共查询到18条相似文献,搜索用时 171 毫秒
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PVC/PE共混体系的研究—ELVALOY741,EVA对PVC/LLDPE共混物的增容作用 总被引:1,自引:0,他引:1
本文采用 ELvaloy741、EVA 作为 PVC/LLDPE 共混物的增容剂,用机械共混法制样,研究了增容剂含量对共混物的力学性能、熔体流动性能及相态结构的影响。实验结果表明,增容剂含量对共混物的上述三种性能影响呈现一定的规律性,增容剂含量适当,能不同程度地改善共混体系的力学和加工性能。 相似文献
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超支化聚(酰胺-酯)对聚丙烯/聚氯乙烯/苯乙烯-甲基丙烯酸甲酯共聚物接枝聚丙烯共混体系的增容作用 总被引:3,自引:2,他引:3
研究了超支化聚(酰胺-酯)(HBP))对聚丙烯/聚氯乙烯/苯乙烯-甲基丙烯酸甲酯共聚物接枝聚丙烯共混体系[PP/PVC/PP-g-(St-co-MMA)]的增容作用。讨论了HBP的用量对PP/PVC(80/20)共混物力学性能的影响;研究了剪切应力、剪切速率和温度对PP/PVC(80/20)共混物熔体黏度的影响。实验结果表明在PP/PVC/PP-g-(St-co-MMA)(80/20/6)共混物中加入1份HBP时,就可以很好改善共混体系的相容性,使共混物拉伸强度达到最大值,同时使熔体表观黏度达到较小值。该共混物熔体属于假塑性流体。扫描电子显微镜(SEM)研究结果证明了HBP增强了PP/PVC/PP-g-(St-co-MMA)的界面粘结作用,减小了共混体系的相分离程度。 相似文献
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CPVC/PVC/CPE三元共混改性的应用 总被引:6,自引:0,他引:6
研究了CPVC/PVC/CPE三元共混物的物理力学性能和流变性能。结果表明 :共混物的维卡软化温度、拉伸屈服强度和熔体粘度随CPVC用量的增加而明显增加 ;CPE的用量为 4~ 8份时可明显改善共混物的冲击强度 相似文献
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通过熔融共混法制备了聚乳酸(PLA)/乙烯-乙酸乙烯酯共聚物(EVA)共混物,采用SEM、DSC、旋转流变仪等研究了VA质量分数为28%,熔体流动速率(MFR)不同的EVA对PLA/EVA共混物性能的影响。结果表明,EVA熔体流动速率越小,其在PLA基体中分散越均匀,EVA颗粒粒径也越小。共混物的结晶度随EVA熔体流动速率的增大而增大,但PLA的玻璃化转变温度(Tg)基本不受EVA的影响。PLA/EVA共混物的复数黏度和储能模量均随EVA的熔体流动速率的增高而减小。力学性能测试结果表明,当EVA的质量分数为15%时,PLA的断裂伸长率明显升高,冲击强度约是纯PLA的2倍。 相似文献
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采用氯化聚乙烯(CPE)对氯化聚氯乙烯(PVC—C)进行抗冲改性,将改性后的PVC—C与PVC进行共混,研究了PVC-C/PVC配比对PVC-C/PVC共混物力学性能、耐热性能及流变形能的影响。结果表明,PVC—C/PVC共混物的维卡软化点随PVC—C的用量增加而上升,在50/50(质量比)处有一拐点,大于50/50时上升更快些。共混物的拉伸强度、弯曲强度和熔体黏度随PVC—C用量的增加而提高;混物中随PVC—C用量增加,塑化时间缩短,塑化能力增强,而冲击强度和断裂伸长率却随PVC—C用量增加而下降。共平衡转矩增加。 相似文献
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《国际聚合物材料杂志》2012,61(1):15-24
In this work, a polyhedral oligomeric silsesquioxane which contains 3-chloropropyl groups (CP-POSS) was synthesized. The rheological behavior of CP-POSS/PVC blends was investigated by torque rheometer and capillary rheometer. Mechanical properties were investigated by electronic material tester. Influences of blending composition, shear rate and shear stress on melt apparent viscosity and non-Newtonian index (n) were discussed. The results show that the plastic time decreases and melt viscosity increases with increasing content of CP-POSS. CP-POSS has a good compatibility with PVC. The blend has the best impact strength when the content of CP-POSS is 7 wt%. The CP-POSS can be used as a processing aid and impact-resistant aid for PVC. 相似文献
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通过熔融共混的方法分别制备了聚氯乙烯/邻苯二甲酸二辛酯/聚羟基烷酸酯(PVC/DOP/PHA)和PVC/PHA共混物。研究了PHA逐步代替DOP对共混物力学性能和熔体流动性能的影响规律,利用扫描电子显微镜对所制备的试样进行微观结构分析。结果表明,随着共混体系中PHA用量的增加和DOP的等量减少,与PVC/DOP共混物相比,PVC/DOP/PHA共混物的拉伸强度由21 MPa提高至42 MPa,断裂伸长率先增加而后降低,在PHA含量为10.7 %(质量分数,下同)时出现极大值(350 %);在PVC/PHA体系中,PHA含量增加,PVC/PHA共混物的力学性能及熔体流动速率都显著提高,说明PHA可以作为PVC的一种有效的绿色增塑剂和增韧剂。 相似文献
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Biju John K.T. Varughese Zachariah Oommen Sabu Thomas 《Polymer Engineering and Science》2010,50(4):665-676
The melt rheological behavior of high‐density polyethylene (HDPE)/ethylene vinyl acetate (EVA) blends has been examined with reference to the effect of blend ratio, shear stress, and temperature. The HDPE/EVA blends exhibit pseudoplastic behavior, and the observed rheological behavior of the blends was correlated with the extrudate morphology. The experimental values of the viscosity were compared with the theoretical models. The effect of maleic‐ and phenolic‐modified PE compatibilizers on the viscosity of H70 blend was analyzed and found that compatibilization did not significantly increase the viscosity. The effect of dynamic vulcanization and temperature on the viscosity was also analyzed. The activation energy of the system decreased with increase in EVA content in the system. The phase continuity and phase inversion points of the blends were theoretically predicted and compared with the experimental values. The melt flow index (MFI) values of the blends were also determined and found that the MFI values decreased with increase in EVA content in the system. POLYM. ENG. SCI., 2010. © 2009 Society of Plastics Engineers 相似文献
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Bharat Indu Chaudhary Elizabeth Takcs John Vlachopoulos 《Polymer Engineering and Science》2002,42(6):1359-1369
The objective of this work was to evaluate the effect of blending minor amounts of ethylene styrene Interpolymer or ethylene vinyl acetate (EVA) with polyethylene on cycle times and impact strength in rotational molding. The blends sintered significantly faster than polyethylene. The sintering rates were primarily influenced by the melting points of the minor blend components, and not by differences in melt viscosity and/or elasticity at low shear rate. Blending Interpolymer or EVA with polyethylene resulted in improved environmental stress crack resistance and decreased flexural modulus. In rotational molding, blending Interpolymer or EVA with polyethylene generally resulted in faster bubble removal, more uniform thickness and shorter cycle times. Ductile failure was generally observed at the peak mean failure energy (MFE). The blend containing Interpolymer yielded significantly increased MFE, possibly because the Interpolymer was compatible with polyethylene and was very well dispersed. 相似文献
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Studies have been made on the melt rheological properties of poly(vinyl chloride) (PVC) with copolymers of methyl methacrylate (MMA) and methyl acrylate (MA), ethyl acrylate (EA), butyl acrylate (BA), and 2-ethyl hexyl acrylate (EHA) at a blending ratio of 80:20. Effect of blend composition on shear stress–shear rate, melt viscosity, melt elasticity, and extrudate distortion have been studied. A significant decrease in the melt viscosity is observed on incorporation of low Tg, acrylate copolymers such as those with BA and EHA, thereby reducing the processing temperature. First normal stress and die swell ratio also decreases with an increase in the side chains of acrylate copolymer. PVC blended with P(MMA-co-BA) and P(MMA-co-EHA) is sensitive to both temperature and shear stress. 相似文献
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Blends from poly(vinyl chloride) (PVC) and epoxidized natural rubber (ENR) were prepared in a Brabender plasticorder by the melt blending technique. The melt flow behavior of these blends with respect to blend ratio and temperature has been examined using a melt flow indexer and capillary rheometer. ENR decreases the Brabender torque, increases the melt flow index (MFI), and decreases the melt viscosity of PVC in the blends. Arrhenius plots were used to study the effect of temperature on melt flow index (MFI) and viscosity. Moreover, the flow behavior index (n′) obtained from capillary rheometer data was found to be dependent on temperature and blend ratio. 相似文献
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通过熔融共混制备了聚乳酸(PLA)/聚丁二酸丁二醇酯(PBS)共混物,采用扫描电子显微镜、差示扫描量热仪、旋转流变仪对其相容性、热性能和黏度等进行了研究,并研究了PBS的加入对PLA力学性能的影响。结果表明,PLA和PBS之间是部分相容的,PBS的少量添加并不影响PLA的拉伸强度,且其冲击强度随着PBS含量的增加呈先上升后下降的趋势,当PBS含量为10份时,共混物的冲击强度最好;与纯PLA相比,共混物的黏度有所增加,且随着PBS含量的增加,共混物的黏度逐渐增大;PBS的添加起到异相成核作用,促进了PLA的结晶。 相似文献