截齿镍基钴包碳化钨激光熔覆涂层磨损性能研究

为解决掘进机截齿的磨损失效问题, 在截齿表面激光熔覆高耐磨的镍基(Ni)钴包碳化钨(WC-Co)涂层。以42CrMo钢为基体, Ni60B商用粉末为粘结相, 纳米WC-Co为增强相, 激光熔覆获得WC-Co陶瓷颗粒增强Ni基复合涂层。利用MM200环块磨损试验机, 测试熔覆涂层在干摩擦和水摩擦环境下的耐磨性能。采用显微硬度计测量涂层磨损前后的表面硬度, 电子扫描显微镜(SEM)、能谱仪(EDS)等观察熔覆涂层磨损前后的显微组织结构和成分变化。结果表明, 激光熔覆涂层可以提高截齿的耐磨性能, 磨损后熔覆层中的细小析出相起到了弥散强化作用, 熔覆层的表面显微硬度提高了10%。相同磨损条件下, 干磨损涂层硬度高于水磨损涂层硬度。     

Mo对铁基合金激光熔覆层组织与性能的影响

采用半导体激光器激光熔覆含有10%Mo的铁基合金熔覆层,借助Leica DM2700M金相显微镜、HVS-5Z数显显微硬度计、WTM-2E可控气氛微型摩擦磨损试验仪、FA2004B高精度电子天平对熔覆层的组织、硬度、摩擦因数及失重量进行了分析。实验结果表明:Mo单质的添加明显增加熔覆层组织的结核率,细化熔覆层组织;Mo单质的添加增强了熔覆层变形的位错阻力,提高了熔覆层的硬度,最高硬度达到HV774;添加Mo单质能够提高熔覆层的变形能力,降低熔覆层的摩擦因数,并且熔覆层组织细化和均匀性提高了摩擦因数的稳定性。熔覆层的失重量远小于基体的失重量。     

激光熔覆镍基纳米Al_2O_3复合涂层的组织和摩擦性能

采用激光熔覆技术在45钢基体上制备了镍基纳米Al2O3复合涂层,对熔覆层进行了微观组织分析和显微硬度及摩擦性能测试.结果表明,激光熔覆层的组成相主要为γ(Fe,Ni)、Cr7(B,C)3、Al15Fe4等,熔覆层的显微硬度HV0.3最高达到830,熔覆层与纯铝试件对摩时的磨损机制为粘着,并且随pv值增大时,粘着现象加剧,摩擦因素增大.     

基于灰铸铁表面多道搭接熔覆成形质量及组织性能研究

为强化修复受损的铸铁件,提高其性能,延长服役寿命.采用高能量密度激光器在灰铸铁H T 250表面制备多道搭接铁基合金熔覆层,通过熔覆层稀释率及表面平整度两个重要质量指标对搭接率进行优化,利用体式显微镜、光学显微镜和数显维氏硬度计等对熔覆层的横截面形貌特征、金相显微组织和显微硬度进行研究.结果表明,在搭接率为35％ 时,...     

扫描速度对车用316L不锈钢熔覆层组织及力学性能的影响

采用不同激光扫描速度在304不锈钢表面制备了316L熔覆层，通过金相显微镜、X射线衍射仪、扫描电镜及显微硬度计分别对316L熔覆层宏观形貌、相组成、微观组织及显微硬度进行研究。结果表明，316L熔覆层呈单相奥氏体结构，随着扫描速度升高，激光功率密度降低，热输入减小，冷却速度加快，熔覆层晶粒尺寸减小。熔覆层显微硬度与扫描速度成正相关，其中扫描速度1 400 mm/min制备的316L熔覆层显微硬度最高，为275HV_0.3。熔覆层显微硬度的升高是晶格畸变导致的固溶强化和细晶强化的协同作用引起的。磨损试验结果表明，316L熔覆层平均摩擦系数显著低于304不锈钢基体，扫描速度1 400 mm/min制备的316L熔覆层摩擦系数为0.424,磨损率为2.29×10^-6mm³/(N·m),磨损机理为磨粒磨损。     

激光熔覆镍基纳米AI2O3复合涂层的组织和摩擦性能

采用激光熔覆技术在45钢基体上制备了镍基纳米AI2O3复合涂层,对熔覆层进行了微观组织分析和显微硬度及摩擦性能测试。结果表明,激光熔覆层的组成相主要为γ（Fe,Ni）、Cr7（B,C）3、Al15Fe4等,熔覆层的显微硬度HV0.3最高达到830,熔覆层与纯铝试件对摩时的磨损机制为粘着,并且随pv值增大时,粘着现象加剧,摩擦因素增大。     

氩弧熔覆制备WC颗粒增强涂层组织及性能研究

采用氩弧熔覆技术, 在45钢表面制备出WC颗粒增强的耐磨复合涂层。利用光学显微镜、SEM、XRD和EDS分析了氩弧熔覆层的显微组织和相组成, 并测试了熔覆层的显微硬度和耐磨性能。结果显示, 熔覆层枝晶中弥散分布WC和W₂C硬质相颗粒, 出现Fe(W)固溶体和M₆C型化合物, 显微硬度最高可达1 277.1 HV0.1, 磨损试验中其磨损量是基体磨损量的1/6, 熔覆层的良好耐磨性能主要得益于未熔的WC颗粒。     

42CrMo表面等离子熔覆层组织与性能研究

采用等离子熔覆技术在42CrMo表面制备耐磨合金层,通过金相显微镜、X射线衍射仪对熔覆层显微组织及物相进行观察分析,采用维氏硬度仪测量熔覆层金属的显微硬度,选用磨损试验机对熔覆层金属耐磨性能进行检测。结果表明:与等离子熔覆制备1Cr13合金层相比,通过等离子熔覆-注入技术制备1Cr13-B4C复合合金层,其熔覆层显微组织晶粒细化,硬度与耐磨性能显著提高。     

单体液压支柱缸体激光熔覆Ni60A+20％WC性能

结合煤矿特殊环境特点,以煤矿单体液压支柱缸体用钢27SiMn为基体,激光熔覆Ni60A+20％WC合金粉末制备熔覆层。采用扫描电镜、硬度计、磨损实验机、盐雾试验机对熔覆层性能进行分析研究。结果表明：熔覆层与基体间为冶金结合,熔覆层耐磨性比基体材料有较大提高。熔覆层有很高的显微硬度和较强的耐腐蚀性能。     

NbC添加量对风电部件用316L熔覆层组织及耐磨性的影响

采用激光熔覆技术在304不锈钢表面制备了316L+x%NbC(x=0,5,10,15)熔覆层,研究了NbC含量对熔覆层相组成、微观形貌、显微硬度及磨损行为的影响。结果表明,NbC含量为5%～15%时,熔覆层相组成为NbC、Cr₇C₃和γ-Fe;添加NbC后,316L基体组织显著细化;少量Nb元素固溶在γ-Fe相中,形成间隙固溶体。添加NbC,熔覆层显微硬度、耐磨性大幅提升,摩擦因数、磨损率显著下降,其中316L+15%NbC熔覆层显微硬度高达381HV_0.3,平均摩擦因数为0.437(比316L熔覆层降低了41%),磨损率为2.95×10⁶μm³/(N·m)(约为316L熔覆层的50%)。     

Al-RE中间合金对变形铝合金组织与性能的影响

本文以工业纯铝和混合稀土RE(Ce和La)为原料,制备出Al-8RE、Al-10RE和Al-15RE中间合金,并探讨了Al-RE中间合金对变形铝合金3102的细化机理。结果表明：Al-RE中间合金由α-Al、Al11RE3(Al11Ce3和Al11La3)、Ce和La组成,不同稀土含量Al-RE中间合金微观组织形貌不同,Al-8RE、Al-10RE和Al-15RE中间合金组织分别为亚共晶组织,伪共晶组织和过共晶组织,随稀土含量增加,Al-RE中间合金中Al11RE3相数量增多,尺寸增大;Al-RE中间合金对3102合金具有显著的细化效果,其中Al-10RE中间合金的细化效果最好;添加Al-RE中间合金可以提高产品性能,当添加10%RE时,性能提升最大。     

镁锰锶合金力学性能的研究

研究了Sr对镁锰铅合金力学性能的影响.拉伸实验结果表明,元素Sr能细化合金中晶粒,提高镁锰铅合金的抗拉强度及伸长率,但同时也会降低合金的弹性模量.     

镁锰锶合金力学性能的研究

研究了Sr对镁锰铅合金力学性能的影响. 拉伸实验结果表明,元素Sr能细化合金中晶粒,提高镁锰铅合金的抗拉强度及伸长率,但同时也会降低合金的弹性模量.     

Temperature dependence of the liquid eutectic lead-lithium alloy density

Lead-lithium alloys are of great interest for practice as the advanced materials to be used in new technique, nuclear energetics, and so forth. Terefore, study on the physico-chemical properties of the latter is of major significance. An analysis of the available literature shows that there are a few works, devoted to study of Pb-Li alloys densities. However, temperature dependence of the density ρ(T), and its temperature coefficientK=dρ/dT for eutectic alloy were obtained by either extrapolation of the density data up to the eutectic alloy''s composition, or calculation method. There is a certain discrepancy amounting to as high as 4,, while the allowable error in the density measurements is less than 0.5,. The discrepancy between the results for the temperature coefficients of density amounts to 80,.In this work we present the experimental data on the temperature dependence of Ph0.83 Li0.17 eutectic alloy''s density in the temperature range 520K to 643 K. The alloys were prepared using Pb and Li with 99. 999, and 99.8, contents of the basic elements, respectively. We use the improved device, which permits to get the results with error less than 0. 15,. The results of 115 measurements of density in 520K to 643K temperature range were processed by the least-square method. Density polytherm of Pb0.83 Li0. 17 eutectic alloy is described by linear equation ρ(T) =9507.89-0. 79813(T-508) , kg/m3 ,where T is the absolute temperature by K. Mearsurement error was 0. 12, at 95, reliability.Discrepancy in the temperature coefficient data was 1.08,.Thus, the temperature dependence of the Pb-Li eutectic alloy density was studied by the precise two-capillary method. The obtained results may be recommended as the most reliable reference data.     

Temperature dependence of the liquid eutectic lead-lithium alloy density

Lead-lithium alloys are of great interest for practice as the advanced materials to be used in new technique, nuclear energetics, and so forth. Terefore, study on the physico-chemical properties of the latter is of major significance. An analysis of the available literature shows that there are a few works, devoted to study of Pb-Li alloys densities. However, temperature dependence of the density ρ(T), and its temperature coefficientK=dρ/dT for eutectic alloy were obtained by either extrapolation of the density data up to the eutectic alloy‘s composition, or calculation method. There is a certain discrepancy amounting to as high as 4%, while the allowable error in the density measurements is less than 0.5%. The discrepancy between the results for the temperature coefficients of density amounts to 80%.In this work we present the experimental data on the temperature dependence of Ph0.83 Li0.17 eutectic alloy‘s density in the temperature range 520K to 643 K. The alloys were prepared using Pb and Li with 99. 999% and 99.8% contents of the basic elements, respectively. We use the improved device, which permits to get the results with error less than 0. 15%. The results of 115 measurements of density in 520K to 643K temperature range were processed by the least-square method. Density polytherm of Pb0.83 Li0. 17 eutectic alloy is described by linear equation ρ(T) =9507.89-0. 79813(T-508) , kg/m3 ,where T is the absolute temperature by K. Mearsurement error was 0. 12% at 95% reliability.Discrepancy in the temperature coefficient data was 1.08%.Thus, the temperature dependence of the Pb-Li eutectic alloy density was studied by the precise two-capillary method. The obtained results may be recommended as the most reliable reference data.     

纳米晶稀土贮氢合金的热处理研究

用快淬法制备的纳米晶稀土贮氢合金活化速度快,比容量高,但充放电循环稳定性差。通过TG—DSC分析,确定了合金热处理条件,经950℃退火2h,再在800℃退火1h两阶段热处理后,合金的充放电循环稳定性明显改善.用2C充放电300次循环后,其比容量由初始的305.1mA·h/g下降至269.9mA·h/g,比容量下降了11.5％。X射线衍射分析结果表明,热处理后合金晶粒尺寸由40nm增大至50nm。该技术指标已达到电池生产厂家对合金粉的技术要求。     

纳米晶稀土贮氢合金的热处理研究

用快淬法制备的纳米晶稀土贮氢合金活化速度快,比容量高,但充放电循环稳定性差.通过TG-DSC分析,确定了合金热处理条件.经950℃退火2 h,再在800℃退火1 h两阶段热处理后,合金的充放电循环稳定性明显改善.用2C充放电300次循环后,其比容量由初始的305.1 mA·h/g下降至269.9 mA·h/g,比容量下降了11.5%.X射线衍射分析结果表明,热处理后合金晶粒尺寸由40 nm增大至50 nm.该技术指标已达到电池生产厂家对合金粉的技术要求.     

复合变质剂对ZL101铝合金力学及电化学腐蚀性能的影响

采用添加Al Ti B和四元复合变质剂对ZL101合金熔体进行处理,研究浇铸产品的力学和耐腐蚀性能。结果表明,Al Ti B和四元复合变质剂不仅能够抑制ZL101合金枝晶的生成,同时也具有良好的晶粒细化作用,加入量为0.5%,保温30 min后,在720℃浇铸变速箱的晶粒由平均150μm减小至62μm,并使合金的强度和伸长率分别提高27%和42%,同时提高ZL101合金的耐蚀性。Al Ti B和四元复合变质剂并不能改变硅形貌,将硅由未变质时的针状生长为球状或块状是Na F的作用。     

ZE-1锌合金腐蚀性能的研究

对挤压态和热处理态的ZE-1锌合金进行了腐蚀性能的分析与比较.结果表明:ZE-1锌合金的腐蚀行为属于均匀腐蚀,没有出现明显的晶间腐蚀;与挤压态相比,热处理态的ZE-1锌合金的耐蚀性有所降低.