动性的影响及适宜的用量范围，本文还介绍了C60泵送粉煤灰高强混凝土在北京航华大厦工程中的使用情况，并总结了混凝土的只要性能以及冬季施工时防冻剂对高强混凝土的影响。     

高强轻骨料混凝土拌合物性能及影响因素试验研究

采用粉煤灰等量取代水泥以及轻质砂代替普通砂,制备了高强轻骨料混凝土.通过试验研究了轻骨料吸水特性,颗粒类型和粒径,砂的细度模数,粉煤灰等级等因素对混凝土拌合物性能的影响,并且利用工业CT分析了骨料内部孔隙.结果表明,页岩陶粒充分预湿以后,轻骨料混凝土具有良好的流动性且经时损失小;圆球型陶粒混凝土相比于碎石型陶粒混凝土的拌合物性能更好,同时,粒径偏大的陶粒容易出现上浮现象.掺入超细粉煤灰的轻骨料混凝土拌合物性能有较大改善,掺入Ⅰ级粉煤灰试样的工作性相差不大,掺入Ⅱ级粉煤灰的试样的工作性有所降低;从拌合物性能优化的角度考虑,细度模数为2.4 ～2.8的砂较适合作为轻骨料混凝土用砂,且用轻质砂代替普通砂可使轻骨料混凝土容重大幅度降低.     

粉煤灰对人工砂高性能混凝土性能的影响

研究了粉煤灰对人工砂高性能混凝土和易性和抗压强度的影响。试验表明:掺加一定量优质粉煤灰,能显著改善人工砂高性能混凝土拌合物的和易性、降低泌水;水泥用量相同时,大掺灰量人工砂混凝土28d强度较高;胶凝材料用量相同,大掺灰量混凝土用水量少、水胶比低,其强度与水泥用量大、掺灰少的混凝土基本相同。     

大掺量粉煤灰混凝土氯离子渗透试验分析

砂率分别为40%、45%、50%;粉煤灰分别取代水泥0、30%、40%、50%、60%,组成15组C30混凝土配合比。然后进行氯离子渗透试验,比较C30混凝土在不同的砂率和粉煤灰掺量时的氯离子渗透性。试验表明,在砂率45%、粉煤灰掺量40%时,C30混凝土的氯离子渗透系数最小,抗渗透性最好。     

粉煤灰及沙漠砂对混凝土抗碳化性能的影响

通过进行单掺粉煤灰、单掺沙漠砂、双掺粉煤灰和沙漠砂混凝土3d、7d、14d、28d和56d抗碳化性能试验,分析了粉煤灰掺量和沙漠砂替代率对混凝土抗碳化性能的影响,建立了混凝土28 d碳化深度与粉煤灰掺量及沙漠砂替代率之间回归关系模型.试验结果表明:对于单掺粉煤灰混凝土,随着粉煤灰掺量增加,混凝土碳化深度逐渐增大,且碳化早期比后期增长较快;对于单掺沙漠砂混凝土,随着沙漠砂替代率增加,混凝土碳化深度呈先减小后增大趋势,沙漠砂替代率20%时混凝土碳化深度最小;对于双掺粉煤灰和沙漠砂混凝土,粉煤灰掺量10%,沙漠砂替代率20%时混凝土碳化深度最小.     

乙苯,苯乙烯的生产及合成乙苯,苯乙烯催化剂的研究进展

苯乙烯是重要的石油化工原料。本文介绍了国内外苯乙烯生产的发展概况，合成乙苯，苯乙烯所用的催化剂种类，并就苯乙烯生产及催化剂的发展趋势提出了自己的观点。     

Synthesis and characterization of homopolymers and copolymers of various acrylates and acrylonitrile

Various homopolymers and copolymers of methyl acrylate, ethyl acrylate, butyl acrylate, and acrylonitrile in different feed ratios were synthesized. These were characterized by IR, ¹³C-NMR, DSC, DTA, and TGA. Spectroscopic characterization helped in differentiating copolymers of different mol ratios. Thermal analysis revealed different degradation patterns for homopolymers and copolymers. The temperature and energy changes associated with various phase transitions were dependent on the chemical composition of homo- and copolymers, as expected. © 1993 John Wiley & Sons, Inc.     

生物质气化及生物质与煤共气化技术的研发与应用

总结了生物质原料的特点及生物质单独气化的缺点;介绍了国内外生物质气化技术及生物质与煤共气化技术的研发与应用现状;分析了在此领域国内外的发展趋势与前景;概括了开展生物质与煤共气化技术研发的意义。     

Comparison of the Adhesion and Cohesion of Triblock and Random Copolymers of Styrene and Butadiene

A substantially greater detachment energy is required to strip a polyethylene tereph-thalate (Mylar) film from a styrene-butadiene-styrene (SBS) triblock copolymer compared to that for peeling from a random styrene-butadiene (SBR) copolymer. This is true even though the intrinsic interaction between the Mylar and each elastomer is expected to be similar because of their virtually identical chemical composition. It is proposed that this difference in peel strength (between the SBS and SBR) is a consequence of the much higher dissipative capacity of the former elastomer. Another manifestation of this is the higher cohesive tear strength of the SBS compared to the SBR. Extents of energy dissipation within each elastomer during detachment of the Mylar adherend are consistent with the hypothesis that the average maximum stress experience before detachment is some similar fraction of each elastomer's tensile strength.     

责任和责任心的涵义与结构

责任是人应主动承担的角色义务和对其因过失所造成后果应承担的责罚.有两层涵义:一是义务;二是后果.责任心是个体自觉做好分内事务和履行道德义务的心理倾向,是个性心理品质成分中自我特征维度上的重要内容.责任心具有两个方面的涵义:一是角色分内职责;二是角色道德义务.责任心是一种通过责任认知、责任个性和责任适应的动态形式表现出来的静态品质,责任心是责任心过程结构与责任心关系结构相互制约、相互影响的统一体.     

二甲基二烯丙基氯化铵和丙烯酰胺的合成及应用

用复合引发体系(过硫酸盐-偶氮类引发剂)和脂肪胺类氧化还原体系引发,在实验室获得了单体转化率≥98%,特性粘数高于13.6 dL/g的阳离子共聚物PDA,探讨了控制聚合物分子量的影响因素.     

Kinetics and Mechanism of Oxidation of Mono- and Polyacetals

Abstract

Kinetics and mechanisms of oxidation of 6 acetals by molecular oxygen and ozone in liquid phase have been studied. Reaction with molecular oxygen (70°C, 15–16 hr) leads to the formation monoethers of the corresponding glycols with 68–90% selectivity. Salts of metals and complexes with crown-ethers have increased the reaction rate significally. Ozone have reacted with acetals with formation similar products. The mechanisms of intermediate stages have been proposed.     

钾盐资源及钾肥供需情况分析及预测

阐述了国内外钾盐资源及钾肥生产现状,对国内外钾盐的供需形势进行了分析及预测,从资源、原材料、国际市场三方面提出了解决我国钾盐短缺的措施。     

Electronic structures and reactivities of monometallic and bimetallic clusters of Au and Cu

The variation of the Au 4f binding energy of Au clusters with the cluster size has been established by measuring the binding energies of clusters whose size distributions were independently determined by HREM and STM. The binding energy increases significantly when the cluster size is less than 2 nm. Au-Cu bimetallic clusters of the composition Cu₃Au have been deposited for the first time on carbon substrates. The shifts in the core level binding energies of the bimetallic clusters show the effect of alloying in the case of large clusters, but show effects of both alloying and cluster size in the case of the small clusters. The interaction of CO with Cu₃Au clusters is stronger than with a bulk Cu metal. The interaction of CO with small Cu clusters also seems to be stronger than with bulk Cu or with large Cu clusters.     

Wetting properties of homopolymers and copolymers of pentafluorostyrene and methylacrylate and homopolymer blends

Polypentafluorostyrene (PPFS), polymethylacrylate (PMA), and poly(pentafluorostyrene-co-methylacrylate), poly(PFS-co-MA) were prepared and the wetting characteristics of polymer blends of PPFS and PMA were compared with that of poly(PFS-co-MA) via contact angle measurements. The critical surface tension of polypentafluorostyrene was found to be 22.6 dyne/cm, which is comparable to the value reported for polytrifluoroethylene (22 dyne/cm). The critical surface tension of poly(PFS-co-MA) is not linearly related to its composition. The polymer blends of PPFS and PMA exhibit significant surface enrichment of the fluoropolymer. The harmonic-mean method¹ was employed to determine surface tensions of these polymers and many known polymers. It is found that the method produces useful surface tension data provided the contact angle values are derived from testing liquids of dissimilar polarity.