共查询到20条相似文献,搜索用时 876 毫秒
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在真空条件下采用高能球磨法以不锈钢粉末、钛粉和碳粉为原料制备了不锈钢-TiC超细复合粉末.X射线、扫描电子显微镜、比表面积评价等分析技术被用来对球磨过程中粉末的微观状态进行了分析.结果表明,随着球磨时间的增加,不锈钢复合粉末逐渐细化,用X射线衍射方法计算的最终晶粒可达到20nm.同时,钛粉和碳粉在球磨过程中发生反应形成TiC,可获得纳米级的不锈钢-TiC复合粉末. 相似文献
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为了获得具有良好微观组织的C-Cu复合粉末,以利于后续的压制、烧结和挤压等工艺,用机械球磨方法制备了3%C-Cu(质量分数)复合粉末.运用扫描电镜、背散射和X射线衍射等分析手段研究了该复合粉末的微观组织随球磨时间的演变规律.实验结果表明,随着机械球磨时间的增加,Cu颗粒由树枝状转变为层片状、块状,最后转变为近球形.球磨2 h,复合粉末中的石墨衍射峰消失.随着球磨的进行,复合粉末中Cu的微观应变逐渐增大.经3 h的机械球磨获得了晶粒尺寸约为20 nm的Cu纳米晶,说明该方法可以有效地细化晶粒组织. 相似文献
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《材料导报》2016,(Z2)
在不同球磨时间条件下,采用机械球磨方法制备TiB_2-Ni(Al)复合粉末,其中Ni粉和Al粉的物质的量比为1∶1,TiB_2陶瓷相含量为40%(体积分数)。采用扫描电子显微镜(SEM)以及X射线衍射仪(XRD)分析球磨后粉末的显微组织结构及物相,研究不同球磨时间对制备TiB_2-Ni(Al)复合粉末物相演变、组织结构的影响。研究结果表明,随着球磨时间的延长,延性金属Ni和Al变形程度逐渐增大,粉末中呈现Ni/Al交替混合组织结构,此种结构有利于金属在球磨过程中扩散形成Ni(Al)固溶体,且逐渐细化的TiB_2相嵌入至金属Ni和Al颗粒中。通过物相分析发现,随着球磨时间的延长,Al衍射峰强度逐渐降低,并发现在球磨时间为36h时形成Ni(Al)固溶体。 相似文献
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何叶易双萍陈其猛赵渺 《材料工程》2009,(S1):188-191
在常温常压环境下,采用食品添加剂卡拉胶为助磨剂,用机械球磨方法制备纳米Fe/卡拉胶复合粉末。采用正交试验法对高能球磨制备的复合粉末的工艺参数进行了研究,并利用X射线衍射(XRD)和扫描电镜(SEM)等测试分析手段,对球磨后的复合粉末相结构、组织形貌、颗粒大小的变化进行了研究。结果表明:以卡拉胶为助磨剂机械球磨后的纳米复合粉末粒度小、纯度高、稳定性好;随着球料比增加,粉末颗粒尺寸减小;随着球磨时间的增加,粉末颗粒尺寸减小。 相似文献
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Synthesis and Characterizations of Nanocrystalline WC-Co Composite Powders by a Unique Ball Milling Process 总被引:2,自引:0,他引:2
Jun SHEN Jianfei SUN Faming ZHANGSchool of Materials Science Engineering Harbin Institute of Technology Harbin China 《材料科学技术学报》2004,20(1):7-10
In order to explore the high efficiency of fabricating nanocrystalline WC-Co composite powders, this paper presented a unique high energy ball milling process with variable rotation rate and repeatious circulation, by which nanocrystalline WC-10Co-0.8VC-0.2Cr3C2 (wt pct) composite powders with mean grain size of 25 nm were prepared in 32 min, and the quantity of the powders for a batch was as much as 800 grams. The as-prepared powders were analyzed and characterized by chemical analysis, X-ray diffraction (XRD), transmission electron microscopy (TEM) and differential thermal analysis (DTA). The results show that high energy ball milling with variable rotation rates and repeatious circulation could be used to produce nanocrystalline WC-Co powder composites with high efficiency. The compositions of the powders meet its specifications with low impurity content. The mean grain size decreases, lattice distortion and system energy increase with increasing the milling time. The morphology of nanocrystalline WC 相似文献
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Mechanical alloying is a suitable method for producing copper based composites. Cu–TiO2 composite was fabricated using high energy ball milling and conventional consolidation. Ball milling was performed at different milling durations (0–24 h) to investigate the effects of the milling time on the formation and properties of produced nanostructured Cu–TiO2 composites. The amount of the TiO2 in the final composition of the composite assumed to be 0, 1, 3, 5 and 7 wt%. The milled composite powders were characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy to investigate the effects of the milling time on the formation of the composite and its properties. Also hardness, density and electrical conductivity of the sintered specimen were measured. High energy ball milling causes a high density of defects in the powders. Thus the Cu crystallite size decreases, generally to less than 50 nm. The maximum hardness value (105 HV) of the sintered compacts belongs to Cu–5 wt%TiO2 which has been milled for 12 h. 相似文献
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1. IntroductionCu-Fe ajloys are potential candidate materials foruse as bearings, bushes and other atifriction components. They are also being considered for manywide ranging applications such as automotive components, fferelitial geajrs for garden tractors, pistonrings for small bore engines, camshaft drive sprockets,and pressure plates for steering systems[1]. However,the near total immiscibility of Cu and Fe in the phasediagram pose a major limitation to the preparation ofthese alloys by c… 相似文献
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Microelectronic circuits require contact with a high thermal conductivity, and controlled low coefficients of thermal expansion packaging materials for the high performance and reliability of the semiconductor chips. The present study was carried out to investigate the microstructural and chemical properties of AlN-Cu nanocomposite powders created by planetary ball milling. X-ray diffraction and scanning electron microscopy analysis of the obtained powders were performed. The residual oxygen and carbon in ball milled AlN-Cu powders were analyzed. AlN-Cu composite powders of 15 μm size and copper crystallites of 25 nm were obtained after milling for 8 h. The amount of residual oxygen was considerably reduced after exposure to hydrogen reduction treatment at 600°C for 2 h. More significantly, 97% of the residual carbon was removed regardless of milling time and alloy composition. Furthermore, residual carbon was removed as a gaseous mixture of carbon monoxide and carbon dioxide. 相似文献
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The influence of milling time on the structure, morphology and thermal stability of multi-walled carbon nanotubes (MWCNTs) reinforced EN AW6082 aluminum alloy powders has been studied. After structural and microstructural characterization of the mechanically milled powders micro- and nano-hardness of the composite powder particles were evaluated. The morphological and X-ray diffraction studies on the milled powders revealed that the carbon nanotubes (CNTs) were uniformly distributed and embedded within the aluminum matrix. No reaction products were detected even after long milling up to 50 h. Nanotubes became shorter in length as they fractured under the impact and shearing action during the milling process. A high hardness of about 436 ± 52 HV is achieved for the milled powders, due to the addition of MWCNTs, after milling for 50 h. The increased elastic modulus and nanohardness can be attributed to the finer grain size evolved during high energy ball milling and to the uniform distribution of hard CNTs in the Al-alloy matrix. The hardness values of the composite as well as the matrix alloy compares well with that predicted by the Hall–Petch relationship. 相似文献
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《Advanced Powder Technology》2021,32(10):3826-3844
Mechanical milling presents an effective solution in producing a homogenous structure for composites. The present study focused on the production of 0.5 wt% yttria nanoparticle reinforced 7075 aluminum alloy composite in order to examine the effects of yttria dispersion and interfacial bonding by ball milling technique. The 7075 aluminum alloy powders and yttria were mechanically alloyed with different milling times. The milled composites powders were then consolidated with the help of hot pressing. Hardness, density, and tensile tests were carried out for characterizing the mechanical properties of the composite. The milled powder and the microstructural evolution of the composites were analyzed utilizing scanning and transmission electron microscopy. A striking enhancement of 164% and 90% in hardness and ultimate tensile strength, respectively, were found compared with the reference 7075 aluminum alloy fabricated with the same producing history. The origins of the observed increase in hardness and strength were discussed within the strengthening mechanisms' framework. 相似文献
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MoSi2?CSiC nanocomposite powders were successfully synthesized by ball milling Mo, Si and graphite elemental powders. Effects of milling time and annealing temperature were also investigated. The composite formation and phase transformation were monitored by X-ray diffraction. The microstructure of milled powders was studied by SEM, TEM and XRD peak profile analysis. Formation of this composite was completed after 10 and 20?h of milling for 25%SiC and 50%SiC, respectively. High temperature polymorph (HTP) of MoSi2 was obtained at the end of milling (20?h). On the other hand, annealing led to transformation of HTP to low temperature polymorph (LTP) of MoSi2. Mo5Si3 was formed during annealing as a product of a reaction between MoSi2 and excess graphite. Mean grain size <50?nm was obtained for 20?h milled sample on the basis of peak profile analysis and TEM images. 相似文献