The Effect of Hybrid Carrageenan on the Thermo-rheological Properties of Gluten-Free Flour Doughs Using a Modified Kneading Protocol

Thermo-rheological behaviour of chestnut flour doughs supplemented with kappa/iota-hybrid carrageenan (HC) (up to 2.0%, flour basis (f.b.)) and sodium chloride (1.8%, f.b.) was determined at both target (C1) and final (C5) mixing peaks. For this purpose, small amplitude oscillatory shear (0.01 to 100 Hz), creep–recovery (loading of 50 Pa for 60 s, 30 °C), temperature sweeps (from 30 up to 180 °C) and heating/cooling cycles (between 30 and 60 °C) were conducted on a controlled stress rheometer. Previously, the thermal-mixing behaviour at proposed mixing temperature (50 °C) was conducted on Mixolab® apparatus. Results showed that the dough stability (from 2.2 to 5.8 min) in mixing stage and starch heat resistance to dough processing were significantly improved at proposed mixing temperature, even in the absence of HC. No statistical differences in rheological properties were observed for doughs evaluated in C1; however, those analysed in C5 were significantly modified in the presence of HC, mainly in terms of viscous behaviour (from 52.1 × 10⁶ to 39.1 × 10⁶ Pa s). Creep–recovery data sets, successfully fitted using Burgers model, revealed that the elasticity (J _r/J _max from 73.3 to 87.6%) of doughs analysed in C5 improved with HC addition. Thermal tests showed that the starch transitions were significantly promoted and stabilized with HC addition.     

Rheology of Gluten-Free Doughs from Blends of Chestnut and Rice Flours

Gluten-free flours blends using chestnut flour (CF) and rice flour (RF) were assayed in order to determine mixing and rheological properties of doughs at 30 °C as well as the thermal behaviour employing heating–cooling temperature steps. CF with different mean particle size (commercial, CCF: 169 μm and low particle size, CF1: 77 μm samples) was employed and blended with RF (46 μm) at several ratios (%) (CCF/RF: 90/10, 80/20, 70/30, 60/40, 50/50; CF1/RF: 25/75, 15/85, 5/95). Doughs from CCF, CF1 and RF flours were employed as reference systems. The rheological characterization of doughs conducted on the rheometer was performed by shear, oscillatory and creep-recovery assays. Rheological properties were significantly modified by flour ratio and by CF particle size. Creep-recovery curves showed that CCF/RF (70/30) and CF1/RF (25/75) improved the doughs elasticity by 41.1 % and 87.5 % compared with CCF and CF1, respectively. Cross, power and Burgers models were used to describe the flow curves, mechanical spectra and creep-recovery behaviour, respectively, of doughs. A mixing rule successfully reproduced the experimental data and fitting parameters of applied models as function of each flour fraction in the blends, except for oscillatory data.     

板栗全粉-小麦混合粉面团的流变特性

以板栗加工残次品为原料通过不同干燥方式制备板栗全粉,对板栗全粉物化特性、板栗全粉-小麦粉面团流变特性进行了研究。结果表明,通过自然干燥的板栗全粉(ZR)糊化度超过50%,熟化处理后的板栗全粉SH-20糊化度高达70.69%,而板栗生全粉糊化度仅为3.28%;随板栗生全粉添加量的增加,面团吸水率和回生值下降、弱化度增加,在添加量30%时分别为50%、0.65 N·m和0.81 N·m,而形成时间、稳定时间、糊化特性和糊化稳定性呈先减小后增加的趋势;随着糊化板栗全粉添加量的增加面团的吸水率增加,而稳定时间、糊化特性、糊化稳定性、弱化度和回生值降低;添加ZR和SH-20面团的形成时间呈小幅上升趋势,而添加其他几种糊化板栗面团形成时间呈先小幅增加后大幅下降的趋势。面团的剖面分析表明添加板栗生全粉主要降低了吸水率、混合和面筋指数;而添加糊化板栗全粉提高吸水率和面筋指数。总之,生板栗全粉和糊化板栗全粉对面团的特性影响不同,这将为板栗残次品的加工和综合利用提供重要理论依据。     

稻米-高筋小麦混合粉面团的静态和动态流变学特性

本实验研究了6 种稻米-高筋混合粉面团的静态和动态流变学特性。结果表明,随着稻米粉添加量的增加,在动态流变频率扫描中,混合面团的储存模量（G’）和损耗模量（G’’）整体呈上升趋势,损耗角正切（tan δ）整体呈规律性下降趋势;在静态流变的蠕变松弛实验中,最大蠕变应变量、最大蠕变柔量和瞬时恢复柔量逐渐减小,零剪切黏度和瞬间恢复比率逐渐增加,表明加入稻米粉后面筋蛋白有所稀释,但稻米粉中的淀粉吸水膨胀相互黏附,且与米蛋白相互作用赋予面团更高的弹性模量和更复杂的内部结构。在动态流变的温度扫描中,糊化温度前后混合面团的黏弹性变化明显,G’和G’’曲线类似淀粉糊化曲线,说明生面团加热的过程中,影响其流变学特性的主要成分为淀粉;降温过程中,稻米粉添加量的影响较小,高温区G’和G’’呈规律性增加,温度低于60 ℃后各项流变指标规律性差;在整个降温的过程中样品均具有类固体的性质。     

DIFFERENTIAL SCANNING CALORIMETRY OF STARCH12

At high water-to-starch (2:1) ratios a single endotherm was obtained for starch gelatinization. As the water-to-starch ratio was decreased the endotherm area decreased and the peak developed a trailing shoulder. At high water-to-starch ratios birefringence is lost over a temperature range of about 7°C. That narrow range increases to about 30°C at a low water-to-starch ratio. Starch and flour gave essentially the same endotherm initiation temperatures. In low-water systems the second DSC peak is much smaller with starch than with flour. It appears that in a starch system, water migrates during gelatinization. In dough, gluten limits that migration. As the level of sucrose was increased in a dough, the transition temperature increased and the gelatinization temperature range decreased. At the levels found in bread doughs both sugar and salt increase starch gelatinization temperatures.     

Rheology of Sol-Gel Thermal Transition in Cowpea Flour and Starch Slurry

A thermal scanning rigidity monitor was used to follow rheological changes during heating of cowpea flour and starch slurries. The gelantinization temperature of cowpea starch was in the range 67–78°C. For cowpea flour, in addition to starch gelatinization, a shallow plateau was observed. The starch gelatinization onset temperature shifted from 67°C for starch to 72C for 25% cowpea flour that contained 12–15% starch. The modulus (G′) of cowpea gels increased with flour concentration according to a power relationship. Rigidity of the cowpea starch and flour gels decreased at temperatures higher than 78 and 87°C, respectively.     

Desorption Isotherms and Net Isosteric Heat of Chestnut Flour and Starch

The desorption isotherms of chestnut flour and chestnut starch were determined at different temperatures (20°C, 35°C, 50°C, and 65°C) using gravimetric method. Desorption isotherms of potato starch were also determined in order to establish a comparison against desorption isotherms of chestnut starch. Several saturated salt solutions were selected to generate different water activities in the range of 0.09 to 0.91. Obtained desorption isotherms were of type II, according to Brunauer’s classification. Three-parameter Brunauer–Emmett–Teller and Guggenheim–Anderson–de Boer (GAB) models satisfactorily fitted the experimental data for all systems studies, although the last one can be considered better based on obtained statistical parameters and because it is applicable in a broader water activity range. The average monolayer moisture content (kilograms per kilogram d.b.) calculated by GAB model was 0.059 ± 0.007 for chestnut flour, 0.103 ± 0.021 for chestnut starch, and 0.060 ± 0.028 for potato starch. The net isosteric sorption heat, calculated by means of Clausius–Clapeyron equation, decreased when moisture content increased. The maximum values of net isosteric sorption heat (kilojoules per mole) were approximately 27.5 for chestnut flour, 16.0 for chestnut starch, and 33.0 for potato starch in the range of temperature from 20°C to 50°C.     

Effect of heating rate at different moisture contents on starch retrogradation and starch–water interactions during gelatinization

The objective of this research was to investigate the effect of heating rate at different moisture contents on starch retrogradation and gelatinization process. Starch retrogradation was not influenced by either moisture content (water/starch ratio of 0.7 or 2.0) or heating rate (5°C/min, 20°C/min, or 40°C/min). In order to further understand the effects of heating rate on starch–water interactions, starch suspensions at a water/starch ratio ranging from 0.7 to 3.0 were heated at 5, 15, or 25°C/min by using a DSC to different final temperatures and rescanned. The deconvoluted G and M1 endotherms and the corresponding additional unfrozen water (AUW) were determined. The results showed that the G and M1 endotherms merged at higher heating rates and at higher moisture contents as expected. A significant interaction was observed between moisture content and heating rate. The results suggest that the gelatinization process is governed by moisture content at the lower heating rate (5°C/min) and by heating rate at the higher heating rates (15 or 25°C/min). Results from the AUW data suggest that the M1 component of gelatinization dominated at moisture content below water/starch ratio of 1.5 and at 5°C/min heating rate. However, at moisture contents above water/starch ratio 1.0, an interaction was observed between moisture content and heating rate. The data suggest that at higher moisture content (>1.5 water/starch ratio) and at higher heating rate (≥15°C/min), there is still a kinetic limitation to the complete melting of the M1 endotherm.     

Thermal and dynamic rheological properties of wheat flour fractions

A commercial high gluten flour (HGF) was fractionated into prime starch (PS), tailing starch (TS), and gluten (G). Fractions were examined alone or in various combinations. Dynamic rheological properties of samples were measured in an oscillatory rheometer (strain 0.02; frequency 0.1 Hz) during heating at 1°C/min. Thermal characteristics of samples were determined by differential scanning calorimetry (DSC) at a heating rate of 10°C/min. The loss (G″) and storage (G′) moduli of PS and mixed G/PS, G/TS, and G/PS/TS increased after 60°C, reaching peak values (e.g. 81, 301, 313, and 3000 Pa in G′, respectively) around 75°C after which the moduli decreased. HGF showed a steady increase in G′ from 32 to 2490 Pa as temperature increased from 65 to 90°C, indicating continuous formation of elastic networks. Cooling increased G′ for G/PS/TS, decreased G′ for HGF, and produced no rheological transitions for all samples. TS and G alone did not exhibit appreciable viscoelastic responses to the heating and cooling temperatures. DSC measurements revealed a major endothermic transition in HGF. This transition, with a peak around 60°C, was due to starch gelatinization. The presence of G or TS resulted in reduced melting enthalpies of starch in the PS fraction. Gluten or TS fractions alone or in combination did not exhibit any endothermic transitions.     

Flow Behavior and Gelatinization of Cowpea Flour and Starch Dispersions

The flow behavior of a 25% cowpea slurry with 8% oil held at 70°C showed shear-thinning behavior and an Arrhenius temperature relationship. Cowpea flour (8%) and starch (2.5%) slurries heated for less than 1 min at 70–87°C exhibited shear-thickening while those heated longer times exhibited shear-thinning behavior. Maximum viscosities attained due to heat-induced gelatinization showed a power relationship with temperature of heating. Starch gelatinization kinetics followed a first-order equation and the temperature dependence of the rate constant followed the Arrhenius relationship with an activation energy of about 47.4 kcal/mol. Heating the slurries for >200 min above 80°C resulted in loss of viscosity.     

Mixing properties and rheological characteristics of dough used to make potato‐cereal soft wraps

We have studied mixing, rheology and stability of potato‐cereal flour doughs. These were prepared using samples of two varieties of cooked and cold‐stored potatoes. Dependent on variety a minimum duration of 24–48 h cold‐storage was required. Dough mixing torque plateau was inversely related to potato water content. This should be <79 g/100 g. It was also necessary to have a stable dough mixing torque plateau of >2 Nm at a specific total mechanical energy input of 18–22 kJ kg^?1. The resting temperature of the dough was also inversely related to its strength (plateau elastic modulus at time zero). Target dough strength should be about 25 kPa in a bob‐cup. Above 15 °C it decreased as a function of time and within 1 h it became too sticky for commercial processing. At 4 °C the dough remained stable. Sufficient potato starch retrogradation is a pre‐requisite to make optimal potato‐cereal flour dough for commercial processing.     

Rheological properties of commercial chestnut flour doughs with different gums

Rheology of chestnut flour (CF) doughs with arabic gum (AG), carboxymethyl cellulose (CMC), guar gum (GG) and tragacanth gum (TG) at different concentrations (up to 2.0%) were determined at 30 °C using a controlled stress rheometer. The mixing characteristics at 30 °C were achieved using Mixolab^® apparatus. Shear (0.01–10 s^?1), oscillatory (1–100 rad s^?1 at 0.1% strain), creep‐recovery (50 Pa for 60 s) and temperature sweep (30–100 °C) tests were performed. Rheological properties were significantly modified by gum added. Apparent viscosity of CF doughs, storage and loss moduli increased at content of AG (above 0.5%), CMC (at 1.0%), GG (above 1.5%) and TG (at 1.0%). Flow curves and mechanical spectra were fitted using Cross model and power models, respectively. The gelatinisation temperatures increased with gums. The same pasting trend was noticed using Mixolab^®. Creep‐recovery data, fitted by Burgers model, showed that elasticity of CF doughs improved with GG.     

Physico- Chemical Characteristics and Functional Properties of Starch and Dietary Fibre in Grass Pea Seeds

Physico-chemical and functional properties of starch and fibre in raw and processed grass pea seeds were evaluated. Whole grass pea seeds were found to contain 41 % starch and 17% total dietary fibre (2% soluble and 15% insoluble) on dry matter basis. Examination by using scanning electron microscopy revealed oval shaped starch granules with an average width of 17 μm and length of 25 μm. Raw sample had a gelatinization onset temperature of 62°C and two endothermic transition peaks at about 73°C and 94°C, in addition the starch isolated from grass pea flour was shown to have a transition enthalpy (ΔH) of 10 Jg⁻¹. The viscosity of the raw sample (using a Brabender amylograph) reached peak maximum at 80–95°C, decreasing during the 30 min holding time (at 95°C) followed by an increase during cooling to 50°C. Raw whole seed flour was shown to have a water absorption and water solubility index (WSI) of 3 and 16%, respectively. Samples that had been cooked for 60 min had a lower WSI than those cooked for 30 min; this was further reduced in the samples cooked after soaking. The carbohydrate extracted from raw flour was found to be mainly high Mwt carbohydrate (55%), eluted at Kav < 0.2.     

Characterization of starch and cell walls from mature-green ambarella (Spondias cytherea Sonnerat) and their enzymatic hydrolysis

Juice from mature-green ambarella contains starch, a characteristic detrimental to its visual appearance due to the white sediment formed upon storage. The purpose of this work was to evaluate the effects of starch and cell wall degrading enzymes on juice residual starch and content in soluble sugars. Starch and cell walls from mature-green ambarella fruits were purified and characterized. Starch was found to contain 21.0% amylose, 78.1% amylopectin and 0.9% other minors compounds. Its average granule size was 20 μm. Its thermal characteristics were: temperatures of onset (T _o = 57.8 °C), peak (T _p = 65.6 °C), and conclusion (T _c = 72.6 °C) of gelatinization and the endothermic enthalpy (ΔH _{gelatinisation} = 12.4 J g^?1). Cell walls represented 2.8% of the edible fresh matter and were mainly constituted of highly methylated (HM) pectic substances and cellulose. The amylolytic preparations we tested, AMG^® 300 L and Hazyme^® C, showed similar behaviours in terms of starch hydrolysis and profit of Brix degree obtained. With 200 μg g^?1 of AMG^® 300 L or Hazyme^® C, the degree of amylolysis of coarse ambarella puree was close to 50% and its increased up to 70% with enzymes concentrations higher than 1,000 μg g^?1 (gelatinization at 75 ± 5 °C for 15 min followed by starch amylolysis at 60 ± 5 °C for 15 min). Total hydrolysis of ambarella starch is possible when pectinolysis occurred before amylolysis treatment, probably because of the fluidification of the medium by the pectocellulolytic enzymes. Pectinex^® Ultra SP-L was the most efficient preparation to degrade the ambarella pectins (～80% of cell wall uronides liberated from 120 mg g^?1 of purified cell walls within 1 h at 30 °C, pH 2.7).     

Effect of Thermal Treatment on Selected Cereals and Millets Flour Doughs and Their Baking Quality

Selected cereals (rice and sorghum) and millets (finger millet and pearl millet) were steamed for 20 min at ambient pressure. The rheological properties of doughs, made from these steamed as well raw grain flours, were characterized in addition to examining their baking quality. The two-cycle compression test was employed and instrumental values were correlated with sensory attributes (color, aroma, taste, stickiness, chewiness, tearing strength, cohesiveness, and rollability) using principal component analysis (PCA). Rice doughs made from both raw as well as thermally treated flour imparted maximum hardness (96.6–99.3 N) and least cohesiveness (0.05–0.09) with highest stickiness values (105–110°) among all the dough samples at the same moisture content. Pearl millet and raw sorghum flour doughs possessed the least instrumental hardness, adhesiveness, and stickiness and were the easiest to flatten. The PCA biplot showed that sensory and instrumental cohesiveness formed a cluster on the left side on the x axis while shear force, and sensory attributes like tearing strength, chewiness, stickiness, and rollability formed another cluster on the other side of the axis. Raw rice and finger millet doughs were associated with the high extent of instrumental and sensory stickiness. Thermally treated pearl millet and sorghum doughs were the best followed by treated rice and finger millet samples to give the desirable dough characteristics, and were quite close to wheat chapathi in texture.     

Effect of Maize Resistant Starch and Transglutaminase: A Study of Fundamental and Empirical Rheology Properties of Pan Bread Dough

The effect of maize resistant starch (MRS) and transglutaminase (TG) on rheological and thermal properties of pan bread dough was studied. The MRS was added as an alternative to increase the fiber ingestion while TG supplies the gluten dilution, catalyzing protein bonds. A second order central composite design (2²) with three central and four star points was applied, and the results were compared to those of pan bread dough prepared without MRS and TG, as control. The presence of MRS and TG significantly (P?n index (degree of strain hardening). Only starch gelatinization enthalpy significantly changed (P?相似文献   

Pasting,thermal, gel texture,resistant starch and colour properties of unripe banana flour from 10 desert banana varieties cultivated in South Africa

Unripe banana flour is a potential commercial ingredient in various food products for increased resistant starch and reduced gluten contents. In the present study, the pasting (rapid visco-analysis), gel texture (penetration test), thermal (differential scanning calorimetry), colour (tri-stimulus colour indices) and the resistant starch properties of unripe banana flour produced from different dessert banana varieties (n?=?10) cultivated in South Africa, were analysed and juxtaposed to wheat and maize flour. The functional properties varied significantly (p?≤?0.05) between banana varieties, and from wheat and maize flours, to various extents. Selected functional property ranges of unripe banana, wheat and maize flours, respectively included; flour colour index (63.16–76.42, 77.34 and 80.96), paste viscosity (405.5–556.6, 124.7 and 115.6 RVU), gelatinization temperature (64.67–71.21, 71.11 and 69.95?°C), gel firmness (7.24–11.44?×?10^??2 N, 3.49?×?10^??2 N and 6.56?×?10^??2 N) and resistant starch content (19.9–47.4, 2.8 and 2.2% w/w). Multivariate analysis (principle component analysis) showed that the unripe banana flours from different varieties were distinguished from each other based on the pasting temperature. The unripe banana flours were distinguished from both wheat and maize flour based on breakdown and peak paste viscosities. The breakdown viscosity was the most positively related measure to the resistant starch content with a linear regression R-squared value of 0.898, indicating a significant role played by granule structure in resistance to enzymatic hydrolysis. The present research demonstrates that selection of appropriate dessert banana variety is important when replacing staple flours (wheat and maize) with unripe dessert banana flour as a functional ingredient.     

Effect of seed treatments on the chemical composition and properties of two amaranth species: starch and protein

The seeds of two Amaranth species were studied. The starch contents were 543 and 623 g kg^?1 while crude protein contents were 154 and 169 g kg^?1 for Amaranthus caudatus and Amaranthus cruentus seeds, respectively. The effect of several treatments, including cooking, popping and germination and flour air classification on the protein and starch properties were studied. Air classification decreased the starch content and increased the protein content, while heating increased the protein but did not affect the starch content. Germination decreased both starch and protein contents. Amylose content was increased by air classification and heating, but was not affected by germination. It was found that all treatments increased the starch swelling power and reduced the falling number. The resistant starch content was increased in the high protein flour (HPF) fraction and germinated flour compared with the raw flour, while its content decreased in the heat treated seed flours. These processes also affected the starch gelatinization temperature and peak viscosity. The thermal properties of the starch flour were not affected by air classification while gelatinization energy was decreased significantly (by 52.0 and 90.0% and by 70.0 and 95.0%) in cooked and popped A caudatus and A cruentus seed flours, respectively. The gelatinization energy was highest in germinated seeds dried at 90 °C with values of 2.67 and 3.87 J g^?1. Air classification reduced the level of all protein fractions. Thermal treatment decreased the water‐soluble fraction (albumins + globulins) and alcohol‐soluble fraction (prolamins) in both species. The levels of all fractions except the water‐soluble fraction (albumins + globulins) were reduced significantly in both species by germination, which mainly increased the amount of aspartic acid, serine and alanine, while the amounts of threonine, arginine and tyrosine decreased in both species. The polypeptide bands of the HPF in both species were unchanged compared with the raw seed flours, but more intensive coloured bands were observed. Thermal treatments eliminated major and minor bands above 35.0 KDa in both species. Copyright © 2004 Society of Chemical Industry     

Wet‐fractionation of Phaseolus lunatus seeds: partial characterization of starch and protein

The optimum extraction conditions for integral use of Phaseolus lunatus seed, in alkaline medium, are 1:6 (w/v) flour:water ratio, pH 11 and a 1 h extraction time. Three main fractions were produced under these conditions: starch; protein isolate and fibrous residue by‐product. The yield is 288.4 g kg^?1 starch, 188.2 g kg^?1 protein isolate and the remaining quantity, fibrous residue. The starch has 98.4% purity, a 75 °C gelatinization temperature and high syneresis even at high concentrations. It also has high viscosity, good stability and middle retrogradation during the heating–cooling cycle. The protein isolate contains 711.3 g kg^?1 protein as well as 75.5 g lysine kg^?1 protein, 10.1 g methionine kg^?1 protein and 12.2 g tryptophan kg^?1 protein. Its in vitro digestibility is 79% with a 2.5 c‐PER. The fibrous residue contains 63 g kg^?1 of protein, 328.4 g kg^?1 of crude fiber and 567.3 g kg^?1 of NFE. Copyright © 2004 Society of Chemical Industry     

Dependence of Thermodynamic Characteristics of Amylose‐Lipid Complex Dissociation on a Variety of Wheat

Native wheat starch contains amylose‐lipid complexes (AMLs) that are formed both upon biosynthesis of native starch and upon heating of starch slurries at gelatinization temperature and above. These complexes have a detrimental impact on physicochemical properties of starch, because they reduce water binding by starch granules and retard their swelling. An objective of the presented work was to analyze the chemical composition of wheat starch and characterize the thermodynamics of gelatinization of different wheat starches and to evaluate the stability of AMLs derived from these starches with the aid of differential scanning calorimetry (DSC). Grains of eight wheat varieties were used throughout the studies. The gelatinization behavior of the eight wheat varieties examined was similar. The lowest temperature of the onset of gelatinization (T_k = 57.07°C) was found for the Jawa variety, and the highest (T_k = 60.58°C) for the Torka variety. Enthalpy of gelatinization (ΔH_k) of the examined wheat starch preparations ranged from 9.14 J/g (Sakwa) to 11.95 J/g (Elena). Temperature and enthalpy of AMLs dissociation depended on wheat starch variety. During the first heating the temperature of the minimum of the endotherm (T_d) ranged from 98.41°C to 100.5°C. During the second heating, the minimum was at slightly higher temperatures, varying from 102.02°C to 104.08°C. Enthalpies of AML dissociation (ΔH_d) varied from 1.45 J/g to 2.14 J/g during the first heating. During the second heating the enthalpy values were slightly lower (1.26 J/g to 1.68 J/g). Enthalpies of AML reassociation ranged from 1.29 J/g to 1.72 J/g during the first cooling, and from 1.17 J/g to 1.63 J/g during the second cooling. A correlation was found between the amount of lipids and AML content.