Comparing ignitability for in situ burning of oil spills for an asphaltenic,a waxy and a light crude oil as a function of weathering conditions under arctic conditions

In situ burning of oil spills in the Arctic is a promising countermeasure. In spite of the research already conducted more knowledge is needed especially regarding burning of weathered oils. This paper uses a new laboratory burning cell (100 mL sample) to test three Norwegian crude oils, Grane (asphalthenic), Kobbe (light oil) and Norne (waxy), for ignitability as a function of ice conditions and weathering degree. The crude oils (9 L) were weathered in a laboratory basin (4.8 m³) under simulated arctic conditions (0, 50 and 90% ice cover). The laboratory burning tests show that the ignitability is dependent on oil composition, ice conditions and weathering degree. In open water, oil spills rapidly become “not ignitable” due to the weathering e.g. high water content and low content of residual volatile components. The slower weathering of oil spills in ice (50 and 90% ice cover) results in longer time-windows for the oil to be ignitable. The composition of the oils is important for the window of opportunity. The asphalthenic Grane crude oil had a limited time-window for in situ burning (9 h or less), while the light Kobbe crude oil and the waxy Norne crude oil had the longest time-windows for in situ burning (from 18 h to more than 72 h). Such information regarding time windows for using in situ burning is very important for both contingency planning and operational use of in situ burning.     

Estimation of potential impacts and natural resource damages of oil

Methods were developed to estimate the potential impacts and natural resource damages resulting from oil spills using probabilistic modeling techniques. The oil fates model uses wind data, current data, and transport and weathering algorithms to calculate mass balance of fuel components in various environmental compartments (water surface, shoreline, water column, atmosphere, sediments, etc.), oil pathway over time (trajectory), surface distribution, shoreline oiling, and concentrations of the fuel components in water and sediments. Exposure of aquatic habitats and organisms to whole oil and toxic components is estimated in the biological model, followed by estimation of resulting acute mortality and ecological losses. Natural resource damages are based on estimated costs to restore equivalent resources and/or ecological services, using Habitat Equivalency Analysis (HEA) and Resource Equivalency Analysis (REA) methods. Oil spill modeling was performed for two spill sites in central San Francisco Bay, three spill sizes (20th, 50th, and 95th percentile volumes from tankers and larger freight vessels, based on an analysis of likely spill volumes given a spill has occurred) and four oil types (gasoline, diesel, heavy fuel oil, and crude oil). The scenarios were run in stochastic mode to determine the frequency distribution, mean and standard deviation of fates, impacts, and damages. This work is significant as it demonstrates a statistically quantifiable method for estimating potential impacts and financial consequences that may be used in ecological risk assessment and cost-benefit analyses. The statistically-defined spill volumes and consequences provide an objective measure of the magnitude, range and variability of impacts to wildlife, aquatic organisms and shorelines for potential spills of four oil/fuel types, each having distinct environmental fates and effects.     

Wireless Sensor for Continuous Real-Time Oil Spill Thickness and Location Measurement

Marine pollution by oil spills is a devastating environmental hazard, requiring a low-cost efficient system for continuous and real-time thickness measurement and localization of oil. Knowing that none of the previous detection methods has managed to fully meet these requirements, it is necessary to devise a new technique for guiding and speeding up the clean-up process of oil spills. This paper presents a sensor device that is capable of sensing, processing, and transmitting information about an oil spill (location and thickness). This paper discusses two new methodologies of detection based on the difference in the absorbance spectral signatures and electric conductivity properties of oil and water. This paper also discusses the mechanical design of the device, the hardware implementation of its components, and the integration and evaluation of the whole system. The experimental results confirm the effectiveness of the proposed method under different lighting, salinity, temperature, and sea conditions.      

Weathering of a subarctic oil spill over 25 years: the Caribou-Poker Creeks Research Watershed experiment

A small experimental oil spill conducted in an open black spruce forest within the Caribou-Poker Creeks Research Watershed (CPCRW), 48 km north of Fairbanks, AK, in the winter of 1976 was designed to examine the effects of crude oil spills in permafrost terrain. No clean-up was attempted, and the site now provides an opportunity to follow the natural weathering of spilled oil under these conditions. In summer 2001, more than 25 years after the spill, we sampled soils from the spill plot and a nearby reference plot to determine how the oil had weathered, and to assess microbial populations and activity. All samples collected from the oiled plot contained substantial amounts of methylene chloride extractable oil, between 4% and 66% by weight. Using 17α(H)21β(H)hopane as a conserved internal marker within the oil, we determined that while some heavily oiled samples were almost unchanged since the spill, others had lost more than 80% of their initial hydrocarbon. Evaporation, biodegradation and photooxidation all seem to have played important roles in this process, but to varying degrees in different samples. Assays of culturable populations of total heterotrophs and crude oil emulsifiers, and mineralization potentials for hexadecane and phenanthrene, indicate that the microbial population in the oiled soils has remained acclimated to degrade hydrocarbons. We conclude that natural weathering processes will eventually lead to the removal of much of the hydrocarbon from these heavily oiled subarctic soils; however, the combination of low rates of nutrient turnover, a short thaw season, and high hydrocarbon concentrations will result in the persistence of oil residue for many more decades. Finding an environmentally appropriate cleanup technology for sites like this remains an important challenge for future research.     

Cost-effectiveness criteria for marine oil spill preventive measures

Oil tanker accidents resulting in large quantities of oil spills and severe pollution have occurred in the past, leading to major public attention and an international focus on finding solutions for minimising the risks related to such events. This paper proposes a novel approach for evaluating measures for prevention and control of marine oil spills, based on considerations of oil spill risk and cost effectiveness. A cost model that incorporates all costs of a shipping accident has been established and oil tanker spill accidents have been further elaborated as a special case of such accidents. Utilising this model, novel implementation criteria, in terms of the Cost of Averting a Tonne of oil Spilt (CATS), for risk control options aiming at mitigating the environmental risk of accidental oil spills, are proposed. The paper presents a review of previous studies on the costs associated with oil spills from shipping, which is a function of many factors such as location of spill, spill amount, type of oil, etc. However, ships are designed for global trade, transporting different oil qualities. Therefore, globally applicable criteria must average over most of these factors, and the spill amount is the remaining factor that will be used to measure cost effectiveness against. A weighted, global average cleanup cost of USD 16,000/tonne of oil spilt has been calculated, considering the distribution of oil tanker traffic densities. Finally, the criteria are compared with some existing regulations for oil spill prevention, response and compensation (OPA 90).     

液体苯系物等类油物质吸附材料综述

近年来,苯系物等类油物质泄漏事故频发。由于苯系物多数具有极强的毒性和挥发性,因此苯系物比原油等重油泄漏事故引发的危害更大。考虑到苯系物和油类物质理化性质的相似性,对苯系物泄漏事故的应急处置办法可以参考溢油事故的处置办法。通过对溢油事故中常用的无机类吸附材料、有机高分子吸附材料和天然高分子吸附材料的研究现状和应用前景进行了综述,希望能够为相关科研工作者解决苯系物泄漏的应急处置提供思路,促进该领域的快速发展。     

Model of spills and fires from LNG and oil tankers

A comprehensive model for predicting the dynamics of spills from LNG and oil product tankers is constructed from fluid mechanics principles and empirical properties of oil and LNG spills on water. The analysis utilizes the significant tanker hold and discharge flow area dimensions to specify the cargo liquid outflow history and the ensuing pool characteristics, including the establishment of a pool fire. The pool fire area, duration, and heat release rate are determined as functions of the tanker cargo variables. Examples of an LNG and gasoline spill show that for likely discharge flow areas these spills may be regarded as instantaneous, simplifying the evaluation of risk consequences.     

Modeling the effectiveness of oil combating from an ecological perspective--a Bayesian network for the Gulf of Finland; the Baltic Sea

Maritime traffic poses a major threat to marine ecosystems in the form of oil spills. The Gulf of Finland, the easternmost part of the Baltic Sea, has witnessed a rapid increase in oil transportation during the last 15 years. Should a spill occur, the negative ecological impacts may be reduced by oil combating, the effectiveness of which is, however, strongly dependent on prevailing environmental conditions and available technical resources. This poses increased uncertainty related to ecological consequences of future spills. We developed a probabilistic Bayesian network model that can be used to assess the effectiveness of different oil combating strategies in minimizing the negative effects of oil on six species living in the Gulf of Finland. The model can be used for creating different accident scenarios and assessing the performance of various oil combating actions under uncertainty, which enables its use as a supportive tool in decision-making. While the model is confined to the western Gulf of Finland, the methodology is adaptable to other marine areas facing similar risks and challenges related to oil spills.     

In-depth analysis of accidental oil spills from tankers in the context of global spill trends from all sources

This study gives a global overview of accidental oil spills from all sources (> or =700t) for the period 1970-2004, followed by a detailed examination of trends in accidental tanker spills. The present analysis of the number and volume of tanker spills includes temporal and spatial spill trends, aspects of spill size distribution as well as trends of key factors (i.e., flag state, hull type, tanker age, accident cause and sensitivity of location). Results show that the total number and volume of tanker spills have significantly decreased since the 1970s, which is in contrast to increases in maritime transport of oil and to popular perceptions following recent catastrophic events. However, many spills still occur in ecologically sensitive locations because the major maritime transport routes often cross the boundaries of the Large Marine Ecosystems, but the substantially lower total spill volume is an important contribution to potentially reduce overall ecosystem impacts. In summary, the improvements achieved in the past decades have been the result of a set of initiatives and regulations implemented by governments, international organizations and the shipping industry.     

Differential laser trigonometry for measuring the oil film thickness on water

A differential laser trigonometry method is presented for measurement of the oil film thickness on a water surface. The thickness of an oil film can be obtained with two off-plane displacements to a benchmark plane obtained by the imaging spot displacement and the configuration parameter of the imaging system subtracted. The method has been tested in the laboratory via the examination of diesel oil and petroleum films. An experimental system setup has been developed, by which the maximum measurable thickness is 12?mm and the average measurement error is 6.05?µm. The results show that the method presented is feasible, and applicable to dynamic online measurement of oil film thickness of oil spills on the sea surface.     

可重组柔顺夹具定位及夹紧元件的研究设计

论述和剖析了可重组柔顺性夹具的定位及夹紧元件的设计研究     

Oil spills debris clean up by thermal desorption

Oil spills represent a significant environmental issue in Brazil. This paper presents the latest results of a comprehensive experimental programme aimed at understanding how the presence of spilled oil affects the properties of sands and at studying alternatives to remediate the affected shores. Results indicate that oil causes a slight increase in grain size and uniformity, and oiled debris presents a smaller void ratio but a larger unit weight. It was also observed that effective strength parameters for both the natural and oiled debris were the same although the undrained strength of a natural sand is much higher than that of the contaminated sand. At ambient temperature, oiled debris emits methane and ammonia, and these emissions tend to increase with rising temperatures. On the other hand, the oil and grease content from oiled debris decreases with rising temperature and prolonged exposure. Finally, in situ thermal desorption seems to be a promising method for cleaning debris from oil spills. It is simple, fast and avoids all the difficulties associated with digging up the soil for disposal or cleanup.     

Fast and selective removal of oils from water surface via highly hydrophobic core-shell Fe2O3@C nanoparticles under magnetic field

The removal of oil spills or organic contaminants from water surface is of great technological importance for environmental protection. A major challenge is the fast distribution and collection of absorbent materials with high separation selectivity, good thermal stability, and excellent recyclability. Here we reported fast and selective removal of oils from water surface through core-shell Fe(2)O(3)@C nanoparticles under magnetic field. These nanoparticles combined with unsinkable, highly hydrophobic and superoleophilic properties, could selectively absorb lubricating oil up to 3.8 times of the particles' weight while completely repelling water. The oil-absorbed nanoparticles were quickly collected in seconds by applying an external magnetic field. More importantly, the oil could be readily removed from the surfaces of nanoparticles by a simple ultrasonic treatment whereas the particles still kept highly hydrophobic and superolephilic characteristics. Experiment results showed that the highly hydrophobic Fe(2)O(3)@C nanoparticles could be reused in water-oil separation for many cycles. Our results suggest a facile and efficient method that might find practical applications in the cleanup of oil spills and the removal of organic pollutants on water surface.     

Oil spill cleanup from sea water by carbon nanotube sponges

Oil spills in the sea have caused many serious environmental problems worldwide. In this study, carbon nanotube (CNT) sponges were used to cleanup oil slicks on sea waters. This method was compared with two traditional representative sorbents, including polypropylene fiber fabric and woolen felt. The CNT sponges had a larger oil sorption capacity than the other two sorbents. The maximum oil sorption capacity (Q_m) of the CNT sponge was 92.30 g/g, which was 12 to 13.5 times larger than the Q_m of the other two sorbents (the Q_m of the polypropylene fiber fabric and woolen felt were 7.45 and 6.74 g/g, respectively). In addition, unlike the other two sorbents, the CNT sponge was super-hydrophobic and did not adsorb any water during oil spill cleanup. CNT sponges are potentially very useful for cleaning up oil spills from sea water.     

A flame-retardant post-synthetically functionalized COF sponge as absorbent for spilled oil recovery

Journal of Materials Science - Frequent oil spills pose severe damages to the marine ecosystems and result in hazardous fires when the spilled oil is ignited. Developing high-performance,...     

标准化在我国海洋溢油应急处置工作中的应用研究

本文主要探讨我国海洋溢油应急处置工作存在的标准化问题以及加强我国海洋溢油应急处置标准化工作的对策。     

A literature review of portable fluorescence-based oil-in-water monitors

The results of a literature search on fluorescence-based portable detectors to measure the real-time concentration of oil are reported. For more than two decades, fluorometers have been commonly employed to monitor dispersed oil levels at oil spills on water. The focus of this paper has been to extract specific information from references about how the instruments were used, including set up and calibration procedures, the oil and dispersant measured, the approximate concentration range of the oil in the water column, and how the real-time data compared to traditional laboratory techniques.     

A review of the U.S. Environmental Protection Agency's Research Program on the prevention and control of hazardous material spills

This paper is a status report on a number of the projects in progress at the Industrial Waste Treatment Research Laboratory of the U.S. Environmental Protection Agency at Edison, New Jersey. The actual causes of numerous hazardous material spills have been documented and analyzed to assign priority to operational areas in which spill prevention and control procedures are urgently needed. Spill alert systems are ready for installation on marginally safe earthen holding pond dikes. Fail-safe systems are being evaluated to reduce spillage from overfilling and from transfer line rupture. The handling of spills in municipalities has been addressed with particular attention to the maintenance and utilization of secondary sewage treatment facilities during spill events.Among the physical and chemical treatment systems that have been or are being produced are trailer-mounted units for processing contaminated water. Also, special devices are being designed for the dispersion and recovery — where necessary — of adsorbents and counteractive chemical reagents for in situ treatment of polluted water bodies. Plastic foams have been developed to dike or confine spills and to plug leaks in ruptured containers. A pickup truck-mounted collection unit, consisting of a battery-powered pump and a self-deploying plastic storage bag, has been constructed and tested.Nearing final testing is a “Sea Curtain”, which extends from the bottom of a stream to the air above. The “Curtain” can be used to isolate a water column that is being contaminated by a soluble, sinking, or floating hazardous material discharged from shore or in stream. Gelling and solidification agents have been shown to be effective in immobilizing spilled hazardous materials. Systems are being built to reprocess treatment agents for reuse and to detoxify whatever agents or recovered materials cannot be salvaged. Field-use packets and other easy-to-deploy items are being developed to trace spills in water and to assess the effectiveness of cleanup. Procedures for enhanced, in-place, biological degradation of spilled hazardous materials are under test.The thrust of the Laboratory's program in these and in related projects is toward the demonstration of practical procedures, hardware, and suitably engineered systems for the prevention and control of spills of hazardous materials.     

Optimal generator maintenance scheduling using a modified discrete PSO

A modified discrete particle swarm optimisation (MDPSO) algorithm to generate optimal preventive maintenance schedule of generating units for economical and reliable operation of a power system, while satisfying system load demand and crew constraints, is presented. Discrete particle swarm optimisation (DPSO) is known to effectively solve large-scale multi-objective optimisation problems and has been widely applied in power system. The MDPSO proposed for the generator maintenance scheduling optimisation problem generates optimal and feasible solutions and overcomes the limitations of the conventional methods, such as extensive computational effort, which increases exponentially as the size of the problem increases. The efficacy of the proposed algorithm is illustrated and compared with the genetic algorithm (GA) and DPSO in two case studies ? a 21-unit test system and a 49-unit system feeding the Nigerian national grid. The MDPSO algorithm is found to generate schedules with comparatively higher system reliability indices than those obtained with GA and DPSO.