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报道了用硫酸铜及硫代硫酸钠从含碘废液中提取碘的工艺,碘的回收率>92%,纯度>99.5%,铜的回收率可达97.5%。 相似文献
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《中国石油和化工标准与质量》2017,(1)
活测定脱硫液中溶解硫化氢含量采用方法Q/SY LS 1503-2009《脱硫液中溶解硫化氢含量的测定(碘量法)》。碘量法的原理是根据脱硫剂吸收硫化氢后会生成相应的盐类,在弱酸性介质中,硫(S2-)被碘(I2)氧化;而过剩的碘用硫代硫酸钠滴定。其反应式如下:S~(2-)+2I_2(过量)→S+2I~-+I_2(剩余)I_2+2Na_2S_2O_3→NaI+Na_2S_4O_6,分析方法Q/SY LS 1503-2009《脱硫液中溶解硫化氢含量的测定(碘量法)》中要求:当硫化氢含量3000mg/L时,同一样品重复测定两个结果之差应≦500mg/L。但在实际分析工程中,经常无法满足这一要求。因此本文进行了研究分析。 相似文献
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Giddappa Nagendrappa S. Subramanya Raj Urs S. Rajalakshmi 《Journal of the American Oil Chemists' Society》1998,75(12):1219-1221
Chloramine T (N-chloro-p-toluenesulfonamide sodium salt) and iodine (2:1, w/w) in carbon tetrachloride and acetic acid (1:1, vol/vol), referred to
as reagent (I) was found to be effective for the determination of Iodine value of edible oils. Reagent (I) reacted quantitatively
with the double bonds of oils of known weight. The reagent left unreacted after 20–25 min was titrated against standard sodium
thiosulfate solution (0.04 M) in presence of potassium iodide (10%, 5 mL). The difference in volume of sodium thiosulfate
solution consumed by reagent (I) without and with oil was a basis to calculate the iodine value of oils used. The iodine values
of different oils were also determined separately following the standard procedure of Wijs, and calculated iodine value was
obtained from the gas chromatographic profile of fatty acids. The iodine value obtained by the new method was in agreement
with the results of the standard methods. The results obtained indicate that the method could be a complementary or an alternative
to the Wijs method. 相似文献
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Giddappa Nagendrappa S. Subramanya Raj Urs S. Rajalakshmi 《Journal of the American Oil Chemists' Society》1998,75(9):1219-1221
Chloramine T (N-chloro-p-toluenesulfonamide sodium salt) and iodine (2:1, w/w) in carbon tetrachloride and acetic acid (1:1, vol/vol), referred to
as reagent (I) was found to be effective for the determination of Iodine value of edible oils. Reagent (I) reacted quantitatively
with the double bonds of oils of known weight. The reagent left unreacted after 20–25 min was titrated against standard sodium
thiosulfate solution (0.04 M) in presence of potassium iodide (10%, 5 mL). The difference in volume of sodium thiosulfate
solution consumed by reagent (I) without and with oil was a basis to calculate the iodine value of oils used. The iodine values
of different oils were also determined separately following the standard procedure of Wijs, and calculated iodine value was
obtained from the gas chromatographic profile of fatty acids. The iodine value obtained by the new method was in agreement
with the results of the standard methods. The results obtained indicate that the method could be a complementary or an alternative
to the Wijs method. 相似文献
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The effect of sodium thiosulfate on the graft copolymerization of methyl methacrylate to cellulose in the hydrogen peroxide initiator system was investigated. The addition of sodium thiosulfate in general was effective for decreasing the per cent grafting and the average molecular weight of grafts and increasing the formation of homopolymer, and the effects became pronounced with increasing hydrogen peroxide concentration. Moreover, the addition of sodium thiosulfate slightly suppressed the formation of grafts at a hydrogen peroxide concentration of 3 mmole/l., but greatly promoted it at 20 mmole/l. Traces of metallic ions present in cellulose could not be eliminated sufficiently by treatment with 3N hydrochloric acid. Such ions were found to interact with hydrogen peroxide and thus participate directly in the initiation and termination of the polymerization reaction. EDTA, the chelating agent, was highly effective for suppressing such participation of metallic ions. In the hydrogen peroxide initiator system applied to the EDTA-treated samples, sodium thiosulfate caused an effective initiation of graft formation. 相似文献
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过氧化二异丙苯(DCP)是强氧化剂,用其强氧化性质将饱和碘化钾溶液中的碘离子还原为碘,在样品中加入碳酸氢钠和浓盐酸,在低温(65℃)条件下使碳酸氢钠和浓盐酸反应生成二氧化碳形成保护气体,防止碘升华与空气中的氧反应而造成测定误差,在酸性条件下以淀粉作指示剂,用硫代硫酸钠标准溶液滴定反应生成的碘,以此方法测定过氧化二异丙苯(DCP)的含量,在实际工作中可操作性较强、精密度和准确度高、方法操作简单且重现性较好、抗干扰能力强,完全能够满足容量分析方法中规定的2个平行测定结果误差不大于0.2%的要求。 相似文献
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Potassium iodate–initiated polymerization of aniline was carried out in an acidified aqueous medium in the presence and in the absence of sodium thiosulfate salt. The nature of the polyaniline (PANI) produced depended on the aniline/potassium iodate (A/PI) mole ratio. Green emeraldine salt (ES) and blue pernigraniline salt (PS) were produced at A/PI mole ratios greater than 2 and less than 2, respectively. The sodium thiosulfate salt played a significant role in the purification and properties of PANI. The optimum aniline‐to‐oxidant mole ratio was found to be 2 : 1. Spectral, thermal, and electrical characteristics and viscosity of the materials were studied and compared with the results. A reaction scheme has been proposed to elucidate the role of iodine(V). Sodium thiosulfate makes it easier for iodine to be separated from a system and increases the conductivity of the products. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 1626–1631, 2007 相似文献
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将氢化腈类橡胶( HNBR) HNBR试样溶于氯仿中,加入过量的Wijs’试剂后,静置适当的时间(2 h)使其与HNBR中的残留不饱和物反应完全.然后用碘化钾还原过量的Wijs’试剂,最后用硫代硫酸钠标准滴定溶液滴定溶液中的游离碘,计算碘值(不饱和度). 相似文献
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The free iodine in Wijs solution is titrated directly, in strong hydrochloric acid solution, with standard potassium iodate
solution. From this titration and the usual sodium thiosulfate titration for total halogen, the iodine/chlorine ratio is calculated.
Results agree closely with those obtained by the longer chlorine-water method of Lopes. The halogen ratio of reagent grade
iodine monochloride, a convenient material from which to prepare Wijs reagent directly, is also determined by the new titration
method. 相似文献
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The adsorption of iodine on chitosan was studied by physico-chemical methods. The scanning electron micrograph measurements of chitosan-iodine adducts showed that iodine molecules were adsorbed uniformly on the chitosan film when the film was treated with aqueous iodine-potassium iodide solution. The thermogravimetric analysis of the adducts revealed that the loss in weight began at about 190°C, and that iodine molecules were thus well-complexed with chitosan. It was also found that the IR spectra of the chitosan films showed the amide I and amide II bands shifted to lower frequencies due to the iodine adsorption. The X-ray diffractometry of these adducts was further carried out, and it was found that the iodine adsorbed chitosan showed no crystalline pattern, different from that of the original chitosan which showed crystallinity in some extent. The chitosan recovered after desorbing iodine by immersion in aqueous sodium thiosulfate solution was amorphous. 相似文献
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