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La,Ce,Pr,Nd and Sm concentrations in Pu'er tea of Yunnan,China 总被引:3,自引:0,他引:3
The rare earth elements contents (La, Ce, Pr, Nd, Sm) in 150 Pu'er tea samples were analyzed by using inductively coupled plasma atomic emission spectroscopy (ICP-AES), to evaluate the safety of Pu'er tea. Among the investigated rare earth elements (REEs), Ce was the highest (35% of the total REEs content) whose concentrations were found to be in the range of 0.11–1.39 mg/kg, whereas that of Sm in the range 0.01–0.21 mg/kg, showing minimum levels (5.2%). La was the second highest element (28%) found in Pu'e... 相似文献
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Effect of Rare Earth on Microstructure of γ-TiAl Intermetallics 总被引:3,自引:0,他引:3
The rare earth (RE) elements (Ce, La) were added to binary Ti-47% Al alloys (atomic fraction) by Induction Skull Melting. The element Ce of 1.0 atomic percent was added individually, and La of 0.2 atomic percent was added individually. This article studied the influences of rare earth metal (Ce, La) on microstructure of as-cast TiA1 based alloy by XRD, SEM, EMPA and TEM measurement methodology. The results show that most of rare earth-rich phases (AlCe, Al-La) are uniformly distributed in grain boundary in the shape of discontinuous network, and some particles of rare earthrich phases within the grains are mainly ellipsoids. In addition, rare earth element can obviously refine the grain size and the lamellar thickness of as-cast TiAl based alloy samples. The grain size of Ti-47Al-1.0Ce-0.2La alloy reaches about 30~80μm, and the lameUar thickness of its γ phase and α2 phase are less than 200 and 20nm, respectively. 相似文献
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用硝酸和氢氟酸溶解试样,高氯酸冒烟除氟,在硝酸介质中用电感耦合等离子体原子发射光谱法(ICP-AES)测定了镝铁电解粉尘中La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu、Y 15种稀土元素。为了提高高含量元素的测定准确度,在测定基体元素Dy时,采用铟作内标;为了消除基体效应对稀土杂质元素测定的影响,采用基体匹配的校准曲线。镝铁电解粉尘中铁含量很低(铁的质量分数不超过1%),对测定没有影响。实验方法测定了一镝铁电解粉尘样品,结果表明,La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Ho、Er、Tm、Yb、Lu和Y 14个稀土杂质元素测定值与ICP-MS的测定值基本一致,镝和14个稀土元素的合量与重量法测得的稀土总量吻合。 相似文献
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《中国稀土学报(英文版)》2016,(6)
Using Chinese cabbage and rape as test material and examining the same soil conditions at different seasons(spring and autumn), the effects of mixed rare earth fertilizer on the yield and nutrient quality of leafy vegetables were studied to provide a theoretical basis for the application of mixed rare earth fertilizer in agriculture. Results showed a seasonal difference in the nutrient quality of Chinese cabbage and rape. For crops planted in autumn, the soluble sugar and vitamin C content were higher, the titratable acid and nitrate content were lower, and the sugar acid ratio was higher relative to crops planted in spring. Mixed rare earth treatments promoted growth of both crops during both seasons. The plot yield, stem and leaf fresh and dry matter weight, and dry and fresh ratio increased. These increases for Chinese cabbage were greater in autumn than in spring while for rape, the increases were greater in spring than autumn. The soluble sugar content, titratable acid content and sugar acid ratio were increased and the nitrate content decreased, in autumn the effects were more obvious than in spring. In spring, the vitamin C content was increased, and the increase was greater for Chinese cabbage than rape. In autumn, the vitamin C content decreased, and the decrease was greater for rape than Chinese cabbage. At the same time, the content of heavy metals such as Cu, Zn, Cd, Pb and Ni in stems and leaves decreased. This decrease was greater in spring for Chinese cabbage and in autumn for rape. 相似文献
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《钢铁冶炼》2013,40(8):594-599
AbstractThe microstructures were observed in C–Mn steel and statistical analysis of the inclusions produced when trace amounts of rare earth were added to the steel. The results show that the content of intragranular acicular ferrite decreased in the order of being treated with La+Ce/La/Ce in C–Mn steel after the treatment of different kinds of rare earths. The optimum mass ratio of La and Ce for La+Ce combined treatment is 3:1.The best incubation time after Le+Ce (3:1) treatment is 5?min. The size of inclusion nuclei favouring intragranular acicular ferrite nucleation concentrates in the range of 1–4?μm. The disregistries between rare earth inclusions and α-Fe are small, which plays an important role in rare earth inclusions inducing intragranular acicular ferrite nucleation. 相似文献
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The effect of rare earth element Ce on mechanical performance and electrical conductivity of aluminum rod for electrical purpose were studied under industrial production condition. Using optical microscope, SEM, TEM, EDS and X-ray diffractometer, the microstructure and phase composition of aluminum rod were measured and analyzed. The results indicate that the content of rare earth element Ce is between 0.05%~0.16% in the aluminum rod for electrical purpose. Its tensile strength is enhanced to some extent. The research also discovers that the tensile strength is enhanced remarkably with impurity element Si content increases. Because influence of Si is big to the conductivity, the Si content should be controlled continuously strictly in the aluminum for electrical purpose. Adding rare earth element Ce reduces the solid solubility of Si in the aluminum matrix, and the negative effect of Si on the aluminum conductor reduces effectively. So the limit of in Si content in aluminum rod for electrical purpose can be relaxed moderately. 相似文献
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Leaching of rare earth elements from contaminated soils using saponin and rhamnolipid bio-surfactant
《中国稀土学报(英文版)》2017,(9)
The effective leaching of rare earth elements(La, Ce, Y and Eu) from simulated contaminated soil using bio-surfactant was investigated in a lab-scale column leaching experiment, where anionic biosurfactant rhamnolipid and non-ionic biosurfactant saponin were used as washing solutions. Soil properties and the rare earth element fractions were analysed to define the effect of leaching on soil and elemental speciation. Column leaching results showed that saponin solution was more effective than rhamnolipid in the removal of the four rare earth elements tested, with the accumulative removal efficiency of La, Ce, Y and Eu following flushing with 400 mL of 25 g/L saponin, reaching 35.258%, 26.072%, 31.476% and 30.849%, respectively. The change in REE speciation showed that REE removed from soils were mainly derived from the acid-soluble and residual fractions released when rhamnolipid solution was used as a leaching agent. However, for saponin leaching, removed REE amounts were derived from acid-soluble and reducible fractions. Complexation interactions were identified between saponin and REEs, according to infrared spectroscopy and ion exchange data, with saponin complexing with La, Ce, Y, and Eu at a complex ratio of 1:1. 相似文献
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采用经碳纳米管改性的亲水化纳滤膜浓缩提取稀土浸出液中的稀土离子,探究纳滤膜表面对La3+、Nd3+、Pr3+、Ce3+和Y3+5种稀土离子吸附动力学行为,考察稀土离子半径的大小对纳滤膜吸附性能和截留性能的影响.结果表明,Freundlich吸附方程比Langmuir方程能更好地描述稀土离子在纳滤膜表面上的动态吸附行为,用Freundlich吸附方程拟合后的结果相关度系数R2能达到0.999以上;在初始浓度为5×105 μg/L,温度为25 ℃,运行压力为0.6 MPa的实验条件下,纳滤膜对稀土离子的浓缩提取过程中,初始阶段的截留机理取决于纳滤膜表面的吸附作用和膜孔的机械筛分效应,膜面吸附达到平衡后以膜孔的机械筛分效应为主,此时La3+、Nd3+、Pr3+、Ce3+和Y3+的截留率分别为94.21 %、81.25 %、85.80 %、89.90 %和81.18 %,表明经碳纳米管改性的亲水化纳滤膜能高效浓缩截留稀土浸出液中的稀土离子. 相似文献
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稀土掺杂锂离子电池正极材料LiCoO2的影响研究 总被引:10,自引:0,他引:10
在合成LiCoO2的基础上,采用共沉淀法掺杂稀土La、Ce、Lu、Y等合成制备了LiRExCo1-xo2,并对其进行了XRD、SEM表征及电性能测试.结果表明,合成的LiRE、Co1-xO2具有LiCoO2结构,当稀土La的加入量x<0.05时,稀土能完全形成单一LiRExCo1-xO2相;稀土的掺入能促进LiCoO2结晶,同时使104面的相对衍射强度增加;LiRExCo1-xO2首次放电容量达147.4 mA·h/g,循环稳定性有所提高. 相似文献
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电感耦合等离子体质谱法(ICP-MS)测定稀土元素时,轻稀土元素Ce、Nd、Sm的氧化物等复合离子严重干扰重稀土元素Tb、Dy、Ho、Er的测定,因此对混合稀土中重稀土元素进行测定前一般需要先对其分离富集。实验在样品溶解后,将N,N,N′,N′-四辛基-3-氧戊二酰胺(TODGA)用硅藻土吸附后装柱,以0.1 mol/L HNO3为样品溶液介质上柱,通过控制洗脱液的种类、酸度以及洗脱液流速,实现了轻稀土元素La、Ce、Pr、Nd与重稀土元素Tb、Dy、Ho、Er、Tm、Yb、Lu的分离和富集,建立了ICP-MS测定混合稀土氧化物中重稀土元素的方法。实验表明:控制洗脱流速为2.0 mL/min,用pH 2.0的HNO3淋洗至淋洗体积约为500 mL,继续收集洗脱液,并用ICP-MS检测其中Nd2O3含量,直至洗脱液中Nd2O3的质量浓度小于200 ng/mL,可将轻稀土元素La、Ce、Pr、Nd及少量Y、Sm、Gd洗脱;再改用350 mL 1 mol/L HCl洗脱重稀土元素,可实现重稀土元素与La、Ce、Pr、Nd及部分Y、Sm、Gd的分离;通过选择159Tb、163Dy、165Ho、167Er、169Tm、172Yb、175Lu为测定同位素可消除质谱干扰。将实验方法应用于混合稀土氧化物中重稀土元素的测定,加标回收率在93%~110%之间,相对标准偏差(RSD,n=8)在1.1%~10%之间。 相似文献
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EffectofRareEarthMetalsonMicrostructureofDirectionalSolidifiedAl-3LiAlloy¥WangLi-Min;DangPing;DuFu-Ying;ZhaoMin-Shou(Changchu... 相似文献
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Zhao Cao Xu Wu Sultan Ahmed Khoso Wenbo Zhang Yuling Liu Mengjie Tian Jieliang Wang 《中国稀土学报(英文版)》2022,40(5):822-830
Monazite((Ce,La)PO4)is one of the major types of light rare earth minerals from which the light rare earth elements cerium(Ce)and lanthanum(La)are economically ... 相似文献
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文中研究了微量稀土元素Ce在金合金中的分布情况,观察了稀土元素Ce不同添加量对金合金铸态组织及其硬度的影响.研究发现:在添加Ce的金合金中,Ce部分固溶,部分作为异质点Ce-Si化合物存在,基本没有Ce的偏聚;添加0.075?金合金铸态组织就可以达到较好的晶粒细化效果,分析其作用机理是添加Ce的金合金以高熔点的Ce-Si化合物和氧化物作为异质点,起到异质晶核的作用而细化组织;在低于Ce的金合金固溶度时,铸态合金的硬度随Ce含量增加而升高,过量Ce对金合金的铸态硬度影响不大;利用时效处理,能显著地提高金合金的硬度,Ce主要强化机制在于固溶强化. 相似文献