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氰基胺固化的水下环氧胶粘剂 总被引:2,自引:1,他引:1
本文给出一种以氰基胺固化的水下环氧胶粘剂的配方。并且通过实验证明了:普通脂肪胺与环氧化合物部分预聚后,可作为水下环氧胶粘剂的固化剂,能有效地提高水中粘接强度;吸水性材料对水下环氧胶粘剂的粘接强度起增强的作用。 相似文献
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用于木材粘接的反应型聚氨酯胶粘剂 总被引:3,自引:0,他引:3
EdwardM.Petrie 《化学与粘合》2004,(2):95-99
本文讨论了反应型聚氨酯胶粘剂的配方及其在木材粘接中应用。重点讨论单组分液体型、热熔型和木材复合板粘接用反应型、湿气固化聚氨酯胶粘剂。 相似文献
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双组分高固含量水性聚氨酯鞋胶的制备 总被引:2,自引:1,他引:2
报道了一种用于鞋胶的双组分水性聚氨酯胶粘剂,包括50%以上的高固含量水性聚氨酯分散体及水可分散多异氰酸酯固化剂的制备。测试结果表明,本实验所制得的样品具有较低的活化温度,范围在50- 75℃之间,且具有很好的耐热温度,耐温高达110℃。所制备的高固含量水性聚氨酯表现出优越的粘接性能,未加固化剂的单组分水性聚氨酯剥离强度(PVC/PVC)高达8.8N/mm。 相似文献
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In this paper, it is demonstrated how the formation of blisters or foaming in a heat-curing epoxy adhesive can be avoided during bonding to sealed sulphuric acid-anodised aluminium. The crucial points to control are the release of water from the anodic film and the total amount of water in the joint. The cure cycle will affect the rate of water release, while the total amount to a large degree depends on the relative humidity in the area of bonding before joint assembly. Besides the adhesive, also the anodic film absorbs water within a short time scale. This behaviour is caused by aluminium sulphate, which is always present in the anodic film after sulphuric acid anodisation. At room temperature the aluminium sulphate is in equilibrium with water vapour at about 30% r.h. It has been experimentally demonstrated that the amount of water stored in the anodic film has a dramatic step change between 30% and 40% r.h. at room temperature. Outside this range up to condensing conditions differences are relatively small. The release of water during the curing of the adhesive can in addition to blistering or gassing also cause a boundary layer with changed properties in between the adhesive and the anodic film. 相似文献
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When a concrete surface is contaminated by water due to rain, saline water, ground water, and water jetty treatment, water, alkalis, and other contaminants on the concrete surface may interact with an epoxy adhesive used for bonding fiber‐reinforced polymer composite sheets to concrete. This can influence both the curing rate and the degree of cure of the curing reaction. This in turn can affect the time required for field application. It can also influence the mechanical properties and durability of epoxy adhesives. In this paper, water effects on the curing and properties of two kinds of commercial adhesives were evaluated. Curing kinetics were studied using isothermal DSC analysis. Results showed that water accelerated the curing reaction. However, excess water offsets part of the accelerating effect. While water is typically considered to be harmful to properties of adhesives, it was seen that a small amount (less than 2%) of water improved degree of cure, mechanical properties, and durability of adhesives. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2261–2268, 2004 相似文献
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Alessandro G. Cassano Siddharth Dev Marianna Maiaru Christopher J. Hansen Scott E. Stapleton 《应用聚合物科学杂志》2021,138(10):49989
Curing of adhesive bondlines is a critical and time-consuming operation in wind turbine blade manufacturing. Significant variation in adhesive thickness can lead to important differences in thermal histories trough the adhesive bonds due to the exothermic nature of the cure process. Reducing bondline cure cycle time and avoiding adhesive overheating are two competing factors in the design of cure temperature cycles. Predictive models on the impact of adhesive thickness variability in bondline cure temperature cycle is currently limited. Adhesive curing and temperature evolution can be simulated by finite element (FE) models coupling the heat transfer problem with the cure kinetics of the adhesive. The cure kinetics of the adhesive system was characterized by isothermal differential scanning calorimetry experiments and implemented in the FE software Abaqus/CAE by user subroutines. Predictions from the FE model were validated experimentally against temperature readings from the curing of 10, 20, and 30 mm thick adhesive bondlines. To highlight the role that predictive models potentially have in the optimization of bondline cure cycles a 2D cross section model representing the trailing edge of a wind turbine blade was used as case study. It was demonstrated that computational models enable customizing cure profiles for nonuniform adhesive thicknesses, ensuring fully cured bondlines with acceptable mechanical properties. 相似文献
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新型复合板材用聚氨酯胶粘剂的研究 总被引:1,自引:1,他引:0
本文介绍了铝-塑复合板用聚氨酯胶粘剂的合成方法,讨论了原料配比反应温度、水含量、NCO/OH的配比对粘合性能和剥离强度的影响。 相似文献
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《Journal of Adhesion Science and Technology》2013,27(16):2111-2130
Since the reliability of adhesively bonded joints is much dependent on the curing status of thermosetting adhesives, the in situ cure monitoring during the cure of adhesive joints could improve the quality of adhesively bonded joints as it enables one to control the cure parameters. In this work, a dielectric method which measures the dissipation factor of the adhesive during the cure of joints and converts it into the degree of cure of the adhesive was devised. Steel adherends were used for the adhesively bonded joints because the steel adherends worked as the electrodes for the measurement of dissipation factor without additional electrodes. The relation between the dissipation factor and the degree of cure of adhesive was investigated, which could eliminate the temperature effect on the dissipation factor that is largely affected by the degree of cure and temperature of adhesive. Comparing the results obtained by the method developed with those by DSC (differential scanning calorimetry), it was found that the dissipation factor showed a trend similar to the cure rate of the adhesive. 相似文献
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The effect of E-glass, cured vinyl ester resin, and silica gel on the curing of an epoxy-anhydride adhesive was examined. The techniques used were calorimetry in both isothermal and scanning modes and Fourier transform infrared spectroscopy in the attenuated total reflectance (ATR-FTIR) mode. Isothermal calorimetry was used to obtain the exotherm, conversion rate, and curing kinetic parameters, and scanning calorimetry was used to obtain the glass transition temperature. ATR-FTIR was used to study the curing kinetics and chemistry of the adhesive. The results suggest either the immobilization of a layer of the epoxy adhesive adjacent to inert solid surfaces or selective adsorption of the accelerator or both, each of which suppresses the cure reaction. This was reversed by the presence of adsorbed water. At least for this epoxy-anhydride system, adsorbed water seems to have had the beneficial effect of increasing the crosslink density in the interfacial region between the adhesive and adherend. Water seems also to change the overall cure reaction, causing more ether formation and less ester formation than without water. An additional finding was that the cured vinyl ester surface appeared to have a catalytic effect on the reaction, perhaps in conjunction with the accelerator, benzyldimethylamine. 相似文献