Internal friction during martensitic transformation in high manganese Mn–Cu alloys

Low-frequency internal friction and elastic modulus were studied for manganese-rich Mn–Cu alloys in the temperature range of martensitic transformation (20–300 °C). It is shown that the some special features of the transformation peak and its temperature are caused by the degree of the spinodal decomposition. The phenomenological model connecting an-elastic effects with the stages of evolution of the structure during martensitic transformation in manganese-rich Mn–Cu alloys (tweed structure–“parquet” structure–classical twinning martensite) is presented.     

Characteristics of Ti–Ni–Pd shape memory alloy thin films

Ti–Ni–Pd thin films were deposited by RF magnetron sputtering. Microstructure and phase transformation behaviors were studied by X-ray diffraction (XRD), by transmission electron microscopy and by differential scanning calorimeter (DSC). Also tensile tests and the internal friction characteristics were examined. Annealing at 750 °C followed by subsequent annealing at 450 °C resulted in relatively homogeneous microstructure and uniform martensite/austenite transformation. The results from DSC showed clearly the martensitic transformation upon heating and cooling, the transformation temperatures are 112 °C (M* peak) and 91 °C (M peak), respectively. The transformation characteristics are also found in strain–temperature curves and internal friction–temperature curves. The film had shape memory effect. The frequency had no effect on the modulus, but the internal friction decreased with increasing frequency.     

The effects of trace Sc and Zr on microstructure and internal friction of Zn–Al eutectoid alloy

The damping properties of Zn–22 wt.% Al alloys without and with Sc (0.55 wt.%) and Zr (0.26 wt.%) were investigated. The internal friction of the determined by the microstructure has been measured in terms of logarithmic decrement (δ) using a low frequency inverted torsion pendulum over the temperature region of 10–230 °C. An internal friction peak was separately observed at about 218 °C in the Zn–Al alloy and at about 195 °C in Zn–Al–Sc–Zr alloy. The shift of the δ peak was found to be directly attributed to the precipitation of Al₃(Sc, Zr) phases from the alloy matrix. We consider that the both internal friction peak in the alloy originates from grain boundary (GB) relaxation, but the grain boundary relaxation can also be affected by Al–Sc–Zr intermetallics at the grain boundaries, which will impede grain boundary sliding. In addition, Al–Sc–Zr intermetallics at the grain boundaries can pin grain boundaries, and inhibit the growth of grains in aging, which increases the damping stability of Zn–22 wt.% Al alloy.     

Effect of temperature fluctuation on energy consumption and quality changes of palletized foods in frozen storage

Pallet lots of frozen okra, peas, and strawberries were stored at: −24°C consstant, ±1°C (−11°F constant); at −24°C (−11°F), but power shutdown overnight, −24°C to −18°C (−11°F to 0°F); at −21°C to −18°C (−6°F to 0°F); and at −18°C to −15°C (0°F to +5°F). The temperature increases in these small rooms were estimated to be similar to the worst conditions that might exist in commercial freezer warehouses. Diurnal fluctuations were much smaller within the packages, particularly in the densely filled products located in the centre of the lots. All three time-temperature indicators provided an approximate history of storage conditions.

Compared to storage at a constant −24°C (−11°F), shutting down power at night yielded 8% saving in energy consumption, which increased to 23% when temperature was brought down to −21°C (−6°F), and to near 30% when temperatures were reduced to −18°C (0°F) only. Weight losses increased from 0.28% in the first chamber to 0.68% in the last chamber. Pouches lost much less weight than cartons, and internal packages less than those on the edge of the lots. Frost formation (in-package desiccation) increased from −24°C to −18°C (11°F to 0°F), and was more severe in the pouches than in the cartons. Clumping was reduced in all treatments with storage time. Sensory quality changes and ascorbic acid were reduced similarly, but the poorest treatment, the last chamber, lost at most half a grade score and up to 10% ascorbic acid. Total solids showed little relation to treatments.

It was tentatively concluded, depending on energy cost and availability, that −20°C to −18°C (−4°F to 0°F), overnight, might be the optimal storage condition for cartons, while pouches might be economically stored at −18°C to −16°C (0°F to 3°F) if for no longer than 6 months.     

Anelastic relaxation peak associated with the presence of incoherent θ phase in Al-4wt.%Cu alloy

Internal friction measurements have been made for Al-4wt.%(1.76at.%)Cu alloy aged at various temperatures. A relaxation peak was observed at around 400 °C (ƒ = 1.6 Hz) after the speciment had been aged within the temperature range 330–450 °C. X-ray diffraction analysis showed that the incoherent θ phase is formed after aging within this temperature range and that it grows and becomes coarsened at increasing aging temperatures according to electron microscopy observations. Consequently the 400 °C internal friction peak observed for the first time is associated with the presence of θ phase in the alloy. Examination of the experimental results showed further that this peak is not due to a process occurring inside the θ phase but is associated with the stress-induced relaxation along phase boundaries between the θ particle and the matrix phase.

The activation energy of this peak is found to be 1.0 eV. The relaxation time and the relaxation strength of this peak calculated on the basis of an equivalent inclusion model are in accord with experimental results.     

Physical models for cleavage fracture at various temperatures—Bases for local approach to fracture of HSLA steel

The author proposes the critical events controlling cleavage at various temperatures: at a very low temperature (−196 °C), critical event is the nucleation of a crack in ferrite at the precrack tip. At a moderate low temperature (around −100 °C), the critical event is the propagation of a carbide crack into the ferrite grain. With increasing temperature (around DBTT −80 °C), the carbide crack eligible to propagate into the ferrite grain should be the one initiated by a critical strain higher than that to initiate a carbide crack at low temperatures. The higher critical strain increases the flow stress by work hardening for making up the effect of lowering yield stress. At a higher temperature (−30 °C) after the crack tip is blunted to more than 60 μm and a fibrous crack extends, the critical event for cleavage fracture is the propagation of a grain-sized crack.     

Interactions of hydrogen in copper studied by internal friction technique

Internal friction (IF) in electrochemically hydrogen-charged copper was studied in the temperature range of 80–500 K. A distinct peak of relaxation caused by hydrogen was observed in the vicinity of 130 K at the frequency of about 1 Hz. The observed peak has an enthalpy and pre-exponential factor of relaxation 0.28 eV and 4.6×10⁻¹³ s, respectively. Effects of copper microstructure and oxygen content on the hydrogen internal friction peak in copper were studied and discussed.     

Synthesis, growth and thermal and Fourier transform infrared spectral characterization of tetraethylammonium tetrachloro manganate (II) monohydrate crystals

Single crystals of a novel tetraethylammonium tetrachloro manganate (II) monohydrate (TEATC-Mn) were grown by slow evaporation solution technique at room temperature. These crystals belong to a class of interesting ferroelectric materials. The grown crystals were characterized through powder X-ray diffraction (XRD), thermogravimetry, differential thermal analysis (TG-DTA), differential scanning calorimetry (DSC) studies and Fourier transform infrared (FTIR) spectra. While the results of the elemental analysis of the compound agree with the stoichiometry, its crystallinity is confirmed by the powder X-ray diffraction pattern. The weight losses observed were suitably explained based on the formulated decomposition pattern. The differential thermal analysis of the compound conforms to the thermogravimetric study. The endothermic peak observed in the high temperature differential scanning calorimetry suggests the occurrence of a phase transition in the compound between 300 and 370 °C while the corresponding low temperature study shows thermal anomalies at −41.7, −51.7 and at −52.4 °C. This suggests the occurrence of both first and second order phase transitions. The characteristic absorptions in the FTIR spectrum further characterize the compound. Further investigations on the ferroelectric behaviour of the compound at low temperatures are in progress.     

Growth of lithium doped silver niobate single crystals and their piezoelectric properties

Lithium doped silver niobate (Ag_1−xLi_xNbO₃, 0 < x < 0.1) is one of the candidate materials for lead-free piezoelectric materials. In this study, Ag_1−xLi_xNbO₃ single crystals were successfully grown by a slow cooling method. Crystal structure was assigned to perovskite-type orthorhombic (monoclinic) phase. Dielectric properties were measured as a function of temperature. As a result, with increasing lithium contents, the phase transition at around 60 °C was shifted to lower temperature while the phase transition at around 400 °C was shifted to higher temperature. On the basis of these peak shifts, the lithium contents in Ag_1−xLi_xNbO₃ single crystals were determined. Moreover, P–E hysteresis measurement revealed that pure silver niobate crystal was weak ferroelectrics with P_r of 0.095 μC/cm² while Ag_0.9Li_0.1NbO₃ (ALN10) crystal was normal ferroelectrics with P_r of 10.68 μC/cm². About this ALN10 crystal, polling treatment was performed and finally piezoelectric properties were measured. As a result, high electromechanical coupling coefficient k₃₁ over 70% was observed.     

Study by resonant ultrasound spectroscopy of the elastic constants of the β phase in Cu---Al---Ni shape memory alloys

The evolution with temperature of the elastic constants of the metastable β phase in a Cu-27.96 at.%Al-3.62 at.% Ni shape memory alloy (SMA) has been studied by resonant ultrasound spectroscopy (RUS). The corresponding elastic constants of this cubic phase have been measured near the martensitic transformation temperature in a single crystal. Above the martensitic transformation temperature, an anomalous behavior has been found in the C′elastic constant which shows a softening as the temperature decreases. The internal friction value Q⁻¹ has been obtained in this temperature range from the RUS spectra. The mechanisms associated with the Q⁻¹ increase must be related to {1 1 0} shear.     

Temperature effects of PTFE diffusers

Poly(tetrafluoroethylene) (PTFE) is the most commonly used diffuser material in ultraviolet irradiance measurements. The temperature sensitivities of five PTFE diffusers were measured over a broad temperature range. The transmittance change varied from −0.015%/°C to −0.1%/°C. At 19 °C there was an unexpected abrupt change in transmittance ranging from 1% to 3%. This change is due to the change of the crystal structure of PTFE at 19 °C. Temperature sensitivity decreases significantly the accuracy of high precision measurements, especially if the temperature of the diffusers is not stabilized.     

First investigations on twin-rolled Zr59Cu20Al10Ni8Ti3 bulk amorphous alloy by mechanical spectroscopy

Zr₅₉Cu₂₀Al₁₀Ni₈Ti₃ is one among compositions of ZrCu-based alloys giving bulk amorphous material by cooling from the melt. Twin-roll casting enabling samples suitable for our inverted torsion pendulum has been processed in strips of about 0.60 mm thick.

Low temperature IF measurements have been conducted on a specimen from room temperature to −120 °C at different heating and cooling rates. IF spectra exhibit peaks at around −40 °C (cooling) and −10 °C (heating) which are sensitive to heating rates and to the number of cycle (heating and cooling). DSC measurements have also been performed to help interpret the phenomena linked to the IF peaks.     

Effect of strain rate on high-temperature low-cycle fatigue of 17-4 PH stainless steels

The effect of strain rate (10⁻², 10⁻³ and 10⁻⁴ s⁻¹) on the low-cycle fatigue (LCF) behavior was investigated for 17-4 PH stainless steels in three different conditions at temperatures of 300–500 °C. The cyclic stress response (CSR) for Condition A tested at 300 and 400 °C showed cyclic hardening due to an influence of dynamic strain aging (DSA). An in situ precipitation-hardening effect was found to be partially responsible for the cyclic hardening in Condition A at 400 °C. For H900 and H1150 conditions tested at 300 and 400 °C, the CSR exhibited a stable stress level before a fast drop in load indicating no cyclic hardening or softening. At 500 °C, cyclic softening was observed for all given material conditions because of a thermal dislocation recovery mechanism. The cyclic softening behavior in Conditions A and H900 tested at 500 °C is attributed partially to coarsening of the Cu-rich precipitates. The LCF life for each material condition, tested at a given temperature, decreased with decreasing strain rate as a result of an enhanced DSA effect. At all given testing conditions, transgranular cracking was the common fatigue fracture mode.     

Influence of steel heat treatment on ultrasonic absorption measured by laser ultrasonics

Laser ultrasonics is combined with the reverberation technique to measure ultrasound absorption during thermal cycles applied to medium-carbon steel samples. During heating to the austenitic phase, a small Snoek peak is observed around 360 °C at 10 MHz along with a signature of the ferromagnetic to paramagnetic transition near 768 °C. Upon cooling, the behavior of the internal friction is much different from that of heating: reduced high-temperature absorption, delayed phase transition, smaller magnetoelastic contribution and stronger Snoek peak are observed. The austenitizing temperature is found to have primary importance on the internal friction behavior during cooling. These measurements show that ultrasound absorption measurements using laser ultrasonics could serve as a basis for a technique to characterize the microstructure evolution of steel in various temperature ranges.     

Effect of negatively charged species on the growth behavior of silicon films in hot wire chemical vapor deposition

The deposition behavior of silicon in hot wire chemical vapor deposition was investigated, focusing on the generation of negatively charged species in the gas phase using a gas mixture of 20% SiH₄ and 80% H₂ at a 450 °C substrate temperature under a working pressure of 66.7 Pa. A negative current of 6–21 µA/cm² was measured on the substrate at all processing conditions, and its absolute value increased with increasing wire temperature in the range of 1400 °C–1900 °C. The surface roughness of the films deposited on the silicon wafers increased with increasing wire temperature in the range of 1510 °C–1800 °C. The film growth rate on the positively biased substrates (+ 100 V, + 200 V) was higher than that on the neutral (0 V) and negatively biased substrates (− 100 V, − 200 V, − 300 V). These results indicate that the negatively charged species are generated in the gas phase and contribute to deposition. The surface roughness evolved during deposition was attributed to the electrostatic interaction between these negatively charged species and the negatively charged growing surface.     

Equilibrium, kinetic and thermodynamic study of the biosorption of uranium onto Cystoseria indica algae

Biosorption equilibrium, kinetics and thermodynamics of binding of uranium ions to Cystoseria indica were studied in a batch system with respect to temperature and initial metal ion concentration. Algae biomass exhibited the highest uranium uptake capacity at 15 °C at an initial uranium ion concentration of 500 mg l⁻¹ and an initial pH of 4. Biosorption capacity increased from 198 to 233 mg g⁻¹ with an decrease in temperature from 45 to 15 °C at this initial uranium concentration. The Langmuir isotherm model were applied to experimental equilibrium data of uranium biosorption depending on temperature. Equilibrium data fitted very well to the Langmuir model C. indica algae in the studied concentration range of Uranium ions at all the temperatures studied. The saturation type kinetic model was applied to experimental data at different temperatures changing from 15 to 45 °C to describe the batch biosorption kinetics assuming that the external mass transfer limitations in the system can be neglected and biosorption is chemical sorption controlled. The activation energy of biosorption (E_A) was determined as −6.15 using the Arrhenius equation. Using the thermodynamic equilibrium coefficients obtained at different temperatures, the thermodynamic constants of biosorption (ΔG°, ΔH° and ΔS°) were also evaluated.     

III-Nitrides growth and AlGaN/GaN heterostructures on ferroelectric materials

The growth of III-nitrides on the ferroelectric materials lithium niobate (LN) and lithium tantalate (LT) via molecular beam epitaxy (MBE) using rf plasma source has been investigated. We have found that gallium nitride (GaN) epitaxial layers have a crystalline relationship with lithium niobate (tantalate) as follows: (0 0 0 1) GaN || (0 0 0 1) LN (LT) with [10−10] GaN || [11−20] LN (LT). The surface stability of LN and LT substrates has been monitored by in situ spectroscopic ellipsometry in the vacuum chamber. Three different temperature zones have been discerned; surface degas and loss of OH group (100–350 °C); surface segregation/accumulation of Li and O-species (400–700 °C); surface evaporation of O-species and Li desorption (over 750 °C). However, LT shows only surface degassing in the range of 100–800 °C. Therefore, congruent LN substrates were chemically unstable at the growth temperature of 550–650 °C, and therefore developed an additional phase of Li-deficient lithium niobate (LiNb₃O₈) along with lithium niobate (LiNbO₃), confirmed by X-ray diffraction. On the other hand, LT showed better chemical stability at these temperatures, with no additional phase development. The structural quality of GaN epitaxial layers has shown slight improvement on LT substrates over LN substrates, according to X-ray diffraction. Herein, we demonstrate AlGaN/GaN heterostructure devices on ferroelectric materials that will allow future development of multifunctional electrical and optical applications.     

Effect of dynamic strain ageing on the deformation behavior of Incoloy alloy MA956

Incoloy alloy MA956 is an oxide dispersion hardened ferritic stainless steel produced by powder metallurgy. It is used as a candidate material for the high temperature components of gas turbines. This material underwent dynamic strain ageing at 300–400°C and strain rate of 1.2 × 10⁻³ s⁻¹. The following features of dynamic strain aging were observed: serrated flow at 300 and 400°C, a peak in the ultimate tensile strength normalized by the elastic modules versus temperature curve at 400°C, a plateau in the 0.2% offset yield stress-temperature curve at 300–400°C, a peak in the deformation rate-temperature curve at 300°C and the elongation-temperature plot showed a minimum at 400°C associated with shear fracture and with a minimum in the reduction in area-temperature plot. These features of dynamic strain ageing were discussed in the view of the recent models of dynamic strain ageing. The effect of dynamic strain ageing on the deformation and fracture behavior of this material was discussed.     

Sintering kinetics of 8Y–cubic zirconia: Cation diffusion coefficient

Zirconia ceramics, mainly of cubic phase, are used in different applications because of their particular electrical and structural properties.

After the forming stage, sintering leads to a material with suitable microstructural characteristics. The sintering process mainly depends on thermal cycle and on starting particle size and its distribution; it also depends on density and the microstructure of green material. Cubic zirconia has a high (2680 °C) melting temperature; however, effective sintering could be observed for temperatures higher than 900 °C (nanoparticles), and it may reach a final density of 96–98% the theoretical value at relative low temperatures.

The objective of this paper is to study the sintering kinetics of stabilized zirconia in its cubic phase with 8% molar of Y₂O₃ under fast firing rates up to nearly isothermal conditions. Samples were shaped from suspensions dispersed with ammonium polyacrylate by slip casting. Sintering was performed in the temperature range between 1200 °C and 1400 °C. The sintering kinetic process was followed by measuring density as a function of time. A sintering model was applied to fit the experimental data of the first steps of densification. It was observed that sintering obeys the same mechanism in the temperature and time ranges under study, which results in an activation energy of 170 kJ mol⁻¹. Sintering is controlled by Zr cation diffusion, for which a lattice diffusion coefficient of D_l = 8 × 10⁻¹² cm² s⁻¹ at 1400 °C was found, and the activation energy of the diffusion process was 223 kJ mol⁻¹.     

Fracture behavior of 9% nickel high-strength steel at various temperatures: Part I. Tensile tests

Fracture behavior of a 9% nickel 1000 MPa grade high-strength steel was investigated with tensile tests at various temperatures. Four critical stresses were found, which determined the fracture behaviors at various temperatures. Various fracture behaviors could be classified into three categories: (1) at −196 °C, a longitudinal crack initiated from the center of the necking region and propagated along the tensile direction to the regions close to both ends of the necking, it then changed the orientation and developed into two transverse cracks which propagated into opposite directions on two separated cross-sections. (2) In the range of −30 °C to 20 °C, the fracture surfaces were composed of typical center-fibrous-initiation region, middle shear-radical region and outer shear-lip region. (3) In the range of −150 °C to −60 °C, the middle shear-radiation region showed a very rough pattern with several convex ridges. Fracture mechanisms were analyzed by combining various fracture morphologies with FEM-calculated results of stress and strain.