压电复合材料层合结构中的SH波

考虑压电耦合效应,通过传递矩阵-二维谱分析研究了压电复合材料层合板稳态SH波的频散特性和瞬态SH波的传播特性。数值分析表明: 压电耦合作用提高了SH波的截止频率和相速度; 由表面扰动激发的SH波, 一部分能量向板深度方向传播, 一部分以表面波的形式在两倍波长深度内传播。所采用的传递矩阵-二维谱分析为层合结构瞬态波动研究提供了一种有效的数值方法。      

用高阶矩谱表征粗糙表面的偏斜程度

基于双谱分析理论，结合表面粗糙度偏斜度参数的定义，提出了偏斜度函数的表达方式，以及二维双谱的对角线切片算法，并将它们用于三维粗糙工程表面的偏斜度描述。文中还对具有对称、正偏态和负偏态分布特征的电火花、精密车削和研磨加工试件进行了实验研究，认为双谱和偏斜度函数可以合理有效地描述三维粗糙表面偏离高斯分布的程度。     

二维原子晶体材料中的各向异性研究概述

二维原子晶体材料简称二维材料,因载流子迁移和热量扩散都被限制在二维平面内,展现出了许多奇特的性质而受到了广泛关注。二维材料的带隙可调特性在场效应管、光电器件、热电器件等领域应用广泛。另外二维材料的自旋自由度和谷自由度的可控性使得二维材料在自旋电子学和谷电子学等领域也引发了深入的研究。不同的二维材料由于晶体结构的特殊性质导致了不同的电学特性或者光学特性的各向异性,包括拉曼光谱、光致发光光谱、二阶谐波谱、光吸收谱、热导率、电导率等性质的各向异性。这些各向异性特性在偏振光电器件、偏振热电器件、仿生器件、偏振光探等领域拥有巨大的发展潜力。二维材料的各向异性还能够用于实现器件性能的最优化。文章介绍了各种二维材料的各向异性的最新研究进展。     

基于面域功率谱密度的金刚石车削相对振动辨识

在金刚石车削中,刀具与工件之间的相对振动会在加工表面上生成具有某种规律性的特征,并恶化表面质量.本文仿真了振动影响下的金刚石端面车削表面的成型,并研究了刀具与工件之间的相对振动对表面形貌的影响.传统的二维轮廓方法并不适用于整个表面特征的分析,只能采用径向、周向和进给螺旋方向的轮廓进行联合分析.采用由二维快速傅里叶变换推导得到的面域功率谱密度函数可以一次性描述加工表面的形貌,并依此形成了一种根据表面数据分析辨识刀具与工件之间相对振动的系统方法,拓展了面域方法在加工表面分析上的应用.最后,通过金刚石实际车削表面的分析验证了该方法的有效性.     

基于二维朗奇光栅的表面形貌测量

本文提出一种采用二维朗奇光栅测量物体表面三维形貌的方法及装置,用一块二维朗奇光栅可同时获取被测表面在两正交方向上的梯度信息,从而仅需一张朗奇光强图便可重构出被测表面的形貌.文章介绍了方法的原理及二维朗奇光栅的结构设计,并用本方法研制的仪器进行了静止的和缓变的表面形貌的测量,取得了良好的测量结果.     

二维原子晶体材料中的各向异性研究概述

二维原子晶体材料简称二维材料,因载流子迁移和热量扩散都被限制在二维平面内,展现出了许多奇特的性质而受到了广泛关注.二维材料的带隙可调特性在场效应管、光电器件、热电器件等领域应用广泛.另外二维材料的自旋自由度和谷自由度的可控性使得二维材料在自旋电子学和谷电子学等领域也引发了深入的研究.不同的二维材料由于晶体结构的特殊性质导致了不同的电学特性或者光学特性的各向异性,包括拉曼光谱、光致发光光谱、二阶谐波谱、光吸收谱、热导率、电导率等性质的各向异性.这些各向异性特性在偏振光电器件、偏振热电器件、仿生器件、偏振光探等领域拥有巨大的发展潜力.二维材料的各向异性还能够用于实现器件性能的最优化.文章介绍了各种二维材料的各向异性的最新研究进展.     

二维超声振动辅助化学机械磨削技术及单晶硅实验

为了提高材料去除率和加工通用性,本文提出了工具施加二维超声波振动辅助的化学机械磨削(CMG)复合加工方式,开发具有伸缩和弯曲两种模态的二维超声波振动子及实验装置.以单晶硅片为加工对象,进行单点切削加工轨迹特性分析,并比较不同加工模式以及加工参数对表面粗糙度和材料去除率的影响.实验结果表明,二维超声辅助下的单点切削轨迹存在更多延性加工趋势.在同样普通机床精度条件下,随着时间的增加,二维超声辅助CMG表面粗糙度明显改善,达到纳米级.较无超声情况下二维超声波辅助CMG复合加工材料去除率提高约1倍,可获得最优表面粗糙度5 nm,一维径向超声辅助加工结果次之.     

盐酸普罗帕酮的核磁共振谱分析

该文利用核磁共振实验技术详细研究了抗心律失常药物盐酸普罗帕酮的化学结构特征，并借助二维核磁共振实验技术对盐酸普罗帕酮的氢谱和碳谱进行了完全归属，为该类化合物的结构解析提供了有益的分析依据。     

1(1/2)维谱及其倒谱在故障诊断中的研究与应用

为了提高故障诊断正确率,通过将倒谱和1(1/2)维谱相结合定义了倒1(1/2)维谱。1(1/2)维谱能够消除高斯噪声,倒谱能够减少谱图中的虚假谱峰,但噪声对倒谱分析的结果具有较大的影响。倒1(1/2)维谱则可以结合1(1/2)维谱和倒谱的优点。通过将1(1/2)维谱、倒谱和倒1(1/2)维谱分别应用于溢流阀故障诊断实验,结果表明,倒1(1/2)维谱可以取得较好的故障诊断效果。     

基于形态学图像处理的点阵式二维条码研究

通过研究二维条码的识别发现,在实际应用中,二维条码多以点阵等形式印刻在物体表面,而目前的检测算法只适用于纸制印刷品表面,不能用于检测印刻在其它材料表面的点阵式二维条码.经过研究,发现对该类二维条码应用形态学图像处理中的闭操作,能将其转换成连续格式的二维条码,有利于二维条码的定位.同时针对闭操作中结构元素的确定,提出以二维条码模块的长、宽平均所占像素为边长的正方形结构元素.     

基于对氯苄胺的2D/3D钙钛矿太阳能电池

三维(3D)有机–无机金属卤化物钙钛矿薄膜的表面和晶界处存在大量缺陷,容易导致载流子的非辐射复合并加快3D钙钛矿分解,进而影响钙钛矿太阳能电池(PSCs)能量转换效率(PCE)及稳定性.本研究通过引入对氯苄胺阳离子,与3D钙钛矿薄膜及其表面过剩的碘化铅反应后原位形成了二维(2D)钙钛矿,实现了对3D钙钛矿薄膜表面和晶界...     

Engineering 2D Architectures toward High‐Performance Micro‐Supercapacitors

The rise of micro‐supercapacitors is satisfying the demand for power storage in portable devices and wireless gadgets. But the miniaturization of the energy‐storage components is significantly limited by their energy density. Electrode materials with adequate electrochemical active surfaces are therefore required for improving performance. 2D materials with ultralarge specific surface areas offer a broad portfolio of the development of high‐performance micro‐supercapacitors in spite of their several critical drawbacks. An architecture engineering strategy is therefore developed to break these natural limits and maximize the significant advantages of these materials. Based on the approaches of phase transformation, intercalation, surface modification, material hybridization, and hierarchical structuration, 2D architectures with improved conductivity, enlarged specific surface, enhanced redox activity, as well as the unique synergetic effect exhibit great promise in the application of miniaturized supercapacitors with highly enhanced performance. Herein, the architecture engineering of emerging 2D materials beyond graphene toward optimizing the performance of micro‐supercapacitors is discussed, in order to promote the application of 2D architectures in miniaturized energy‐storage devices.     

三维表面粗糙度参数的矩表征

以分形几何理论为基础,利用轮廓谱矩和表面谱矩对三维表面粗糙度评定参数进行了分形表征;并且从理论上提出了一些新的三维评定参数,如均一性、等方性等;最后还进行了实验验证。     

Interface Engineering in 2D/2D Heterogeneous Photocatalysts

Assembling different 2D nanomaterials into heterostructures with strong interfacial interactions presents a promising approach for novel artificial photocatalytic materials. Chemically implementing the 2D nanomaterials’ construction/stacking modes to regulate different interfaces can extend their functionalities and achieve good performance. Herein, based on different fundamental principles and photochemical processes, multiple construction modes (e.g., face-to-face, edge-to-face, interface-to-face, edge-to-edge) are overviewed systematically with emphasis on the relationships between their interfacial characteristics (e.g., point, linear, planar), synthetic strategies (e.g., in situ growth, ex situ assembly), and enhanced applications to achieve precise regulation. Meanwhile, recent efforts for enhancing photocatalytic performances of 2D/2D heterostructures are summarized from the critical factors of enhancing visible light absorption, accelerating charge transfer/separation, and introducing novel active sites. Notably, the crucial roles of surface defects, cocatalysts, and surface modification for photocatalytic performance optimization of 2D/2D heterostructures are also discussed based on the synergistic effect of optimization engineering and heterogeneous interfaces. Finally, perspectives and challenges are proposed to emphasize future opportunities for expanding 2D/2D heterostructures for photocatalysis.     

Supramolecular Chiral 2D Materials and Emerging Functions

Chiral materials are widely applied in various fields such as enantiomeric separation, asymmetric catalysis, and chiroptical effects, providing stereospecific conditions and environments. Supramolecular concepts to create the chiral materials can provide an insight for emerging chiro-optical properties due to their well-defined scaffolds and the precise functionalization of the surfaces or skeletons. Among the various supramolecular chiral structures, 2D chiral sheet structures are particularly interesting materials because of their extremely high surface area coupled with many unique chemical and physical properties, thereby offering potential for the next generation of functional materials for optically active systems and optoelectronic devices. Nevertheless, relatively limited examples for 2D chiral materials exhibiting specific functionality have been reported because incorporation of molecular chirality into 2D architectures is difficult at the present stage. Here, a brief overview of the recent advances is provided on the construction of chiral supramolecular 2D materials and their functions. The design principles toward 2D chirality and their potential applications are also discussed.     

New perspectives on the roles of nanoscale surface topography in modulating intracellular signaling

The physical properties of biomaterials, such as elasticity, stiffness, and surface nanotopography, are mechanical cues that regulate a broad spectrum of cell behaviors, including migration, differentiation, proliferation, and reprogramming. Among them, nanoscale surface topography, i.e., nanotopography, defines the nanoscale shape and spatial arrangement of surface elements, which directly interact with the cell membranes and stimulate changes in the cell signaling pathways. In biological systems, the effects of nanotopography are often entangled with those of other mechanical and biochemical factors. Precise engineering of 2D nanopatterns and 3D nanostructures with well-defined features has provided a powerful means to study the cellular responses to specific topographic features. In this Review, we discuss efforts in the last three years to understand how nanotopography affects membrane receptor activation, curvature-induced cell signaling, and stem cell differentiation.     

Experimental and numerical analyses of manufacturing process of a composite square box part: Comparison between textile reinforcement forming and surface 3D weaving

Textile reinforcement forming is frequently used in aeronautic and automobile industries as a composite manufacturing process. The double-curved shape forming may be difficult to control and can lead to defects. Numerical simulation analysis can predict the suitable forming conditions and minimize the defects. Wrinkling as one of the most common flaws can be experienced easily during textile composite forming for certain specific shapes, for example the square box. In order to product a composite square box without wrinkles, a surface 3D weaving process has been developed to weave directly the shape of final part without the step of 2D preforming. In the surface 3D weaving the three directions are completely designed. The warp and weft yarns on all the surfaces of square box are absolutely under control and the final 3D ply has a homogeneous fibre volume fraction.     

Surface integrity studies on abrasive water jet cutting of AISI D2 steel

This article investigates the 3D surface topography and 2D roughness profiles, and micrographs were analyzed in the abrasive water jet (AWJ) cutting of AISI D2 steel kerf wall cut surfaces by varying water jet pressures and jet impact angles. In 3D surface topography, roughness parameters such as Sq, Ssk, Sp, Sv, Sku, Sz, and Sa were improved by various jet impact angles with different water jet pressures. However, the roughness parameters Ssk and Sku strongly depend on the water jet pressure and jet impact angle. This is confirmed by kerf wall cut profile structures. Fine irregularities of peaks and valleys are found on the AWJ cut surfaces, as evident from 2D roughness profiles. The scanning electron microscope micrographs confirm the production of an upper zone not very much damaged and a lower striation free bottom zone, by using the jet impact angle of 70° with a water jet pressure of 200?MPa. Finally, the results indicate a jet impact angle of 70° maintaining the surface integrity of D2 steel better than normal jet impact angle of 90°. The results are useful in mating applications subjected to wear and friction. This has resulted in enhancement of the functionality of the AWJ machined D2 steel components.     

3D culturing of human adipose-derived stem cells enhances their pluripotency and differentiation abilities

Human mesenchymal stem cells,such as human adipose-derived stem cells(hASCs),are typically cultured on a two-dimensional(2 D)monolayer material surface,on which 2 D culturing methods are easily performed and time-saving.However,hASCs usually suffer from decreased pluripotency and differentiation ability when cultured with a 2 D monolayer culturing method compared to hASCs cultured with a three-dimensional(3 D)culturing method,such as suspension culture.In this study,we evaluated whether the pluripotency and differentiation ability of hASCs can be reversibly changed during sequential cultivation with 2 D and 3 D culturing processes.The hASCs cultivated with a 3 D culturing process after 2 D culture showed at least 2-fold enhanced pluripotency(Sox2,Nanog,and OCT4)compared with that of hASCs cultured with the 2 D culture process alone.Furthermore,hASCs obtained from the 3 D culture process expressed increased levels of differentiation markers of chondrocytes and osteoblasts compared with hASCs obtained from the 2 D culture process when hASCs were induced to differentiate.However,their pluripotency and differentiation ability were extensively reduced when hASCs were shifted from 3 D culture to 2 D culture and vice versa,which indicates that hASCs show reversibility in terms of their pluripotency and differentiation ability depending on their environment in 2 D and 3 D culture.The reversibility of pluripotency and differentiation ability were found to last for at least 5 passages in culture during the alternative and sequential culture of cells with 2 D and 3 D culturing processes.Our study revealed the importance of the culture microenvironment in maintaining the pluripotency and differentiation ability of hASCs,which may reduce the effects of the aging process in hASCs.We discuss whether the environment of stem cell culture(i.e.,2 D or 3 D cultivation)can affect stem cell fate in terms of pluripotency and differentiation reversibility.     

Magnetic Field-Assisted Interface Embedding Strategy to Construct 2D/3D Composite Structure for Stable Perovskite Solar Cells with Efficiency Over 24%

Perovskite solar cells (PSCs) based on 2D/3D composite structure have shown enormous potential to combine high efficiency of 3D perovskite with high stability of 2D perovskite. However, there are still substantial non-radiative losses produced from trap states at grain boundaries or on the surface of conventional 2D/3D composite structure perovskite film, which limits device performance and stability. In this work, a multifunctional magnetic field-assisted interfacial embedding strategy is developed to construct 2D/3D composite structure. The composite structure not only improves crystallinity and passivates defects of perovskite layer, but also can efficiently promote vertical hole transport and provide lateral barrier effect. Meanwhile, the composite structure also forms a good surface and internal encapsulation of 3D perovskite to inhibit water diffusion. As a result, the multifunctional effect effectively improves open-circuit voltage and fill factor, reaching maximum values of 1.246 V and 81.36%, respectively, and finally achieves power conversion efficiency (PCE) of 24.21%. The unencapsulated devices also demonstrate highly improved long-term stability and humidity stability. Furthermore, an augmented performance of 21.23% is achieved, which is the highest PCE of flexible device based on 2D/3D composite perovskite films coupled with the best mechanical stability due to the 2D/3D alternating structure.