非晶态碲镉汞薄膜的射频磁控溅射生长及其结构和光学特性

在玻璃衬底上用射频磁控溅射技术进行了非晶态碲镉汞(α-HgCdTe,α-MCT)薄膜的低温生长.采用X射线衍射(XRD)和原子力显微(AFM)技术对所生长的薄膜进行分析研究,所生长的非晶态HgCdTe薄膜表面平整,没有晶粒出现,获得了射频磁控溅射生长非晶态HgCdTe薄膜的"生长窗口".采用傅里叶红外透射光谱分析技术对非晶态HgCdTe薄膜进行了光学性能研究,在1.0～2.0μm范围内研究了薄膜的透射谱线,获得了薄膜的吸收系数(～8×104cm-1),研究了其光学带隙(约0.83eV)和吸收边附近的3个吸收区域.     

非晶态锑化铟薄膜的射频磁控溅射生长及其结构和光学特性研究

在玻璃衬底上用射频磁控溅射技术进行了非晶态锑化铟(a-InSb)薄膜的低温生长.采用X射线衍射(XRD)和原子力显微(AFM)技术对所生长的薄膜进行分析研究,所生长的非晶态锑化铟薄膜表面平整,没有晶粒出现,获得了射频磁控溅射生长非晶态锑化铟薄膜的"生长窗口".采用傅立叶红外透射光谱分析技术对非晶态锑化铟薄膜进行了光学性能研究,在0.9～2.0μm范围内研究了薄膜的透射谱线,获得了薄膜的吸收系数,研究了其光学带隙和吸收边附近的3个吸收区域.     

非晶态碲镉汞薄膜的射频磁控溅射生长及其晶化过程研究

在玻璃衬底上用射频磁控溅射技术进行了非晶态碲镉汞(a-HgCdTe或a-MCT)薄膜的低温生长,获得了射频磁控溅射生长a-HgCdTe薄膜的"生长窗口".利用X射线衍射(XRD)技术对所生长的薄膜进行分析研究,a-HgCdTe薄膜的XRD衍射为典型的非晶衍射波包.椭圆偏振光谱研究结果表明,a-HgCdTe薄膜与晶态HgCdTe薄膜的折射率和消光系数均表现出明显的差异,椭圆偏振光谱技术可以作为一种非晶态半导体的结构判定手段.在90℃-215℃范围内对非晶态碲镉汞薄膜进行了真空退火处理研究其晶化过程,其晶化温度在130℃～140℃之间.     

非晶态碲镉汞的光学性质(英文)

采用椭圆偏振光谱技术研究了射频磁控溅射生长非晶态碲镉汞(amorphous Hg1-xCdxTe,amorphous MCT,a-MCT)薄膜的光学性质,发现非晶态碲镉汞薄膜的介电函数谱特征与晶态碲镉汞材料的明显不同,表现出与其他非晶态半导体材料类似的"波包"结构特征。基于修正的FB模型在1.0～4.0eV的能量范围内对实验结果进行了拟合分析,得到了不同组分非晶态碲镉汞薄膜的光学带隙随组分关系。通过与单晶碲镉汞光学带隙随组分变化关系的对比研究,结果表明碲镉汞的结构从晶态向非晶态转变过程中,材料的光学待续发生了明显的"蓝移"。     

生长功率对HgCdTe薄膜微观结构以及表面形貌影响

实验采用射频磁控溅射生长了HgCdTe薄膜,并利用台阶仪、XRD、原子力显微镜等现代分析手段对HgCdTe薄膜的生长速率、物相、表面形貌进行了研究。实验结果表明,随着溅射功率增大,其生长速率成线性增大,当溅射功率低于30w时,薄膜XRD衍射图谱上没有出现任何特征衍射峰,只是在2θ=23°附近出现衍射波包,材料具有明显的非晶态特征,当溅射功率高于30w时,XRD表现为多晶结构;AFM和SEM分析表明生长速率对HgCdTe薄膜表面粗糙度、形貌、形成机理等有直接影响,随着生长速率提高,薄膜表面粗糙度逐渐增大,且薄膜逐渐形成“迷津”结构。     

溅射气压对氧化镓薄膜光学特性的影响

采用射频磁控溅射法在石英衬底上制备了氧化镓(Ga2O3)薄膜.利用X射线衍射仪和紫外-可见-红外分光光度计分别对Ga2O3薄膜的晶体结构和光学带隙进行了表征,并在室温下测量了 Ga2O3薄膜的光致发光(PL)谱.结果表明:制备的Ga2O3薄膜呈非晶态.吸收边随着溅射气压的增加先蓝移后红移,光学带隙值范围为5.06～5.37 eV,溅射气压为1 Pa时,制备的Ga2O3薄膜具有最大的光学带隙.在325 nm激光激发下,400 nm附近和525 nm附近处出现与缺陷能级相关的发光峰.     

退火对非晶态碲镉汞薄膜微结构和光敏性的影响

对射频磁控溅射生长的非晶态碲镉汞(a-MCT)薄膜在真空状态下进行退火,并通过X射线衍射(XRD)技术指出原生及低于125℃退火后的MCT薄膜均为非晶态.采用双体相关函数g(r)和电学测试系统研究了退火对a-MCT薄膜微结构和光敏性的影响.结果表明:经110℃,115℃和120℃退火后的a-MCT薄膜短程有序畴Rs由退火前的13.9 分别增大至17.9 、20.8 和26.2 ;光敏性则由原来的1.17,分别增加至退火后的2.01、2.67和4.25.     

纳米硅镶嵌薄膜的光学性质及对1342nm激光的被动调Q

采用射频磁控溅射技术和热退火处理制备了石英衬底的纳米Si镶嵌SiN<,x>(ne-SiN<,x>)薄膜.通过对薄膜的小角度X射线衍射和吸收光谱测试,确定了硅晶粒尺寸和光学带隙.采用Z-扫描技术研究了薄膜的三阶非线性光学特性,结果表明薄膜的非线性吸收属于双光子吸收.把ne-Si/SiN<,x>薄膜作为可饱和吸收体插入LD...     

退火对非晶态碲镉汞薄膜稳定态光电导的影响

利用射频磁控溅射方法,在宝石衬底上制备了非晶态碲镉汞(a-HgCdTe)薄膜。对原生a-HgCdTe薄膜进行了不同退火时间和不同退火温度的热退火,在80～300K温度范围内,分别测量了原生和退火处理后的a-HgCdTe薄膜样品的稳定态光电导,研究了退火时间和退火温度对非晶态HgCdTe薄膜的稳定态光电导和激活能的影响。结果表明,原生和退火a-HgCdTe薄膜的稳定态光电导具有热激活特性;随着退火时间增加或退火温度升高,a-HgCdTe薄膜的晶化程度提高,导致光电导增大,光电导激活能降低。利用非晶-多晶转变机制讨论了实验结果。     

非晶态硅的TED和TEM的研究

一、引言近年来,非晶态物质的制备和物性研究已受到广泛的重视,大量的研究结果表明,非晶态物质具有许多优异的特性。已经在非晶态半导体、非晶态磁性材料、非晶态超导体、非晶态金属合金等材料中取得了令人注目的进展。在前一工作的基础上,我们利用高分辨率透射电子显微镜(TEM)对非晶态硅(a—Si:H,a—Si:Cl)薄膜样品进行研究,观测到薄膜样品中的原子团(atom cluster)和微结构,并探讨了其生长机理。二、实验我们采用射频辉光放电(RFGD)方法,使SiH_4(或SiCl_4)气体在射频场作用下离解,产生等离子体,通过     

溶胶—凝胶法制备的PbTiO3薄膜的光学性质研究

采用溶胶－凝胶法在石英玻璃衬底上制备出均匀透明的无定形PbTiO3薄膜，并对其 光学性质进行了详细的研究，发现其折射率的波形符合经典的Cauchy函数。由半导体理论计算得到无定形的PbTiO3薄膜的光学禁带宽度为3．84eV.FTIR透射光 谱研究表明无定形PbTiO3薄膜在中红外波段没有吸收峰出现，对于在550℃下 快速热退火得到的PbTiO3薄膜，通过远红外反射光谱测量，观察到了6个约外活性声子膜。     

Effect of sputtering power on optical properties of prepared TiO2 thin films by thermal oxidation of sputtered Ti layers

In this research, TiO₂ thin films prepared via thermal oxidation of Ti layers were deposited by RF-magnetron sputtering method at three different sputtering powers. The effects of sputtering power on structure, surface and optical properties of TiO₂ thin films grown on glass substrate were studied by X-ray diffraction (XRD), atomic force microscopic (AFM) and UV–visible spectrophotometer. The results reveal that, the structure of layers is changed from amorphous to crystalline at anatase phase by thermal oxidation of deposited Ti layers and rutile phase is formed when sputtering power is increased. The optical parameters: absorption coefficient, dielectric constants, extinction coefficient, refractive index, optical conductivity and dissipation factor are decreased with increase in sputtering power, but increase in optical band gap is observed. The roughness of thin films surface is affected by changes in sputtering power which is obtained by AFM images.     

a-GaP薄膜的制备及其光学性质研究(英文)

We present a new deposition method of amorphous GaP films-Plasma Enhanced Chemical Transport Deposition (PECTD) and have successfully obtained a series of a-GaP films with a mirror-like surface and a stable chemical structure. The character of structure and composition ratio of a-GaP films have been investigated by XRD-spectra, IR absorption spectra and XPS. The results indicate that the stoichiometric composition of a-GaP films can be controlled by changing the deposition conditions such as the pressure in the deposition region, the temperature in the source region and the density of r.f. power.The optical properties of a-GaP films have been also studied systematically. The value of Egopt is aboat 1.6eV -which is greater than that reported by other group. We temporarily interpret this phenomenon by means of the existence of H and Cl atoms in a-GaP structure network. A long absorption band-tail in the energy band gap of a-GaP films was discovered.     

Magnetron sputtering synthesis of silicon–carbon films: structural and optical characterization

This study deals with the growth control and characterization of wide band gap silicon–carbon films obtained by reactive hydrogen plasma sputtering. The films were grown in a pure hydrogen plasma with different values of the carbon-to-silicon sputtered area ratio, r_C. During deposition, the substrate temperature was maintained at 730°C. Infrared absorption, Raman scattering and X-ray photoelectron spectroscopy, in addition to optical absorption, were used for the investigations. For C-poor samples (r_C≤30%), Si nanocrystals were formed, together with a small fraction of amorphous SiC. Further increase of sputtered carbon (r_C≥35%) led to a drastic change, resulting in SiC crystallization at the expense of Si and a near-stoichiometric composition of the layers (C/Si atomic ratio of 1.04). Excess carbon in the layers segregates in graphitic-like configuration, being likely located in the intergrain regions. The abrupt structural change observed for 30%≤r_C≤35% is accompanied by a consistent widening of the optical band gap. This is observed by a significant blue shift of the optical absorption towards the values reported for single crystal SiC. The energy gap at which optical absorption is 5×10⁴ cm⁻¹ shifts from 2.2–2.3 eV to about 4.1 eV. This structural change also correlates with a significant decrease of the refractive index.     

Influence of oxygen flow rate on microstructural,electrical and optical properties of indium tin tantalum oxide films

Indium tin oxide (ITO) and indium tin tantalum oxide (ITTO) films were deposited on glass substrates by magnetron sputtering technology with one or two targets. Properties of ITO and ITTO films deposited at different oxygen flow rates were contrastively studied. Ta-doping strengthens along the orientation of (400) plane and leads to better crystalline structure as well as to a decrease in surface roughness. The increase in oxygen flow rate increases sheet resistance and reduces carrier concentration, and ITTO films show higher carrier concentration. Certain oxygen flow rates can improve the visible light transmittance of films, but excessive oxygen can worsen the optical properties. The carrier concentration has an important influence on near-IR reflection, near-UV absorption and optical band gap. The optical band gap decreases with the increasing of oxygen flow rate, and ITTO films show wider optical band gap than ITO films. ITTO films prepared by co-sputtering reveal better optical–electrical properties and chemical and thermal stability than ITO films.     

非晶As2S3半导体薄膜在激光作用下的性能及结构研究

在激光辐照或退火作用下 ,As2 S3非晶半导体薄膜的光学吸收边出现红移现象 ,并且随着激光功率的增大和辐照时间的延长 ,红移值增大 ,并最后达到饱和。这种红移在先经过退火处理再激光辐照的薄膜中是可逆的。从扫描电镜的形貌图中也可以看出 ,经激光辐照后 ,薄膜表面有晶相出现 ,且随着激光功率的增加 ,晶相出现增多。As2 S3非晶半导体薄膜中光致效应的产生是由于光致结构变化所致 ,对其产生原因 ,进行了机理分析     

磁控溅射法制备的PZT非晶薄膜光学性质研究

采用磁控溅射方法在石英玻璃上制备了PbZrxTi1-xO3(PZT)(x=0．52)非晶薄膜,并测量了200～1100nm的紫外．可见．近红外透射光谱．基于薄膜的结构和多层结构的透射关系,发展了仅有6个拟合参数的光学常数计算模型．利用该模型,可以同时获得薄膜在宽波段范围内的光学常数和厚度,得到折射率的最大值为2．68,消光系数的最大值为0．562,拟合薄膜厚度为318．1nm．根据Tauc′s法则,得到PZT非晶薄膜的直接禁带宽度为3．75eV．最后,利用单电子振荡模型成功地解释了薄膜的折射率色散关系．     

氮气流量对磁控溅射C掺杂TiO2薄膜光学性能的影响

采用磁控溅射法制备了C掺杂TiO₂薄膜,并研究了氮气引入溅射过程对薄膜光学性能的影响。利用X射线衍射仪、拉曼光谱仪、X射线光电子能谱仪、分光光度计和原子力显微镜分析了不同氮气流量下薄膜的微结构、元素价态、透光性能和表面形貌。结果表明,沉积的薄膜主要是非晶结构,拉曼光谱中存在少量锐钛矿相,且随着氮气流量增大,锐钛矿特征峰强度减弱,意味着晶粒出现细化。当氮气流量增大为4cm³/min时,C掺杂TiO₂薄膜内氮元素含量为3.54%,其光学带隙从3.29eV变化至3.55eV,可见光区的光学透过率明显提高。可见改变氮气流量可实现对C掺杂TiO₂薄膜光学带隙和光吸收率的有效调控。     

Comparison of ZnO thin films deposited by three different SILAR processes

ZnO thin films were deposited on amorphous glass substrates using successive ionic layer adsorption and reaction (SILAR). The employed baths were ammonium zincate, with NH₃ and NH₄OH as complex agents and ZnSO₄ and Zn(NO₃)₂ as precursor sources. The comparison between films deposited by three processes was studied by means of X-ray diffraction (XRD), optical absorption, and micro Raman. The band gap is between 3.14 and 3.30 eV. By μ-Raman spectroscopy, the principal vibration modes around 435 and were determined in all the films.