Chemical change from diffused hydrogen gas to hydroxyl ion in silica glass optical fibres

The chemical change from hydrogen gas that diffuses into silica glass for optical fibres to hydroxyl function has been investigated. Hydrogen molecules that diffuse into GeO2-doped silica glass at 500°C easily change into OH ions by thermal energy, while this chemical change does not occur in pure silica glass at 500°C. Also, germanium-doped silica fibre, in which hydrogen gas is dissolved at room temperature, shows OH ion absorption loss increase with chemical change by heat treatment at above 100°C, while pure silica core fibre shows no OH ion absorption loss increase by the same treatment.     

Dopant effect on transmission loss increase due to hydrogen permeation

The transmission loss increase due to hydrogen permeation in a GeO2-doped silica fibre and a P2O5-doped silica fibre are investigated. As a result, the difference of the loss increase between them is observed, and is considered to be due to the difference of the electronegativity between silica, germanium and phosphorus.     

Low-Loss single-mode fibre at the material-dispersion-free wavelength of 1.27 ?m

A GeO2-doped silica single-mode optical fibre with a low attenuation loss of 0.5 dB/km at 1.27 ?m, where the material dispersion of the silica glass falls to zero, has been made by a C.V.D. technique. Attention was paid to reducing OH absorption losses in the single-mode fibre.     

光纤中的多级斯托克斯及反斯托克斯谱线

本文叙述在多模光纤中产生的多级受激拉曼散射谱，作了两种不同掺杂的SiO2光纤中的受激拉曼散射谱。对掺锗硅光纤得到16级斯托克斯线及10级反斯托克斯线。对掺磁硅光纤获得了13级斯托克斯线及4～5级斯托克斯线。测出了各级谱线的峰值波长及相对强度分布，并作了简单讨论。     

Low-loss high-numerical-aperture optical fibre fabricated by v.a.d. method

Low-loss high-numerical-aperture optical fibres, consisting of GeO2/P2O5-doped silica core and silica cladding, have been made by the v.a.d. method. The minimum transmission loss of the fibre with an n.a. 0.32 was 0.8 dB/km at 1.55 ?m.     

La_2O_3-SnO_2材料乙醇气敏性能与催化活性间关系

通过测量La2O3-SnO2的气敏性能和催化活性,考察了La2O3对SnO2气敏性能和催化性能的影响,同时讨论了该材料对甲烷(CH4)和乙醇(C2H5OH)的灵敏度与其催化氧化反应间的关系。结果表明:300℃时,掺杂w(La2O3)为3%时,可使乙醇的转化率从84.5%提高到100%,对体积分数为1×10-4的乙醇的灵敏度由11.06提高到53.22。说明目标气体的反应活性越高,其灵敏度也越高。掺杂La2O3提高乙醇气体的灵敏度的原因是因为增加了SnO2表面乙醇反应中的耗氧率。     

V_2O_5掺杂MgTiO_3-CaTiO_3陶瓷的介电性能

采用固相反应法制备了V2O5掺杂的MgTiO3-CaTiO3(MCT)介质陶瓷。研究了V2O5掺杂量对陶瓷晶相组成、烧结温度和介电性能的影响。结果表明:V2O5掺杂的MCT陶瓷的主晶相为MgTiO3和CaTiO3两相结构,当掺杂量较低时,有第二相CaVO3产生;V2O5掺杂能降低MCT陶瓷的烧结温度并使其介电性能得到改善。当x(V2O5)为1%时,在1250℃烧结2.5h获得最佳性能:εr为20.17,tanδ为2×10–3,αε为4.9×10–5/℃。     

Fabrication of low-loss Al2O3-doped silica fibres

This letter is concerned with the alternative dopant of Al2O3 for VAD silica-based optical fibres. In order to clarify basic loss characteristics of Al2O3-doped silica glass fibres, single-mode fibres were made. The fabricated single-mode fibre shows an ideal step-index profile and a low transmission loss of 0.65 dB/km at 1.56 ?m.     

Nb_2O_5对Ba_(0.68)Sr_(0.32)Ti_(1-x)Sn_xO_3陶瓷介电性能的影响

采用传统固相法,制备了Nb2O5掺杂的Ba0.68Sr0.32Ti1–xSnxO3(BSTS)介电陶瓷,研究了Sn4+加入量和掺杂Nb2O5对材料介电性能的影响,用SEM研究了SnO2对材料微观结构的影响,当x(SnO2)为0.010,x(Nb2O5)为0.008时制得了εr为3689,tanδ为0.0006的高压低损耗陶瓷电容器瓷料,探讨了二者改性作用的机理。     

Pulse delay measurements in the zero-material-dispersion region for germanium- and phosphorus-doped silica fibres

Wavelength-dependent pulse dispersion in germanium- and phosphorus-doped silica fibres of different concentrations was measured using mode-locked subnanosecond pulses in the 1.064?1.55 ?m wavelength range. Zero dispersion for GeO2-SiO2 fibres was observed in the 1.3?1.33 ?m region depending on the concentration. P2O5-doped silica fibres showed zero dispersion near 1.28 ?m, independent of doping concentration.     

Spectral loss characteristics of GeO2-P2O5-doped silica graded-index fibres in long-wavelength band

Spectral loss characteristics of GeO2-P2O5-doped silica graded-index fibres were investigated in the long-wavelength band. A broad absorption loss, increasing in proportion to the OH-ion concentration, was observed in the vicinity of 1.60 ?m wavelength.     

BaO－P_2O_5和R_2O－BaO－P_2O_5系统磷酸盐激光玻璃RAP法除

研究了熔炼温度和气相反应剂（ＣＣｌ４，ＳＯＣｌ２和ＰＯＣｌ３）对ＢａＯ－Ｐ２Ｏ５（Ｎ２１）和Ｒ２Ｏ－ＢａＯ－Ｐ２Ｏ５（ＨＬＣ－５）系统磷酸盐激光玻璃ＲＡＰ法除水速率的影响．讨论了Ｎ２１和ＨＬＣ－５型玻璃中Ｎｄ３＋的荧光寿命与ＯＨ基含量的关系，井对除水前后玻璃的激光性能和物理性质进行了比较。     

掺Er~(3+)碲硼酸盐玻璃1.53μm波段荧光强度提高研究

用高温熔融法制备了系列70TeO2-(25-x)B2O3-xGeO2-5Na2O(x=5,10,15和20 mol%)掺Er3+碲硼酸盐玻璃。为提高1.53μm波段的荧光发射强度,测试了玻璃样品的吸收光谱、红外透射谱、1.53μm波段荧光谱及4I13/2能级Er3+荧光寿命,结合Judd-Ofelt(J-O)理论分析了Er3+光谱特性随玻璃组分含量的变化,进而研究了玻璃中OH基对1.53μm波段荧光强度的影响。结果表明,碲硼酸盐玻璃具有较好的宽带荧光谱特性,其有效带宽大于72 nm;随着玻璃中GeO2逐步替代B2O3,1.53μm波段荧光强度相应提高。同时,通过O2鼓泡除水处理,能减少玻璃中OH基含量并减弱4I13/2能级上Er3+到OH基的无辐射能量传递,从而进一步提高了Er3+荧光寿命和1.53μm波段荧光强度。     

利用水和二茂铁的化学气相沉积方法制备α-Fe2 O3纳米颗粒的圆形图形的研究

利用水和二茂铁作原料,通过化学气相沉积的方法在950℃以上可以在二氧化硅表面上制备出二氧化铁纳米颗粒组成的圆形图形.研究发现,这些圆形图形的特点,包括图形的平均尺寸和尺寸分布、图形之间的平均间隔、以及组成这些图形的氧化铁纳米颗粒的大小等,同沉积温度、水和二茂铁的比例等密切相关.通过调整这些实验参数,我们在较大面积的二氧化硅基片上成功地制备出氧化铁纳米颗粒的圆形图形阵列.这些圆形图形阵列有可能作为纳米碳管等一维材料的制备模板.这些图形以及组成它们的纳米颗粒的特点有可能对沉积的纳米材料的形貌和性能等产生影响.     

Preparation and laser properties of Yb3+-doped microstructure fiber based on hydrolysis-melting technique

The Yb3+-doped silica glass was prepared by the SiCl4 hydrolysis doping and powder melting technology based on high frequency plasma. The absorption and emission characteristics of the Yb3+-doped silica glass are studied at room temperature. The integrated absorption cross section, stimulated emission cross section and fluorescence lifetime are calculated to be 8.56×104 pm3, 1.39 pm2 and 0.56 ms, respectively. The Yb3+-doped microstructure fiber (MSF) was also fabricated by using the Yb3+-doped silica glass as fiber core. What’s more, the laser properties of the Yb3+-doped MSF are studied.     

Microbending losses of P2O5-doped graded-index multimode fibre

Measurement results showing that the cabling loss of P2O5-doped MCVD graded-index multimode fibre increases for wavelengths longer than 1.3 ?m have been obtained. This letter investigates the cause for this loss increase. It also has been found that the loss increase is caused by P-OH bond absorption near the core-cladding boundary, where OH ions are diffused from the fused-quartz tube.     

火焰水解法制备硅基二氧化硅材料的析晶研究

用火焰水解法在硅基片上制备了掺杂GeO2和B2O2的SiO2光波导材料.用X射线物相衍射法(XRD)分析了掺杂和烧结工艺对材料的析晶现象的影响.结果表明,当烧结时采取自然降温,GeO2-SiO2材料由于严重析晶而完全碎裂;而当烧结后期采取快速降温,析晶过程受到很大抑制,但仍有析晶.在此GeO2-SiO2材料中掺入适量的B2O3后,得到了完全非晶态的GeO2-B2O3-SiO2材料,但B2O3掺入量过多时,又会导致析晶.     

离子束溅射制备氧化物薄膜沉积速率调整方法

采用正交试验设计方法,系统研究了离子束溅射HfO2、Ta2O5 和SiO2 薄膜的沉积速率与工艺参数（基板温度、离子束压、离子束流和氧气流量）之间的关联性。采用正交表L9（34）设计了9 组实验,采用时间监控的离子束溅射沉积方法,分别制备HfO2、Ta2O5 和SiO2 薄膜,并对三种薄膜的27 个样品采用椭圆偏振法测量并计算物理厚度,继而获得沉积速率。实验结果表明:对Ta2O5 和SiO2 薄膜沉积速率影响的工艺参数相同,影响权重从大到小依次为离子束流、离子束压、氧气流量和基板温度;对 HfO2 薄膜沉积速率影响的工艺参数按权重从大到小依次为离子束流、离子束压、基板温度和氧气流量。研究结果为调整HfO2、Ta2O5 和SiO2 薄膜沉积速率提供了依据。     

The Zn(S,O,OH)/ZnMgO buffer in thin film Cu(In,Ga)(S,Se)2‐based solar cells part I: Fast chemical bath deposition of Zn(S,O,OH) buffer layers for industrial application on Co‐evaporated Cu(In,Ga)Se2 and electrodeposited CuIn(S,Se)2 solar cells

This paper is focused on the basic study and optimization of short time (<10 min) Chemical Bath Deposition (CBD) of Zn(S,O,OH) buffer layers in co‐evaporated Cu(In,Ga)Se₂ (CIGSe) and electrodeposited CuIn(S,Se)₂ ((ED)‐CIS) solar cells for industrial applications. First, the influence of the deposition temperature is studied from theoretical solution chemistry considerations by constructing solubility diagrams of ZnS, ZnO, and Zn(OH)₂ as a function of temperature. In order to reduce the deposition time under 10 min, experimental growth deposition studies are then carried out by the in situ quartz crystal microgravimetry (QCM) technique. An optimized process is performed and compared to the classical Zn(S,O,OH) deposition. The morphology and composition of Zn(S,O,OH) films are determined using SEM and XPS techniques. The optimized process is tested on electrodeposited‐CIS and co‐evaporated‐CIGSe absorbers and cells are completed with (Zn,Mg)O/ZnO:Al windows layers. Efficiencies similar or even better than CBD CdS/i‐ZnO reference buffer layers are obtained (15·7% for CIGSe and 8·1% for (ED)‐CIS). Copyright © 2009 John Wiley & Sons, Ltd.     

Refractive index dispersion of lightguide glasses at high temperature

The refractive index of pure and GeO2-doped silica glasses was measured at wavelengths from 0.4 ?m to 2.1 ?m, over a temperature range from 20°C to 540°C. Values for the thermal coefficient of the refractive index (about 1.2×10?5/°C at 1.3 ?m) were almost identical for both glasses. The data showed that material dispersion for optical fibres increases with increasing temperature.