基于电容层析成像技术的流化床内固相体积分数分布特性研究

针对煤清洁转化过程流化床内复杂气固两相流动特性,采用电容层析成像(简称ECT)技术,考察了流化床内玻璃珠和树脂颗粒瞬时和时均的固相体积分数分布特性。结果表明,利用不同时刻的瞬时固相体积分数等值图,可实现对截面颗粒分布的量化检测;局部时均固相体积分数沿径向呈"中心低、边壁高"的对称分布,截面时均固相体积分数沿轴向呈"下浓上稀"分布,测量结果与经典理论和实验观察相一致,表明ECT方法可以定性与定量测定流化床内气固两相流动过程固相体积分数。     

旋转压滤机单位过滤面积质量流量的试验研究

研究了旋转式压滤机单位过滤面积上的滤液质量流量、末级滤液质量流量、滤渣含固率及入料悬浮液的平均含固浓度。通过测定充满某体积容器的时间来标定滤液质量流量,绘制滤液质量流量及末级滤液质量流量占滤液质量流量比重基于时间的函数关系曲线,并计算出整个压滤过程中的滤液总量。在压滤过程结束后,从滤渣中取样、烘干,得出样品的含固率,最后通过物料平衡原理计算出入料悬浮液的平均含固浓度。     

循环流态化：（Ⅲ）气,固流动模型

根据气、固两相流动的基本特征,循环流态化气、固两相流动模型可分为局部流动结构模型及整体流动结构模型两类。局部流动结构模型主要描述床内稀相及絮状物相的局部分布及变化,而整体流动结构模型主要描述床中空隙率。颗粒速度以及气体速度轴、径向分布及变化,其中根据实用层次不同,整体流动结构模型可分为一维、一维两区及两维模型。本文对循环流态化气、固流动模型进行了分类评述,供循环流化床反应器设计时参考。     

基于LBM-DEM的鼓泡床内气泡-颗粒动力学数值模拟

将修正后的格子Boltzmann方法（LBM）与离散单元法（DEM）相结合,建立LBM-DEM四向耦合模型对单口射流鼓泡床中气泡运动进行模拟。其中,流体相采用格子Boltzmann方法中经典的D2Q9模型,颗粒相求解采用离散单元软球模型,颗粒曳力求解采用Gidaspow模型,流固耦合基于牛顿第三定律。应用Fortran语言编程对上述模型进行求解,模拟得到了鼓泡床内气泡演化过程,并与相关实验进行对比,有效验证了当前模型的准确性。同时,分析了床层内颗粒速度、颗粒体积分数以及能量分布。结果表明：颗粒时均速度分布不仅能体现颗粒运动强弱,也可以反映气泡运动过程;床内空隙率与颗粒体积分数分布在预测床层膨胀高度上具有高度的一致性;初始堆积效应使得床内颗粒势能始终大于颗粒动能;随颗粒密度增加,势能增大,动能逐渐减小。     

基于LBM-DEM的鼓泡床内气泡-颗粒动力学数值模拟

将修正后的格子Boltzmann方法 (LBM)与离散单元法(DEM)相结合,建立LBM-DEM四向耦合模型对单口射流鼓泡床中气泡运动进行模拟。其中,流体相采用格子Boltzmann方法中经典的D2Q9模型,颗粒相求解采用离散单元软球模型,颗粒曳力求解采用Gidaspow模型,流固耦合基于牛顿第三定律。应用Fortran语言编程对上述模型进行求解,模拟得到了鼓泡床内气泡演化过程,并与相关实验进行对比,有效验证了当前模型的准确性。同时,分析了床层内颗粒速度、颗粒体积分数以及能量分布。结果表明:颗粒时均速度分布不仅能体现颗粒运动强弱,也可以反映气泡运动过程;床内空隙率与颗粒体积分数分布在预测床层膨胀高度上具有高度的一致性;初始堆积效应使得床内颗粒势能始终大于颗粒动能;随颗粒密度增加,势能增大,动能逐渐减小。     

基于重置温度方法的双参数介尺度气固传热模型构建

颗粒聚团等介尺度结构在气固两相流中普遍存在,这些介尺度非均匀结构直接影响气固流动特性及气固接触效率,进而影响气固相间传热、传质及化学反应过程。在更适合工业大尺度气固传热模拟的粗网格方法中缺乏准确度高、简单易用且可以考虑介尺度非均匀结构影响的传热模型。采用计算流体力学-离散单元法（CFD-DEM）研究了气固两相流相间传热,为了保证气固相间持续传热,采用了两种维持气固相间传热温差的方法,并讨论了两种方法的优缺点。方法一：给气相能量方程添加热源项;方法二：每间隔一段时间重置气相温度,重置温度后气固两相自由传热,两种方法中均保持固相温度不变。结果表明聚团界面位置的局部单位体积气固传热量最大,重置温度方法在稀相和界面位置的局部单位体积传热量与总单位体积传热量之比大于热源项方法,而在浓相位置的局部单位体积传热量与总单位体积传热量之比小于热源项方法。通过过滤CFD-DEM计算数据,为重置温度方法构建了双参数（过滤固含率、过滤尺度）传热系数修正因子模型,通过先验分析评价了模型的表现,研究表明所构建模型在过滤网格尺度为5~40倍颗粒直径范围内优于文献中已有的双参数模型。     

网格和数值格式对TBPBM-CFD模型模拟鼓泡塔的影响

基于气泡动力学属性的现有认识,把气泡分成大、小气泡,首次建立了完整的双气泡相-群平衡模型(TBPBM)以预测气泡尺寸.通过编写用户自定义程序实现了TBPBM模型、Luo破碎模型以及Prince 聚并模型,并耦合TBPBM与CFD双流体模型对直径440 mm鼓泡塔进行数值模拟,详细考察了网格与数值格式对TBPBM-CFD模型模拟结果的影响.结果表明,网格与数值格式对各物理变量的模拟结果影响非常大,特别是网格和体积分数方程对流项离散格式的影响最为显著.随着计算精度的提高,湍流耗散率和整体气含率分布梯度增大,气泡平均直径减少,大气泡所占气相比率降低,液相速度及气含率径向分布与实验值更趋吻合.     

水力压裂管柱弯管处的固体颗粒冲蚀研究

为了研究固/液两相流体对压裂管柱弯管处的冲蚀问题,运用DPM冲蚀模型对弯管处在不同固相颗粒体积分数条件下的冲蚀进行计算与分析,追踪固体颗粒粒子路径,研究结果表明:弯管内壁管径最大区域最易产生冲蚀;在不同固相颗粒体积分数条件下,弯管最大冲蚀率随着固体颗粒含量的增加而增加,且固相颗粒体积分数与弯管的冲蚀率呈线性变化趋势。     

吸附剂孔内扩散对模拟移动床分离过程的影响

为考察孔内扩散对模拟移动床分离过程的作用,采用综合速率模型对其进行研究,其中流动相模型为轴向扩散活塞流,颗粒相为Fiek定律描述的扩散方程,液相和固相之间的吸附平衡采用改进的Langmuir吸附等温线．对流动相和颗粒相分别采用有限元Galerkin法和正交配置法,沿空间方向离散化后的常微分方程组运用MATI。AB的ODE求解器求解．在验证了模型和离散方法对模拟移动床吸附分离过程计算的可靠性的基础上,模拟了EMD53986对映体的模拟移动床分离过程,跟文献中使用忽略孔内传质过程的模型得到的计算值相比,模拟值与实验值吻合得更好,表明孔内扩散传质过程对模拟移动床模拟计算的重要性．     

液-固流化床中单个变形气泡的上升速度

以气泡在上升运动过程中的受力分析为基础,建立了描述单个变形气泡在液－固流化床中上升速度的理论模。应用该模型分别对球形和球帽形气泡在液－固流化床中的上升速度进行了计算,并将计算民在不同的床内压力,温度与颗粒相体积分数下气泡上升速度的实验测量数据进行了比较。     

Experimental and numerical research for fluidization behaviors in a gas–solid acoustic fluidized bed

The effects of sound assistance on fluidization behaviors were systematically investigated in a gas–solid acoustic fluidized bed. A model modified from Syamlal–O'Brien drag model was established. The original solid momentum equation was developed and an acoustic model was also proposed. The radial particle volume fraction, axial root‐mean‐square of bed pressure drop, granular temperature, and particle velocity in gas–solid acoustic fluidized bed were simulated using computational fluid dynamics (CFD) code Fluent 6.2. The results showed that radial particle volume fraction increased using modified drag model compared with that using the original one. Radial particle volume fraction was revealed as a parabolic concentration profile. Axial particle volume fraction decreased with the increasing bed height. The granular temperature increased with increasing sound pressure level. It showed that simulation values using CFD code Fluent 6.2 were in agreement with the experimental data. © 2009 American Institute of Chemical Engineers AIChE J, 2010     

不同气速下喷动床喷泉区颗粒特性的模拟分析

以欧拉多项流模型为基础,对底角锥度为60°、床直径为0.44 m的喷动床内气固两相流的动力学特性进行了模拟研究,并对不同气速下喷泉高度、颗粒体积分数、颗粒速率的变化进行分析,结果发现喷泉高度与进口气速在u/ums=1.2～1.8范围内具有良好的线性关系,拟合度可达到0.9997。固体颗粒体积分数在轴心区域较高,随着径向距离的增加逐渐下降,且随高度的增加呈现先减小后增大的趋势;颗粒体积分数受速率的影响较大,随着喷动速率的增大,颗粒体积分数趋于减小,但减小幅度不同。颗粒速度在喷泉核心区随床层高度增大而减小。同一床层高度上的颗粒速度随气速的增加而增大,但增大值不同。     

白云石对稻草水蒸气气化特性的影响

以稻草为生物质原料,水蒸气为介质,白云石为催化剂,在固定床气化炉中进行生物质水蒸气气化等反应,考察了白云石粒径(5~20mm)、白云石床高(550~1 000mm)和煅烧白云石等对生物质水蒸气气化特性的影响。结果表明,在气化炉中装入白云石,有助于生物质水蒸气气化、催化裂解、二氧化碳重整和水蒸气重整等反应进行。白云石粒径减小、白云石床高和煅烧白云石含量增加,有利于产气中氢体积分数的增加。当白云石粒径为5~10mm、白云石床高为1 000mm和煅烧白云石为100%时,产气中氢体积分数最大为53.18%,产氢率最大为0.92m³/kg,产气率最大为1.72m³/kg,气化效率最大为99.93%,水蒸气近似分解率最大为51.28%。     

A basic population balance model for fluid bed spray granulation

A basic population balance approach is developed for a granulation process in a fluid bed spray granulator. The particle size distribution predicted by the model is confirmed by plant data. Hence this model is considered to be useful to describe and optimize an industrial process. The model depends on a limited number of parameters (most of these factors can be measured or are known): the spray volume flux, the nucleation fraction (the fraction of the spray volume flux which leads to new particles formed), the nucleation particle diameter, the product withdrawal threshold diameter, and the product withdrawal rate. Analysis of the model reveals a steady-state constraint; a steady state does not exist if the nucleation fraction is too large. For cases where the steady state does exist, the steady-state particle size distribution is solved analytically. A numerical implementation of the model is used to illustrate the transient evolution of the process. The steady-state solution appears to be stable for a constant nucleation fraction. However, if the nucleation fraction depends on the bed height the steady state can be unstable. Such a situation may occur if the spray inlet is near the height of the bed surface. Instead of convergence towards a steady state, the transient solution displays ongoing oscillatory behavior with an oscillation period of a number of hours. A linear stability analysis is performed to confirm the findings on the stability of the steady state.     

Experimental and computational study on the bubble behavior in a 3-D fluidized bed

The results from a two-fluid Eulerian–Eulerian three-dimensional (3-D) simulation of a cylindrical bed, filled with Geldart-B particles and fluidized with air in the bubbling regime, are compared with experimental data obtained from pressure and optical probe measurements in a real bed of similar dimensions and operative conditions. The main objectives of this comparison are to test the validity of the simulation results and to characterize the bubble behavior and bed dynamics. The fluidized bed is 0.193 m internal diameter and 0.8 m height, and it is filled with silica sand particles, reaching a settle height of 0.22 m. A frequency domain analysis of absolute and differential pressure signals in both the measured and the simulated cases shows that the same principal phenomena are reproduced with similar distributions of peak frequencies in the power spectral density (PSD) and width of the spectrum. The local dynamic behavior is also studied in the present work by means of the PSD of the simulated particle fraction and the PSD of the measured optical signal, which reveals as well good agreement between both the spectra. This work also presents, for the first time, comparative results of the measured and the simulated bubble size and velocity in a fully 3-D bed configuration. The values of bubble pierced length and velocity retrieved from the experimental optical signals and from the simulated particle fraction compare fairly well in different radial and axial positions. Very similar values are obtained when these bubble parameters are deduced from either simulated pressure signals or simulated particle volume fraction. In addition, applying the maximum entropy method technique, bubble size probability density functions are also calculated. All these results indicate that the two-fluid model is able to reproduce the essential dynamics and interaction between bubbles and dense phase in the 3-D bed studied.     

混合物入选体积量对振动流化床分离特性的影响

利用计算机在线测量床层密度及分析颗粒在床层中的分布,考察入选体积量对流化床中床层密度及颗粒分离效率的影响。研究表明,当入选体积量的分选上限为２０％时,流化床才能对颗粒混合物进行有效的分选,并且在振动条件下比在非振动条件下的分选效率略高一些,这些研究结果对有振动重介质流化床分离细粒焦渣混合物具有一定的指导意义。     

Comprehensive experimental investigation on biomass-glass beads binary fluidization: A data set for CFD model validation

Fluidization behavior of biomass and glass beads binary mixtures in a bubbling fluidized bed was experimentally investigated. Mixtures containing different mass fraction of Loblolly Pine white wood and glass beads were fluidized at different fluidization velocities. The particle properties were characterized in a QICPIC that uses a dynamic image processing method to measure both particle size and sphericity. The minimum fluidization velocity was determined using the pressure drop method. An image processing method was developed to capture the dynamic expanded bed height at a very high frequency. The effect of biomass mass fraction and inlet gas velocity on mixing and segregation behavior was studied and analyzed through pressure drop measurements. Pressure drop fluctuations and expanded bed height fluctuations via fast Fourier transform were analyzed and compared. The complete and accurate experimental data reported in this study could provide a benchmark data set for various computational fluid dynamics models validation, calibration, and identification.     

提升管内气固流动行为的数值模拟

应用计算流体力学软件Fluent,对空气为连续相、固相为催化裂化反应催化剂的循环流化床提升管内的气固流动行为进行模拟。采用用户自定义函数引入颗粒与壁面的恢复系数和颗粒的镜面反射系数,对颗粒在边壁处的部分滑移运动进行描述。采用不同的计算动力学模型及参数,数值模拟了径向颗粒浓度、轴向床层压降的空间分布,以及用以描述颗粒脉动动能的颗粒温度与固含率的关系,并与文献报道的实验和数值模拟结果进行对比分析。结果表明,选取的颗粒动力学理论模型及参数、颗粒部分滑移边界条件及气固曳力模型,可计算得到合理的颗粒轴向及径向分布,验证了提升管中存在典型的径向环核流动结构和轴向压降分布。进一步分析表明固含率显著影响颗粒温度,当固含率为0.05~0.1,颗粒温度存在转折区。     

复合移动床电石反应器中颗粒运动的离散单元法模拟

针对复合移动床反应器内固体颗粒运动,采用离散单元法模型（DEM）考察布料器分别为扇形开口和矩形开口时,布料器转速和开口对颗粒运动的影响,并基于文献结果论证了本文模型的准确性。模拟结果表明：①对于不同布料器,颗粒在移动床中呈现平推流和汇聚流两种流动形态。②随布料器转速及开口的增加,颗粒质量通量非线性增加。③随布料器转速的增加,下落床径向上颗粒分布更均匀;随布料器开口的增大,下落床径向上颗粒分布范围变大,颗粒分布更均匀;对下落床径向上颗粒分布,布料器扇形开口时分布呈U形、矩形开口时分布呈M形。④沿反应器轴向向下,颗粒分布有均匀化趋势;扇形开口布料器对颗粒分布的离散系数大于1,矩形开口布料器对颗粒分布的离散系数约为0.5。