薄板坯连铸保护渣的研制及使用

通过对保护渣理化性能、熔化特性的基础研究，确定了适合高拉速薄板坯连铸用保护渣的组成及成分范围。利用数值仿真建立的传热数学模型确定的保护渣熔化温度，粘度被实践证明是合理的，这为保护渣的研究提供了理论依据。通过工业性试验的应用证明所研制的保护渣系能满足薄板坯连铸的需要，使用效果良好，为我国高速连铸用保护渣的配制提供了方向。     

薄板坯连铸用保护渣

薄板坯连铸用保护渣与厚板坯连铸用保护渣在其物理性能上有较大差异。薄板坯连铸保护渣应具有较低的粘度，较低的结晶、软化及熔融温度，合适的碱度以及较快的熔化速度。配制薄板坯连铸保护渣时应限制ＣａＦ２、Ｎａ２Ｏ的加入量，适量添加ＢａＯ、Ｂ２Ｏ３、Ｌｉ２Ｏ、Ｋ２Ｏ和ＭｇＯ等助熔剂是有益的。     

萤石含量对连铸保护渣结晶性能的影响

通过热丝法得出保护渣连续冷却转变（CCT）和时间-温度转变（TTT）曲线,并用偏光显微分析和X-射线衍射分析方法研究了萤石含量（8%~16%）对碱度1.0的薄板坯连铸结晶器保护渣结晶性能的影响。结果表明,萤石含量每增加2%,保护渣的临界冷却速度平均增加2.5℃;同一冷却速度下,随保护渣中萤石含量的增加,结晶温度升高,结晶率增大,有利于提高界面热阻,控制渣膜传热,减少铸坯表面裂纹产生;因萤石含量超过14%时,渣膜中大量生成结晶矿物枪晶石,对连铸润滑要求较高的钢种,应控制萤石含量≤14%。     

CaO-Al2O3基低反应性保护渣熔化及流动特性的成分控制区域研究

摘要：传统CaO-SiO2系保护渣在浇铸高锰高铝钢时,渣中SiO2易被钢中Al还原,造成保护渣成分改变和性能恶化,危害铸坯表面质量和连铸过程顺行。为了抑制钢 渣反应,旨在减少渣中氧化性组分的低反应性,CaO-Al2O3基渣系是重要选择方向。在评估高锰高铝钢凝固特性和传统反应性保护渣基础上,提出了低反应性保护渣基本性能要求,并采用单纯形法设计了CaO-Al2O3基保护渣系的试样组成。通过测试实验渣样的熔化特性和流动特性,获得了5组低反应性连铸保护渣熔化流动特性的成分控制区域。典型区域基本性能为：熔化温度（半球点温度）900～1100℃,1300℃的黏度0.1～0.2Pa·s,转折温度900～1150℃。     

CSP薄板坯连铸低碳钢结晶器保护渣的研究

高拉速薄板坯连铸保护渣与常规板坯连铸保护渣在物理性能上有较大差异，通过对保护渣理化性能、熔化特性的研究，确定了适合高拉速薄板坯低碳钢连铸用保护渣的理化指标。     

CaO-Al_2O_3基低反应性保护渣熔化及流动特性的成分控制区域研究

传统CaO-SiO_2系保护渣在浇铸高锰高铝钢时,渣中SiO_2易被钢中Al还原,造成保护渣成分改变和性能恶化,危害铸坯表面质量和连铸过程顺行。为了抑制钢-渣反应,旨在减少渣中氧化性组分的低反应性,CaO-Al_2O_3基渣系是重要选择方向。在评估高锰高铝钢凝固特性和传统反应性保护渣基础上,提出了低反应性保护渣基本性能要求,并采用单纯形法设计了CaO-Al_2O_3基保护渣系的试样组成。通过测试实验渣样的熔化特性和流动特性,获得了5组低反应性连铸保护渣熔化流动特性的成分控制区域。典型区域基本性能为:熔化温度(半球点温度)900～1 100℃,1 300℃的黏度0.1～0.2 Pa·s,转折温度900～1 150℃。     

高速连铸保护渣的物化性能分析

高速连铸保护渣的物化性能不同于普通连铸，应具有低粘度、低结晶温度、低软化及熔融温度、较快的熔化速度以及合适的碱度和化学成分等特性，以满足高拉速的需要，减少生产事故，提高铸坯质量。以中碳包晶钢为例，设计并试验了不同的保护渣方案，提出了改进意见。     

连铸保护渣的熔化温度、凝固温度和结晶温度研究

采用CaO-SiO2-Na2O-CaF2-Al2O3-MgO渣系,通过测定熔渣的熔化温度、凝固温度和结晶温度,研究连铸保护渣的熔化温度凝固温度和结晶温度与化学成分之间的关系。熔化温度高于凝固温度和结晶温度。凝固温度和结晶温度之间的关系与连铸保护的玻璃性能有关。     

连铸保护渣析晶温度的调查

连铸保护渣的结晶性能和结晶温度对连铸工艺顺行和铸坯质量有着重要作用.笔者采用差示扫描量热分析法测试了保护渣的析晶温度,分析了生产现场常规板坯连铸和薄板坯连铸使用的部分保护渣,将分析结果与浇铸效果进行了对比.结果表明,结晶器内的粘结是中碳钢连铸中最突出的生产事故.当保护渣的析晶温度超过1200℃时,发生粘结的几率明显增多.     

FTSC薄板坯连铸中碳钢保护渣研究及开发

针对唐钢FTSC薄板坯连铸所产生的板坯裂纹、表面夹渣、卷渣及漏钢现象进行保护渣生产试验研究与理论分析。研究结果表明,组分变化对保护渣熔化温度和粘度等指标有着重要的影响。通过实验室对保护渣组份及其变化对其性能影响的研究,结合唐钢FTSC薄板坯连铸自身特点,设计出保护渣基本配方,且在不断试验改进中,最终开发出适合唐钢薄板坯连铸用中碳钢保护渣C2.     

Chinalco Signed Framework Agreement for Strategic Cooperation with Harbin Municipal Government

正Last month,Chinalco signed framework agreement for strategic cooperation with Harbin Municipal Government in Harbin Xiong Weiping,Chairman of Chinalco,said that based on the strategic deployment to build world top-class mining company with the highest growth potential,Chinalco was now concentrating all efforts on making strategic transition and structural adjustment,strategic cooperation with the local governments where     

Jiangxi Promotes Jiangxi Copper Corporation To Become The World's Most Competitive Mining Company

<正>According to the latest info from Jiangxi Province State-owned Assets Supervision and Administration Commission,Jiangxi Copper Corporation was approved to become the first pilot enterprise for deepening reform.Contents of the pilot work is"Three Self"(self expansion,self decision-making,self     

Journal of Rare Earths Contents List of Vol.32(2014)

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Contributions to Baosteel Technical Research wanted

正Baosteel Technical Research,a quarterly journal,which is issued domestically and abroad,is run and sponsored by Baosteel Group Corporation.Baosteel Technical Research mainly reports the achievements in technological innovation,academic research,new product development and industrial equipment improvement by Baosteel.It will continue to follow up on hot topics and serve the company’s technological development and progress.Its readers include experts in     

Ministry of Industry and Information Technology: No Short Term Solution For Our Country’s Excess Nonferrous Metal Smelting Capacity

【正】According to the Ministry of Industry and Information Technology,the Ministry has released the 2013 Operation Report on China’s Industrial Communication Indu...     

Chinalco Signed Framework Agreement for Strategic Cooperation with Gansu Province

正Recently,Chinalco and Gansu Provincial People’s Government signed"Framework Agreement for Strategic Cooperation on Reform,Restructuring and Transition Development of Chinalco’s Electrolytic Aluminum Enterprises in Gansu",signifying that the strategic cooperation between Chinalco and Gansu Province had made new substantive progress.     

Unavoidable Economic Cycle:30% Of Nonferrous Metal Companies Were Involved In Restructuring

正Owing to continual downturn in real estate and bulk commodity markets,a number of traditional industries in China suffered unfavorable impact in performance.With the progressive disclosure of third quarter report,the no-pleasant-surprise performance of     

Baotou Rare Earth Became the World's Biggest High Performance Magnetic Material Base

正The High Performance Magnetic Material Phase II Project,an industry upgrading project implemented by Inner Mongolia Baotou IronSteel Rare Earth(Group)Hi-tech Co.,Ltd,recently basically finished equipment commissioning,signifying that the enterprise had developed the production capacity of15000 t/a Nd-Fe-B strip casting alloy and 5000t/a Nd-Fe-B magnet,thus becoming the world’s     

Introducing Two Central Enterprises to Integrate Rare Earth Industry,Shandong Rare Earth Group Breaks Surface

正With the signing of"Letter of intention for Propelling Integration of Shandong Rare Earth Enterprises"between Shandong Province Commission Of Economy and Informatization,China IronSteel Research Institute Group("China Steel Institute"),and China Rare MetalsRare Earth Co.,Ltd("China Rare Earth"),the"Shandong Rare Earth Group"jointly set up by the 3 units thus broke surface.On August 9,reporters of the China Economic Herald learned from Shandong Province     

Aluminium Production by Province or City in 2014

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