纯氧曝气活性无烟煤过滤去除微污染水高浓度氨氮研究

通过小试对比研究了活性无烟煤和石英砂两种滤料对水中高浓度氨氮的去除效果。试验结果表明,活性无烟煤对浊度的去除效果与石英砂相当,滤后水浊度能达标;滤柱进水氨氮为4.00~7.35mg/L,采用纯氧曝气时,活性无烟煤过滤对氨氮的去除率可达95%,明显强于石英砂过滤,且无亚硝酸盐氮的积累。中试研究结果表明活性无烟煤能在传统的处理工艺中代替石英砂滤料,在纯氧曝气的条件下,活性无烟煤滤料能使传统的过滤工艺具备深度处理功能,适合处理受高浓度氨氮污染的原水。这对于水厂的传统工艺改造具有重要的现实意义。     

纯氧预曝气-生物过滤组合工艺处理微污染水中试研究

采用中试规模设备研究纯氧预曝气和生物过滤组合工艺对微污染水源水中多种污染物的处理效果。在沉淀池末端进行纯氧预曝气,能够提高溶解氧浓度至9.43~13.05mg/L,比较了活性无烟煤和活性炭两种滤料生物过滤工艺。原水氨氮为3mg/L时,出水氨氮平均值为0.07mg/L,且无亚硝态氮积累,CODMn平均去除率为71.72%,出水CODMn浓度均值为0.94mg/L,铁离子平均去除率为98.29%,出水铁离子浓度均值为0.011 mg/L,对典型臭味物质二甲硫醚的去除率为95.24%。结果表明活性无烟煤和活性炭两种滤料的性能类似。纯氧预曝气-生物过滤组合工艺适用于水厂常规处理工艺改造,对传统水厂技术升级具有重要的价值。     

改性锰砂滤料处理含氨氮的高铁锰水最佳运行参数研究

针对辽河铁岭新区段地下水中铁锰氨氮同时偏高的现象,由于传统的锰砂滤料并未起到较好的去除效果,故对其过滤工艺进行整改,使用了一种改性锰砂滤料。比较了2种传统滤料与改性锰砂滤料的处理效果,并且确定了改性滤料运行的最佳参数。结果表明:该滤料具有稳定的处理效果,在除铁除锰等方面性能优于普通的锰砂滤料以及石英砂等等。KMnO_4最优的浸渍浓度为5%,5%KMnO_4改性锰砂滤料过滤处理含氨氮的高铁锰井水的最佳工艺参数为:流量为35 ml/min,pH值为7.2,反冲洗周期与时长分别为18 h与5 min。在熟料运行条件下最佳DO值为10 mg/L。研究了此改性滤料不同滤层深度中溶解氧与铁锰氨氮去除效果的关系:发现铁最先在滤层上部最先去除,锰较氨氮优先使用溶解氧。     

活性无烟煤表面结构与过滤性能研究

针对常规饮用水过滤工艺中,石英砂滤料吸附水体中有机物质能力较弱、反冲洗周期较短的弊端,研究了利用新型滤料———活性无烟煤,原位替代石英砂过滤的整改措施。并以深圳市大冲水厂、东湖水厂沉淀池后出水为研究对象,开展小试、中试过滤试验,对比分析活性无烟煤过滤性能。实验室小试对活性无烟煤的表面物理孔隙与化学物性做了检测分析,利用扫描电镜对其表面结构物性做了观测。结果表明,活性无烟煤对亚甲基蓝的吸附能力为112mg/g,高于试验所用的活性炭,说明其比表面积大于活性炭。表面有约为1·1mmol/g的含氧官能团,其表面等电点为10mV左右…     

曝气炭砂滤池去除氨氮的生产性示范工程研究

通过运行炭层空气曝气活性炭-石英砂双层滤池(简称曝气炭砂滤池)生产性示范工程,并与无曝气炭砂滤池及砂滤池进行对比,研究了曝气炭砂滤池作为快滤池时对水中氨氮及亚硝酸盐氮的去除性能。结果表明,曝气炭砂滤池可将氨氮浓度低于2.5mg/L的进水处理至0.5mg/L以下,且进水氨氮低于1.5mg/L时不需曝气,其去除效果显著优于普通炭砂滤池和石英砂滤池;曝气炭砂滤池亦可有效去除亚硝酸盐氮。用曝气炭砂滤池替代石英砂滤池是水厂提升氨氮去除能力的一种可行的滤池改造方式。     

金属氧化物改性滤料过滤去除水中残余铝的效能与机理研究

采用连续流等速过滤试验方法研究了金属氧化物改性滤料对水中残余铝的去除效能,并探讨其过滤机理.研究结果表明,金属氧化物改性滤料较石英砂能够更有效地过滤去除沉后水中的残余铝,对颗粒铝和溶解铝都有很好的去除效果.石英砂对颗粒铝具有较好地去除效果,而对溶解性铝的去除能力较差.改性滤料的表面性质更有利于水中残余铝的去除.     

涂铁砂过滤去除水中磷的研究

试验制备一种涂铁砂(IOCS)滤料用于对水中磷的去除,与石英砂相比IOCS表面粗糙,空隙多,比表面积大,且附有α-Fe_2O_3晶体,吸附能力增强。通过过滤试验研究了IOCS滤料在不同的试验条件下(pH、空床接触时间、进水磷浓度、滤床深度等)对水中磷的去除效果。结果表明:中性条件下磷的去除效果最佳,pH太高和太低都不利于磷的去除;中性条件下,当空床接触时间为13min,进水磷浓度为1.0 mg/L,滤床深度为50 cm时,去除效果较好,平均去除率可达82%;空床接触时间、进水磷浓度、滤床深度等是影响过滤运行周期的主要因素。     

接触过滤-活性炭吸附-超滤一体化净水装置处理长江原水的研究

试验采用接触过滤-活性炭吸附-超滤工艺处理长江原水.结果表明,接触过滤能有效地去除较大悬浮物,活性炭能吸附水中大量有机物,有效防止膜污染.并且用0.4%的HCl和0.4%的NaOH对膜进行化学清洗,能使膜的过滤性能得到很好的恢复.当原水平均浊度为114.8 NTU、氨氮为0.35 mg/L、TOC为2.47 mg/L、CODMn为2.7 mg/L、细菌数为700 CFU/mL时,工艺出水浊度为0.07 NTU、氨氮为0.09 mg/L、TOC为0.3 mg/L、CODMn为0.88 mg/L、细菌总数为0.     

沸石去除地下水源水中氨氮的试验研究

地下水源水中氨氮的去除有其特殊性,研究利用沸石直接过滤氨氮超标地下水,并对沸石去除氨氮的机理进行了探讨。试验结果表明,滤速和进水氨氮浓度对沸石柱运行效果有很大影响,沸石对低浓度氨氮具有良好的去除作用。在滤速为6m/h,进水氨氮浓度分别为0.8mg/L和1.42mg/L时,以《城市供水水质标准》(CJ/T 206—2005)规定的0.5mg/L为出水水质标准,沸石柱可以分别运行65h和18h。沸石柱对氨氮的去除是吸附和离子交换共同作用的结果。     

季节性污染原水预处理和常规处理工艺强化技术集成与示范

针对珠江下游普遍存在的水源季节性氨氮和有机物污染问题,采用原水生物预处理和强化常规处理工艺技术路线,开发了三种主要的集成工艺技术,包括高速生物过滤强化常规工艺、高锰酸钾与粉末活性炭、纯氧曝气及活性无烟煤联合强化常规工艺、以平板陶瓷膜为主的集成工艺等,建立了中试基地和示范工程,有效处理氨氮浓度为3～5 mg/L的原水,出水水质达到GB 5749-2006标准,经济有效,稳定可靠,为常规工艺升级改造提供了多样化技术选择.     

曝气生物滤池去除有机物及氨氮的影响因素分析

采用以陶粒为填料的曝气生物滤池(BAF)处理生活污水,研究气水比、水力负荷、进水COD和NH3-N负荷对BAF去除COD及NH3-N的影响,分析COD及NH3-N沿滤柱的变化规律。结果表明:当试验进水COD及NH3-N质量浓度分别为300~370mg/L和20~40mg/L时,最佳气水比为4∶1~5∶1,最佳水力负荷为1.0~2.0 m3/(m2.h)。当进水COD负荷为1.69~6.47 kg/(m3.d)时,COD去除率与进水COD负荷成正相关。BAF的硝化性能与进水NH3-N和COD负荷成负相关。     

不同条件对高效菌去除污水中氨氮效果影响研究

本文研究了pH值、温度、曝气时间、茵投入量（体积比）、溶解氧、水力停留时间、进水碳氮比、冲击负荷等影响因素对氨氮去除率的影响,对项目参数进行了优化。研究结果如下：在高效菌处理氨氮废水时,为了得到较好的去除效果,pH值应控制在7．0到8．O之间;温度应控制在25℃到35℃之间;曝气时间应保持在5h到6h之间;茵投入量（体积比）应保持在0．004到0．006之间;溶解氧浓度应保持在2mg／L到3mg／L之间：水力停留时间为16h．高效茵对污水中氨氮的去除效果最佳。     

Nitrification and denitrification in partially aerated biological aerated filter (BAF) with dual size sand media.

A 104-mm (4-inch) diameter pilot-scale biological aerated filter (BAF) with a media depth of 2.5 m (8.3 feet) was operated with an anaerobic, anoxic and oxic zone at a temperature of 23 degrees C. The medium for the anaerobic and anoxic zones was 10 mm diameter sand while the medium for the oxic zone was 5 mm diameter sand. The influent sCOD and total nitrogen concentrations in the feedwater were approximately 250 mg/L and 35 mg N/L, respectively. sCOD removal at optimum hydraulic retention time (HRT) of 3 h with recirculation rates of 100, 200 and 300% in the column was above 96%. Nitrification was found to be more than 96% for 3 h HRT at 200 and 300% recirculation. Total nitrogen removal was consistent at more than 80% for 4 and 6 h HRT at 300% recirculation. For 3 h HRT and 300% recirculation, total nitrogen removal was approximately 79%. The ammonia loading rates for maximum ammonia removed were 0.15 and 0.19 kg NH3-N/m3-day for 100 and 200% recirculation, respectively. The experimental results demonstrated that the BAF can be operated at an HRT of 3h with 200-300% recirculation rates with more than 96% removal of sCOD and ammonia and at least 75% removal of total nitrogen.     

Biofiltration as pre-treatment to water harvesting and recycling

This paper presents the results of the long term biofilter experiments conducted with raw stormwater collected from a canal at Carlton, in Sydney. Anthracite and granular activated carbon (GAC) were used as a single filter media in biofilter columns. Media heights of 75 and 40 cm were used. The filter columns were operated at filtration velocities of 0.12 and 0.25 m/h. The removal efficiency for turbidity and DOC for the GAC filter media were found to be 75% and almost 100% respectively. The removal efficiency for the anthracite filter was much lower. Molecular weight distribution analysis showed an almost similar trend to the DOC removal. Compared with anthracite filter media, the GAC biofilter removed a much larger range of organic compounds present in the stormwater. The GAC biofilter removes organic matter earlier as compared to anthracite. Based on a limited sample of stormwater, the removal efficiency for phosphorus was upto 74% and that of nitrogen was up to 30%. In general GAC filter shows higher heavy metal removal efficiency than anthracite. The removal of zinc, iron, lead and nickel were good. However the concentration of heavy metal in the raw surface water sample was low.     

Pre-ozonation in the activated sludge process: fate of nitrogen species

The objective of this research was to include ozonation prior to an activated sludge treatment and investigate the effect on the nitrogen species, their fate and the consequences of this oxidation upon the biomass. Three parallel treatment systems were used: the base system, where feed went directly to the activated sludge reactor, and two others, where the influent was ozonated at two different dosages, 15 and 25 mg/L of influent, prior to the biological reactors. The results from the ozonation chamber show a high oxidation capacity of the entering ammonia and organic nitrogen, proportional to the ozone dose. The oxidation product was nitrate. No de-nitrification was expected because a high oxygen concentration (4 mg/L) was maintained in the reactors. The reactors receiving ozonated influent showed a lower assimilation of nitrogen by the biomass. The sludge nitrogen content resulted in 11, 9.3 and 7.4% dry-weight corresponding to no-ozone, low ozone and high ozone dosages, respectively. In spite of the lower ammonia available in the ozonated flows, the corresponding reactors showed a higher specific nitrification rate. The ozonated system also performed better in terms of chemical oxygen demand (COD) and biochemical oxygen demand (BOD5) removals, besides showing a higher true biomass yield coefficient.     

臭氧-非均相Fenton工艺在焦化废水处理中的应用研究

通过对江苏沙钢集团厂区现有的焦化废水处理工艺进行深入的调研后,合理优化现有处理单元,采用增加前处理以及末端深度处理环节的方式,达到提高污染去除效率的目的。通过现场中试实验,获取改良工艺对焦化废水去除效果的最优工况参数。中试实验的工艺路线为“破乳→隔油→臭氧催化Fenton→气浮→EGSB→BACT→臭氧催化Fenton→气浮”,在前处理段臭氧浓度设置为100mg/L、深度处理单元臭氧浓度设置为50mg/L、BACT段分流比为1∶1、污泥回流比为1∶1时,工艺运行稳定后,在COD进水浓度为4100~5600mg/L时,系统对COD去除率可稳定达到95%以上,在氨氮进水浓度为250~310mg/L时,系统对氨氮去除率可稳定达到91%以上。     

Nitrogen removal in an upflow sludge blanket (USB) reactor combined by aerobic biofiltration systems.

A new nitrogen removal process (up-flow sludge blanket and aerobic filter, USB-AF) was proposed and tested with real sewage. In the USB reactor, the larger part of influent organic and nitrogen matters were removed, and ammonia was effectively oxidized in the subsequent aerobic filter. The role of the aerobic filter was to convert ammonia into nitrate, an electron acceptor that could convert soluble organic matters into volatile suspended solid (VSS) in the USB. The accumulated as well as influent VSS in the USB was finally degraded to fermented products that were another good carbon source for denitrification. Total COD, settleable COD and soluble COD in the raw sewage were 325, 80 and 140 mg/l, respectively. Most unsettleable COD as well as some SCOD in the influent was successfully removed in the USB. TCOD removal in the anoxic filter was by denitrification with the recycled nitrate. Low COD input to the aerobic filter could increase nitrification efficiency, reduce the start-up period and save the aeration energy in the USB-AF system. About 95% of ammonia was nitrified in the aerobic filter with no relation to the influent ammonia concentration. Denitrification efficiency of the recycled nitrate in the anoxic filter was about 85, 83, and 72% at recycle ratios of 100, 200, and 300%, respectively. T-N removal efficiency was 70% at recycle ratio of 300%.     

Pilot-scale studies on biological treatment of hypersaline wastewater at low temperature.

In order to investigate the feasibility of biological treatment of hypersaline wastewater produced from toilet flushing with seawater at low temperature, pilot-scale studies were established with plug-flow activated sludge process at low temperature (5-9 degrees C) based on bench-scale experiments. The critical salinity concentration of 30 g/L, which resulted from the cooperation results of the non-halophilic bacteria and the halophilic bacteria, was drawn in bench-scale experiments. Pilot-scale studies showed that high COD removal efficiency, higher than 80%, was obtained at low temperature when 30 percent seawater was introduced. The salinity improved the settleability of activated sludge, and average sludge value dropped down from 38% to 22.5% after adding seawater. Seawater salinity had a strong negative effect on notronomonas and nitrobacter growth, but much more on the nitrobacter. The nitrification action was mainly accomplished by nitrosomonas. Bench-scale experiments using two SBRs were carried out for further investigation under different conditions of salinities, ammonia loadings and temperatures. Biological nitrogen removal via nitrite pathway from wastewater containing 30 percent seawater was achieved, but the ammonia removal efficiency was strongly related not only to the influent ammonia loading at different salinities but also to temperature. When the ratio of seawater to wastewater was 30 percent, and the ammonia loading was below the critical value of 0.15 kgNH4+-N/(kgMLSS.d), the ammonia removal efficiency via nitrite pathway was above 90%. The critical level of ammonia loading was 0.15, 0.08 and 0.03 kgNH4+-N/(kgMLSS.d) respectively at the different temperature 30 degrees C, 25 degrees C and 20 degrees C when the influent ammonia concentration was 60-80 mg/L and pH was 7.5-8.0.     

曝气生物滤地在污水回用中去除氨氮的试验研究

采用曝气生物滤地(BAF)工艺处理某污水处理厂模拟二级出水,研究了水力负荷及滤料层高度对NH_3-N去除效果的影响.试验结果表明,当进水NH_3-N≤25 mg/L时,平均NH_3-N去除率达到93.12%,出水NH_3-N可降至3 mg/L以下.当水力负荷为1.44 m~3/(m~2·h),HRT为1.8 h时,氨氮的去除效果最好,去除率达到95.32%,出水NH_3-N在1.5 mg/L以下.BAF对NH_3-N的去除作用主要发生在滤料的中上层.     

生物接触氧化流化床处理氨氮污水的实验研究

为了提高生物接触氧化流化床处理氨氮污水的脱氮效果,采用生物接触氧化流化床在自然温度下处理人工配制模拟生活污水实验的方法,研究了氨氮污水脱氮处理的可行性、方法与效果。实验结果表明:氨氮被氧化成硝酸可由两类独立的细菌分别催化完成;反应的适宜温度为20~35℃;亚硝酸菌的最适pH值为7~8.5之间,硝酸菌为6~7.5;亚硝酸菌和硝酸菌溶解氧质量浓度在0.5 mg/L以上才能取得较好的硝化效果。反应器内填料粒径在10 mm左右有利于提高氨氮的去除效率;间歇式进水方式使活性污泥具有良好的沉降性,可为氨氮的去除提供良好的环境条件。