微束等离子喷涂NiCrBSi涂层

采用微束等离子喷涂方法在St37低碳钢上制备了NiCrBSi涂层.研究了基材温度、等离子气体流量、喷涂距离和电流强度等工艺参数对涂层组织结构和性能的影响.采用光学显微镜观察涂层的组织结构,用Perthometers M4P 150测定涂层的表面粗糙度,以及用LECO TC316气体抽提仪检测涂层的氧含量.结果表明,在试验条件下,喷涂参数对涂层组织和性能产生较大的影响.随着电流和基材温度的增加涂层的粗糙度降低,涂层的氧含量随着基材温度和喷涂距离的增加而增加.大多数涂层的显微硬度大于600 HV0.2.尽管粒子速度较低,涂层的平均结合强度仍然大于50 MPa.     

大气等离子喷涂锆酸镧热障涂层

利用自制的稀土元素复合掺杂锆酸镧热喷涂粉末,采用大气等离子喷涂技术,在镍基高温合金表面制备La1.6Nd0.4Ce1.0Zr1.0O7(LNCZ)热障涂层,研究了喷涂参数对涂层沉积率、显微结构、结合强度及抗热震性能的影响。结果表明,增大喷涂功率,降低送粉速率可以有效地提高涂层的沉积率,但对涂层结合和抗热震性能不利。减小喷涂距离不仅提高沉积率,还有利于获得孔径细小、孔隙率适中的层状组织结构,该结构对提高涂层的抗热震性能极为有利。采用DH-1080大气等离子喷涂设备制备LNCZ涂层较好的喷涂条件为:功率40 kW,喷涂距离9 cm,送粉速率12 g/min。     

超音速大气等离子喷涂TiB2−SiC涂层的制备与性能

将喷雾造粒制备的TiB2?SiC粉末进行真空煅烧,采用超音速大气等离子喷涂制备TiB2?SiC涂层,研究喷涂功率和喷涂距离对TiB2?SiC涂层性能的影响,并对超音速等离子喷涂制备TiB2?SiC涂层的工艺进行优化。结果表明:煅烧后的喷涂粉末粒径分布均匀,球形度良好,流动性增强。煅烧粉末制备的涂层结构致密、沉积效率高。当采用超音速等离子喷涂煅烧后的TiB2?SiC粉末、喷涂功率为95 kW、喷涂距离为150 mm时,制备的TiB2?SiC涂层综合性能最好:孔隙率为5.6%,显微硬度为3.57 GPa,结合强度为18.3 MPa,电阻率为10.8 mΩ·cm。     

喷涂距离对冷喷涂Al涂层性能的影响

采用冷喷涂法制备Al涂层,测定所获涂层的沉积率、显微硬度,并分析涂层与基体的结合情况,研究了喷涂距离对Al涂层的影响。结果表明,喷涂距离为30 mm时涂层的沉积率及显微硬度较高,与基体结合效果较好,而其他距离下涂层性能劣化的原因为颗粒下降速度不稳或发生粒子散射。     

等离子喷涂钼涂层的工艺性能研究

在45钢基材上用等离子喷涂方法制备纯钼涂层,对不同工艺参数下制得的涂层进行了性能、SEM分析.结果表明,涂层的工艺性能与喷涂工艺参数有密切关系.不同喷涂电流下,涂层的显微硬度与涂层孔隙率成反比例关系,而孔隙率又是随电流的增大先增加后减小的.工作气体的流量在25～45L/min时,喷涂粉末沉积效率最高.送粉量过大则气孔率增大,降低了涂层之间的粘结强度和涂层的显微硬度;过小则粉末沉积效率降低.     

超音速等离子喷涂工艺对纳米Al_2O_3-13%TiO_2涂层的影响

采用四因素三水平正交试验,通过显微硬度和孔隙率两项指标的评估,对超音速等离子喷涂电流、电压、Ar气流量和喷涂距离4个工艺参数进行了优化设计。结果表明,4个因素对纳米Al2O3-13%TiO2涂层综合性能的影响主次顺序是:喷涂电压、Ar气流量、喷涂距离、喷涂电流,并最终确定了最优的喷涂参数。利用XRD、SEM等手段分析了纳米Al2O3-13%TiO2复合粉末和涂层的相结构和微观结构,采用显微硬度计和图像处理方法测定了涂层的显微硬度和孔隙率。最优工艺参数制备的涂层显微硬度值1208 HV,孔隙率为2.26%,拉伸法测定其结合强度为48 MPa。     

等离子喷涂WC-Ni涂层的组织结构及力学性能

采用等离子喷涂技术在不同的喷涂工艺条件下制备WC-Ni涂层。采用X射线衍射(XRD)和扫描电镜(SEM)表征和观察涂层的相结构和显微组织,同时运用压痕法对涂层的显微硬度、弹性模量和断裂韧性进行测试。结果表明,等离子喷涂工艺参数对涂层的组织结构和相结构有显著影响,等离子喷涂功率增加,粒子的熔化程度增加,适当的喷涂距离下沉积形成的涂层致密;等离子功率增加,喷涂过程中会产生WC粒子的失碳,相对于W_2C相,WC_(1-x)相的增加可以同时提高涂层的显微硬度和断裂韧性;与涂层的相组成相比,致密的组织结构对涂层显微硬度、弹性模量和断裂韧性的综合性能的提高更显著。     

等离子喷涂TiO2基涂层工艺参数优化研究

目的对TiO_2基涂层的等离子喷涂工艺参数进行优化。方法采用正交实验、基材温度采集并结合涂层微观形貌分析、能谱分析、结合强度试验、显微硬度测试等方法,研究了喷涂电流、喷涂距离、主气流量对涂层组织及性能的影响规律,并获得了优化的喷涂工艺参数。结果涂层分熔融区和部分熔融区,呈现双模结构的混合微观结构特征,截面形貌凹凸不平,并以机械结合为主。拉断后,涂层断裂面呈韧窝状,由陶瓷层到粘结层呈台阶状过渡,陶瓷层整体的内聚结合强度优于陶瓷层与粘结层结合界面的结合强度。涂层条带状夹杂随着粉末流到达基板的温度的增加而减少,对结合强度影响不显著,但对硬度影响较显著。等离子喷涂过程中,粉末流到达基板的温度在一定范围内时,涂层性能随着粉末流到达基板的温度的增加而增加,但粉末流到达基板的温度过大,涂层性能降低。结论获得最优涂层必须采用最优工艺参数,工艺参数对涂层综合性能的影响主次顺序为喷涂电流、喷涂距离、主气流量,得到的优化工艺参数为:喷涂电流350 A,喷涂距离110 mm,主气流量2100 L/h。     

Cr_3C_2-NiCr涂层等离子喷涂工艺参数的优化

采用正交试验方法研究了等离子喷涂工艺参数对Cr_3C_2-NiCr涂层显微硬度的影响,并应用极差分析方法对试验结果进行了分析.结果表明,影响涂层性能的因素从主到次依次为喷涂距离、电流、送粉气流量和电压.Cr_3C_2-NiCr涂层最佳的等离子喷涂工艺参数是电流500 A,电压65 V,喷涂距离100 mm,送粉气流量7 L/min.采用优化后的等离子喷涂工艺制备的涂层,粒子熔化充分,涂层均匀致密,孔隙率低,界面结合良好,是高质量的热喷涂涂层.     

金属喷涂、堆焊与修复——金属喷涂工艺与设备

富氧条件下电弧喷涂反应合成纳米氧化铝粉末;高速电弧喷涂FeCrNi／CBN复合涂层的组织与性能;含碳化物陶瓷粉芯丝材电弧喷涂层的结构和性能;应用于反应釜的超音速电弧喷涂涂层的耐蚀性;高速电弧喷涂涂层的结合强度与结合方式研究;等离子喷涂纳米团聚体粉末的熔化特性研究;等离子熔覆铁基涂层开裂行为研究。     

电弧喷涂制备铁基耐磨陶瓷涂层的工艺优化

采用电弧喷涂方法在Q235钢基体上喷涂铁基涂层,并用正交设计的方法对工艺参数进行了优化。确定优化后的工艺参数为:喷涂电流180A,喷涂电压32V,雾化空气压力0.6MPa,喷涂距离100mm。试验结果表明:采用优化后的最优工艺参数进行喷涂,所得涂层的耐磨性为Q235钢的13.7倍。     

Effect of spraying distance on the microstructure and mechanical properties of a Colmonoy 88 alloy deposited by HVOF thermal spraying

The present work has been conducted in order to determine systematically the influence of the spraying distance on the microstructure and mechanical properties of a Colmonoy 88 alloy deposited by means of HVOF thermal spray onto a SAE 1045 steel substrate. The spray distance varied between 380-470 mm and the evaluation of the deposits characteristics and properties was carried out both on their surface and on cross section. Both hardness and elastic modulus of the coatings were determined according to the model of Oliver and Pharr. The yield strength of the coatings was also estimated following the methodology developed by Zeng and Chiu for the analysis of the loading and unloading curves obtained from nanoindentation experiments, as well as from classical static spherical indentation tests. The microstructural analysis indicated a significant increase in the unmelted particles volume fraction and the development of interlamellar microcracks as the spraying distance increases, leading to a decrease in the elastic modulus of the coatings. Both hardness and elastic modulus showed an anisotropic behavior and were found to be higher on the cross section of the coating than on the deposition plane. A satisfactory comparison between the predicted and experimental values of the coatings yield strength was observed for all the conditions investigated.     

Low conductivity plasma sprayed thermal barrier coating using hollow psz spheres: Correlation between thermophysical properties and microstructure

Life and thermal properties of plasma sprayed TBCs - widely used in gas turbine engines - are closely related to the microstructure of the ceramic top coating. Especially, the thermal behaviour of this coating is induced by the void shapes and networks which are in turn determined by both the spraying conditions and the feedstock material.A specific hollow yttria partially stabilised zirconia powder was produced in a one-step process by spray drying and an experimental statistical design study was conducted to investigate the influence of spraying variables (primary and secondary gas flow rates, arc current, spraying distance, spraying angle and traverse speed) on structure and properties of resulting plasma sprayed coatings. The coatings were characterized with respect to deposition efficiency, roughness, porosity and thermal conductivity. A reduction of 25% of the thermal conductivity was achieved by improving the spray and powder parameters. A quantitative characterization of the porous structure using image analysis of polished cross-sections was implemented. The parameters that have relevant influence on the coating porous structure were identified, and their relative importance was determined. An attempt was made to identify morphological criteria of the porous network (coarse/fine porosity ratio, cracks total length, cracks orientation) correlating with the thermal conductivity values.     

喷涂工艺参数对硅灰石涂层结构的影响

采用等离子喷涂方法,在不同喷涂距离、主气流量和喷涂功率下制备硅灰石涂层.使用扫描电镜观察了涂层的微观形貌,研究了喷涂工艺参数对涂层结构的影响.结果表明,在较大主气流量下,随着喷涂距离增加,涂层粒子扁平化程度降低,涂层内孔隙逐渐增多;在较小主气流量下,涂层粒子扁平化程度随喷涂距离增加呈现先增加后减小的趋势.主气流量增加,涂层致密,粒子扁平充分.喷涂功率增加,粒子熔化好,涂层致密;但随喷涂功率进一步增加,涂层中出现较多的圆形孔隙.喷涂工艺参数对涂层结构的影响主要通过影响熔融粒子的温度和速度所致.     

超音速等离子喷涂工艺参数对AlSi20%Al/Ni涂层结合强度的影响

为使AlSi-20%Al/Ni超音速等离子喷涂涂层获得优良的结合性能,采用正交实验法研究了喷涂距离、喷涂电压、喷涂电流等喷涂工艺参数对结合强度的影响。利用X射线衍射、扫描电镜等手段对涂层的相组成和断口形貌进行分析,利用WDW-E100D微机控制式万能拉伸试验机对涂层结合强度进行测试。结果表明:涂层由AlSi和AlNi两相组成,影响AlSi-20%Al/Ni涂层结合强度工艺参数的主次顺序为喷涂距离、喷涂电压、喷涂电流,优化后的工艺参数为主气流量3.2m3/h,喷涂电流为380A,喷涂电压为130V,喷涂距离为90mm,在此参数下制备的涂层组织致密,其结合强度为65.5MPa。     

HVOF喷涂Cr3C2-NiCr涂层的磨粒磨损性能

探讨了氧气流量、燃气流量和喷涂距离三个喷涂工艺参数对ＨＶＯＦ喷涂Ｃｒ３Ｃ２－ＮｉＣｒ涂层硬度和磨粒磨损性能的影响。结果表明,燃气流量、氧气流量和喷涂距离对涂层的显微硬度和磨粒磨损性能的规律有所不同。在较高的燃气流量、适中的氧气流量和喷涂距离条件下,涂层具有较高的显微硬度;而氧气流量和燃气流量对涂层的磨粒磨损性能影响较大,适中的燃气流量条件下,涂层的磨粒磨损失重量较低,高的氧气流量条件下,磨损失重量     

喷距对低温超音速火焰喷涂钛涂层显微结构与性能的影响

目的分析喷距对钛涂层显微结构和性能的影响。方法采用低温超音速火焰喷涂工艺,在不同的喷距下制备钛涂层,分析钛涂层的显微组织、相结构及显微硬度,探讨涂层受喷距影响的机制。结果低温超音速火焰喷涂钛涂层的表面粗糙度较高,涂层的孔隙率随喷距的增加呈先减小、后增大的趋势,当喷距为150 mm时,涂层的孔隙率最小。钛涂层没有发生明显的氧化,粒子主要以固态形式沉积。结论当喷距为150 mm时,粒子在焰流中加热较为充分,同时具有较高的飞行速度,粒子的扁平化程度高,因此涂层具有较高的致密度。     

Effects of power level on characteristics of vacuum plasma sprayed hydroxyapatite coating

In this study, hydroxyapatite coatings were obtained with a vacuum plasma spray system at different power levels that were achieved by altering the plasma current and voltage. The effects of spray power level on coating characteristics were investigated. X-ray diffraction was used to identify the crystallinities of as-sprayed coatings, Electron Probe Microanalysis was employed to detect the surface chemical composition of as-sprayed coatings and Scanning Electron Microscopy revealed the microstructure. The results indicated that spray power greatly affected the crystallinity, chemical composition, and microstructure of as-sprayed hydroxyapatite coatings, which were linked to the melting state of hydroxyapatite powder. Presently at School of Materials Science and Engineering, Shanghai Jiaotong University, 1954 Huashan Road, Shanghai 200030, Republic of China.     

电弧及高速电弧喷涂FeCrAl涂层的微观性能研究

用相同的喷砂和喷涂工艺参数,分别在４５＾＃钢基体上制备了电弧喷涂与高速电弧喷涂ＦｅＣｒＡｌ涂层,用扫描电镜分析了它们的表面形貌,测试分析了两种涂层及各种基体在距涂层－基体界面不同距离上的显微硬度值,得到了电弧喷涂及高速电弧喷涂基体上的热影响区宽度,讨论了涂层的显微组织对其硬度的影响,并测试分析了涂层和基体的截面线波动系数。试验结果表明,高速电弧喷涂ＦｅＣｒＡｌ涂层比普通电弧喷涂ＦｅＣｒＡｌ涂人有更