共查询到20条相似文献,搜索用时 140 毫秒
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采用透射电镜研究了以膨胀石墨为主体材料合成的CuCl2-EGICs微观结构,包括垂直和平行石墨碳原子层的层间结构、层面结构.根据X射线衍射参数计算获得2、3、4阶CuCl2-EGICs的层间距Ic值,与理论计算值近似.选区电子衍射获得面内结构参数.发现EGICs衍射斑点是由石墨碳原子层单斑点和氯化物层多斑点簇组两套相迭而成.EGICs层面内碳原子层原子排布保持了石墨六角网格状的特点;氯化钢分子相对碳原子层分布有三种堆垛方式.倒易点分析认为有(2x2)R(30°)、(71/2x71/2)R(0°)、(31/2x31/2)R(0°)三种超晶格结构.二阶、三阶CuCl2-GIC中氯化铜点阵与碳原子点阵之间存在30°的偏转角,而在一阶CuCl2-GIC中偏转角等于零度.根据高分辨电镜(HREM)、选区电子衍射(SAD)、能谱微区成分、光电子能潜(XPS-ESCA)和俄歇电子能谱(XAES)等结果,探讨和分析了CuCl2-EGICs微观结构. 相似文献
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超微粉石墨层间化合物CuCl2—NiCl2—GICs合成及电学性能 总被引:4,自引:0,他引:4
常规的GICs合成原料均采用合成石墨或者粒度较粗的天然石墨,这里采用超微粉石墨作原料,进行受主金属氯化物CuCl2-NiCl2-GIC的合成研究。使用山东南墅石墨(3000目)、Cu-Cl2和NiCl2(5n:0.5:0.5摩尔比),在528℃,真空度10.3Pa条件下,得到超微粉的CuCl2-NiCl2-GICs,STEM单原子能谱扫描结果显示出铜离子和镍离子分布基本均匀,合成的1,2,3和4阶 相似文献
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为了得到用于1.3μm光通讯窗口掺镨化镓铟(PGICE)高数值孔光纤,本文报道以ZrF4-BaF2-LaF3-AlF3-Na(Li)F-PbF2(ZBLAN(Li)Pb)和NaPO3-BaF2-ZnF2-PbF2(FPG)玻璃作为包层材料,研究了芯和包层玻璃在物理性质和化学组分上的匹配性,差热扫描(DSC)和电镜(SEM)分析表明PGICZ/ZBLAN(Li)Pb虽在物理性质上匹配,但在化学组分不 相似文献
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以三氟甲基磺酸铝(CF_3SO_3)_3Al为引发剂,正己烷为溶剂,通过阳离子聚合,合成了1,3-戊二烯-苯乙烯共聚物。用IR、 ̄1HNMR对共聚物结构进行了分析,并用SEC(GPC)对共聚物分子量进行了表征,对共聚物的环化度也进行了研究,用Kelen-Tudos方法测定的共聚合反应体系苯乙烯(M_1)和1,3-戊二烯(M_2)的竞聚率分别为γ_1=2.1,γ_2=0.6。 相似文献
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传秀云 《材料科学与工程学报》1998,(2)
常规的GICs合成原料均采用合成石墨或者粒度较粗的天然石墨,这里采用超微粉石墨作原料,进行受主金属氯化物CuCl2-NiCl2-GIC的合成研究。使用山东南墅石墨(3000目)、Cu-Cl2和NiCl2(5n:0.5∶0.5摩尔比),在528℃、真空度10.3Pa条件下,得到超微粉的CuCl2-NiCl2-GICs,STEM单原子能谱扫描结果显示出铜离子和镍离子分布基本均匀。合成的1,2,3和4阶GICs的电导率分别为1.536×104,1.638×104,3.773×104,和5.727×104。而石墨原料的电导率为1.851×104,从整体来看合成的GICs的电导率是石墨原料的0.8-3倍。对比合成的GICs的电导率发现,阶数不同,电导率不同,并且随着阶数的升高,电导率增大。 相似文献
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利用RT-PCR技术,检测了BMP-3及BMP-5在不同组织中的表达,并将PCR扩增出的bmp-3和bmp-5 cDNA克隆入pGEX表达载体,在大肠杆菌中得到高效表达。 相似文献
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钕铁硼稀土永磁材料室温熔盐电镀铝的研究 总被引:4,自引:3,他引:1
在钕铁硼(NdFeB)稀土材料表面直接进行水溶液电镀时,存在镀层分层、易起泡等缺陷.采用AlCl3/EMIC(1-甲基-3-乙基氯化咪唑)室温熔盐电解质在NdFeB永磁材料表面电镀铝,是提高其表面防护质量的有效方法.探讨了NdFeB永磁材料在室温熔盐中电镀铝的可行性、熔盐配比和芳香化合物对电镀铝层组织形态的影响,同时对镀层形成的机理进行了初步探讨.研究表明:采用AlCl3/EMIC室温熔盐电解质可在NdFeB永磁材料表面获得满意的铝镀层;铝镀层纯度很高,较完整平滑;添加芳香化合物可以大大提高镀层的质量,使晶粒细小、致密. 相似文献
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低温熔融盐电镀铝的研究 总被引:11,自引:0,他引:11
低温熔融盐电镀我国发展较晚,在低碳钢上开展得更迟.为此,采用熔融盐电镀法对Q235钢在AlCl3-NaCl-KCl熔融盐中电镀铝的可能性以及电镀工艺对电镀铝层组织形态的影响进行了研究.结果表明,Q235钢在熔融盐中可以进行电镀铝.经X射线衍射分析表明,镀层的相结构为单相铝.镀层的厚度随电流密度的增大和电镀时间的延长而增加,与电镀时间的平方根成线性关系.镀铝层由许多分布均匀的铝颗粒组成,电流密度低时,铝颗粒呈片状;电流密度高时,铝颗粒呈球状.同时,对电镀铝层的形成机理也进行了初步探讨. 相似文献
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用AlCl_3-NaCl-KCl三元无机熔盐体系在Q235低碳钢基体上镀铝,运用涂层测厚仪、X射线衍射仪、金相显微镜、静态浸泡失重法等手段,对铝镀层的厚度、相结构、表面形貌和耐蚀性等进行了研究.结果表明:铝镀层厚度随电流密度的增加近似成线性增长,电镀前期随电镀时间延长明显增大,之后变化率逐渐减小;镀层为面心立方结构单相铝,主要由(200)面组成;铝镀层与碳钢基体结合良好,具有较好的耐蚀性能. 相似文献
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Aluminum nitride is of interest as a material for electrolysis cells in the aluminum industry due to its chemical stability when in contact with molten aluminum and/or cryolite-based salt melts. It has also been considered in combination with electrically conductive materials (i.e. AlN/Al-composite) as a material for drained cathode systems in Hall-Heroult processes. Knowledge of the interfacial properties of AlN in contact with molten aluminum and/or cryolite-based melts is therefore important. This paper reports observations of the wettability of AlN by aluminum under salt cover at high temperature using an X-ray technique. Results obtained in this work combined with previously published data are used for the assessment of the work of adhesion of molten aluminum on AlN under vacuum as well as under a cryolitic salt. Scanning electron microscopy examination of metallographic sections was used to confirm the nature of the interfaces. The measured contact angle between AlN and molten aluminum beneath a salt cover at 850 °C is 136° demonstrating the non-wettability of AlN by liquid aluminum under these conditions. The work of adhesion of molten aluminum on AlN is higher under vacuum than under salt. Previously published data allowed the determination of the interfacial properties between liquid aluminum and AlN under a salt cover. The interfacial energy between molten aluminum and salt is 773 mN/m at 850 °C. The work of adhesion of aluminum on AlN is 217 and 1322 mN/m under salt and under vacuum, respectively. 相似文献
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Ionic liquids, defined here as room-temperature molten salts, composed mainly of organic cations and (in)organic anions ions that may undergo almost unlimited structural variations with melting points below 100?°C. They offer a unique series of physical and chemical properties that make them extreme important candidates for several energy applications, especially for clean and sustainable energy storage and conversion materials and devices. Ionic liquids exhibit high thermal and electrochemical stability coupled with low volatility, create the possibility of designing appropriate electrolytes for different type batteries and supercapacitors. Herein, varieties of ionic liquids applications are reviewed on their utilization as electrolytes for Li-ion batteries, Na-ion batteries, Li-O2(air) batteries, Li-Sulfur (Li-S) batteries, supercapacitors and as precursors to prepare and modify the electrode materials, meanwhile, some important research results in recent years are specially introduced, and the perspective on novel application of ionic liquids is also discussed. 相似文献
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Tongxiang Cai Yanwei Zeng Shilong Yin Ling Wang Chuanming Li 《Materials Letters》2011,65(17-18):2751-2754
Ce0.8Sm0.2O1.9 (SDC)–carbonates composite electrolytes for SOFCs have been prepared for the first time via molten salt infiltration approach by infiltrating LiNaCO3 molten carbonates into porous SDC ceramic. A range of techniques including XRD, SEM, Mercury Porosimeter and A.C. impedance, have been employed to characterize SDC and composite electrolytes. It has been found that the porous SDC shows a monomodal pore size distribution with average pore size of 300 nm. SDC–carbonates composite electrolytes via molten salt infiltration show a kind of SDC/carbonates co-continuous composite structure, with one SDC ceramic skeleton of bonded grains surrounded by carbonates phase. Both phases provide a continuous pathway for ionic transport and a large interfacial surface area. SDC–carbonates composite electrolytes prepared by molten salt infiltration have a higher mechanical strength than that of mixing–pressing composite electrolytes. Moreover, they show higher conductivity and lower activation energy than that of mixing–pressing composite electrolytes according to the measurements of AC impedance in the temperature range of 350 °C–650 °C. 相似文献
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This study is a continuation of our previous work (Baumli et al. J Mater Sci 45:5177–5190, 2010) in which the wettability of graphite by liquid aluminum was studied under different molten chlorides containing K2TiF6 as function of the cation of the molten chloride. In the present paper, the same was studied as function of the anion in different potassium halides (fluxes). The fluxes consisted of different potassium halides (KX) + 10 wt% potassium hexafluoro-titanate (K2TiF6). The potassium halides studied were potassium iodide (KI), potassium chloride (KCl), and their equimolar mixture. For perfect wettability of graphite by liquid Al under different molten KX-10 wt% K2TiF6 systems at 800 °C, certain critical values of the salt:Al mass ratio should be achieved, the value of which increases from KI toward KCl. Comparing the present results with the results of our previous study, we found that the critical value of the salt:Al mass ratio increases with the cation size and decreases with the anion size of the salt. 相似文献